scholarly journals Hydrogeochemical Investigation of Elevated Arsenic Based on Entropy Modeling, in the Aquifers of District Sanghar, Sindh, Pakistan

Water ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 3477
Author(s):  
Zahid Ullah ◽  
Muhammad Afnan Talib ◽  
Abdur Rashid ◽  
Junaid Ghani ◽  
Asfandyar Shahab ◽  
...  
Keyword(s):  
Environmental Problem ◽  
Principal Component ◽  
Mean Value ◽  
Water Type ◽  
High Concentration ◽  
Reverse Ion Exchange ◽  
Rock Water Interaction ◽  
Groundwater Samples ◽  
Sindh Province ◽  
Statistical Summary

Arsenic (As) contamination in drinking groundwater is a common environmental problem in Pakistan. Therefore, sixty-one groundwater samples were collected from various groundwater sources in District Sanghar, Sindh province, Pakistan, to understand the geochemical behavior of elevated As in groundwater. Statistical summary showed the cations and anions abundance in decreasing order of Na+ > Ca2+ > Mg2+ > K+, and HCO3− > Cl− > SO42− > NO3−. Arsenic was found with low to high concentration levels ranging from 5 µg to 25 µg/L with a mean value of 12.9 µg/L. A major water type of groundwater samples was mixed with NaCl and CaHCO3 type, interpreting the hydrochemical behavior of rock–water interaction. Principal component analysis (PCA) showed the mixed anthropogenic and natural sources of contamination in the study area. Moreover, rock weathering and exchange of ions controlled the hydrochemistry. Chloro-alkaline indices revealed the dominance of the reverse ion exchange mechanism in the region. The entropy water quality index (EWQI) exposed that 17 samples represent poor water, and 11 samples are not suitable for drinking.

scholarly journals Hydrogeochemical Characterization and Vulnerability Assessment of Shallow Groundwater in Basement Complex Area, Southwest Nigeria

2018 ◽  
Vol 7 (1) ◽  
pp. 72-103 ◽  
Author(s):  
A.J. Adewumi ◽  
A.Y.B. Anifowose ◽  
F.O. Olabode ◽  
T.A. Laniyan
Keyword(s):  
Major Ions ◽  
Shallow Groundwater ◽  
Mean Value ◽  
Ionic Concentration ◽  
Water Type ◽  
High Concentration ◽  
Drastic Model ◽  
Groundwater Samples ◽  
Southwest Nigeria ◽  
Hydrogeochemical Characterization

Abstract Thirty-five (35) groundwater samples from Owo area were analyzed for physicochemical parameters. Results show that the mean value of pH is 6.32, TDS is 208.92 mg/l, temperature is 28.77°C, EC is 545.16 μs/cm; TH is 111.09 mg/l, SO4 is 71.73 mg/l, Cl is 0.07 mg/l, HCO3 is 14.09 mg/l, Na is 25.06 mg/l, Ca is 37.07 mg/l, K is 24.36 mg/l and Mg is 4.41 mg/l. The results were compared to the WHO and NDSQW standards. All parameters were within the permissible limit except EC in well OW6 and K is above the stipulated standards in 69% of the total samples. The high concentration of K is linked to the use of NPK fertilizer in the area for agricultural purposes. The groundwater belongs to Ca-Na-K-SO4 and Na-Ca-SO4 water type respectively. The ionic concentration in the groundwater is due to the dissolution of the rock that makes up the aquifer. Plagioclase and silicate-bearing rocks are the sources of major ions in the water. SAR, PI, RSBC and KR reveals that groundwater in the area is good for irrigation purpose. DRASTIC model further revealed that groundwater in the area is less vulnerable to contamination under the current environmental conditions.

scholarly journals Groundwater quality assessment of Shahdadkot, Qubo Saeed Khan and Sijawal Junejo Talukas of District Qambar Shahdadkot, Sindh

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Muhammad Farooque Lanjwani ◽  
Muhammad Yar Khuhawar ◽  
Taj Muhammad Jahangir Khuhawar
Keyword(s):  
Water Quality ◽  
Principal Component ◽  
Quality Parameters ◽  
World Health ◽  
Coefficient Of Determination ◽  
High Concentration ◽  
Permissible Limits ◽  
Groundwater Samples ◽  
Health Organization

AbstractThe study examines the water quality of Shahdadkot, Qubo Saeed Khan and Sijawal Junejo talukas of Qambar Shahdadkot District, less affected by industrial contamination. A total of 38 groundwater samples were collected and analysed for 28 parameters. The results indicated that 57.89% samples were not suitable for drinking purpose with total dissolved solids above than maximum permissible limit of World Health Organization (WHO) (1000 mg/L). The pH, total phosphate, orthophosphate and nitrite were within WHO limits. The concentration of essential metals more than half samples, fluoride in 60.52% and heavy metals 0–50% were contaminated higher than permissible limits of WHO. The statistical analysis of water quality parameters was also carried out to evaluate coefficient of determination among the parameters, cluster analysis and principal component analysis. Water quality determined for irrigation based on Kelly index (KI), sodium percentage (Na%), chloride–sulphate ratio, sodium adsorption ratio, permeability index (PI), chloroalkaline indices 1 (CAI-1), residual sodium carbonate and chloride bicarbonate ratio indicated that samples (55 to 100%) could be used for irrigation purposes. The consumption of water with high concentration of salts and fluoride above the permissible limits may be a cause of a number of diseases in the area.

scholarly journals Hydrogeochemical Assessment of Groundwater and Suitability Analysis for Domestic and Agricultural Utility in Southern Punjab, Pakistan

Water ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 3589
Author(s):  
Javed Iqbal ◽  
Chunli Su ◽  
Abdur Rashid ◽  
Nan Yang ◽  
Muhammad Yousuf Jat Baloch ◽  
...  
Keyword(s):  
Groundwater Quality ◽  
Environmental Changes ◽  
Anthropogenic Activities ◽  
Exchange Process ◽  
Management Strategies ◽  
Principal Component ◽  
Suitability Analysis ◽  
Ion Exchange Process ◽  
Reverse Ion Exchange ◽  
Groundwater Samples

Groundwater is a critical water supply for safe drinking water, agriculture, and industry worldwide. In the Khanewal district of Punjab, Pakistan, groundwater has severely deteriorated during the last few decades due to environmental changes and anthropogenic activities. Therefore, 68 groundwater samples were collected and analyzed for their main ions and trace elements to investigate the suitability of groundwater sources for drinking and agricultural purposes. Principal component analysis (PCA) and cluster analysis (CA) were employed to determine the major factors influencing groundwater quality. To assess the groundwater’s appropriateness for drinking and irrigation, drinking and agricultural indices were used. The pH of the groundwater samples ranged from 6.9 to 9.2, indicating that the aquifers were slightly acidic to alkaline. The major cations were distributed as follows: Na+ > Ca2+ > Mg2+ > K+. Meanwhile, the anions are distributed as follows: HCO3− > SO42− > Cl− > F−. The main hydrochemical facies were identified as a mixed type; however, a mixed magnesium, calcium, and chloride pattern was observed. The reverse ion exchange process helps in exchanging Na+ with Ca2+ and Mg2+ ions in the groundwater system. Rock weathering processes, such as the dissolution of calcite, dolomite, and gypsum minerals, dominated the groundwater hydrochemistry. According to the Weight Arithmetic Water Quality Index (WAWQI), 50% of the water samples were unsafe for drinking. The Wilcox diagram, USSL diagram, and some other agricultural indices resulted in around 32% of the groundwater samples being unsuitable for irrigation purposes. The Khanewal’s groundwater quality was vulnerable due to geology and the influence of anthropogenic activities. For groundwater sustainability in Khanewal, management strategies and policies are required.

scholarly journals Assessment of groundwater quality for drinking and irrigation purpose using hydrochemical studies in Dera Bassi town and its surrounding agricultural area of Dera Bassi Tehsil of Punjab, India

2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Nitish Sharma ◽  
Upma Vaid ◽  
Sanjay Kumar Sharma
Keyword(s):  
Physicochemical Analysis ◽  
Agricultural Area ◽  
Water Type ◽  
Base Exchange ◽  
Reverse Ion Exchange ◽  
Groundwater Samples ◽  
Irrigation Purpose ◽  
Hydrochemical Studies ◽  
Kelly’S Ratio ◽  
Almost All

AbstractPresent research aims to assess the suitability of groundwater of Dera Bassi town (Punjab) and its surrounding agricultural area for drinking as well as irrigation purpose. Thirty groundwater samples were collected (in February 2020) and analyzed for various physicochemical parameters. Results of physicochemical analysis were compared with Indian (IS 10500:2012) as well as WHO (2006) standards to ascertain the suitability of the groundwater samples for drinking purpose, and it has been found that results for almost all the parameters except alkalinity (at few sites) are within the permissible limit. The pattern of ionic dominance was observed in the order of Ca2+ > Mg2+ > Na+ > K+ for cations and Cl− > NO3− > SO42− > F− for anions. Further, according to the observed Kelly’s ratio, sodium adsorption ratio, sodium percentage, corrosivity ratio and permeability index, the groundwater samples were found to be fit for irrigation purpose. However, the magnesium ratio and residual sodium carbonate revealed that groundwater of the area under study is not fit for irrigation purpose at some sites. The plot of SAR values versus EC values in the US Salinity Laboratory diagram revealed that the majority of the samples fall under water type C3-S1 (high salinity—low SAR) and 36.77% samples fall under water type C2-S1 (medium salinity—low SAR). Gibb’s diagram revealed that all samples fall under rock dominance category. The values of index of base exchange (CAI 1 and CAI 2) indicate that both direct ion and reverse ion exchange processes are taking place in the region.

Assessment of Pre-and Post-Monsoon Groundwater Resource for Irrigation in Bhopalpatnam area, Bijapur District, Chhattisgarh, India

2020 ◽  
Vol 37 (2) ◽  
pp. 27-36
Author(s):  
Rajeeva Guhey ◽  
Korsa Munna
Keyword(s):  
Chemical Characterization ◽  
Water Type ◽  
High Concentration ◽  
Post Monsoon ◽  
Groundwater Irrigation ◽  
Physico Chemical ◽  
Groundwater Samples ◽  
The Us ◽  
Kelly’S Ratio

A  study  was  conducted  to  determine  the  suitability  of  groundwater  used  for  irrigation  in  and  around  the Bhopalpatnam  area  of  Bijapur District, Chhattisgarh,  during pre-and post-monsoon seasons of 2016. In this study, sixty two groundwater samples were collected different villages and analyzed for various hydrochemical parameters like pH, EC, Alkalinity, Hardness , TDS, Ca, Mg, Na, K, CO3, HCO3, Cl, SO4, NO3, PO4, Fe and F. Physico-chemical characterization of the samples revealed that groundwater from  most  of  the  sources  was  not  fit  for  drinking owing  to  a  high  concentration  of  EC, HCO3, NO3, Fe and F. Irrigation indices such as Sodium adsorption ratio (SAR), Sodium percentage (Na %), Residual sodium carbonate (RSC), Permeability Index (PI), Kelly's Ratio (KR), Magnesium Hazard (MH) and EC were also calculated. The SAR values obtained for all the samples were plotted against EC values in the US Salinity Laboratory diagram and it was revealed that the most of the samples fall under water type C3-S1 indicating high salinity and low SAR. The  analysis  of  the  various  parameters  indicated  the  moderate  suitability  of groundwater for irrigation purpose. Keywords : Groundwater, Irrigation, SAR, %Na, KR, PI and MH.

scholarly journals Analyzing the major ions and trace elements of groundwater wells in Kuala Langat, Selangor

2021 ◽  
Vol 17 (1) ◽  
pp. 56-61 ◽  
Author(s):  
Hazimah Haspi Harun ◽  
Mohamad Roslan M. K. ◽  
S. Nurhidayu ◽  
Zulfa Hanan Asha’ari ◽  
Faradiella Mohd Kusin
Keyword(s):  
Trace Elements ◽  
Major Ions ◽  
Principal Component ◽  
Water Source ◽  
High Concentration ◽  
Suitable Alternative ◽  
Groundwater Samples ◽  
Alternative Water ◽  
Iron Manganese ◽  
Groundwater Wells

The analysis of trace elements and major ions on groundwater wells in Kuala Langat become the aim of this paper for the purposes to investigate the quality of the groundwater to be considered as a suitable alternative water source for domestic purposes. The groundwater sampling was conducted in thirteen stations of groundwater wells. The groundwater samples were taken from the groundwater wells which scatter in agricultural areas in Kuala Langat, Selangor. The major ions parameters have analyzed in the groundwater samples were calcium, magnesium, potassium, bicarbonate, chloride, and sulfate (Ca2+, Mg2+, K+, Na+, HCO3 -, Cl-, SO4 2-). Meanwhile, the trace element parameters were aluminum, iron, manganese, strontium, zinc, and copper (Al, Fe, Mn, Sr, Zn, and Cu). Principal Component Analysis (PCA) was conducted to determine the influence of major ions and trace elements concentration in groundwater. Chloride, potassium, magnesium, strontium, calcium, and bicarbonate (Cl-, Na+, K+, Mg2+, Sr2+, Ca2+, and HCO3 -) were principal parameters in the first component of PCA analysis. The concentration of trace elements shows iron is the high concentration in groundwater samples. Hence, the concentration of iron in current sampling shows exceed the recommended level for raw water of the Ministry of Health. The influences from seawater intrusion and Sodium Adsorption Ratio (SAR) in groundwater also have been discussed.

scholarly journals Genetic diversity analysis of parental lines for hybrid development in rice (Oryza sativa L.)

2013 ◽  
Vol 37 (4) ◽  
pp. 617-624 ◽  
Author(s):  
MJ Hasan ◽  
Umma Kulsum ◽  
MMH Rahman ◽  
MMH Chowdhury ◽  
AZMKA Chowdhury
Keyword(s):  
Genetic Diversity ◽  
Oryza Sativa L ◽  
Principal Component ◽  
Mean Value ◽  
Cluster Distance ◽  
Parental Lines ◽  
Almost All ◽  
Yield Maximization ◽  
Hybrid Development ◽  
Panicle Weight

Genetic divergence of 40 parental lines comprising 30 restorer and 10 maintainer lines were studied through Mohalanobis's D2 and principal component analysis for eleven characters. Genotypes were grouped into five different clusters. Cluster V comprised maximum number of genotypes (thirteen) followed by cluster I and II. The inter-cluster distance was maximum between clusters I and V (13.495) indicating wide genetic diversity between these two clusters followed by the distance between cluster I and 11 (9.489), cluster IV, and cluster V (8.969) and cluster I and cluster III (8.039). The minimum inter-cluster distance was observed between cluster II and cluster III (3.034) followed by cluster 111 and cluster IV (3.834) and cluster II and cluster V (4.945) indicating that the genotypes of these clusters were genetically close. The intra cluster distance in the entire five clusters was more or less low which indicated that the genotypes within the same cluster were closely related. Among the characters panicle weight contributed most for divergence in the studied parental lines. Difference in cluster means existed for almost all the characters studied. Highest mean value for number of effective tillers (7.8), days to 50% flowering (95.5), panicles/m2 (192.6), panicle weight (2.9), spikelet fertility (84.8), number of grains/panicle (177.8), days to maturity (123.6), and grain yield/plot (1065.5) were observed in cluster I indicated the parental lines fallen in this cluster having the genetic potentiality to contribute better for yield maximization of hybrid rice. DOI: http://dx.doi.org/10.3329/bjar.v37i4.14386 Bangladesh J. Agril. Res. 37(4): 617-624, December 2012

scholarly journals An assessment of atmospheric deposition of metals and the physico -chemical parameters of a rainwater harvesting system in Rio de Janeiro Brazil, by means of statistical multivariate analysis

2020 ◽  
Vol 15 (4) ◽  
pp. 1
Author(s):  
Gabrielle Nunes da Silva ◽  
Letícia Delduque Alves ◽  
Isabella Escobar dos Santos ◽  
Daniele Maia Bila ◽  
Alfredo Akira Ohnuma Júnior ◽  
...  
Keyword(s):  
Rio De Janeiro ◽  
Fine Particles ◽  
Rainwater Harvesting ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
High Concentration ◽  
Physico Chemical ◽  
Pearson Coefficient ◽  
Coefficient Corrélation ◽  
Pre Treatment

This study evaluates the rainwater harvesting system to determine the chemical quality of the water and allocate it for use. Samples were collected in the city of Rio de Janeiro at the points of Direct Precipitation (DP), First Flush (FF) and Reservoir (RR). The methodology involved carrying out an analysis of Ca, Cd, Cu, Na, Ni, Fe, K, Mg, Pb, Zn, conductivity, turbidity, pH and chloride. The R language was used for the principal component analysis, Pearson coefficient correlation, hierarchical cluster analysis, Tukey test and boxplot. The results show that when there is no interference from the catchment surface (DP), the rainwater has a low concentration of metals, although the first millimeters of rain have a concentration above what is permissible in the guidelines issued by the Ministry of Health (Ordinance n° 05/2017). The disposal system (FF) reduced the concentration of pollutants in the RR, but not enough to comply with legislation. It was noted that Ca, K and Na are the main metals found in rainwater. During the dry period, there were significant correlations between the physico-chemical and meteorological parameters. The high concentration of metals in the wet period suggests that rain assists the cleaning of the atmosphere and that most metals are present in the form of aerosols or fine particles suspended in the air. The findings reveal significant indications of acid rain and pre-treatment is recommended to ensure rainwater can be used safely for more mundane purposes.

scholarly journals Hydrochemistry of Groundwater in Northeast Part of Anbar Governorate – West of Iraq

2019 ◽  
Vol 16 (1) ◽  
pp. 0088
Author(s):  
Hussein Ilaibi Zamil Al-Sudani
Keyword(s):  
Electrical Conductivity ◽  
Groundwater Quality ◽  
Total Dissolved Solids ◽  
Water Type ◽  
Hydrochemical Parameters ◽  
Dissolved Solids ◽  
Drinking Purposes ◽  
Groundwater Samples ◽  
Geological Formation ◽  
Continental Origin

A groundwater quality assessment has been carried out in northeast part of Anbar governorate in western Iraq. We analyzed hydrochemical parameters such as pH, electrical conductivity, total dissolved solids presence of ions to describe groundwater quality. The study area has the only confined aquifer within the geological formation extended in area. Values of groundwater hydrochemical parameters were ranged from (7) to (7.9) for ph, (1599) to (6800) µmhos/cm for electrical conductivity (EC) and (1048) to (4446) mg/l for total dissolved solids (TDS). The origins and types of groundwater in the area were of marine origin and MgCl2 water type while only (6) samples were of continental origin and Na2SO4 water type. Groundwater utilization indicated that it can't be used for drinking purposes, while few groundwater wells can be used for agricultural and (33) groundwater samples can be used for animal purposes. However, the nature of the soil in the area and the depth of the groundwater qualified water for agricultural uses in significant and wide ranges.

scholarly journals Hydrogeochemical Properties Providing Links to Methanogenesis in Deep Aquifer of Bhola Island, Bangladesh

2019 ◽  
Vol 45 (2) ◽  
pp. 217-228
Author(s):  
Masuma Chowdhury ◽  
Sarmin Sultana ◽  
Md Atikul Islam ◽  
Aziz Hasan ◽  
Kazi Matin Uddin Ahmed
Keyword(s):  
Geothermal Gradient ◽  
Water Type ◽  
Gas Generation ◽  
Deep Aquifer ◽  
Upward Migration ◽  
Methane Generation ◽  
Biogenic Methane ◽  
Low Concentrations ◽  
Groundwater Samples ◽  
Favourable Environment

This paper compares the hydrogeochemical signatures between naturally flowing wells with methane (FWs) and non-flowing wells (require pumping) without methane (NFWs) by analyzing a total of 59 groundwater samples to find possible links for methane gas generation. Relatively higher concentration of HCO3 ⁻ indicates oxidation of organic matter (OM) for both the cases which is corroborated by the dominance of Na-Mg-HCO3 and Na- Mg-HCO3-Cl water type. Low concentrations of redox sensitive parameters i.e., NO3 ⁻, SO4 2⁻, Fe2+ and Mn2+ are indicating prevalence of extremely reducing condition and relatively lower concentrations of SO₄²⁻ in FWs suggest microbial sulphate reduction reaching final stage of redox ladder i.e., methanogenesis. Comparatively higher temperature and subsequent higher electrical conductivity (EC) in FWs possibly attributed by the chemical reactions of methane generation or vice versa. Low geothermal gradient, presence of OM and distribution of the FWs over a paleo valley in the deep confined aquifer zone refer to the existence of favourable environment for biogenic methane production rather than the upward migration or leakage of thermogenic gas from the reservoir below. Asiat. Soc. Bangladesh, Sci. 45(2): 217-228, December 2019

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