scholarly journals Micro-Fabric Transformations of Ball Clay in Alkaline Environment

Author(s):  
V. Sai Kumar ◽  
P. Hari Prasad Reddy ◽  
Ch. Rama Vara Prasad

Based on the strong evidence of case histories, this study focused on mineralogical and morphological changes of an artificial kaolinitic soil -Ball clay, when exposed to different concentrations of sodium hydroxide (0.1N, 1N, 4N, and 8N) under different curing periods (7, 28 and 100 days). Sediment volume tests are conducted on Ball clay with all combinations and results are analyzed with the help of analytical techniques. XRD and SEM studies are analyzed to understand the micro-level changes of alkali contaminated Ball clay. Mineralogical and morphological transmutations of Ball clay are investigated for 7, 28, and 100 days curing period. Results revealed new mineral formations like Sodalite under 4N and 8N concentrations of NaOH with 100 days interactions are well observed. The morphological transformation from needle shape to pellet shape is clear evidence of the rate of dissolution and precipitation of minerals under 100 days curing periods.

2011 ◽  
Vol 39 (1) ◽  
pp. 20-43 ◽  
Author(s):  
A. Ashirgade ◽  
P. B. Harakuni ◽  
W. J. Vanooij

Abstract Adhesion between rubber compound and brass-plated steel tire cord is crucial in governing the overall performance of tires. The rubber-brass interfacial adhesion is influenced by the chemical composition and thickness of the interfacial layer. It has been shown that the interfacial layer consists mainly of sulfides and oxides of copper and zinc. This paper discusses the effect of changes in the chemical composition and the structure of the interfacial layers due to addition of adhesion promoter resins. Grazing incidence x-ray diffraction (GIXRD) experiments were run on sulfidized polished brass coupons previously bonded to five experimental rubber compounds. It was confirmed that heat and humidity conditions lead to physical and chemical changes of the rubber-steel tire cord interfacial layer, closely related to the degree of rubber-brass adhesion. Morphological transformation of the interfacial layer led to loss of adhesion after aging. The adhesion promoter resins inhibit unfavorable morphological changes in the interfacial layer, thus stabilizing it during aging and prolonging failure. Tire cord adhesion tests illustrated that the one-component resins improved adhesion after aging using a rubber compound with lower cobalt loading. Based on the acquired diffraction profiles, these resins were also found to impede crystallization of the sulfide layer after aging, leading to improved adhesion. Secondary ion mass spectrometry depth profiles and scanning electron microscopy micrographs strongly corroborated the findings from GIXRD. This interfacial analysis adds valuable information to our understanding of the complex nature of the rubber-brass bonding mechanism.


Blood ◽  
2012 ◽  
Vol 120 (21) ◽  
pp. 1069-1069
Author(s):  
Lining Ju ◽  
Cheng Zhu ◽  
Miguel A. Cruz ◽  
Yunfeng Chen

Abstract Abstract 1069 Binding of GPIbα to VWF tethers platelets to disrupted vascular surface during the haemostatic process. The GPIbα –VWF interaction can also trigger outside-in signaling cascade, resulting in platelet activation, characterized by morphological transformation from discoid to a more spiky shape as well as activation of integrin α IIbβ3. Using the adhesion frequency assay with a biomembrane force probe (BFP), we studied signal initiation by repeated brief contacts of a single platelet with a glass bead coated with VWF-A1 domain and/or fibronectin III 7–10 domain (FNIII7–10) in a precisely controlled fashion (Fig. A). Contacting platelets with beads coated VWF-A1 only resulted in adhesion kinetics mediated by GPIbα –VWF interaction kinetics independent of the activation stage of the platelet. Contacting platelets with beads coated FNIII7–10 only resulted in adhesion kinetics that correlated with the activation stage of the platelet. Discoid-shaped platelets yielded low level adhesions mediated by FN interaction with inactive α IIbβ3 (Fig. B, blue). By comparison, spiky-shaped platelets produced high level adhesions mediated by FN interaction with activated α IIbβ3 (Fig. B, red)that was four times stronger than the interaction with inactive α IIbβ3. Contacting platelets with beads coated both VWF-A1 and FNIII7–10 resulted in two-stage adhesion kinetics. The first stage was mediated by GPIbα –VWF binding, which triggered a second stage consisting of an increase in adhesion after a sub-second delay. The second-stage binding coincided with morphological changes characteristic of platelet activation and matched that mediated by FN interaction with activated α IIbβ3. On the other hand, the concurrent calcium imaging showed as the platelet target was brought to the A1 bead in a repeating manner, the recorded calcium fluorescence intensity climbed up as the repeated touches continue (Fig. C). The peak temporally correlates with the morphological change. Our data indicates that binding of VWF-A1 to platelet GPIbα initiates outside-in signaling, leading to rapid irreversible platelet shape changes and calcium mobilization within a few seconds. Disclosures: No relevant conflicts of interest to declare.


Author(s):  
Tapas Kumar Mandal

Infections by Vibrio Cholerae (a gram-negative bacterial organism) in the Indian subcontinent are frequently encoutered. The polypeptide antibiotic polymyxin-B (PB) is a clinically important antibiotic which is used to treat infections caused by a number of gr am-negative bacteria. It has been observed that PB causes disruption of u U1rastructure of outer membrane (OW) , as revealed by the electron microscopic studies for a number of bacteria, through the formation of blebs and crenations (finger-like structures) on the OM . In this context, it is relevant to look specifically at the morphological changes induced by PB on Vibrio cells. PB produces dose dependent changes in the surface topography of pathogenic Vibrio cholerae cells. The susceptibilities of various vibrio strains to PB are also studied through analytical techniques.


2008 ◽  
Vol 1071 ◽  
Author(s):  
Antonio Cacciato ◽  
Laurent Breuil ◽  
Geert Van den bosch ◽  
Olivier Richard ◽  
Aude Rothschild ◽  
...  

AbstractThe nitride-based SONOS cell, for its excellent scalability and process simplicity, is the candidate to push the scaling roadmap for FLASH memories beyond the limit imposed on floating-gate memories by the electrostatic interference between adjacent cells. The traditional SONOS cell consists of a nitride layer (the storage element) encapsulated by two SiO2 layers which isolate the nitride layer from the Si substrate and the poly-Si gate (Poly-Si/SiO2/Si3N4/SiO2/c-Si). However, the thick tunnel oxide necessary to meet the retention requirements imposes a severe limit on the erase performance because of the erase saturation phenomenon. One possibility to guarantee both the erase and the retention performance is the replacement of the top SiO2 layer with materials of higher dielectric constant (high-k dielectric). The presence of a high-k dielectric reduces the electric field across the top dielectric, thus decreasing the unwanted parasitic electron injection from the gate during the erase operation. This will allow the cell to erase deep so to meet a basic requirement for Gigabit multilevel NAND memories. The introduction of high-k materials in the SONOS stack is unfortunately not straightforward. One problem is the Fermi-level pinning at the poly-Si/high-k interface. Another problem is the morphological changes the high-k material undergoes during the device fabrication thermal budget. These changes can modify the k-value and affect the band offset between gate and high-k material. The results may, in both cases, be the decrease of the barrier for electron injection from the gate and, as a consequence, the deterioration of the erase performance. In this paper we study the effect of gate material and of the morphological transformation associated with the high-k post deposition anneal on the erase and the retention behaviour of nitride-based cells. Two different high-k dielectrics are investigated: Al2O3 (which has already been found to be able to significantly improve the erase operation, guaranteeing at the same time excellent endurance and sufficient bake retention) and HfAlO. We show that both for Al2O3 and HfAlO a trade-off exists between erase and retention, higher PDA temperatures being beneficial for erase but detrimental for retention. We also discuss the effect of Fermi level pinning and poly-Si depletion on the erase behaviour and compare the erase performances of several PVD- and AVD-deposited metal gates.


2018 ◽  
Vol 3 (4) ◽  
pp. 31
Author(s):  
Mubeena Shaikh

The nanoparticle-Equilibrium polymer (or Wormlike micellar) system shows morphological changes from percolating network-like structures to non-percolating clusters with a change in the minimum approaching distance (EVP-excluded volume parameter) between nanoparticles and the matrix of equilibrium polymers. The shape anisotropy of nanoparticle clusters can be controlled by changing the polymer density. In this paper, the synergistic self-assembly of nanoparticles inside equilibrium polymeric matrix (or Wormlike micellar matrix) is investigated with respect to the change in the strength of attractive interaction between nanoparticles. A shift in the point of morphological transformation of the system to lower values of EVP as a result of a decrease in the strength of the attractive nanoparticle interaction is reported. We show that the absence of the attractive interaction between nanoparticles leads to the low packing of nanoparticle structures, but does not change the morphological behavior of the system. We also report the formation of the system spanning sheet-like arrangement of nanoparticles which are arranged in alternate layers of matrix polymers and nanoparticles.


1998 ◽  
Vol 18 (12) ◽  
pp. 7095-7105 ◽  
Author(s):  
Olga Kustikova ◽  
Dmitrii Kramerov ◽  
Mariam Grigorian ◽  
Vladimir Berezin ◽  
Elisabeth Bock ◽  
...  

ABSTRACT Two cell lines originating from a common ancestral tumor, CSML0 and CSML100, were used as a model to study AP-1 transcription factors at different steps of tumor progression. CSML0 cells have an epithelial morphology; they express epithelial but not mesenchymal markers and are invasive neither in vitro nor in vivo. CSML100 possesses all characteristics of a highly progressive carcinoma. These cells do not form tight contacts, are highly invasive in vitro, and are metastatic in vivo. AP-1 activity was considerably higher in CSML100 cells than in CSML0 cells. There was a common predominant Jun component, namely, JunD, detected in both cell lines. We found that the enhanced level of AP-1 in CSML100 cells was due to high expression of Fra-1 and Fra-2 proteins, which were undetectable in CSML0 nuclear extracts. Analysis of the transcription of different AP-1 members in various cell lines derived from tumors of epithelial origin revealed a correlation of fra-1 expression with mesenchymal characteristics of carcinoma cells. Moreover, we show here for the first time that the expression of exogenous Fra-1 in epithelioid cells results in morphological changes that resemble fibroblastoid conversion. Cells acquire an elongated shape and become more motile and invasive in vitro. Morphological alterations were accompanied by transcriptional activation of certain genes whose expression is often induced at late stages of tumor progression. These data suggest a critical role of the Fra-1 protein in the development of epithelial tumors.


2016 ◽  
Vol 96 (3) ◽  
pp. 233-259 ◽  
Author(s):  
Edwin P.L. Elias ◽  
Ad J.F. van der Spek ◽  
Marian Lazar

AbstractThe estuaries in the SW Netherlands, a series of distributaries of the rivers Rhine, Meuse and Scheldt known as the Dutch Delta, have been engineered to a large extent as part of the Delta Project. The Voordelta, a coalescing system of the ebb-tidal deltas of these estuaries, extendsc.10 km offshore and coversc.90 km of the coast. The complete or partial damming of the estuaries had an enormous impact on the ebb-tidal deltas. The strong reduction of the cross-shore directed tidal flow triggered a series of morphological changes that continue until today. This paper aims to give a concise overview of half a century of morphological changes and a sediment budget, both for the individual ebb-tidal deltas and the Voordelta as a whole, based on the analysis of a unique series of frequent bathymetric surveys. The well-monitored changes in the Voordelta, showing the differences in responses of the ebb-tidal deltas, provide clear insight into the underlying processes. Despite anthropogenic dominance, knowledge based on natural inlets can still explain the observed developments. Complete damming of the three northern estuaries Brielse Maas, Haringvliet and Grevelingen resulted in a regime shift, from mixed-energy to wave-dominated, and sediments are transported in landward and downdrift direction. This results in large morphodynamic changes – sediments are redistributed from the delta front landward – but small net volume changes – a 0.1–0.2 × 106m3a−1increase in volume over the period 1965–2010 – since the dams block sediment transport into the estuaries. Sediment volume losses of 106m3a−1are observed on the ebb-tidal delta of the partially closed Eastern Scheldt and still open Western Scheldt estuary. As a result of a reduction of the estuarine tide in the mouth of the Eastern Scheldt, the north–south-running North Sea tidal wave has gained impact on its ebb-tidal delta, which causes morphological adjustments and erosion of the Banjaard shoal area. Moreover, the Eastern Scheldt ebb-tidal delta delivers sediment to its neighbours. The stable ebb-tidal delta configuration in the Western Scheldt, despite major dredging activities, illustrates that these large inlet systems are robust and resilient to significant anthropogenic change, as long as the balance between the dominant hydrodynamic processes (tides and waves) does not alter significantly.


2016 ◽  
Vol 40 (1) ◽  
pp. 464-474 ◽  
Author(s):  
Yucun Liu ◽  
Yanfeng Dai ◽  
Bingzhu Yin

T-shaped organic π-conjugates and their F4TCNQ charge-transfer (CT) complexes are developed as LMOGs. The morphological changes of the organogels occur obviously due to the CT interaction.


Parasitology ◽  
1990 ◽  
Vol 101 (3) ◽  
pp. 337-343 ◽  
Author(s):  
C. R. Davies ◽  
A. M. Cooper ◽  
C. Peacock ◽  
R. P. Lane ◽  
J. M. Blackwell

SUMMARYDevelopment and forward migration ofLeishmaniaparasites in the sandfly gut is accompanied by morphological transformation to highly motile, non-dividing ‘metacyclic’ forms. Previous studiesin vitrohave demonstrated that this metacyclogenesis is associated with developmentally regulated changes in expression of two major surface glycoconjugates ofLeishmania, the lipophosphoglycan (LPG) and the glycoprotein protease GP63. Studies presented here are the first to examinein situthe changes in expression of these two important surface molecules which occur during amastigote-initiated development ofL. majorin its natural vectorPhlebotomus papatasi. Immunocytochemical analysis using a GP63-specific monoclonal (3.8). and others recognizing metacyclic-specific (3F12) and common (WIC79.3) epitopes of LPG on logarithmic and metacyclic promastigotes, demonstrates: (1) clear expression of LPG and GP63 from 2 and 7 days post-bloodfeeding, respectively; (2) developmental modification of the LPG molecule as parasites undergo forward migration and morphological changes associated with metacyclogenesis; and (3) striking deposition of large amounts of parasite-free excreted LPG on/in the epithelial cells of the gut wall.


2018 ◽  
Vol 24 (1) ◽  
pp. 71-79 ◽  
Author(s):  
Jitka Čejková ◽  
Martin M. Hanczyc ◽  
František Štěpánek

Protocells are objects that mimic one or several functions of biological cells and may be embodied as solid particles, lipid vesicles, or droplets. Our work is based on using decanol droplets in an aqueous solution of sodium decanoate in the presence of salt. A decanol droplet under such conditions bears many qualitative similarities with living cells, such as the ability to move chemotactically, divide and fuse, or change its shape. This article focuses on the description of a shape-changing process induced by the evaporation of water from the decanoate solution. Under these conditions, the droplets perform complex shape changes, whereby the originally round decanol droplets grow into branching patterns and mimic the growth of appendages in bacteria or axon growth of neuronal cells. We report two outcomes: (i) the morphological changes are reversible, and (ii) multiple protocells avoid contact between each other during the morphological transformation. The importance of these morphological changes in the context of artificial life are discussed.


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