An ecological approach to printing industry: Development of ecofriendly offset printing inks using vegetable oils and pine resin as renewable raw materials and evaluation of printability

Author(s):  
Pelin Hayta ◽  
Mehmet Oktav ◽  
Özlem Ateş Duru
Author(s):  
Khidmet Shikhaliev ◽  
Nadezhda Stolpovskaya ◽  
Michael Krysin ◽  
Anna Zorina ◽  
Denis Lyapun ◽  
...  

Oligo- and polyesters of polyglycerol and polyricinoleic acid are widely used as emulsifiers in various industries. Based on the condensation of glycerol and its oligomers with epoxidized derivatives of vegetable oils, new promising emulsifiers for oil-water systems were obtained. Complex structural and functional spectral analysis of synthesized substances showed that the main reactions leading to the formation of the desired products were the opening of epoxide cycles, the transesterification of esters and the condensation of fatty acid derivatives. The new combination of renewable raw materials is of undoubted interest for deeper vegetable oils chemical processing.


2020 ◽  
Vol 11 (2) ◽  
pp. 11-17
Author(s):  
Cem Aydemir ◽  
◽  
Samed Ayhan Özsoy ◽  

In the Printing Industry, printing inks, varnishes, lacquers, moistening solutions and washing solvents (ethanol, methyl acetate, ethyl acetate, isopropanol, n-propanol, hexane, benzene, toluene, xylene, isopropyl acetate, propyl acetate, dimethyl ketone, glycols and glycol ethers) contain volatile organic compounds (VOCs) and air pollutants (HAPs). Especially solvent based inks used for flexo, gravure and screen printing, offset printing dampening solutions and cleaning solvents contain high concentration of VOC. These organic compounds evaporate during the production process or contribute to the photochemical reaction. VOCs and HAPs, together with sunlight and nitrogen oxides, cause photochemical smoke, air particles and ground level ozone emission in the atmosphere. The VOCs and heavy metals can lead to soil and even water pollution when left in landfill. The amount of solvent retained by flexo, gravure and screen-printed products is 3-4% of total ink solvent used. The solvent in the printed ink content, except for the one held by the printed material evaporates in its own environment after the printing process. Most of these solvents and organic compounds used in printing environment contain at least one carbon and hydrogen atom and have negative effects on health and environment.In this study, the environmental impacts and risks of inks and solvents used in the printing industry have been evaluated. Measures to be taken to reduce and manage these environmental effects and risks have been addressed and recommendations have been made.


2014 ◽  
Vol 67 (2) ◽  
Author(s):  
Zuhaili Idham ◽  
Mohd Azizi Che Yunus ◽  
Mustafa Kamal Abdul Aziz ◽  
Siti Hamidah Mohd Setapar ◽  
Hasanah Mohamad

The extensive use of petroleum product has caused a number of environmental pollution. The printing industry is one of our nation’s largest producers of hazardous waste and volatile organic compound. One of the major alternatives is to use vegetable oil based products as biorenewable raw materials. Hence, the formulation of palm olein based varnish has been discussed in the present study. Palm olein from palm oil was prepared first, and their physical properties were determined. Varnishes were prepared with the palm olein and four different types of resin (F-2136, F-210, F-2110 and F-2118). Rheological properties, yield value, heptanes tolerance of the varnish were determined. From this study, it was found that palm olein with the F-210 resin is promising as the alternative varnish materials for the production of offset printing ink.


2020 ◽  
pp. 48-55
Author(s):  
M.E. Sharanda ◽  
◽  
E.A. Bondarenko ◽  

Ethylene glycol and propylene glycol are important representatives of polyols. On an industrial scale, they are obtained from petrochemical raw materials. Within a decade, significant efforts were made for the producing of polyols from biologically renewable raw materials - carbohydrates. The general trend for carbohydrate hydrogenolysis includes application of liquid-phase process with the use of modified metal-oxide catalysts, at 120-120 ° C and pressure of 3MPa or above. So high pressure is used for the reason to increase hydrogen solubility, and also due to the high partial pressure of low boiling solvents. We supposed that usage of high boiling solvents could allow hydrogenolysis to be performed at the lower pressure. Ethylene glycol and propylene glycol are of particular interest as such kind of solvent since they are both the main products of glucose hydrogenolysis. In this work, the process of hydrogenolysis of glucose and fructose over Cu / MgO-ZrO2 catalyst have been studied at temperature range of 160-200 °C and a pressure of 0.1-0.3 MPa in a flow reactor. The solvents were simultaneously the target products of the reaction - ethylene glycol and / or propylene glycol. Gas chromatography and 13C NMR were used for the reaction products identification. It was found that the solubility of glucose in propylene glycol is 21 % by weight, and in ethylene glycol 62% by weight. It was pointed out that the process of hydrogenolysis can take place at a pressure close to atmospheric. Under these conditions, the conversion of hexoses reaches 96-100 %. The reaction products are preferably propylene glycol and ethylene glycol. The total selectivity for C3-2 polyols is 90-94 %, that is higher than in the hydrogenolysis of glucose in aqueous solution.


2008 ◽  
Vol 59 (11) ◽  
Author(s):  
Cristina Dusescu ◽  
Anca Borcea ◽  
Vasile Matei ◽  
Ion Popa ◽  
Irina Gabriela Radulescu

The present paper studies biodiesel samples preparation by transesterification and compares their physical and chemical properties (biofuels prepared from different raw materials - vegetable oils: sunflower oil, crocus oil and soya bean oil) and the biodegradability degree, as well as the possibilities of the integration of such production unit in industrial diagram of auto fuels production.


2020 ◽  
Vol 164 ◽  
pp. 08031
Author(s):  
Evgeniy Velichko ◽  
Edward Tshovrebov ◽  
Ural Niyazgulov

The article deals with issues of monitoring, planning, organizational and technical support, economic regulation and improving the efficiency of the infrastructure for processing, recycling and disposal of waste, resource conservation and management of secondary resources, their use as secondary raw materials for production, services, work and power generation. The Russian Federation has significant potential for economic growth due to the efficient use of secondary resources from billions of tons of generated production and consumption waste annually. These ecologically unsafe anthropogenic objects can be characterized as a source of valuable renewable raw materials, material and fuel and energy resources. However, the scale and level of use of various types of secondary resources are characterized by considerable unevenness and depend on the demand for secondary raw materials, the resource value of the waste, the environmental situation arising from treating them as environmental polluters, on the real economic conditions that determine the profitability of each specific type. economic activities that use secondary resources for the manufacture of products, works, services, energy production. The methods of monitoring the industry for the treatment, disposal and disposal of waste are: information-analytical, information-statistical, sociological, geo-information. The legal status of the monitoring system of the industry for the treatment, disposal and disposal of waste is determined by the limitations of its functionality within the framework of the goals and objectives facing it.


2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Darfizzi Derawi ◽  
Bashar Mudhaffar Abdullah ◽  
Hasniza Zaman Huri ◽  
Rahimi M. Yusop ◽  
Jumat Salimon ◽  
...  

Palm olein (POo) is widely produced as edible oil in tropical countries. POois considered as renewable raw material for the new industrial and pharmaceutical products synthesis based on its characterization. Palm olein was good on its viscosity index, oxidative stability, and flash and fire point. POocontained unsaturated triacylglycerols (TAGs): POO (33.3%); POP (29.6%) which plays an important role in chemical modification process to produce new industrial products. The double bond was detected on1H-NMR (5.3 ppm) and13C-NMR (130 ppm) spectra. The chemical compositions of POowere tested by using high performance liquid chromatography (HPLC) and gas chromatography (GC) techniques. This unsaturated oil is potentially to be used as renewable raw materials in chemical modification process to synthesise polyols, polyurethane, and biolubricant for industrial and pharmaceutical products application.


2018 ◽  
Vol 16 (3) ◽  
pp. 689-697 ◽  
Author(s):  
Tobias Robert ◽  
Steven Eschig ◽  
Toine Biemans ◽  
Frank Scheifler

2019 ◽  
Vol 2019 (4) ◽  
pp. 119-126
Author(s):  
CH Bekmurotov ◽  

The article reviewed the certification and quality control of the technological process for the production of vegetable oil. There is a procedure for packaging, quality control of products, determination of quality indicators and quality control of finished products. The procedure for using refined cottonseed oil and its varieties, the requirements for placement and storage of vegetable oils, as specified in the regulatory documents, the quality control of vegetable oils and other solutions for cottonseed oil are provided. The gas analyzer shows a solution for measuring the amount of solution by painting the tubes of a mixture of gas and air in oil. Detailed information on the production of vegetable oils, the cost of raw materials, the level of fat content of cotton seeds and the methods used to produce oil from cotton seeds. Methods for certification of vegetable oils, types of quality control, methods of testing and quality determination are presented. It was shown that the procedure for refined production of cottonseed oils and their types, as well as the state of the product classification of products based on the method of producing vegetable oils for consumer purposes, analysis of the sequence of refined oils and refining processes.


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