Effect of Calcium Hydroxide Content on Pozzolanic Reaction of Calcined Clays: Their Mechanical Properties and Microstructures

2021 ◽  
Vol 1034 ◽  
pp. 161-168
Author(s):  
Supaluk Suttikul ◽  
Kanyarat Ano ◽  
Kedsarin Pimraksa
Keyword(s):  
Mechanical Properties ◽  
Calcium Hydroxide ◽  
Clay Minerals ◽  
Pozzolanic Reaction ◽  
Montmorillonite Clay ◽  
Strength Development ◽  
Calcined Clay ◽  
Pozzolanic Material ◽  
Phase Development ◽  
Calcium Aluminosilicate

The research aimed to investigate the effect of calcium hydroxide content on pozzolanic reaction of calcined clays. Pozzolanic reaction of calcined clay was determined in terms of its mechanical properties, phase development and microstructures. Three clay minerals (two kaolinitic clays and kaolinite-montmorillonite clay) were chosen to produce pozzolanic materials via calcination at temperature of 700 °C to allow dehydroxylation of clay minerals. Ratios of calcium hydroxide to calcined clays were varied from 0.1 to 0.5. Mixing water contents or liquid to solid ratios (0.62, 0.75 and 0.80) and curing times (7 and 28 days) were also studied. It was found that calcium aluminosilicate hydrate (stratlingite) could be formed after pozzolanic reactions of all clay minerals. The development of stratlingite agreed with the strength development showing the highest compressive strength at 26 MPa (28 days) when kaolinite-montmorillonite clay was used as pozzolanic material and the ratio of calcium hydroxide to calcined clay was 0.5.

scholarly journals Mechanical properties of kenaf fibrous pulverized fuel ash concrete

2018 ◽  
Vol 250 ◽  
pp. 05007
Author(s):  
Norazura Mizal Azzmi ◽  
Jamaludin Mohamad Yatim ◽  
Hazlan Abdul Hamid ◽  
Azmahani Abdul Aziz ◽  
Adole Michael Adole
Keyword(s):  
Mechanical Properties ◽  
Natural Fiber ◽  
Coal Ash ◽  
Physical And Mechanical Properties ◽  
Short Fiber ◽  
Pozzolanic Reaction ◽  
Strength Development ◽  
Kenaf Fiber ◽  
Fuel Ash ◽  
Pulverized Fuel

The main objective of the experimental work is to identify the mechanical properties of Kenaf Fiber incorporate with Ordinary Portland Cement (OPC) and Pulverised Fuel Ash (PFA) in the mix proportions of concrete. Kenaf Fibrous Concrete (KFC) and Kenaf Fibrous Pulverised Fuel Ash Concrete (KFPC) will be measured on physical and mechanical properties in order to investigate the suitability of this natural fiber as a composite material. A comparison of properties between these two composites will determine the density, workability, compressive, tensile, and flexural strength of the concrete. Eight different mixes with varying percentage of Kenaf fiber were prepared with 30N/mm2 strength at 28days ,56 days and 90 days. Short fiber with 25mm and 50mm length were randomly distribute in composite to enhance the tensile and durability. PFA was obtained by the process of burning in the Power Station Coal Ash at Tanjung Bin, Johor. The unburning powder from the process is called as a PFA generally suitable for cement replacement in the concrete mix. The pozzolanic reaction will improve the adhesion of cement gel, hence increased the properties of concrete in a long-term strength development. The result shows that the inclusion of Kenaf fiber improve tensile strength of composite, furthermore the 25% PFA mix increase the durability of concrete.

Thermal Activation on Phase Formation of Alkaline Activated Kaolin Based System

2013 ◽  
Vol 770 ◽  
pp. 262-266 ◽  
Author(s):  
Somsak Boonjaeng ◽  
Kedsarin Pimraksa ◽  
Arnon Chaipanich ◽  
Sutin Kuharuangrong ◽  
Prinya Chindaprasirt
Keyword(s):  
Calcium Silicate ◽  
Calcium Silicate Hydrate ◽  
Thermal Activation ◽  
Pozzolanic Reaction ◽  
Zeolite X ◽  
High Concentration ◽  
Phase Development ◽  
Naoh Solution ◽  
Calcium Aluminosilicate ◽  
Alkali Activated

The research aim was to investigate phase development after pozzolanic reaction between metakaolin (MK) and calcium hydroxide (CH) with alkaline and thermal activations. The CH to MK ratio (C/M) of 0.4 generating CaO/SiO2 of 1.18 was selected in this study. Various concentrations of NaOH solutions (0.01, 0.1, 1, 3, 5 and 10 M) were used. The alkali activated samples were thermally activated at 25 °C, 70 °C, 90 °C and 130 °C for 4 h. Phase development under thermal activation of alkali activated metakaolin based system were investigated. At every temperature, C/M mixtures with 0.01 and 0.1 M NaOH promoted the formations of poorly crystalline calcium silicate hydrate (C-S-H(I)) and calcium aluminosilicate hydrate (CASH) compounds. With 3 and 5 M NaOH activations, sodium aluminosilicate hydrate (NASH) and sodium calcium silicate hydrate (NCSH) was formed. 1 M NaOH was found to be a boundary of phase transformation from C-S-H(I) and CASH to NASH and NCSH. In addition, zeolite X and sodalite appeared when NaOH solution reached 10 M. Thermal activation significantly affected phase development at high concentration of alkaline activation (1-10 M). At 1 M NaOH, NASH compounds in a form of gmelinite and zeolite ZK-14 were found at 70-90 °C. At 3-5 M, katoite was found at 70-130 °C. At 10 M, zeolite X was found at 70-90 °C. Sodalite was also found at 130 °C with 10 M NaOH.

scholarly journals Hydration Model and Evaluation of the Properties of Calcined Hwangtoh Binary Blends

2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Han-Seung Lee ◽  
Xiao-Yong Wang
Keyword(s):  
Calcium Hydroxide ◽  
Reaction Model ◽  
Pozzolanic Reaction ◽  
Mineral Admixture ◽  
Binary Blends ◽  
Kinetic Reaction ◽  
Pozzolanic Material ◽  
Hydration Model ◽  
Kinetic Reaction Model ◽  
Boundary Reaction

AbstractCalcined hwangtoh is a pozzolanic material that is increasingly being used as a mineral admixture in the concrete industry. This study shows a hydration model for cement–hwangtoh blends and evaluates the various properties of hwangtoh-blended concrete using reaction degrees of binders. First, a kinetic reaction model is proposed for analyzing the pozzolanic reaction of hwangtoh. The reaction of hwangtoh includes three processes: the initial dormant period, boundary reaction process, and diffusion process. The mutual interactions between the binary reactions of cement and hwangtoh are thought to be in line with the items in capillary water and calcium hydroxide. Second, the reaction degrees of cement and hwangtoh are determined based on a blended hydration model. Furthermore, the chemical (chemically combined water and calcium hydroxide contents), mechanical (compressive strength), thermal (hydration heat), and durability aspects (carbonation depth) of hwangtoh-blended concrete are systematically predicted. The results show good agreement with experimental results.

Competition between Hydration and Carbonation in Hydraulic Lime and Lime-Pozzolana Mortars

2010 ◽  
Vol 133-134 ◽  
pp. 241-246 ◽  
Author(s):  
Özlem Cizer ◽  
Koen Van Balen ◽  
Dionys Van Gemert
Keyword(s):  
Mechanical Properties ◽  
Moisture Content ◽  
Strength Development ◽  
Strength Gain ◽  
Carbonation Reaction ◽  
Hydraulic Lime ◽  
Pozzolanic Material ◽  
Dry Conditions ◽  
Sufficient Strength

A combined reaction of hydration and carbonation takes place in hydraulic lime and lime-pozzolana mortars. Hydration reactions are the first reaction and carbonation of lime is the complementary reaction in the strength gain. Competition between these two reactions can occur in lime-pozzolana mortars if the pozzolanic material has low reactivity with lime, leading to the consumption of lime by carbonation reaction. The degree and the order of these reactions are strongly influenced by the moisture content. Hydration reactions are enhanced under moist conditions while carbonation is delayed. Curing under dry conditions does not sufficiently increase their strength because the hydration reactions are slowed down or even terminated by the full carbonation of lime in lime-pozzolana mortars. The consequence of this on the mechanical properties of the mortars is remarkable while the same impact is not observed in their porosity. Such mortars require moist conditions to ensure sufficient strength development.

scholarly journals DFT Study of Electronic Structure and Optical Properties of Kaolinite, Muscovite, and Montmorillonite

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 618
Author(s):  
Layla Shafei ◽  
Puja Adhikari ◽  
Wai-Yim Ching
Keyword(s):  
Mechanical Properties ◽  
Optical Properties ◽  
Electronic Structure ◽  
Hydrogen Bonds ◽  
Clay Minerals ◽  
Clay Mineral ◽  
Bond Order ◽  
Deep Understanding ◽  
Pharmaceutical Applications ◽  
Structure Properties

Clay mineral materials have attracted attention due to their many properties and applications. The applications of clay minerals are closely linked to their structure and composition. In this paper, we studied the electronic structure properties of kaolinite, muscovite, and montmorillonite crystals, which are classified as clay minerals, by using DFT-based ab initio packages VASP and the OLCAO. The aim of this work is to have a deep understanding of clay mineral materials, including electronic structure, bond strength, mechanical properties, and optical properties. It is worth mentioning that understanding these properties may help continually result in new and innovative clay products in several applications, such as in pharmaceutical applications using kaolinite for their potential in cancer treatment, muscovite used as insulators in electrical appliances, and engineering applications that use montmorillonite as a sealant. In addition, our results show that the role played by hydrogen bonds in O-H bonds has an impact on the hydration in these crystals. Based on calculated total bond order density, it is concluded that kaolinite is slightly more cohesive than montmorillonite, which is consistent with the calculated mechanical properties.

scholarly journals Mechanical Properties of Cement-Treated Soil Mixed with Cellulose Nanofibre

2021 ◽  
Vol 11 (14) ◽  
pp. 6425
Author(s):  
Hidenori Takahashi ◽  
Shinya Omori ◽  
Hideyuki Asada ◽  
Hirofumi Fukawa ◽  
Yusuke Gotoh ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Flexural Strength ◽  
Geotechnical Engineering ◽  
Strength Development ◽  
Soft Ground ◽  
Wood Cellulose ◽  
Treated Soil ◽  
Made In ◽  
Cement Treatment

Cellulose nanofibre (CNF), a material composed of ultrafine fibres of wood cellulose fibrillated to nano-order level, is expected to be widely used because of its excellent properties. However, in the field of geotechnical engineering, almost no progress has been made in the development of techniques for using CNFs. The authors have focused on the use of CNF as an additive in cement treatment for soft ground, where cement is added to solidify the ground, because CNF can reduce the problems associated with cement-treated soil. This paper presents the results of a study on the method of mixing CNF, the strength and its variation obtained by adding CNF, and the change in permeability. CNF had the effect of mixing the cement evenly and reducing the variation in the strength of the treated soil. The CNF mixture increased the strength at the initial age but reduced the strength development in the long term. The addition of CNF also increased the flexural strength, although it hardly changed the permeability.

scholarly journals Utilization of Solid Waste from Brick Industry and Hydrated Lime in Self-Compacting Cement Pastes

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1109
Author(s):  
Mati Ullah Shah ◽  
Muhammad Usman ◽  
Muhammad Usman Hanif ◽  
Iqra Naseem ◽  
Sara Farooq
Keyword(s):  
Mechanical Properties ◽  
Solid Waste ◽  
Manufacturing Industry ◽  
Setting Time ◽  
Hydrated Lime ◽  
Pozzolanic Reaction ◽  
Early Age ◽  
Cement Pastes ◽  
Brick Powder ◽  
High Degree

The huge amount of solid waste from the brick manufacturing industry can be used as a cement replacement. However, replacement exceeding 10% causes a reduction in strength due to the slowing of the pozzolanic reaction. Therefore, in this study, the pozzolanic potential of brick waste is enhanced using ultrafine brick powder with hydrated lime (HL). A total of six self-compacting paste mixes were studied. HL 2.5% by weight of binder was added in two formulations: 10% and 20% of waste burnt brick powder (WBBP), to activate the pozzolanic reaction. An increase in the water demand and setting time was observed by increasing the replacement percentage of WBBP. It was found that the mechanical properties of mixes containing 5% and 10% WBBP performed better than the control mix, while the mechanical properties of the mixes containing 20% WBBP were found to be almost equal to the control mix at 90 days. The addition of HL enhanced the early-age strength. Furthermore, WBBP formulations endorsed improvements in both durability and rheological properties, complemented by reduced early-age shrinkage. Overall, it was found that brick waste in ultrafine size has a very high degree of pozzolanic potential and can be effectively utilized as a supplementary cementitious material.

scholarly journals Controlling the Thermal Stability of Kyanite-Based Refractory Geopolymers

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2903
Author(s):  
Juvenal Giogetti Nemaleu Deutou ◽  
Rodrigue Cyriaque Kaze ◽  
Elie Kamseu ◽  
Vincenzo M. Sglavo
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
High Strength ◽  
Treatment Temperature ◽  
Strength Development ◽  
Particle Sizes ◽  
Cold Setting ◽  
Thermal Stability Of ◽  
Geopolymer Composites ◽  
Refractory Composites

The present project investigated the thermal stability of cold-setting refractory composites under high-temperature cycles. The proposed route dealt with the feasibility of using fillers with different particle sizes and studying their influence on the thermo-mechanical properties of refractory geopolymer composites. The volumetric shrinkage was studied with respect to particle sizes of fillers (80, 200 and 500 µm), treatment temperature (1050–1250 °C) and amount of fillers (70–85 wt.%). The results, combined with thermal analysis, indicated the efficiency of refractory-based kyanite aggregates for enhancing thermo-mechanical properties. At low temperatures, larger amounts of kyanite aggregates promoted mechanical strength development. Flexural strengths of 45, 42 and 40 MPa were obtained for geopolymer samples, respectively, at 1200 °C, made with filler particles sieved at 80, 200 and 500 µm. In addition, a sintering temperature equal to 1200 °C appeared beneficial for the promotion of densification as well as bonding between kyanite aggregates and the matrix, contributing to the reinforcement of the refractory geopolymer composites without any sign of vitrification. From the obtained properties of thermal stability, good densification and high strength, kyanite aggregates are efficient and promising candidates for the production of environmentally friendly, castable refractory composites.

scholarly journals Experimental investigation on strength development of lime stabilized loess

RSC Advances ◽  
2019 ◽  
Vol 9 (34) ◽  
pp. 19680-19689 ◽  
Author(s):  
Liang Jia ◽  
Jian Guo ◽  
Zhidong Zhou ◽  
Yong Fu ◽  
Kai Yao
Keyword(s):  
Mechanical Properties ◽  
Experimental Investigation ◽  
Ground Improvement ◽  
Strength Development ◽  
Lime Stabilization

Lime stabilization has been widely used in pavement subbases and ground improvement, but the investigation of the mechanical properties and the microstructure of lime stabilized loess is still insufficient.

Mechanical and microstructural properties of polystyrene based composites: positron lifetime spectroscopic and DSC studies

2011 ◽  
Vol 31 (2-3) ◽  
Author(s):  
Abdullah Mohammed Ali Mohammed Altaweel ◽  
Jaya Madhu Raj ◽  
Malalvalli Nagarajaiah Chandrashekara ◽  
Puttegowda Ramya ◽  
Parthasarathy Sampathkumaran ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Free Volume ◽  
Positron Lifetime ◽  
Tensile Modulus ◽  
Silica Content ◽  
Scanning Calorimetry ◽  
Dsc Studies ◽  
Microstructural Property ◽  
Calcium Aluminosilicate

Abstract Polystyrene (PS) based composites respectively with cenosphere (CS) and calcium aluminosilicate (CAS) as fillers were studied using the positron lifetime technique to reveal the correlation between free volume, a microstructural property, and mechanical properties of the composites (tensile strength and tensile modulus). The thermal stability of the composites was determined using differential scanning calorimetry. The results showed that addition of CAS filler lead to a significant improvement in the mechanical properties of the composite, whereas addition of CS resulted in improvement in tensile modulus only. Both PS/CAS and PS/CS composites showed enhancement in thermal stability compared with that of the pure PS matrix. The positron results showed that the average free volume size for the PS/CAS composite (at 40 phr CAS) was reduced significantly compared with that of the pure PS. These results are understood in terms of the influence of silica content, filler-matrix interaction, and particle size.

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