Durability of Lightweight Slurries for Oilwell Cementing

2016 ◽  
Vol 711 ◽  
pp. 203-210
Author(s):  
Vivian Karla Castelo Branco Louback Machado Balthar ◽  
Romildo Dias Toledo Filho ◽  
Eduardo de Moraes Rego Fairbairn ◽  
Cristiane Richard de Miranda

In a deepwater environment, unconsolidated formations at seabed and naturally fractured carbonates at reservoir zones with high permeability are commonly found. In this context, the use of lightweight slurries is necessary to effectively cementing these formations, in order to mitigate slurry losses to the formations and to prevent their fracture. This work investigates the mechanical properties and durability of high performance lightweight slurries to be used in this environment. The mixtures were formulated within the framework of the Compressible Packing Model and were extended using hollow ceramic or glass microspheres. Tests were carried out to determine the slurries apparent density, rheology, free fluid, sedimentation, fluid loss, resistance to acid attack, sorptivity and total water absorption. A mechanical characterization was performed by uniaxial and triaxial compression and splitting tensile strength tests and were correlated with the durability tests. The reference slurry, extended with bentonite, presented a 1.46 g/cm3 density and compressive strength of 3 MPa (cure at 27oC/ 2.7 days). The slurries containing glass and ceramic microspheres were slightly lighter and presented a higher mechanical performance as compared to ordinary slurry. Besides, these mixtures presented a higher resistance to acid attacks and lower sorptivity, especially the lightweight slurry containing ceramic microspheres.

Pharmaceutics ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 1130
Author(s):  
Mariana Pires Figueiredo ◽  
Ana Borrego-Sánchez ◽  
Fátima García-Villén ◽  
Dalila Miele ◽  
Silvia Rossi ◽  
...  

This work presents the development of multifunctional therapeutic membranes based on a high-performance block copolymer scaffold formed by polyether (PE) and polyamide (PA) units (known as PEBA) and layered double hydroxide (LDH) biomaterials, with the aim to study their uses as wound dressings. Two LDH layer compositions were employed containing Mg2+ or Zn2+, Fe3+ and Al3+ cations, intercalated with chloride anions, abbreviated as Mg-Cl or Zn-Cl, or intercalated with naproxenate (NAP) anions, abbreviated as Mg-NAP or Zn-NAP. Membranes were structurally and physically characterized, and the in vitro drug release kinetics and cytotoxicity assessed. PEBA-loading NaNAP salt particles were also prepared for comparison. Intercalated NAP anions improved LDH–polymer interaction, resulting in membranes with greater mechanical performance compared to the polymer only or to the membranes containing the Cl-LDHs. Drug release (in saline solution) was sustained for at least 8 h for all samples and release kinetics could be modulated: a slower, an intermediate and a faster NAP release were observed from membranes containing Zn-NAP, NaNAP and Mg-NAP particles, respectively. In general, cell viability was higher in the presence of Mg-LDH and the membranes presented improved performance in comparison with the powdered samples. PEBA containing Mg-NAP sample stood out among all membranes in all the evaluated aspects, thus being considered a great candidate for application as multifunctional therapeutic dressings.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3781
Author(s):  
Tianyu Wang ◽  
Yahong Zhao ◽  
Baosong Ma ◽  
Cong Zeng

The acid–alkaline-inducd corrosive environments inside wastewater concrete pipelines cause concrete structural deterioration and substantial economic losses all over the world. High-performance concrete/mortar (HPC) was designed to have better resistance to corrosive environments, with enhanced service life. However, the durability of HPC in wastewater pipeline environments has rarely been studied. A high-performance mortar mixture (M) reinforced by supplemental materials (including fly ash and silica fume) and polyvinyl alcohol (PVA) fibers, together with a mortar mixture (P) consisting of cement, sand and water with similar mechanical performance, were both designed and exposed to simulated wastewater pipeline environments. The visual appearance, dimensional variation, mass loss, mechanical properties, permeable pore volume, and microstructure of the specimens were measured during the corrosion cycles. More severe deterioration was observed when the alkaline environment was introduced into the corrosion cycles. Test results showed that the M specimens had less permeable pore volume, better dimensional stability, and denser microstructure than the P specimens under acid–alkaline-induced corrosive environments. The mass-loss rates of the M specimens were 66.1–77.2% of the P specimens after 12 corrosion cycles. The compressive strength of the M specimens was 25.5–37.3% higher than the P specimens after 12 cycles under corrosive environments. Hence, the high-performance mortar examined in this study was considered superior to traditional cementitious materials for wastewater pipeline construction and rehabilitation.


2013 ◽  
Vol 368-370 ◽  
pp. 1112-1117
Author(s):  
Jin Hui Li ◽  
Liu Qing Tu ◽  
Ke Xin Liu ◽  
Yun Pang Jiao ◽  
Ming Qing Qin

In order to solve the environment pollution of limestone powder during production of limestone manufactured sand and gravel and problem of lack of high quality fly ash or slag powder in ocean engineering, ultra-fine limestone powder was selected for preparation of green high-performance marine concrete containing fly ash and limestone powder and that containing slag powder and limestone powder for tests on workability, mechanical performance, thermal performance, shrinkage, and resistance to cracking and chloride ion permeability. And comparison was made between such green high-performance concrete and conventional marine concrete containing fly ash and slag powder. Moreover, the mechanism of green high-performance marine concrete was preliminary studied. Results showed that ultra-fine limestone powder with average particle size around 10μm had significant water reducing function and could improve early strength of concrete. C50 high-performance marine concrete prepared with 30% fly ash and 20% limestone powder or with 30% slag powder and 30% limestone powder required water less than 130kg/m3, and showed excellent workability with 28d compressive strength above 60MPa, 56d dry shrinkage rate below 300με, cracking resistance of grade V, 56d chloride ion diffusion coefficient not exceeding 2.5×10-12m2/s. Mechanical performance and resistance to chloride ion permeability of limestone powder marine concrete were quite equivalent to those of conventional marine concrete. But it had better workability, volume stability and cracking resistance. Moreover, it can serve as a solution to the lack of high quality fly ash and slag powder.


2022 ◽  
pp. 136943322110651
Author(s):  
Mizan Ahmed ◽  
Qing Quan Liang ◽  
Ahmed Hamoda

Circular concrete-filled double-skin steel tubular (CFDST) columns with external stainless-steel are high-performance composite columns that have potential applications in civil construction including the construction of offshore structures, bridge piers, and transmission towers. Reflecting the limited research performed on investigating their mechanical performance, this study develops a computationally efficient fiber model to simulate the responses of short and slender beam-columns accounting for the influences of material and geometric nonlinearities. Accurate material laws of stainless steel, carbon steel, and confined concrete are implemented in the mathematical modeling scheme developed. A new solution algorithm based on the Regula-Falsi method is developed to maintain the equilibrium condition. The independent test results of short and slender CFDST beam-column are utilized to validate the accuracy of the theoretical solutions. The influences of various column parameters are studied on the load-axial strain [Formula: see text] curves, load-lateral deflection [Formula: see text] curves, column strength curves, and interaction curves of CFDST columns. Design formulas are suggested for designing short and beam-columns and validated against the numerical results. The computational model is found to be capable of simulating the responses of CFDST short and slender columns reasonably well. Parametric studies show that the consideration of the concrete confinement is important for the accuracy of the prediction of their mechanical responses. Furthermore, high-strength concrete can be utilized to enhance their load-carrying capacity particularly for short and intermediate slender beam-columns. The strengths of CFDST columns computed by the suggested design model are in good agreement with the test and numerical results.


Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1794 ◽  
Author(s):  
Lu ◽  
Yi ◽  
Ning ◽  
Ge ◽  
S.M.

Meta-aramid fibrids (MAF) have attracted much attention. However, it is difficult for this high mechanical performance fiber to form sufficient interface adhesion between the MAF and polyurethane (PU) matrix due to the chemical inertness of its surface. Thus, the surface activity of MAF should be improved to obtain a high-performance MAF/PU composite. A novel methodology to modify the surface of MAF with a sodium dichloroisocyanurate solution (DCCNa) was developed to obtain chlorinated MAF (MAFC) in this study. A series of MAFC/PU composites was prepared by in situ polymerization processes. The results of Fourier-transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) demonstrated that the chlorine-contained chemical groups were introduced onto the MAF surfaces after chlorination. Dynamic contact angle analysis (DCAA) revealed that the surface wettability and the surface free energy of the MAFC were significantly improved, which allowed for strong chemical bonding to PU. Scanning electron microscopy (SEM) showed a uniform distribution of MAFC and good interfacing bonding between the MAFC and PU. With the incorporation of 1.5 wt% MAFC into the polyurethane matrix, the tensile and tear strength values of MAFC/PU were 36.4 MPa and 80.1 kN·m−1 respectively, corresponding to improvements of approximately 43.3% and 21.1%, as compared to those of virgin PU as 25.4 MPa and 66.1 kN·m−1, respectively.


Author(s):  
Pramod Chamarthy ◽  
H. Peter J. de Bock ◽  
Boris Russ ◽  
Shakti Chauhan ◽  
Brian Rush ◽  
...  

Heat pipes have been gaining a lot of popularity in electronics cooling applications due to their ease of operation, reliability, and high effective thermal conductivity. An important component of a heat pipe is the wick structure, which transports the condensate from condenser to evaporator. The design of wick structures is complicated by competing requirements to create high capillary driving forces and maintain high permeability. While generating large pore sizes will help achieve high permeability, it will significantly reduce the wick’s capillary performance. This study presents a novel experimental method to simultaneously measure capillary and permeability characteristics of the wick structures using fluorescent visualization. This technique will be used to study the effects of pore size and gravitational force on the flow-related properties of the wick structures. Initial results are presented on wick samples visually characterized from zero to nine g acceleration on a centrifuge. These results will provide a tool to understand the physics involved in transport through porous structures and help in the design of high performance heat pipes.


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