scholarly journals Investigation Of Ferroelectric Properties of Rochelle Salt Type Crystals Using A Modified Model

2021 ◽  
Vol 16 (2) ◽  
Author(s):  
Balkrishna Kandpal ◽  
Mayank Joshi ◽  
Trilok Chandra Upadhyay

Rochelle salt type crystals show ferroelectricity. Previously suggested model is little modified to explain ferroelectric behaviour of three crystals. Simple Green’s function approach is used to obtain normal mode frequency formula. This frequency is calculated for different temperatures for Rochelle salt crystal. Theoretical results are compared with others experimental data formulae for dielectric constant and spontaneous polarization are obtained. Values are calculated for Rochelle salt crystal and compared with experimental data of F. Sandy and R. V. Jones (1968).

2021 ◽  
Vol 16 (2) ◽  
Author(s):  
Mayank Joshi ◽  
Balkrishna Kandpal ◽  
Trilok Chandra Upadhyay

The formulae to describe ferroelectric effect in PbHPO4 (Lead Hydrogen Phosphate) type crystal are derived. For its simple modified model is used. Simple Green Function formalism is used for derivation numerically thermal variations of normal mode frequency (which brings ferroelectric effect) is obtained anomalous dielectric constant and spontaneous polarization are numerically calculated for PbHSO4 of example for different temperatures. Experimental data are matched with our values. Agreement is found good.


2021 ◽  
Vol 16 (2) ◽  
Author(s):  
Pawan Singh ◽  
Trilok Chandra Upadhya ◽  
Muzaffar Iqbal Khan ◽  
Sidharth Kashyap

A simple pseudospin lattice coupled mode model with addition of third and fourth-order phonon anharmonic interactions terms, direct spin-spin interactions terms and external electric field term has been considered for investigation of transition phenomena and dielectric properties of hydrogen bonded ferroelectric crystal Rubidium dihydrogen arsenate (RDA). A double-time thermal dependent Green’s function method has been used for derivation of response function. From response function shift, width and soft mode frequency have been derived for RDA crystal. Response function is also related to dielectric constant which has been obtained in present paper. By fitting model values of different parameters in obtained expressions, the temperature variations of normal mode frequency, dielectric constant, and loss tangent have been calculated numerically for RDA crystal. Our theoretical results are compared with experimental results. It is observed that our theoretical results agree with experimental results. Therefore, it can be concluded that the modified pseudo-spin lattice coupled mode model with the simplest approximation is quite suitable to explain the transition and dielectric properties of RDA crystal.


The analysis of the previous results of the study on concrete stress-strain behavior at elevated temperatures has been carried out. Based on the analysis, the main reasons for strength retrogression and elastic modulus reduction of concrete have been identified. Despite a significant amount of research in this area, there is a large spread in experimental data received, both as a result of compression and tension. In addition, the deformation characteristics of concrete are insufficiently studied: the coefficient of transverse deformation, the limiting relative compression deformation corresponding to the peak load and the almost complete absence of studies of complete deformation diagrams at elevated temperatures. The two testing chambers provided creating the necessary temperature conditions for conducting studies under bending compression and tension have been developed. On the basis of the obtained experimental data of physical and mechanical characteristics of concrete at different temperatures under conditions of axial compression and tensile bending, conclusions about the nature of changes in strength and deformation characteristics have been drawn. Compression tests conducted following the method of concrete deformation complete curves provided obtaining diagrams not only at normal temperature, but also at elevated temperature. Based on the experimental results, dependences of changes in prism strength and elastic modulus as well as an equation for determining the relative deformation and stresses at elevated temperatures at all stages of concrete deterioration have been suggested.


Author(s):  
Hellismar W. da Silva ◽  
Renato S. Rodovalho ◽  
Marya F. Velasco ◽  
Camila F. Silva ◽  
Luís S. R. Vale

ABSTRACT The objective of this study was to determine and model the drying kinetics of 'Cabacinha' pepper fruits at different temperatures of the drying air, as well as obtain the thermodynamic properties involved in the drying process of the product. Drying was carried out under controlled conductions of temperature (60, 70, 80, 90 and 100 °C) using three samples of 130 g of fruit, which were weighed periodically until constant mass. The experimental data were adjusted to different mathematical models often used in the representation of fruit drying. Effective diffusion coefficients, calculated from the mathematical model of liquid diffusion, were used to obtain activation energy, enthalpy, entropy and Gibbs free energy. The Midilli model showed the best fit to the experimental data of drying of 'Cabacinha' pepper fruits. The increase in drying temperature promoted an increase in water removal rate, effective diffusion coefficient and Gibbs free energy, besides a reduction in fruit drying time and in the values of entropy and enthalpy. The activation energy for the drying of pepper fruits was 36.09 kJ mol-1.


1990 ◽  
Vol 112 (4) ◽  
pp. 590-595 ◽  
Author(s):  
J. H. Steward

In this paper, the requirements for an accurate 3D model of the tooth contact-line load distribution in real spur gears are summarized. The theoretical results (obtained by F.E.M.) for the point load compliance of wide-faced spur gear teeth are set out. These values compare well with experimental data obtained from tests on a large spur gear (18 mm module, 18 teeth).


2018 ◽  
Vol 140 (8) ◽  
Author(s):  
Eduard Amromin

According to several known experiments, an increase of the incoming flow air content can increase the hydrofoil lift coefficient. The presented theoretical study shows that such increase is associated with the decrease of the fluid density at the cavity surface. This decrease is caused by entrainment of air bubbles to the cavity from the surrounding flow. The theoretical results based on such explanation are in a good agreement with the earlier published experimental data for NACA0015.


2013 ◽  
Vol 2013 ◽  
pp. 1-4
Author(s):  
A. Gonzalez-Cisneros ◽  
F. L. Castillo-Alvarado ◽  
J. Ortiz-Lopez ◽  
G. Contreras-Puente

In CdS/CdTe solar cells, chemical interdiffusion at the interface gives rise to the formation of an interlayer of the ternary compoundCdSxCdTe1-x. In this work, we evaluate the effects of this interlayer in CdS/CdTe photovoltaic cells in order to improve theoretical results describing experimentalC-V(capacitance versus voltage) characteristics. We extended our previous theoretical methodology developed on the basis of three cardinal equations (Castillo-Alvarado et al., 2010). The present results provide a better fit to experimental data obtained from CdS/CdTe solar cells grown in our laboratory by the chemical bath deposition (for CdS film) and the close-spaced vapor transport (for CdTe film) techniques.


2014 ◽  
Vol 8 (1) ◽  
pp. 44-48
Author(s):  
Grzegorz Mieczkowski ◽  
Krzysztof Molski

Abstract The increasing application of composite materials in the construction of machines causes strong need for modelling and evaluating their strength. There are many well known hypotheses used for homogeneous materials subjected to monotone and cyclic loading conditions, which have been verified experimentally by various authors. These hypotheses should be verified also for composite materials. This paper provides experimental and theoretical results of such verifications for bimaterial structures with interfacial cracks. Three well known fracture hypotheses of: Griffith, McClintock and Novozhilov were chosen. The theoretical critical load values arising from each hypotheses were compared with the experimental data including uni and multi-axial loading conditions. All tests were carried out with using specially prepared specimens of steel and PMMA.


2018 ◽  
Vol 12 (2) ◽  
pp. 171
Author(s):  
Enobong E. Joshua ◽  
Cec Ekemini T. Akpan

This paper investigates the global asymptotic stability of a Delayed Extended Rosenzweig-MacArthur Model via Lyapunov-Krasovskii functionals. Frequency sweeping technique ensures stability switches as the delay parameter increases and passes the critical bifurcating threshold.The model exhibits a local Hopf-bifurcation from asymptotically stable oscillatory behaviors to unstable strange chaotic behaviors dependent of the delay parameter values.Hyper-chaotic fluctuations were observed for large delay values far away from the critical delay margin. Numerical simulations of experimental data obtained via non-dimensionalization have shown the applications of theoretical results in ecological population dynamics.


2011 ◽  
Vol 1 (32) ◽  
pp. 15
Author(s):  
Yang-Yih Chen ◽  
Meng-Syue Li ◽  
Hung-Chu Hsu ◽  
Ying-Pin Lin

In this paper, a new third-order Lagrangian asymptotic solution describing nonlinear water wave propagation on the surface of a uniform sloping bottom is presented. The model is formulated in the Lagrangian variables and we use a two-parameter perturbation method to develop a new mathematical derivation. The particle trajectories, wave pressure and Lagrangian velocity potential are obtained as a function of the nonlinear wave steepness  and the bottom slope  perturbed to third order. The analytical solution in Lagrangian form satisfies state of the normal pressure at the free surface. The condition of the conservation of mass flux is examined in detail for the first time. The two important properties in Lagrangian coordinates, Lagrangian wave frequency and Lagrangian mean level, are included in the third-order solution. The solution can also be used to estimate the mean return current for waves progressing over the sloping bottom. The Lagrangian solution untangle the description of the features of wave shoaling in the direction of wave propagation from deep to shallow water, as well as the process of successive deformation of a wave profile and water particle trajectories leading to wave breaking. The proposed model has proved to be capable of a better description of non-linear wave effects than the corresponding approximation of the same order derived by using the Eulerian description. The proposed solution has also been used to determine the wave shoaling process, and the comparisons between the experimental and theoretical results are presented in Fig.1a~1b. In addition, the basic wave-breaking criterion, namely the kinematical Stokes stability condition, has been investigated. The comparisons between the present theory, empirical formula of Goda (2004) and the experiments made by Iwagali et al.(1974), Deo et al.(2003) and Tsai et al.(2005) for the breaking index(Hb/L0) versus the relative water depth(d0/L0) under two different bottom slopes are depicted in Figs 2a~2b. It is found that the theoretical breaking index is well agreement with the experimental results for three bottom slopes. However,for steep slope of 1/3 shown in Fig 2b, the result of Goda‘s empirical formula gives a larger value in comparison with the experimental data and the present theory. Some of empirical formulas presented the breaking wave height in terms of deepwater wave condition, such as in Sunamura (1983) and in Rattanapitikon and Shibayama(2000). Base on the results depicted in Fig. 3a~3b, it showed that the theoretical results are in good agreement with the experimental data (Iwagali et al. 1974, Deo et al.2003 and Tsai et al. 2005) than the empirical formulas. The empirical formula of Sunamura (1983) always predicts an overestimation value.


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