Influence of Crystallization Admixture on Mechanical Parameters and Microstructure of Polymer-Cement Mortars with Waste Limestone

2019 ◽  
Vol 296 ◽  
pp. 27-34
Author(s):  
Jakub Hodul ◽  
Nikol Žižková ◽  
Rostislav Drochytka ◽  
Ruben Paul Borg

Many years of experience in practice not only in the Czech Republic but also around the world have shown that crystallising waterproofing technology (mortars, coatings) improves the water and water-vapor impermeability of the treated structures and thus positively affects the durability of concrete. The sealing of pores, capillaries and cracks also prevents degradation due to physical and mechanical structural actions (e.g. the effects of ice and salts in pores, etc.). In the presented research, the influence of different crystallization admixture (CA) contents on the mechanical properties of polymer-cement mortar with 24% cement substitution by waste limestone was investigated. The crystallization admixture (CA) was added in different amounts at 0.8, 1.6 and 2.4% of the cement content in the mix. It was determined that the mechanical properties, namely the compressive and flexural strengths were not significantly influenced by the CA addition, with the highest difference recorded in the compressive strength (7%). The cohesion with the base concrete containing different amounts of limestone was sufficient, and the bond of the mortar to concrete was also closely examined using scanning electron microscopy (SEM). Through the SEM investigation it was determined that the presence of waste limestone of particle size below 250 μm did not affect the formation of crystals during the proper hydration process, in a climatic chamber at a high relative humidity (99%).

2019 ◽  
Vol 9 (11) ◽  
pp. 2178 ◽  
Author(s):  
Jie Fan ◽  
Gengying Li ◽  
Sijie Deng ◽  
Zhongkun Wang

The mechanical properties of cement mortars with 0~2.0% (by mass) polyvinyl alcohol (PVA) were experimentally studied, and the effects of PVA incorporation on the hydration products and microstructure of the cement mortar were determined with differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The results show that the rational content of PVA formed evenly dispersed network-like thin films within the cement matrix, and these network-like films can bridge cracks in the cement matrix and improve the mechanical properties of the cement mortar. Over- incorporation of PVA may result in the formation of large piece polymer films that coat the cement particles, delay the hydration of the cement mortar and adversely affect its performance. The mechanical properties of the cement mortar show a significant increase and then decrease with a change in the PVA incorporation. When the PVA content was 0.6% and 1.0%, the mortar had the best compressive and flexural strengths, respectively. The compressive strength of the cement mortar increased by 12.15% for a PVA content of 0.6%, and the flexural strength of the cement mortar increased by 24.83% for a PVA content of 1.0%.


2020 ◽  
Vol 70 (340) ◽  
pp. 235
Author(s):  
I. Sanrı-Karapınar ◽  
A. O. Pehlivan ◽  
S. Karakuş ◽  
A. E. Özsoy-Özbay ◽  
A. U. Yazgan ◽  
...  

This study is a preliminary attempt to present the preparation and the first time a κ-carrageenan/PVA/eggshell nanostructure is used as a novel biodegradable and homogeneous nanostructure in cement composition. In order to clearly understand the effects these additives have on the mechanical properties of cementitious composites, they were synthesized in double and triple combinations and added into mortar mixtures. Three different cement mortar specimens were prepared by integrating the additives in ratios of 0, 0.1, 0.5 and 1% by cement weight and flexural and compressive strengths of the specimens were determined at the ages of 7 and 28 days. The flowability of the presented nanostructures was also discussed. The results revealed a 10–11% increase in both compressive and flexural strengths for the specimens prepared with the triple combination of the proposed additives. Moreover, strain capacity was enhanced as a result of the efficient dispersion of additives in the cement matrix.


2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.


2018 ◽  
Vol 27 (3) ◽  
pp. 348-354 ◽  
Author(s):  
Jakub Jura ◽  
Małgorzata Ulewicz

The article presents the results of research aimed at using glass waste and ash from biomass. The tests were carried out for cement mortars samples with using glass cullet, ash from biomass and using both wastes in 50/50 proportions. The physical and mechanical properties of the standard mortar and modified mortars were tested. Standard mortar and cement mortar samples were made in which 10, 20 and 30% of the cement mass was used as part of the standard sand. The samples were made of CEM I 42.5R. Mortars containing fly ash addition had an increased compressive strength and a smaller drop in compressive strength after frost resistance tests than standard mortar. The use of glass cullet in the amount of up to 20% did not reveal any changes in the mechanical properties of mortars, but using them in a larger amount resulted in unfavorable results. The use of a mixture of these two waste materials did not improve the results. The research has shown the possibility of using this waste to modify cement mortars.


Nanomaterials ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 113 ◽  
Author(s):  
Hongfang Sun ◽  
Li Ling ◽  
Zhili Ren ◽  
Shazim Ali Memon ◽  
Feng Xing

This paper evaluated the effect of graphene oxide/graphene (GO/GR) hybrid on mechanical properties of cement mortar. The underlying mechanism was also investigated. In the GO/GR hybrid, GO was expected to act as a dispersant for GR while GR was used as reinforcement in mortar due to its excellent mechanical properties. For the mortar specimen, flexural and compressive strength were measured at varied GO to GR ratios of 1:0, 3:1, 1:1, 1:3, and 0:1 by keeping the total amount of GO and GR constant. The underlying mechanism was investigated through the dispersibility of GR, heat releasing characteristics during hydration, and porosity of mortar. The results showed that GO/GR hybrid significantly enhanced the flexural and compressive strength of cement mortars. The flexural strength reached maximum at GO:GR = 1:1, where the enhancement level was up to 23.04% (28 days) when compared to mortar prepared with only GO, and up to 15.63% (7 days) when compared to mortar prepared with only GR. In terms of compressive strength, the enhancement level for GO:GR = 3:1 was up to 21.10% (3 days) when compared with that of mortar incorporating GO only. The enhancement in compressive strength with mortar at GO:GR = 1:1 was up to 14.69% (7-day) when compared with mortar incorporating GR only. In addition to dispersibility, the compressive strength was also influenced by other factors, such as the degree of hydration, porosity, and pore size distribution of mortar, which made the mortars perform best at different ages.


2021 ◽  
Vol 325 ◽  
pp. 65-70
Author(s):  
Martin Vyšvařil ◽  
Patrik Bayer ◽  
Tomáš Žižlavský

In this study, the utilization of two types of spongilites in various addition in cement mortars has been investigated with the purpose of exploring a new application of this natural pozzolans as cement mortar additives. The influence of the addition of spongilites on the physico-mechanical properties, frost-resistance, and microstructure of cement mortars as a function of time was studied. The results revealed that the rising proportion of spongilites in cement mortars causes increase in water retention of mortars, reduction of their bulk density, increase in porosity of mortars due to the growing predominance of capillary pores maintaining sufficient mortars strengths, and slightly increase in the frost-resistance of mortars. After initial tests, partial replacement of cement in fine-grained cement mortars with hitherto unexploited spongilites seems to be very promising. Based on the achieved results, a 20% cement replacement can be recommended as optimal.


2018 ◽  
Vol 276 ◽  
pp. 254-258
Author(s):  
Karel Mikulica ◽  
Dušan Dolák

In the current construction industry, great importance is given to the usage of thermally insulating building materials. One of the many such materials can be a cement foam or foam concrete, a mixture of cement mortar and technical foam. This material can be, due to its consistency right after mixing, applied to uneven horizontal surfaces where usage of conventional thermal board insulation materials would be complicated. This paper discusses the methodology of testing of the physical and mechanical properties of foaming additives such as strength, density, foaming number and half-separability of technical foams. Then this methodology was subsequently verified on the five commonly used foaming additives in the Czech Republic.


2013 ◽  
Vol 687 ◽  
pp. 311-315 ◽  
Author(s):  
Teresa María Piqué ◽  
Luis Fernandez Luco ◽  
Analía Vázquez

The development of new materials for specific applications is an increasing field in the construction industry, so is the employment of nanotechnology for this goal. When poly(vinyl alcohol) (PVA) is added to a Portland cement mortar, a film is formed in between the hydration products. This film has low elasticity modulus and high tensile strength and it enhances the mortar’s mechanical properties in the fresh and hardened states. The addition of nano montmorillonites (MMT) gives the polymer a better compatibility with the cement matrix. In this work, the changes in the microstructure of Portland cement mortars modified with PVA and PVA with MMT are assessed by means of transport of fluids capacity as an indicator. The reference is a standard mortar according to EN 196-1. The parameters measured are: weight loss under drying and air permeability. Complementary measures, such as compressive and flexural strengths and drying shrinkage have also been performed. From the obtained results, it can be concluded that the inclusion PVA + MMT to Portland cement mortar doesn’t affect the microstructure, when compared with Portland cement mortar with PVA, and even increase its tensile strength.


Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3756 ◽  
Author(s):  
Magdalena Janus ◽  
Szymon Mądraszewski ◽  
Kamila Zając ◽  
Ewelina Kusiak-Nejman ◽  
Antoni W. Morawski ◽  
...  

In this paper, studies of the mechanical properties and photocatalytic activity of new photoactive cement mortars are presented. The new building materials were obtained by the addition of 1, 3, and 5 wt % (based on the cement content) of nitrogen-modified titanium dioxide (TiO2/N) to the cement matrix. Photocatalytic active cement mortars were characterized by measuring the flexural and the compressive strength, the hydration heat, the zeta potential of the fresh state, and the initial and final setting time. Their photocatalytic activity was tested during NOx decomposition. The studies showed that TiO2/N gives the photoactivity of cement mortars during air purification with an additional positive effect on the mechanical properties of the hardened mortars. The addition of TiO2/N into the cement shortened the initial and final setting time, which was distinctly observed using 5 wt % of the photocatalyst in the cement matrix.


2010 ◽  
Vol 8 (2) ◽  
pp. 129-134
Author(s):  
Kumar Rathish

Ferrocement works demand cement mortars of good workability and high strength. Reduction in water-cement ratio combined with a refined pore structure increases the compressive strength in addition to the enhancement of durability characteristics, but the workability decreases. Workability becomes important, as the mortar has to easily penetrate between the layers of the mesh wires. A reasonably workable high strength cement mortar can be obtained by using a high cement content coupled with the use of superplasticizers. These were also found to retain the cohesiveness and check undesirable bleeding and segregation. An experimental program was conducted to study the functional efficacy of an SNF condensate used as a water reducing superplasticizer. The compressive strength and flow characteristics of the mortars were determined to decide their suitability for ferrocement works. The parameters included the mix proportions, the grade of cement, age of curing and the dosage of superplasticizer. It was concluded from the study that the addition of an optimum dosage of superplasticizer improved the workability and strength characteristics of silica fume mortars. There was a late gain in the compressive strength of silica fume mortars.


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