scholarly journals Adsorption of metal ions in red marine algae Lithothamnium calcareum in the treatment of industrial effluents

2021 ◽  
Vol 16 (5) ◽  
pp. 1
Author(s):  
Jaíza Ribeiro Mota e Silva ◽  
Luiz Fernando Coutinho de Oliveira ◽  
Camila Silva Franco ◽  
Juliano Elvis de Oliveira ◽  
Bárbara Belchior Silvério
Keyword(s):  
Metal Ions ◽  
Adsorption Kinetics ◽  
Metal Ion ◽  
Marine Algae ◽  
Thermochemical Treatment ◽  
Industrial Effluents ◽  
Absorption Spectrometry ◽  
Batch Adsorption ◽  
High Concentration ◽  
Equilibrium Concentrations

This study investigated the adsorption capacity of the elements Chromium (Cr), Manganese (Mn) and Zinc (Zn) to marine algae Lithothamnium calcareum by means of adsorption kinetics and batch adsorption tests, with a view to the development of a simple technique for the treatment of effluents that have a high concentration of metal ions. The algae was sieved, washed and subjected to treatment. In the adsorption kinetics, 0.2 g of algae was weighed, an amount transferred to 125 mL Erlenmeyer flasks, to which was added 15 mL of solution with a concentration of 5 mg L-1 of the metal ion. The flasks were stirred at 60 rpm for 240 minutes. In batch adsorption, 0.2 g of algae was weighed, amount transferred to 125 mL Erlenmeyer flasks, to which was added 15 mL of solution with concentrations of 5, 10, 20, 50, 100, 250 e 500 mg L-1 of the metal ion. The flasks were stirred at 60 rpm for 24 hours. In the two tests, the supernatant solutions collected were centrifuged at 2000 rpm for 5 minutes and the equilibrium concentrations of metal ions were determined by atomic absorption spectrometry. It was found that, in 240 minutes of contact, the Lithothamnium calcareum removed 15.5% of Cr, 33.0% of Mn and 8.0% of Zn in solution; and that in 24 hours of contact, at a concentration of 5 mg L-1, it removed 0.4% of Cr, 52.5% of Mn and 92.6% of Zn; and, at a concentration of 500 mg L-1, it removed 20.0% of Cr, 22.6% of Mn and 40.8% of Zn.  The results showed that the Lithothamnium calcareum submitted to thermochemical treatment presented potential for use in the adsorption of Cr, Mn and Zn.

scholarly journals Batch Sorption Experiments: Langmuir and Freundlich Isotherm Studies for the Adsorption of Textile Metal Ions onto Teff Straw (Eragrostis tef) Agricultural Waste

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Mulu Berhe Desta
Keyword(s):  
Heavy Metals ◽  
Metal Ions ◽  
Contact Time ◽  
Metal Ion ◽  
Low Cost ◽  
Agricultural Waste ◽  
Equilibrium Concentration ◽  
Eragrostis Tef ◽  
Batch Adsorption ◽  
Textile Effluents

Adsorption of heavy metals (Cr, Cd, Pb, Ni, and Cu) onto Activated Teff Straw (ATS) has been studied using batch-adsorption techniques. This study was carried out to examine the adsorption capacity of the low-cost adsorbent ATS for the removal of heavy metals from textile effluents. The influence of contact time, pH, Temperature, and adsorbent dose on the adsorption process was also studied. Results revealed that adsorption rate initially increased rapidly, and the optimal removal efficiency was reached within about 1 hour. Further increase in contact time did not show significant change in equilibrium concentration; that is, the adsorption phase reached equilibrium. The adsorption isotherms could be fitted well by the Langmuir model. The value in the present investigation was less than one, indicating that the adsorption of the metal ion onto ATS is favorable. After treatment with ATS the levels of heavy metals were observed to decrease by 88% (Ni), 82.9% (Cd), 81.5% (Cu), 74.5% (Cr), and 68.9% (Pb). Results indicate that the freely abundant, locally available, low-cost adsorbent, Teff straw can be treated as economically viable for the removal of metal ions from textile effluents.

Studies on the biofilm produced by Pseudomonas aeruginosa grown in different metal fatty acid salt media and its application in biodegradation of fatty acids and bioremediation of heavy metal ions

2017 ◽  
Vol 63 (1) ◽  
pp. 61-73 ◽  
Author(s):  
P. Abinaya Sindu ◽  
Pennathur Gautam
Keyword(s):  
Pseudomonas Aeruginosa ◽  
Fatty Acid ◽  
Metal Ions ◽  
Metal Ion ◽  
High Performance ◽  
Toxic Metal ◽  
Industrial Effluents ◽  
Aquatic Organism ◽  
Fatty Acid Salt ◽  
Planktonic Form

Metal fatty acid salts (MFAS) in untreated industrial effluents cause environmental pollution. The use of biocompatible agents for remediation may help in reducing the harm caused to the ambient aquatic organism. Pseudomonas aeruginosa is a ubiquitous organism that thrives under harsh conditions and is resistant to toxic metal ions. The present study shows a proof-of-concept of using this organism in the biodegradation of MFAS. MFAS were prepared and we studied their effect on the growth of the planktonic form and the formation of biofilm by P. aeruginosa. We observed biofilm formation in the presence of all the MFAS when used as the sole carbon source, albeit the quantity of biofilm formed in the presence of cadmium and copper was less. There was no effect on the planktonic form of the organism but the formation of biofilm increased in the presence of magnesium palmitate. This study shows that metal ions play a pivotal role in the formation of biofilm. HPLC (high-performance liquid chromatography) analysis of the biofilm polysaccharide showed that hexose sugar was a major component when compared with pentose sugar. The structure of biofilm polysaccharide and the coordination of the metal ion with the biofilm polysaccharide were confirmed by FTIR (Fourier transform infrared spectroscopy) and Raman spectroscopy.

scholarly journals Adsorption and desorption studies of <i>Delonix regia</i> pods and leaves: removal and recovery of Ni(II) and Cu(II) ions from aqueous solution

2020 ◽  
Vol 13 (2) ◽  
pp. 15-27 ◽  
Author(s):  
Bolanle M. Babalola ◽  
Adegoke O. Babalola ◽  
Cecilia O. Akintayo ◽  
Olayide S. Lawal ◽  
Sunday F. Abimbade ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Ions ◽  
Metal Ion ◽  
Agricultural Waste ◽  
Waste Product ◽  
Operating Conditions ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Adsorbent Dosage ◽  
Delonix Regia

Abstract. In this study, the adsorption of Ni(II) and Cu(II) ions from aqueous solutions by powdered Delonix regia pods and leaves was investigated using batch adsorption techniques. The effects of operating conditions such as pH, contact time, adsorbent dosage, metal ion concentration and the presence of sodium ions interfering with the sorption process were investigated. The results obtained showed that equilibrium sorption was attained within 30 min of interaction, and an increase in the initial concentration of the adsorbate, pH and adsorbent dosage led to an increase in the amount of Ni(II) and Cu(II) ions adsorbed. The adsorption process followed the pseudo-second-order kinetic model for all metal ions' sorption. The equilibrium data fitted well with both the Langmuir and Freundlich isotherms; the monolayer adsorption capacity (Q0 mg g−1) of the Delonix regia pods and leaves was 5.88 and 5.77 mg g−1 for Ni(II) ions respectively and 9.12 and 9.01 mg g−1 for Cu(II) ions respectively. The efficiency of the powdered pods and leaves of Delonix regia with respect to the removal of Ni(II) and Cu(II) ions was greater than 80 %, except for the sorption of Ni(II) ions onto the leaves. The desorption study revealed that the percentage of metal ions recovered from the pods was higher than that recovered from the leaves at various nitric acid concentrations. This study proves that Delonix regia biomass, an agricultural waste product (“agro-waste”), could be used to remove Ni(II) and Cu(II) ions from aqueous solution.

Regularities and mechanism of heavy metal cations sorption and (or) proton desorption by chitosan from aqueous solutions

2019 ◽  
Vol 97 (8) ◽  
pp. 621-628 ◽  
Author(s):  
T.E. Nikiforova ◽  
V.A. Kozlov ◽  
M.K. Islyaikin
Keyword(s):  
Heavy Metal ◽  
Aqueous Solutions ◽  
Metal Ions ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
Metal Cations ◽  
Batch Adsorption ◽  
Amino Groups ◽  
Acidic Media ◽  
Chitosan Beads

The sorption process of heavy metal ions from aqueous solutions using chitosan flakes and chitosan beads was studied. Chitosan gel beads were prepared using covalent crosslinking of chitosan chains by epichlorohydrin with ionic gelation by sodium tripolyphosphate. The capability of chitosan beads to absorb the heavy metal ions from aqueous solutions was studied, and the physicochemical characteristics of the sorbent were evaluated using SEM and FTIR on the model solution treatment. It was found that competitive proton sorption takes place in acidic media, which results in a transformation of amino groups into inactive ammonium-salt form and decreases in heavy metal sorption onto chitosan from aqueous acidic media. Batch adsorption experiments were performed to examine the influence of various factors such as the initial concentration of metal salts, pH, and agitation duration on the process. It was established that metal ion sorption is pH dependent and has an optimum effect at a pH of 6.0. Following the Langmuir equation, the maximum sorption of Cu2+ions is estimated to be 1,6 mol/kg of modified chitosan. The kinetic study revealed that the adsorption kinetics are well-fitted to the kinetic equation of pseudo second order. Thus, sorption of heavy metal ions by chitosan is considered to be a competitive process that occurs on amino groups of the sorbent with equivalent coordinated participation of metal cations, protons, and anions.

scholarly journals A New Chelating Resin for Preconcentration and Determination of Mn(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(II) by Flame Atomic Absorption Spectrometry

2003 ◽  
Vol 86 (6) ◽  
pp. 1218-1224 ◽  
Author(s):  
Mohan A Maheswari ◽  
Mandakolathur S Subramanian
Keyword(s):  
Metal Ions ◽  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Flame Atomic Absorption Spectrometry ◽  
Water Samples ◽  
Metal Ion ◽  
Absorption Spectrometry ◽  
Metal Ion Extraction ◽  
Ion Extraction ◽  
Flame Atomic Absorption

Abstract A new polychelatogen, AXAD-16-1, 2-diphenylethanolamine, was developed by chemically modifying Amberlite XAD-16 with 1, 2-diphenyl-ethanolamine to produce an effective metal-chelating functionality for the preconcentration of Mn(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(II) and their determination by flame atomic absorption spectrometry. Various physiochemical parameters that influence the quantitative preconcentration and recovery of metal were optimized by both static and dynamic techniques. The resin showed superior extraction efficiency with high-metal loading capacity values of 0.73, 0.80, 0.77, 0.87, 0.74, and 0.81 mmol/g for Mn(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(II), respectively. The system also showed rapid metal-ion extraction and stripping, with complete saturation in the sorbent phase within 15 min for all the metal ions. The optimum condition for effective metal-ion extraction was found to be a neutral pH, which is a great advantage in the preconcentration of trace metal ions from natural water samples without any chemical pretreatment of the sample. The resin also demonstrated exclusive ion selectivity toward targeted metal ions by showing greater resistivity to various complexing species and more common metal ions during analyte concentration, which ultimately led to high preconcentration factors of 700 for Cu(II); 600 for Mn(II), Ni(II), and Zn(II); and 500 for Cd(II) and Pb(II), arising from a larger sample breakthrough volume. The lower limits of metal-ion detection were 7 ng/mL for Mn(II) and Ni(II); 5 ng/mL for Cu(II), Zn(II), and Cd(II), and 10 ng/mL for Pb(II). The developed resin was successful in preconcentrating metal ions from synthetic and real water samples, multivitamin-multimineral tablets, and curry leaves (Murraya koenigii) with relative standard deviations of &lt;3.0% for all analytical measurements, which demonstrated its practical utility.

scholarly journals Polyaza macroligands as potential agents for heavy metal removal from wastewater

2013 ◽  
Vol 78 (4) ◽  
pp. 591-602 ◽  
Author(s):  
Martínez Elizondo ◽  
Martínez Nájera ◽  
Rodríguez Pérez ◽  
Hinojosa Reyes ◽  
Del Río
Keyword(s):  
Heavy Metals ◽  
Metal Ion ◽  
Metal Removal ◽  
Equilibrium Constants ◽  
Heavy Metal Removal ◽  
Industrial Effluents ◽  
Absorption Spectrometry ◽  
Spectroscopic Techniques ◽  
Metal Ion Extraction ◽  
Residual Concentration

Two polyaza macroligands N,N?-bis(2-aminobenzyl)-1,2- ethanediamine (L1) and 3,6,9,12-tetraaza-4(1,2),11(1,2)-dibenzo-1(1,3)- piridinaciclotridecafano (L2) were characterized and investigated for their metal ion extraction capabilities. The nature of all complexes was established by spectroscopic techniques. The equilibrium constants were determined by spectrophotometric and potentiometric techniques and the residual concentration of metals in the solutions by Atomic Absorption Spectrometry (AAS). The capacity of the ligands to remove heavy metals such as Cu(II), Ni(II), Cd(II), Zn(II) and Pb(II) as insoluble complexes was evaluated in wastewater from industrial effluents. These agents showed high affinity for the studied metals. The values of equilibrium constants of the isolated complexes (between 1 x 104 and 2 x 107) demonstrated the feasibility of applying these chelating agents as an alternative to remove heavy metals from industrial effluents.

Development of Cotton Linter Nanocellulose for Complexation of Ca, Fe, Mg and Mn in Effluent Organic Matter

Water ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 2765
Author(s):  
Vinícius de Jesus Carvalho de Souza ◽  
José Cláudio Caraschi ◽  
Wander Gustavo Botero ◽  
Luciana Camargo de Oliveira ◽  
Danielle Goveia
Keyword(s):  
Organic Matter ◽  
Metal Ions ◽  
Industrial Effluents ◽  
Absorption Spectrometry ◽  
Physicochemical Characteristics ◽  
Metallic Ions ◽  
Cotton Linter ◽  
Effluent Organic Matter ◽  
Wastewater Treatment Process ◽  
Sustainable Technologies

Effluent organic matter (EfOM) is present in different domestic and industrial effluents, and its capacity to hold metallic ions can interfere in the wastewater treatment process. Due to the low quality of water, new sustainable technologies for this purpose have become extremely important, with the development of renewable-source nanomaterials standing out in the literature. Nanocellulose (NC) deserves to be highlighted in this context due to its physicochemical characteristics and its natural and abundant origin. In this context, the interactions between NC extracted from cotton linter, organic matter fraction (humic substances) and metal ions have been evaluated. Free metal ions (Ca, Fe, Mg and Mn) were separated by ultrafiltration and quantified by atomic absorption spectrometry. The nanomaterial obtained showed potential for the treatment of effluents containing iron even in the presence of organic matter. The probable interaction of organic matter with NC prevents the efficient removal of calcium, magnesium and manganese. For these elements, it is desirable to increase the interaction between metal and NC by modifying the surface of the nanomaterial.

scholarly journals Adsorption of Copper, Zinc and Nickel Ions from Single and Binary Metal Ion Mixtures on to Chicken Feathers

2002 ◽  
Vol 20 (9) ◽  
pp. 849-864 ◽  
Author(s):  
Sameer Al-Asheh ◽  
Fawzi Banat ◽  
Dheaya‘ Al-Rousan
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
Batch Adsorption ◽  
Nickel Ions ◽  
Chicken Feathers ◽  
Binary Metal ◽  
Adsorption Processes ◽  
Copper Zinc

Certain industries often produce mixtures of heavy metal ions in their waste products. Because of the nature of heavy metal ions and the adsorption process, such metal ions can compete with each other for the sorption sites on an adsorbent during adsorption processes. In the present work, binary systems composed of copper, zinc and nickel ions were selected as examples of heavy metal ion mixtures and tested via batch adsorption processes using chicken feathers as an adsorbent. The uptake of individual metal ions was depressed by the presence of another. Thus, the uptake of copper ions from an initial copper ion solution of 20 ppm concentration was reduced from 0.042 mmol/g to ca. 0.019 mmol/g by the presence of a similar concentration of nickel ions. The Freundlich, Langmuir and Sips multi-component adsorption models were employed to predict the uptake of metal ions from binary metal ion solutions using constants obtained from adsorption isotherm models applied to single-solute systems.

scholarly journals Cholinesterase from the Liver of Diodon hystrix for Detection of Metal Ions

2020 ◽  
Vol 28 (S2) ◽  
Author(s):  
Noreen Nordin ◽  
Ronaldo Ron Cletus ◽  
Mohd Khalizan Sabullah ◽  
Siti Aishah Muhammad Khalidi ◽  
Rahmath Abdulla ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Metal Ions ◽  
Metal Ion ◽  
Industrial Effluents ◽  
High Technology ◽  
Effective Coefficient ◽  
Preliminary Screening ◽  
Acetylthiocholine Iodide ◽  
Foreign Materials ◽  
Living Organisms

The discharge of industrial effluents into nearby water bodies affects the inhabitants including living organisms. The presence of foreign materials such as heavy metals can be a threat to the ecosystem as they are enormously carcinogenic even though in minute concentration. Hence, an economical and time-efficient preliminary screening test is crucial to be developed for the detection of heavy metals, prior to employment of high technology instruments. In this study, cholinesterase (ChE) from Sabah porcupine fish, Diodon hystrix was purified to test for its potential as an alternative biosensor in detecting metal ions. Few enzymatic parameters including specificity of substrate, temperature and pH were applied to determine its optimal enzymatic activity. ChE enzyme was found to be more sensitive towards the presence of substrate, butyrylthiocholine iodide (BTC), in contrast to acetylthiocholine iodide (ATC) and propionylthiocholine iodide (PTC) with the effective coefficient at 7193, 3680.15 and 2965.26 Vmax/Km, respectively. Moreover, the extracted ChE enzyme showed the optimum activity at pH 9 of 0.1 M Tris-HCl and at 25°C to 30°C range of temperature. When subjected to heavy metals, ChE enzyme was significantly inhibited as the enzyme activity was reduced in the sequence of Hg > Ag > Cr > Cu > Cd > Pb ≥ Zn > As. As a conclusion, the partially purified ChE enzyme proved its sensitivity towards metal ion exposure and can be used as an alternative method in screening the level of contamination in the environment.

scholarly journals Eco Friendly Sorbent for the Removal of Iron and Lead from Industrial Waste Water

2019 ◽  
pp. 125-128
Author(s):  
Renjusha S ◽  
Shyama Nair
Keyword(s):  
Waste Water ◽  
Heavy Metals ◽  
Industrial Waste ◽  
Contact Time ◽  
Metal Ion ◽  
Industrial Effluents ◽  
Batch Adsorption ◽  
Industrial Waste Water ◽  
Adsorption Studies ◽  
Removal Of Heavy Metals

Industrial effluents loaded with heavy metals are a cause of hazards to human and other forms of life. Conventional methods such as chemical precipitation, evaporation, electroplating, ion exchange, reverse osmosis etc., used for removal of heavy metals from waste water however, are often cost prohibitive having inadequate efficiencies at low metal ion concentrations. Biosorption can be considered as an alternative technology which has been proved as more efficient and economical for removal of heavy metals from the industrial waste water. In the present study, the adsorption capacity of epicarp of Atrocarpus heterophyllus for the removal of heavy metals, lead and iron were determined by batch adsorption studies. Adsorption of heavy metals were studied till equilibrium was reached. Studies were carried by using different doses of adorbent, varying the conditions of adsorption and contact time. The results obtained shows that, the adsorption of the metal ions is contact time and adsorbent dosage dependent. Adsorption studies obeys both Langmuir isotherm model and Freundlich models. The goal for this work is to develop inexpensive, highly available, effective adsorbents from epicarp of jackfruit as alternative to existing commercial adsorbents.

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