Implementation of Fusel Oil as an Octane Enhancer with Commercial Gasoline to Operate Gasoline Engine

The rise of energy demand and ecological contaminations encourage the utilization of alcohol bases on substitutes fuels in spark ignition (SI) engine. The fusel oil is a byproduct acquired from fermentation process with higher alcohol content. It has high-octane and less exhaust emissions; therefore, it takes significant place between the substitutes fuels. During this study, the impact of utilizing mixtures of pure gasoline & fusel oil on engine exhaust emissions & performance has been evaluated after water extraction from fusel oil. A single-cylinder, four-stroke SI engine has been utilized in these tests. The examinations execute at different speeds. The experiment fuels mixed with fusel oil at proportions of 5%, 10%, 20%, and 30%. At each speed, the engine’s performance & emissions measurement have been conducted. During the experimentations, it has been noticed that the torque (T) and specified fuel consumption (SFC) rises as the quantity of fusel oil risen in the mixture. Carbon monoxide (CO) and carbon dioxide (CO2) emissions are decreased as the quantity of fusel oil is raised in mixtures.

Liquid Propane Injection in Flash-Boiling Conditions

This study aimed to investigate the influence of flash-boiling conditions on liquid propane sprays formed by a multi-hole injector at various injection pressures. The focus was on spray structures, which were analysed qualitatively and quantitatively by means of spray-tip penetration and global spray angle. The effect of flash boiling was evaluated in terms of trends observed for subcooled conditions. Propane was injected by a commercial gasoline direct injector into a constant volume vessel filled with nitrogen at pressures from 0.1 MPa up to 6 MPa. The temperature of the injected liquid was kept constant. The evolution of the spray penetration was observed by a high-speed camera with a Schlieren set-up. The obtained results provided information on the spray evolution in both regimes, above and below the saturation pressure of the propane. Based on the experimental results, an attempt to calibrate a simulation model has been made. The main advantage of the study is that the effects of injection pressure on the formation of propane sprays were investigated for both subcooled and flash-boiling conditions. Moreover, the impact of the changing viscosity and surface tension was limited, as the temperature of the injected liquid was kept at the same level. The results showed that despite very different spray behaviours in the subcooled and flash-boiling regimes, leading to different spray structures and a spray collapse for strong flash boiling, the influence of injection pressure on propane sprays in terms of spray-tip penetration and spray angle is very similar for both conditions, subcooled and flash boiling. As for the numerical model, there were no single model settings to simulate the flashing sprays properly. Moreover, the spray collapse was not represented very well, making the simulation set-up more suitable for less superheated sprays.

Increasing the Yield of Light Distillates by Wave Action on Oil Raw Materials

The article presents the results of the electromagnetic activation of petroleum feed in the vortex layer apparatus. It is shown that under the electromagnetic influence, there is a significant increase in the proportion of straight-run gasoline fraction distillate, as well as a change in the physicochemical parameters of the light fractions obtained as a result of the cavitation effect and the low-temperature cracking. It has been established that the processes of wave action on oil occurring in the electromagnetic field zone lead to a change in the individual and group hydrocarbon composition of the distillates obtained. The gasoline fraction produced from activated petroleum, due to an increase in the proportion of aromatic compounds, has a high octane number compared to the original straight-run fraction and low content of alkenes, which allows us to recommend its use as a high-octane component of motor fuels in the compounding and production of commercial gasoline.

Influence of WPO (Waste Plastic Oil) - gasoline mixtures for emission characteristics on working spark-ignition engine

The utilization of liquid products as transportation fuel derived from the thermal decomposition of different plastic waste mixtures was investigated. The production of pyrolysis oils was performed in a laboratory-scale batch reactor utilizing polystyrene (PS), polypropylene (PP), and high-density polyethylene (HDPE) waste blends. Two different mixtures (10% PS – 60% PP – 30% HDPE; 10% PS – 30% PP – 60% HDPE) were prepared, and the influence of reflux was also studied. The pyrolysis oils were blended to commercial gasoline in the 0-100% range. It was found that each blend could be successfully used as an alternative fuel in a traditional spark-ignition engine without any prior modifications or fuel additive. However, based on the engine tests, the presence of the reflux is vital as the composition of the pyrolysis oil is closer to the commercial gasoline. The emission measurements showed increasing NOx emissions compared to neat gasoline, but, on the other side, a decrease in CO was noticed. These changes were much smaller in cases when reflux was used during oil production. Based on the obtained results, the utilization of reflux-cooling is an effective method to enhance the gasoline range hydrocarbons in the plastic waste pyrolysis oils, and therefore blending these oils to commercial gasoline might be viable.

Benzene Exposure and Cancer Risk from Commercial Gasoline Station Fueling Events Using a Novel Self-Sampling Protocol

Tens of millions of individuals go to gasoline stations on a daily basis in the United States. One of the constituents of gasoline is benzene, a Group 1 carcinogen that has been strongly linked to both occupational and non-occupational leukemias. While benzene content in gasoline is federally regulated, there is approximately a thirty-year data gap in United States research on benzene exposures from pumping gasoline. Using a novel self-sampling protocol with whole air canisters, we conducted a gasoline pumping exposure assessment for benzene, toluene, ethylbenzene, and xylene (BTEX) on Baltimore, MD consumers. Geometric mean exposures (geometric standard deviations) were 3.2 (2.7) ppb,9.5 (3.5) ppb, 2.0 (2.8) ppb, and 7.3 (3.0) ppb, respectively, on 32 samples. Using the benzene exposures, we conducted consumer and occupational probabilistic risk assessments and contextualized the risk with ambient benzene exposure risk. We found that the consumer scenarios did not approach the 1:1,000,000 excess risk management threshold and that the occupational scenario did not exceed the 1:10,000 excess risk management threshold. Further, in all Monte Carlo trials, the ambient risk from benzene exposure exceeded that of pumping risk for consumers, but that in approximately 30% of occupational trials, the pumping risk exceeded the ambient risk.

OPTIMIZATION OF THE PROCESS OF PREPARING MOTOR FUELS AT REFINERIES

One of the key tasks of modern oil refining in Kazakhstan is the production of commercial oil products that meet international environmental standards K-4, K-5. Undoubtedly, this is facilitated by the modernization of primary and secondary production facilities of refineries, which allows you to expand the range of commercial products and improve their quality. The compounding process plays an equally important role in the formation of quantitative and qualitative indicators of commercial gasoline.The article considers the main mathematical models for calculating the preparation of commercial gasoline, the main purpose of which is to select a recipe that ensures compliance of petroleum products with GOST requirements. the basis is a mathematical model for calculating the detonation resistance of gasoline, taking into account the intermolecular interactions of the mixture components. Currently, the modeling of mathematical models of various oil refining processes is of particular relevance, since this allows reducing the cost of the experimental part, calculate all possible scenarios and make the most appropriate choice.

Hydro-catalytic isomerization of light gasoline fraction of Zhanazhol field’s oil

The purpose of the present work is to show that light straight-run gasoline fraction can be used as feedstock for hydro-catalytic isomerization process, and the isomerized product can serve as a component for obtaining pure ecological commercial gasoline brand Euro-4 and Euro-5. Transformation of n-alkanes of Zhanazhol oil’s light gasoline fraction with boiling temperature 180°C was studied. Isomerization was carried out in a flow unit with a stationary layer of modified sample of industrial aluminum-platinum catalyst at 200-300°C and 2.0-4.0 MPa, with volume feed rate of 1.0-3.0 h-1 and circulation ratio of hydrogen containing gas circulation 1000-1500 m3/m3 of catalyst feed. Light gasoline fraction are subjected to a number of chemical transformations: n-paraffins isomerization, five-membered and six-membered cycloalkanes dehydroisomerization and hydrocracking. n-Alkanes are isomerized in iso-alkanes, naphthenic hydrocarbons are first subjected to hydrocracking with opening the cycle and forming n-alkanes, which are then isomerized into iso-alkanes. Thus, the reaction products contain isopentane, 2,3-dimethylbutane with octane number 92 and 104 correspondingly, and other iso-paraffinic hydrocarbons that lead to raise of gasoline octane number. By study of individual hydrocarbon composition of feedstock and isomerizate it is possible to establish some regularities hydrocarbons in the process of hydro-catalytic isomerization of light gasoline fraction.

Production of motor benzene via plastic processing as perspective direction of "green" fuel power industry

The paper reviews the topicality and practical significance of the implementation of processing technology of plastic with the purpose of obtaining raw material for manufacturing motor benzene. It is shown that this case is the advantageous strategy for the damage reduction to the environment from the oil-gas complex and usage of commercial gasoline based on the fossil hydrocarbon crude and for the utilization of plastic wastes as well. The perspective technologies of plastic processing including pyrolysis, catalytic cracking, hydrothermal liquefaction based on the bibliographic review and the recommendations on the improvement of benzene component obtained as a basis for industrial production of motor benzene are presented. In the capacity of the last ones, the implementation of alcohol mixed octane-increasing additives based on the ethanol is justified. It is shown that using alcohol not only increases octane number of the fuel, but also saves expensive hydrocarbon components, allows reducing the toxic high-octane aromatic hydrocarbons in the gasoline, improves the distribution of octane numbers by benzene fractions based on the reformat, as well as expands the crude base for fuel production due to the non-oil raw. The studies showed that adding 10 % of alcohol is the optimum concentration, as on the one hand it provides the growth of knock characteristics and phase stability of the gasoline, on the other hand does not require additional regulation of motor engine for using such fuel.

Assessment on the Effective Green-Based Nepal Origin Plants Extract as Corrosion Inhibitor for Mild Steel in Bioethanol and its Blend

Effects of Nepal origin plant species of Vitex negundo, Catharanthus roseu, Aegle marmelos and Elaeocarpus ganitrus extracts on mild steel corrosion were explored in bioethanol (E100) and its blend (E15) in airtight condition at 25±2 °C using static immersion, inhibition efficiency and mechanism tests which were complemented with adsorption isotherms and potentiodynamic polarization studies. Corrosion resistance of the mild steel was increased with increasing 500-2000 ppm concentrations of each plant extract in E100 and E15 biofuels. Additions of V. negundo and C. roseus extract separately in both the biofuels seems to be more effective inhibition actions to prevent the mild steel corrosion than A. marmelos or E. ganitrus addition so as the corrosion rates of the mild steel in E100 and E15 are successfully lowered even than in commercial gasoline (E0). The results obtained from the corrosion rate revealed the order of the corrosion inhibition efficiency (IE) as V. negundo > C. roseus > A. marmelos > E. ganitrus. The maximum IE (IEmax) in V. negundo and C. roseus leaves was showed about 89-86% and 71-75%, respectively, at 2000 ppm concentration, in spite of the other two more plants leaf extract also used as the corrosion inhibitors for the mild steel in both E100 and E15 biofuels. The IE increased on increasing inhibitor concentration following the Langmuir and Temkin adsorption isotherms but decreased with immersion time which suggested that the corrosion inhibition mechanism is of physical type of adsorption of the leaves constituents on the mild steel surface. A. marmelos extract acted as an anodic type of inhibitor in E100 and E15, while E. ganitrus acted as mixed