Achieving Productivity and Clean Inflow from an Unconventional Reservoir in North Kuwait

Jurassic Kerogen shale/carbonate reservoir in North Kuwait provides the same challenges as North American shales in addition to ones not yet comparable to any other analogue reservoir globally. It is the Kerogen's resource density; however, that makes this play so attractive. Like ‘conventional’ unconventional in the US and Canada this kerogen is believed to be a source rock and is on the order of micro-to nano-Darcy permeability. As such, industry learnings show that likely long horizontal laterals with multiple hydraulic fractures will be necessary to make commercial wells. Following this premise, the immediate objective is to establish clean inflow into wellbore as the previous attempts to appraise failed due to "creep" of particulate material and formation flowing into the wellbore. Achieving this milestone will confirm that this formation is capable of solids free inflow and will open a new era in unconventional in Kuwait. Planning for success, the secondary objective is to then upscale to full field development. The main uncertainties lie in both producibility and ‘frac-ability’, and certainly, these challenges are not trivial. A fully integrated testing program was applied to both better understand the rock mechanical properties and to land on an effective frac design. Scratch, unconfined stress, proppant embedment and fluid compatibility tests were conducted on full core samples for geo-mechanics to prepare a suite of strength measurements ahead of frac design and to custom-design the fracture treatment and "controlled" flowback programs to establish inflow from Kerogen without "creep". Unlike developed shale reservoirs, the Jurassic Kerogen tends to become unconsolidated when treated. The pre-frac geomechanics tests will be outlined in this paper with the primary objective of finding the most competent reservoir unit to select the limited perforation interval to frac through so that formation competency can be maintained. Previous attempts failed to maintain a competent rock matrix even only after pumping data-fracs. Acidizing treatments also turn the treated rock volume into sludgy material with no in-situ stability nor ability to deliver "clean inflow". A propped fracturing treatment with resin-coated bauxite was successfully placed in December 2019 in a vertical appraisal well perforated over 6 ft at 12 spf shot density. "Controlled" flowback carried out in January 2020 achieved the strategically critical "clean inflow" with reservoir fluids established to surface. Special proppant technologies provided by an industry leading manufacturer overcame the embedment effects and to control solids flowback. A properly designed choke schedule to balance unloading with a delicate enough drawdown to avoid formation failure was executed. Local oilfields relied on the vast reserves and produced easily from carbonate reservoirs that required only perforating or acid squeezes to easily meet or exceed high production expectations. This unconventional undertaking in Kuwait presents a real challenge as it is a complete departure from the ways of working yet it points towards a very high upside potential should the appraisal campaign can be completed effectively.

Indoor Nanoparticle Characterization in Construction Waste Recycling Companies over Time

Building activity is a significant source of atmospheric contamination by ultrafine dust. Cognizant of this fact, those active in the use and recycling of construction materials must be aware of the risks associated with exposure to nanoparticles (NPs) and ultra-fine particles (UFPs), as well as the associated health impacts. This work analyzed NPs and UFPs generated in a small building-material recycling company using high-resolution electron microscopes and X-ray Diffraction. A self-made passive sampler (LSPS) that can obtain particulate samples without physical and morphological changes, especially where there is a suspension of particulate material, was used in this study. A total of 96 particulate samples, using the LSPS for three months in four seasons, were collected during the study. Thus, the dry deposition of the particles, which are considered highly harmful to human health, was found in each of the four seasons of the year. It is suggested that for future research, the toxicological evaluations of the particulates in the construction industry should be investigated through the consideration of measures to control and mitigate the health risks of workers regarding exposure to NPs and UFPs.

Nano-Structured Lipid Carrier-Based Oral Glutathione Formulation Mediates Renoprotection against Cyclophosphamide-Induced Nephrotoxicity, and Improves Oral Bioavailability of Glutathione Confirmed through RP-HPLC Micellar Liquid Chromatography

The study aimed to develop a new glutathione (GSH) oral formulation to enhance the delivery of GSH and counter the nephrotoxicity of the anticancer drug, cyclophosphamide (CP). A nanostructured lipid carrier glutathione formulation (GSH-NLCs) composed of glutathione (500 mg), stearic and oleic acid (300 mg, each), and Tween® 80 (2%, w/v) was prepared through the emulsification-solvent-evaporation technique, which exhibited a 452.4 ± 33.19 nm spheroidal-sized particulate material with narrow particle size distributions, −38.5 ± 1.4 mV zeta potential, and an entrapment efficiency of 79.8 ± 1.9%. The GSH formulation was orally delivered, and biologically tested to ameliorate the CP-induced renal toxicity in a rat model. Detailed renal morphology, before and after the GSH-NLCs administration, including the histopathological examinations, confirmed the ameliorating effects of the prepared glutathione formulation together with its safe oral delivery. CP-induced oxidative stress, superoxide dismutase depletion, elevation of malondialdehyde levels, depletion of Bcl-2 concentration levels, and upregulated NF-KB levels were observed and were controlled within the recommended and near normal/control levels. Additionally, the inflammatory mediator marker, IL-1β, serum levels were marginally normalized by delivery of the GHS-NLCs formulation. Oral administration of the pure glutathione did not exhibit any ameliorating effects on the renal tissues, which suggested that the pure glutathione is reactive and is chemically transformed during the oral delivery, which affected its pharmacological action at the renal site. The protective effects of the GSH-NLCs formulation through its antioxidant and anti-inflammatory effects suggested its prominent role in containing CP-induced renal toxicity and renal tissue damage, together with the possibility of administrating higher doses of the anticancer drug, cyclophosphamide, to achieve higher and effective anticancer action in combination with the GSH-NLCs formulation.

First Successful Pilot Testing of Unconventional Reservoir in North Kuwait from Scratch to Productivity

Jurassic's kerogen shale-carbonate reservoir in North Kuwait is categorized as a source rock exhibiting micro- to Nano Darcy permeability and is Kuwait Oil Company's focus in recent years. Although the challenges are significant (formation creep, fracturing initiation, etc.), the efforts toward producing from unconventional reservoirs and applying experience from both USA and Canada in this field are ongoing. As a step toward development, the gas field development group selected a vertical pilot well to measure the inflow of hydrocarbon from a single fracture while minimizing formation creep (flowing of particulate material and formation into the wellbore that blocks the production). This step was required prior to drilling a long horizontal lateral wells and completing it with multiple hydraulic fractures to confirm commercial production. A comprehensive design process was executed with the full integration of operator and service company competencies to achieve the three main objectives: First, characterize the kerogen rock mechanics which allows selection of the most competent kerogen beds to prevent collapse of the hole during fracturing (creep effect) by conducting scratch, unconfined stress, proppant embedment, and fluid compatibility tests. Then, prepare a suit of strength measurements on full core samples to help in fracturing design and minimize creep effect. The second objective was to design and implement a robust proppant fracturing program that avoids the kerogen concerns after selecting the most competent reservoir unit and suitable proppant type. Third, perform controlled flowback to unload the well and attempt to establish clean inflow unlike previous attempts that failed to either suitably stimulate or prevent solids production (deliver clean inflow). After analyzing the lab test results, choosing the optimal fracturing design, and preparing the vertical well for proppant hydraulic fracturing, the treatment was performed. In December 2019, the hydraulic fracturing treatment with resin-coated bauxite proppant was successfully pumped through 6 ft of perforation interval and followed by a controlled flowback. Resin-coated bauxite proppant was specifically selected to overcome the creep and embedment effects during the fracture closure and flowback. Moreover, a properly designed choke schedule was implemented to balance unloading with a delicate enough drawdown to avoid formation failure. This paper discusses in detail the lab testing, evolution of fracturing design, treatment analysis, and the robust workflow that led to successfully achieving all main objectives, paving the way for long horizontal lateral wells. This unconventional undertaking in Kuwait presents a real challenge. It is a departure from traditional methods, yet it points toward a high upside potential should the appraisal campaign be completed effectively.

Numerical analysis of a tire shredder machine to produce rubber particulate material

The main objective of this work is to develop a numerical analysis of a shredder machine to generate rubber particulate material for its implementation in different sectors such as construction, artisanal, and road as aggregates in the raw material. As part of the methodology, modern design theories were considered to select the materials for the different elements of the crushing machine; for this purpose, the SolidWorks design software was used to obtain a conceptual design model of the prototype. The mathematical and numerical results indicate that the prototype of the crushing machine will work in good conditions, always guaranteeing high levels of safety and performance based on the mechanical and physical properties of the materials selected through the design theories. Likewise, this machine will be low-cost to promote growth and competitive capacity for studies of different products with rubber aggregates to solve global environmental problems. Finally, the physical behavior of the new materials can be obtained with rubber particles aggregate will allow evaluating and optimizing a different kind of products that can be used in different sectors aiding sustainability sources.

Indoor, outdoor and ICU Environment monitoring of COVID-19

The disease caused by the SARS-CoV-2 virus, which originated in Wuhan, Hubei Province, China, in December 2019 spread rapidly, causing a high number of deaths worldwide. The difficult ability to contain the transmission of the disease raised doubts about the possible forms of contamination. Studies have shown an increase in new cases of the disease on days when the level of pollution was high, raising questions that pollutants may be carriers of the virus. In this study, we investigated the involvement of fine particulate matter (PM2.5) in virus loading in common circulation (indoor and outdoor) environments and in the intensive care unit (ICU) of a hospital. PM2.5 was collected from May to November 2020, and the collection time per day was 48 to 72 h. After collection, the material was stored at a temperature of -80°C until the moment of analysis. Our results demonstrated that SARS-CoV-2 can be found in fine particulate material (PM2.5), but there is an essential interference of temperature, humidity and UV rays in the preservation of viral RNA.

Advanced Modeling Capability to Enhance Near-Wellbore and Far-Field Bridging in Acid Fracturing Field Treatments

Different applications of fracture bridging and diversion are used regularly in carbonate acid fracturing without an in-depth understanding of the physical phenomena that dominate the processes involved in the bridging and diversion process. The extension of modeling capabilities in conjunction with yard-scale and field-scale experiences will increase our understanding of these processes. A robust multimodal diversion pill and polylactic acid fiber-laden viscous acid were utilized for near-wellbore and far-field bridging, respectively. Numerous field treatments demonstrated the uncertainty of achieving effective diversion. An existing multiphysics model was extended to develop functionalities to model diversions at different scale. Extensive laboratory testing was conducted to understand the scale of bridging and diversion mechanisms. Finally, a bridging yard test was designed, and field case studies were used to integrate all the branches. Field cases showed a diversion pressure up to 4,000 psi depending on perforation strategy, pill volume, and pill seating rate. Correlations showed the interdependence of multiple parameters in diversion processes. The field studies motivated modeling capabilities to simulate the critical diversion processes at high resolution and quality. The model simulates diverting agents that reduce leakoff in the fracture area and their effects on fracture geometry. The approach considers the acid reaction kinetics coupled with geomechanics and fluid transport. Different diverting agent concentrations required for bridging can be modeled effectively. A yard test was designed to confirm the integrity of the pill material through completion valves (minimum inside diameter 9.5 mm) and analyzed with high-resolution imaging. All the theoretical, mathematical, and numerical findings from modeling were integrated with laboratory- and yard-scale experimentation results to develop and validate near-wellbore and far-field diversion modeling. Analytical correlations were formulated from injection rate, particulate material concentration, pill volumes, fracture width, etc., to incorporate and validate the model. This study enhances understanding of the different diversion mechanisms from high-fidelity theoretical modeling approach integrated with a practical experimental view at laboratory and field scale. Current comprehensive research has significant potential to make the modeling approach a reliable method to develop tight carbonate formations around the globe.

Revisiting the Gage–Bidwell Law of Dilution in Relation to the Effectiveness of Swimming Pool Filtration and the Risk to Swimming Pool Users from Cryptosporidium

The transfer of water from a swimming pool to the treatment location is key in determining the effectiveness of water treatment by filtration in removing turbidity and managing the risk from particulate material, including microbial pathogens, such as Cryptosporidium spp. A key recommendation for pool operators when dealing with an accidental faecal release (the likely main source of high Cryptosporidium oocyst concentrations in pools) is that the pool water should be filtered for at least six turnover cycles prior to use. This paper briefly outlines the theoretical basis of what has become known as the Gage–Bidwell Law of Dilution, which provides a basis for this recommendation, and extends the idea to account for the impact of filter efficiency. The Gage–Bidwell Law reveals that for each pool turnover 63% of the water resident in the pool at the start of the turnover period will have been recirculated. Building on this, we demonstrate that both filter efficiency and water-turnover time are important in determining filtration effectiveness and can be combined through a single parameter we term ‘particle-turnover’. We consider the implications of the Gage–Bidwell Law (as referred to in the original 1926 paper) for the dynamics of the ‘dirt’ content of pool water, whether in terms of a specific particle size range (e.g., Cryptosporidium oocysts) or turbidity.