scholarly journals Deformation recorded in polyhalite from evaporite detachments revealed by <sup>40</sup>Ar ∕ <sup>39</sup>Ar dating

Geochronology ◽  
2021 ◽  
Vol 3 (2) ◽  
pp. 545-559
Author(s):  
Lachlan Richards ◽  
Fred Jourdan ◽  
Alan Stephen Collins ◽  
Rosalind Clare King
Keyword(s):  
Meteoric Water ◽  
Closure Temperature ◽  
Water Infiltration ◽  
Northern Pakistan ◽  
The North ◽  
Salt Range ◽  
Diffusion Characteristics ◽  
Two Samples ◽  
Step Heating ◽  
Deformation Event

Abstract. The Salt Range Formation is an extensive evaporite sequence in northern Pakistan that has acted as the primary detachment accommodating Himalayan orogenic deformation from the north. This rheologically weak formation forms a mylonite in the Khewra Mine, where it accommodates approximately 40 km displacement and is comprised of intercalated halite and potash salts and gypsiferous marls. Polyhalite [K2Ca2Mg(SO4)4⚫2H2O] grains taken from potash marl and crystalline halite samples are used as geochronometers to date the formation and identify the closure temperature of the mineral polyhalite using the 40Ar/39Ar step-heating laser and furnace methods. The diffusion characteristics measured for two samples of polyhalite are diffusivity (D0), activation energy (Ea), and %39Ar. These values correspond to a closure temperature of ca. 254 and 277 ∘C for a cooling rate of 10 ∘C Myr−1. 40Ar/39Ar age results for both samples did not return any reliable crystallisation age. This is not unexpected as polyhalite is prone to 40Ar* diffusion loss and the evaporites have experienced numerous phases of deformation resetting the closed K/Ar system. An oldest minimum heating step age of ∼514 Ma from sample 06-3.1 corresponds relatively well to the established early Cambrian age of the formation. Samples 05-P2 and 05-W2 have measured step ages and represent a deformation event that partially reset the K/Ar system based on oldest significant ages between ca. 381 and 415 Ma. We interpret the youngest measured step ages, between ca. 286 and 292 Ma, to represent the maximum age of deformation-induced recrystallisation. Both the youngest and oldest measured step ages for samples 05-P2 and 05-W2 occur within the time of a major unconformity in the area. These dates may reflect partial resetting of the K/Ar system from meteoric water infiltration and recrystallisation during this non-depositional time. Otherwise, they may result from mixing of Ar derived by radiogenic decay after Cambrian precipitation with partially reset Ar from pervasive Cenozoic deformation and physical recrystallisation.

scholarly journals Deformation recorded in polyhalite from evaporite detachments revealed by <sup>40</sup>Ar/<sup>39</sup>Ar dating

2021 ◽  
Author(s):  
Lachlan Richards ◽  
Fred Jourdan ◽  
Alan Stephen Collins ◽  
Rosalind Clare King
Keyword(s):  
Meteoric Water ◽  
Closure Temperature ◽  
Water Infiltration ◽  
Northern Pakistan ◽  
The North ◽  
Salt Range ◽  
Diffusion Characteristics ◽  
Two Samples ◽  
Step Heating ◽  
Deformation Event

Abstract. The Salt Range Formation is an extensive evaporite formation in northern Pakistan that has acted as the primary detachment accommodating Himalayan orogenic deformation from the north. This rheologically weak formation forms a mylonite in the Khewra mines, where it accommodates approximate 40 km displacement and is comprised of intercalated halite and potash salts and gypsiferous marls. Polyhalite [K2Ca2Mg(SO4)4•2H2O] grains taken from potash marl and crystalline halite samples are used as geochronometers to date the formation and identify the closure temperature of the mineral polyhalite using the 40Ar/39Ar step heating method. The diffusion characteristics measured for two samples of polyhalite are diffusivity (D0), activation energy (Ea), and %39Ar. These values correspond to a closure temperature of ca. 281 and 296 °C for a cooling rate of 10 °C/Ma. 40Ar/39Ar age results for both samples did not return any reliable crystallization age. This is not unexpected as polyhalite is prone to 40Ar* diffusion loss and the evaporites have experienced numerous phases of deformation resetting the closed K/Ar system. An oldest minimum heating step age of 514 ± 3 Ma from sample 06-3.1 corresponds relatively well to the established early Cambrian age of the formation. Samples 05-P2 and 05-W2 have apparent step ages and represent a deformation event that partially reset the K/Ar system based on oldest significant ages between ca. 381 Ma and 415 Ma. We interpret the youngest apparent step ages, between ca. 286 Ma and 292 Ma, to represent the maximum age of deformation-induced recrystallisation. Both the youngest and oldest apparent step ages for Samples 05-P2 and 05-W2 occur within the time of a major unconformity in the area. These dates may reflect partial resetting of the K/Ar system from meteoric water infiltration and recrystallisation during this non-depositional time. Else, they may result from mixing of Ar derived by radiogenic decay after Cambrian precipitation with partially reset Ar from pervasive Cenozoic deformation and physical recrystallisation.

Subsurface stratigraphy and basin-fill architecture of the late Paleozoic eastern Taos trough, northern New Mexico, U.S.A.

2020 ◽  
Vol 57 (3) ◽  
pp. 149-176
Author(s):  
Nur Uddin Md Khaled Chowdhury ◽  
Dustin E. Sweet
Keyword(s):  
New Mexico ◽  
Sediment Accumulation ◽  
Late Paleozoic ◽  
North Central ◽  
The North ◽  
Basement Rocks ◽  
Basin Geometry ◽  
Deformation Event ◽  
Thrust System ◽  
Basin Fill

The greater Taos trough located in north-central New Mexico represents one of numerous late Paleozoic basins that formed during the Ancestral Rocky Mountains deformation event. The late Paleozoic stratigraphy and basin geometry of the eastern portion of the greater Taos trough, also called the Rainsville trough, is little known because the strata are all in the subsurface. Numerous wells drilled through the late Paleozoic strata provide a scope for investigating subsurface stratigraphy and basin-fill architecture of the Rainsville trough. Lithologic data obtained predominantly from petrophysical well logs combined with available biostratigraphic data from the greater Taos trough allows construction of a chronostratigraphic framework of the basin fill. Isopach- and structure-maps indicate that the sediment depocenter was just east of the El Oro-Rincon uplift and a westerly thickening wedge-shaped basin-fill geometry existed during the Pennsylvanian. These relationships imply that the thrust system on the east side of the Precambrian-cored El Oro-Rincon uplift was active during the Pennsylvanian and segmented the greater Taos trough into the eastern Rainsville trough and the western Taos trough. During the Permian, sediment depocenter(s) shifted more southerly and easterly and strata onlap Precambrian basement rocks of the Sierra Grande uplift to the east and Cimarron arch to the north of the Rainsville trough. Permian strata appear to demonstrate minimal influence by faults that were active during the Pennsylvanian and sediment accumulation occurred both in the basinal area as well as on previous positive-relief highlands. A general Permian decrease in eustatic sea level and cessation of local-fault-controlled subsidence indicates that regional subsidence must have affected the region in the early Permian.

scholarly journals Statherian (ca. 1714–1680 Ma) Extension-Related Magmatism and Deformation in the Southwestern Korean Peninsula and Its Geological Significance: Constraints from the Petrological, Structural, Geochemical and Geochronological Studies of Newly Identified Granitoids

Minerals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 557
Author(s):  
Byung-Choon Lee ◽  
Weon-Seo Kee ◽  
Uk-Hwan Byun ◽  
Sung-Won Kim
Keyword(s):  
Korean Peninsula ◽  
Tectonic Setting ◽  
Alkali Feldspar ◽  
Ductile Deformation ◽  
Southwestern Part ◽  
The North ◽  
Deformation Event ◽  
Geochemical Analyses ◽  
A Minor ◽  
T Values

In this study, petrological, structural, geochemical, and geochronological analyses of the Statherian alkali feldspar granite and porphyritic alkali feldspar granite in the southwestern part of the Korean Peninsula were conducted to examine petrogenesis of the granitoids and their tectonic setting. Zircon U-Pb dating revealed that the two granites formed around 1.71 Ga and 1.70–1.68 Ga, respectively. The results of the geochemical analyses showed that both of the granites have a high content of K2O, Nb, Ta, and Y, as well as high FeOt/MgO and Ga/Al ratios. Both granites have alkali-calcic characteristics with a ferroan composition, indicating an A-type affinity. Zircon Lu-Hf isotopic compositions yielded negative εHf(t) values (−3.5 to −10.6), indicating a derivation from ancient crustal materials. Both granite types underwent ductile deformation and exhibited a dextral sense of shear with a minor extension component. Based on field relationships and zircon U-Pb dating, it was considered that the deformation event postdated the emplacement of the alkali feldspar granite and terminated soon after the emplacement of the porphyritic alkali feldspar granite in an extensional setting. These data indicated that there were extension-related magmatic activities accompanying ductile deformation in the southwestern part of the Korean Peninsula during 1.71–1.68 Ga. The Statherian extension-related events are well correlated with those in the midwestern part of the Korean and eastern parts of the North China Craton.

Paleomagnetism of the Clam Bank Formation and paleolatitude estimates for western Newfoundland

1993 ◽  
Vol 30 (4) ◽  
pp. 776-786
Author(s):  
G. Murthy ◽  
R. Pätzold
Keyword(s):  
North American ◽  
Early Paleozoic ◽  
The North ◽  
Northerly Direction ◽  
Deformation Event ◽  
Recent Origin ◽  
Component C ◽  
Acadian Orogeny ◽  
North American Craton ◽  
Devonian Age

The Pridolian Clam Bank Formation around Lourdes Cove on the Port au Port Peninsula, western Newfoundland, underwent deformation during the Acadian orogeny. As a result, some of the beds were overturned, but the stratification planes can be accurately determined everywhere. Paleomagnetic studies of the Clam Bank Formation have yielded three well-defined components of magnetization, all acquired subsequent to the deformation event: component A with D = 337.3°, I = −28.3°, (N = 16 sites, k = 25.3, α95 = 7.5°), with a corresponding paleopole at 23.2°N, 145.0°E (dp, dm = 4.5°, 8.2°); component B with D = 172.9°, I = 5.7° (N = 35 specimens, k = 10.2, α95 = 6.4°), with a corresponding paleopole at 38.2°N, 130.1°E (dp, dm = 3.2°, 6.4°); component C with D = 350.4°, I = 69.8° (N = 33 specimens, k = 8.9, α95 = 8.9°). A pre-Mesozoic origin of the A and B components is indicated by the presence of normal and reversed components in specific sites; by the lack of correspondence between the A and B paleopoles and the Mesozoic and later pole positions from the Appalachians and the North American craton; and by agreement with Paleozoic poles from the region. The A component was probably acquired immediately after deformation during the Acadian orogeny. The B component is probably a chemical remanence that was acquired during Permo-Carboniferous (Kiaman) time. The C component is of recent origin, probably acquired in the present Earth's field. Paleomagnetic data from western Newfoundland are used in a localized setting to construct a paleopole sequence and to estimate paleolatitudes for western Newfoundland during the Paleozoic. Keeping in mind the paucity of data for Siluro-Devonian age from this region, western Newfoundland seems to have been at its southernmost position at the end of the Ordovician and to have occupied equatorial latitudes during the Permo-Carboniferous. The paleolatitude trend suggests that this block, which is part of the North American craton, moved in a southerly direction during the early Paleozoic and in a northerly direction during the middle and late Paleozoic.

Organic Heterojunctions for Photovoltaic Applications: C60 Growth on Pentacene

2010 ◽  
Vol 1263 ◽  
Author(s):  
Rebecca Ann Cantrell ◽  
Paulette Clancy
Keyword(s):  
Atomic Scale ◽  
Short Axis ◽  
Energy Functions ◽  
Potential Energy Functions ◽  
The North ◽  
Diffusion Characteristics ◽  
Static Energy ◽  
Semi Empirical ◽  
Organic Heterojunctions ◽  
And Diffusion

AbstractUsing atomic-scale Molecular Dynamics (MD) and energy minimization techniques in conjunction with semi-empirical MM3 potential energy functions, we consider the adsorption of a C60 molecule on a series of hypothetical pentacene structures that vary only in the tilt of the angle that the short axis of the pentacene molecules makes with the underlying surface (the long axis lying essentially flat, as on a metal substrate). Important relationships were discovered between the angle adopted by the short axis of pentacene on the surface, φ1, and the adsorption and diffusion characteristics of C60. Static energy calculations show that there is a transition of the deepest energy minima from between the pentacene rows at low values of φ1 to within the rows at high values of φ1, where φ1 is the angle the pentacene short axis makes with the surface. MD confirms this trend by the predominant residence locations at the extreme φ1 values. Furthermore, MD results suggest that the C60 traverses the pentacene surface in the east-west direction for lower φ1 values (φ1 ≤ 40°) and in the north-south direction for higher φ1 values (φ1 ≥ 70°). Taking both static and dynamic results together, the most favorable tilt angles for mono-directional nanowire growth should occur between 70° and 80° off-normal.

scholarly journals Investigation of Sinkhole Formation with Human Influence: A Case Study from Wink Sink in Winkler County, Texas

2020 ◽  
Vol 12 (9) ◽  
pp. 3537
Author(s):  
Shannon English ◽  
Joonghyeok Heo ◽  
Jaewoong Won
Keyword(s):  
Land Cover ◽  
Climate Changes ◽  
Meteoric Water ◽  
Oil And Gas ◽  
Water Infiltration ◽  
Direct Result ◽  
Land Cover Changes ◽  
Hydrologic Systems ◽  
Current State

The formation of sinkholes in Winkler County, Texas is concerning due to the amount of oil and gas infrastructure and the potential for catastrophic losses. Evidences of new and potential sinkholes have been documented, and determining the cause of these sinkholes is paramount to mitigate the devastating consequences thereof. Studies have shown that the Wink sinkholes result from both natural and anthropogenic influences. Data depicting land-cover changes, alterations in the hydrologic systems, climate changes, and oil and gas activity were analyzed in an effort to better understand the link between these processes and sinkhole formation. Results indicate that the combination of these processes lead to the current state. Land cover changes were highest in shrub versus grasses, undeveloped to developed and croplands. Rises in temperature and a decrease in precipitation indicate a shift towards a more arid climate. Changes to the hydraulic system are a direct result of these land cover changes while the groundwater quality depicts an environment prone to dissolution. Historical oil and gas activities have created pathways of meteoric water infiltration to the underlying limestone and evaporite formation. The combination of these processes create an environment that accelerates sinkhole formations. Understanding these processes allows for the development and implementation of better land practices, better groundwater protections, and the need for monitoring and maintaining aging oil and gas infrastructure.

Sea lice, Lepeophtheirus salmonis and Caligus elongatus, levels on salmon returning to the west coast of Ireland, 2003

2005 ◽  
Vol 85 (1) ◽  
pp. 87-92 ◽  
Author(s):  
L. Copley ◽  
T.D. Tierney ◽  
F. Kane ◽  
O. Naughton ◽  
S. Kennedy ◽  
...  
Keyword(s):  
West Coast ◽  
Sea Lice ◽  
Lepeophtheirus Salmonis ◽  
The West ◽  
North West ◽  
The North ◽  
Two Samples ◽  
Significant Difference ◽  
Total Female ◽  
Cephalothorax Length

Mobile lice levels of two species of sea lice, Lepeophtheirus salmonis and Caligus elongatus, were examined on two samples of Atlantic salmon from the west coast of Ireland. The samples examined were taken two weeks apart from salmon caught by drift net in June 2003 at two different locations off the west coast of Ireland, one in the north-west and one in the west. Both samples of salmon caught were comparable in terms of numbers of total lice counted. No significant differences in male, female and ovigerous L. salmonis levels between the two samples were recorded, however, a significant difference was recorded between juvenile L. salmonis levels. Morphometric comparisons of male and ovigerous L. salmonis examined for each of the two salmon samples examined revealed some differences. There was a significant difference in male L. salmonis in terms of cephalothorax length between the samples. In the females significant differences were found between cephalothorax length, overall total length and egg length. Significant positive correlations within samples were also observed, between total female body length and both total egg number and egg string length in one of the samples examined.

Jurassic and Cretaceous clays of the northern and central North Sea hydrocarbon reservoirs reviewed

Clay Minerals ◽  
2006 ◽  
Vol 41 (1) ◽  
pp. 151-186 ◽  
Author(s):  
M. Wilkinson ◽  
R. S. Haszeldine ◽  
A. E. Fallick
Keyword(s):  
Oxygen Isotope ◽  
North Sea ◽  
Meteoric Water ◽  
Threshold Temperature ◽  
Common Belief ◽  
The North ◽  
Wide Range ◽  
The North Sea ◽  
Uplift And Erosion ◽  
Central North Sea

AbstractThe principal clays of the northern and central North Sea are illite (sometimes with interlayered smectite) and kaolin. Chlorite is only locally important. Although it has been proposed that kaolin within North Sea sandstones is detrital in origin, the majority of workers have concluded that it is authigenic, largely the product of feldspar alteration. Kaolin is found within a wide range of sedimentary settings (and within shales) apparently defying the notion that kaolin is an indicator of meteoric water deposition. Within sandstones, the earliest authigenic kaolin has a vermiform morphology, the distribution of which is controlled by the availability of detrital mica to act as a nucleus, and the composition of the post-depositional porewaters. This vermiform kaolin formed in meteoric water, the presence of which is easily accounted for below sub-aerial exposure surfaces in non-marine formations, and below unconformities over marine units. In fully marine sands, and even marine shale units, kaolin still occurs. It has therefore been suggested that even these locations have been flushed with meteoric water.Early vermiform kaolin recrystallizes to a more blocky morphology as burial proceeds, at least in the Brent Group. Blocky kaolin has been reported as growing before, synchronously with, and after the formation of quartz overgrowths, though oxygen isotope studies support low-temperature growth, pre-quartz. Blocky kaolin may form during meteoric flushing associated with lower Cretaceous uplift and erosion, though it is found in fault blocks that are thought to have remained below sea level. Here, the kaolin may form in stagnant meteoric water, relics of the post-depositional porewater. It has also been proposed that the blocky kaolin grew in ascending basinal waters charged with carboxylic acids and CO2, though this hypothesis is not supported by stable oxygen isotope data. Some of the blocky kaolin is dickite, the stable polymorph above ∼100°C.Fibrous illite occurs almost ubiquitously within the clastic sediments of the North Sea. An early pore-lining phase has been interpreted as both infiltrated clastic clay, and as an early diagenetic phase. Early clays may have been quite smectite-rich illites, or even discrete smectites. Later, fibrous illite is undoubtedly neoformed, and can degrade reservoir quality significantly. Both within sandstones and shales, there is an apparent increase in the K content deeper than 4 km of burial, which could be due to dilution of the early smectite-rich phase by new growth illite, or to the progressive illitization of existing I-S. Much of the ‘illite’ that has been dated by the K-Ar method may therefore actually be I-S.The factors that control the formation of fibrous illite are only poorly known, though temperature must play a role. Illite growth has been proposed for almost the entire range of diagenetic temperatures (e.g. 15–20°C, Brent Group; 35–40°C, Oxfordian Sand, Inner Moray Firth; 50–90°C, Brae formation; 100–110°C, Brent Group; 130–140°C, Haltenbanken). It seems unlikely that there is a threshold temperature below which illite growth is impossible (or too slow to be significant), though this is a recurring hypothesis in the literature. Instead, illite growth seems to be an event, commonly triggered by oil emplacement or another change in the physiochemical conditions within the sandstone, such as an episode of overpressure release. Hence fibrous illite can grow at any temperature encountered during diagenesis.Although there is an extensive dataset of K-Ar ages of authigenic illites from the Jurassic of the North Sea, there is no consensus as to whether the data are meaningful, or whether the purified illite samples prepared for analysis are so contaminated with detrital phases as to render the age data meaningless. At present it is unclear about how to resolve this problem, though there is some indication that chemical micro-analysis could help. It is a common belief that illite ages record the timing of oil charge, and so can be used to calibrate basin models.Grain-coating Fe-rich chlorite cements can preserve exceptional porosity during burial. They are found in marginal marine sandstones, formed during diagenesis from precursor Fe-rich clays such as berthierine or verdine.

scholarly journals STRATEGI PENGELOLAAN HUTAN KOTA WADUK SUNTER UTARA DALAM RANGKA MEMPERTAHANKAN FUNGSI WADUK SEBAGAI RESAPAN AIR

2017 ◽  
Vol 6 (1) ◽  
pp. 51
Author(s):  
Sri Rahayu Maykewati
Keyword(s):  
Forest Management ◽  
Swot Analysis ◽  
Urban Forest ◽  
Group Discussion ◽  
Stakeholder Analysis ◽  
Water Infiltration ◽  
Reservoir Water ◽  
The North ◽  
Future Expectation ◽  
Internal And External Factors

Forest of North Sunter Reservoir is one of the urban forest that has been determined by Decree of Jakarta Governor No.317 Year 1999 about Sunter North Road Forest Size Establishment +2,2 ha as jungle city forest in North Jakarta Municipality. This study aims to find out how the strategy of Forest Management of North Sunter Reservoir City that can be applied, how the role of stakeholders in management, internal and external factors what, what solution has been done and how the success and what the future expectation. The method used is descriptive qualitative approach. Data collection techniques and procedures used are: (1) Observation; (2) Interviews; (3) Documents; (4) FGD (Focus Group Discussion). The analysis was conducted using environmental analysis, stakeholder analysis, SWOT analysis (Strength Weakness Opportunity Treath) and QSPM (Quantitative Strategic Planning Matrix) analysis.The North Sunter City Forest Management Strategy can be implemented with the collaboration of relevant stakeholders, it is expected to increase the benefit value of its strengths and opportunities, and can minimize the value of weaknesses and threats, so that the North Sunter Reservoir Forest can function optimally and can maintain the function of the reservoir water infiltration.

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