Nanostructured Materials: Industrial Applications

Author(s):  
Kristin Clement ◽  
Angela Iseli ◽  
Dennis Karote ◽  
Jessica Cremer ◽  
Shyamala Rajagopalan
Nanomaterials ◽  
2022 ◽  
Vol 12 (2) ◽  
pp. 177
Author(s):  
Ahmed Barhoum ◽  
María Luisa García-Betancourt ◽  
Jaison Jeevanandam ◽  
Eman A. Hussien ◽  
Sara A. Mekkawy ◽  
...  

Nanomaterials are becoming important materials in several fields and industries thanks to their very reduced size and shape-related features. Scientists think that nanoparticles and nanostructured materials originated during the Big Bang process from meteorites leading to the formation of the universe and Earth. Since 1990, the term nanotechnology became very popular due to advances in imaging technologies that paved the way to specific industrial applications. Currently, nanoparticles and nanostructured materials are synthesized on a large scale and are indispensable for many industries. This fact fosters and supports research in biochemistry, biophysics, and biochemical engineering applications. Recently, nanotechnology has been combined with other sciences to fabricate new forms of nanomaterials that could be used, for instance, for diagnostic tools, drug delivery systems, energy generation/storage, environmental remediation as well as agriculture and food processing. In contrast with traditional materials, specific features can be integrated into nanoparticles, nanostructures, and nanosystems by simply modifying their scale, shape, and composition. This article first summarizes the history of nanomaterials and nanotechnology. Followed by the progress that led to improved synthesis processes to produce different nanoparticles and nanostructures characterized by specific features. The content finally presents various origins and sources of nanomaterials, synthesis strategies, their toxicity, risks, regulations, and self-aggregation.


2018 ◽  
Vol 9 ◽  
pp. 1050-1074 ◽  
Author(s):  
Jaison Jeevanandam ◽  
Ahmed Barhoum ◽  
Yen S Chan ◽  
Alain Dufresne ◽  
Michael K Danquah

Nanomaterials (NMs) have gained prominence in technological advancements due to their tunable physical, chemical and biological properties with enhanced performance over their bulk counterparts. NMs are categorized depending on their size, composition, shape, and origin. The ability to predict the unique properties of NMs increases the value of each classification. Due to increased growth of production of NMs and their industrial applications, issues relating to toxicity are inevitable. The aim of this review is to compare synthetic (engineered) and naturally occurring nanoparticles (NPs) and nanostructured materials (NSMs) to identify their nanoscale properties and to define the specific knowledge gaps related to the risk assessment of NPs and NSMs in the environment. The review presents an overview of the history and classifications of NMs and gives an overview of the various sources of NPs and NSMs, from natural to synthetic, and their toxic effects towards mammalian cells and tissue. Additionally, the types of toxic reactions associated with NPs and NSMs and the regulations implemented by different countries to reduce the associated risks are also discussed.


MRS Bulletin ◽  
1994 ◽  
Vol 19 (11) ◽  
pp. 43-49 ◽  
Author(s):  
Sumio Iijima

Nanostructured materials have recently attracted the attention of some materials scientists. Because of their unique properties occurring in low-dimensional structures, nanostructured materials are sought for their possible industrial applications. This article introduces a specific nanostructured material, the carbon nanorube—an extremely thin filaments of graphite considered to be a quasi one-dimensional structure, with a simple well-understood atomic structure. Because of these qualities, the carbon nanorube has elicited great interest from diverse fields of basic and technological research. My discovery of carbon nanotubes was inspired by the discovery of C60 and its family and their mass production. The carbon nanotubes were serendipitously found during the examination of fullerene materials by a high-resolution transmission electron microscope (HRTEM). Since introducing this technique in 1971, I have been employing HRTEM to characterize the microscopic structural details of a variety of materials, including carbonaceous materials. So far, only nanotubes have been revealed with HRTEM.Interest in the carbon nanorube is multifold. Academically the nanotube is an ideal model structure for a quasi one-dimensional structure since its known atomic structure makes computer simulations more reliable. It is worthwhile to study both rare structures of graphite—cylindrical forms with a helical arrangement of carbon atom hexagons and flexible graphitic sheets containing topological surface defects. These materials may find practical uses as tough graphite fibers, molecular wires, catalyst supports, molecular adsorbers, and so on.


2013 ◽  
Vol 829 ◽  
pp. 879-883 ◽  
Author(s):  
Mohammadjavad Mahdavinejad ◽  
Marzieh Nazari ◽  
Sina Khazforoosh

Ultrafine grained, nanostructured materials and other types of recombinant nanomaterials open new windows for future technology which make a revolutionary progress in key technologies such as chemistry, material sciences etc. Literature review of the paper shows that nanomaterials have a lot to do with building construction however there is not an influential relationship between usage of nanostructured materials and building industry. In the other word, commercialization and industrial applications of recombinant nanomaterials had yet to find its own role in contemporary architecture and the building construction industry. Therefore the most important question of the research is: what are the most important commercialization strategies regarding to industrial usage of nanomaterials in building construction? The results of the paper show that there is not a meaningful coherence between scientific researches and professional requirements. Moreover academic disciplines generally focus on theoretical era rather than professional fields. In order to make a more prosperous researches regarding to recombinant nanomaterials; should focus on 1-energy, 2-light, 3-security and 4-intelligence; as the most important commercialization strategies regarding to industrial usage of nanomaterials in building construction. Through these four determining strategies, nanomaterials may be adopted in coatings, panels and insulation in building construction; especially in partial requirements like roofs and facades, interior and exterior spaces.


Author(s):  
Liang Tian ◽  
Lin Li

Nanostructured materials, whose characteristic microstructure size is under 100 nm, can be either single-phase nanocrystalline materials or multi-phase nanocomposite materials. Nanocrystalline materials can also be treated as nanocomposites with grain interior as matrix and grain boundary as secondary phase. The strengthening models of nanostructured materials resemble those strengthening models of conventional composite structures, but have substantial deviations from conventional strengthening mechanisms due to their distinctive nanoscale structure and the complex hierarchy of their nanoscale microstructure. This paper reviewed the current progress in developments of strengthening models for nanostructured materials with emphasis on single-phase nanocrystalline and multiphase nanocomposite materials, which would help guide the design of new nanostructured materials and other similar nanoscale composite structures. Furthermore, practical large scale industrial applications of high strength nanostructured materials require these materials to possess decent formability, ductility or other functional properties to satisfy both structural and multifunctional applications. Therefore, the latest developments of novel nanostructured materials are discussed to highlight their potential of overcoming the strength ductility trade-off and strength-conductivity trade-off by various approaches. Their complex and distinctive nanoscale microstructure suggests the potential challenges and opportunities in developing new strengthening models for designing future advanced nanostructured materials with unprecedented properties.


Author(s):  
C. F. Oster

Although ultra-thin sectioning techniques are widely used in the biological sciences, their applications are somewhat less popular but very useful in industrial applications. This presentation will review several specific applications where ultra-thin sectioning techniques have proven invaluable.The preparation of samples for sectioning usually involves embedding in an epoxy resin. Araldite 6005 Resin and Hardener are mixed so that the hardness of the embedding medium matches that of the sample to reduce any distortion of the sample during the sectioning process. No dehydration series are needed to prepare our usual samples for embedding, but some types require hardening and staining steps. The embedded samples are sectioned with either a prototype of a Porter-Blum Microtome or an LKB Ultrotome III. Both instruments are equipped with diamond knives.In the study of photographic film, the distribution of the developed silver particles through the layer is important to the image tone and/or scattering power. Also, the morphology of the developed silver is an important factor, and cross sections will show this structure.


Author(s):  
W.M. Stobbs

I do not have access to the abstracts of the first meeting of EMSA but at this, the 50th Anniversary meeting of the Electron Microscopy Society of America, I have an excuse to consider the historical origins of the approaches we take to the use of electron microscopy for the characterisation of materials. I have myself been actively involved in the use of TEM for the characterisation of heterogeneities for little more than half of that period. My own view is that it was between the 3rd International Meeting at London, and the 1956 Stockholm meeting, the first of the European series , that the foundations of the approaches we now take to the characterisation of a material using the TEM were laid down. (This was 10 years before I took dynamical theory to be etched in stone.) It was at the 1956 meeting that Menter showed lattice resolution images of sodium faujasite and Hirsch, Home and Whelan showed images of dislocations in the XlVth session on “metallography and other industrial applications”. I have always incidentally been delighted by the way the latter authors misinterpreted astonishingly clear thickness fringes in a beaten (”) foil of Al as being contrast due to “large strains”, an error which they corrected with admirable rapidity as the theory developed. At the London meeting the research described covered a broad range of approaches, including many that are only now being rediscovered as worth further effort: however such is the power of “the image” to persuade that the above two papers set trends which influence, perhaps too strongly, the approaches we take now. Menter was clear that the way the planes in his image tended to be curved was associated with the imaging conditions rather than with lattice strains, and yet it now seems to be common practice to assume that the dots in an “atomic resolution image” can faithfully represent the variations in atomic spacing at a localised defect. Even when the more reasonable approach is taken of matching the image details with a computed simulation for an assumed model, the non-uniqueness of the interpreted fit seems to be rather rarely appreciated. Hirsch et al., on the other hand, made a point of using their images to get numerical data on characteristics of the specimen they examined, such as its dislocation density, which would not be expected to be influenced by uncertainties in the contrast. Nonetheless the trends were set with microscope manufacturers producing higher and higher resolution microscopes, while the blind faith of the users in the image produced as being a near directly interpretable representation of reality seems to have increased rather than been generally questioned. But if we want to test structural models we need numbers and it is the analogue to digital conversion of the information in the image which is required.


Author(s):  
M. José-Yacamán

Electron microscopy is a fundamental tool in materials characterization. In the case of nanostructured materials we are looking for features with a size in the nanometer range. Therefore often the conventional TEM techniques are not enough for characterization of nanophases. High Resolution Electron Microscopy (HREM), is a key technique in order to characterize those materials with a resolution of ~ 1.7A. High resolution studies of metallic nanostructured materials has been also reported in the literature. It is concluded that boundaries in nanophase materials are similar in structure to the regular grain boundaries. That work therefore did not confirm the early hipothesis on the field that grain boundaries in nanostructured materials have a special behavior. We will show in this paper that by a combination of HREM image processing, and image calculations, it is possible to prove that small particles and coalesced grains have a significant surface roughness, as well as large internal strain.


Author(s):  
C J R Sheppard

The confocal microscope is now widely used in both biomedical and industrial applications for imaging, in three dimensions, objects with appreciable depth. There are now a range of different microscopes on the market, which have adopted a variety of different designs. The aim of this paper is to explore the effects on imaging performance of design parameters including the method of scanning, the type of detector, and the size and shape of the confocal aperture.It is becoming apparent that there is no such thing as an ideal confocal microscope: all systems have limitations and the best compromise depends on what the microscope is used for and how it is used. The most important compromise at present is between image quality and speed of scanning, which is particularly apparent when imaging with very weak signals. If great speed is not of importance, then the fundamental limitation for fluorescence imaging is the detection of sufficient numbers of photons before the fluorochrome bleaches.


Author(s):  
R. T. Chen ◽  
R.A. Norwood

Sol-gel processing has been used to control the structure of a material on a nanometer scale in preparing advanced ceramics and glasses. Film coating using the sol-gel process was also found to be a viable process technology in applications such as optical, porous, antireflection and hard coatings. In this study, organically modified silicate (Ormosil) coatings are applied to PET films for various industrial applications. Sol-gel materials are known to exhibit nanometer scale structures which havepreviously been characterized by small-angle X-ray scattering (SAXS), neutron scattering and light scattering. Imaging of the ultrafine sol-gel structures has also been performed using an ultrahigh resolution replica/TEM technique. The objective of this study was to evaluate the ultrafine structures inthe sol gel coatings using a direct imaging technique: atomic force microscopy (AFM). In addition, correlation of microstructures with processing parameters, coating density and other physical properties will be discussed.The materials evaluated are organically modified silicate coatings on PET film substrates. Refractive index measurement by the prism coupling method was used to assess density of the sol-gel coating.AFM imaging was performed on a Nanoscope III AFM (by Digital Instruments) using constant force mode. Solgel coating samples coated with a thin layer of Ft (by ion beam sputtering) were also examined by STM in order to confirm the structures observed in the contact type AFM. In addition, to compare the previous results, sol-gel powder samples were also prepared by ultrasonication followed by Pt/Au shadowing and examined using a JEOL 100CX TEM.


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