Strong Concentration Enhancement of Molecules at the Interface of Aqueous Microdroplets

2020 ◽  
Vol 124 (44) ◽  
pp. 9938-9944
Author(s):  
Hanqing Xiong ◽  
Jae Kyoo Lee ◽  
Richard N. Zare ◽  
Wei Min
2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ji-wook Kim ◽  
Jie Wang ◽  
Hyungsub Kim ◽  
Seongtae Bae

AbstractMagnetic dipole coupling between the colloidal superparamagnetic nanoparticles (SPNPs) depending on the concentration has been paid significant attention due to its critical role in characterizing the Specific Loss Power (SLP) in magnetic nanofluid hyperthermia (MNFH). However, despite immense efforts, the physical mechanism of concentration-dependent SLP change behavior is still poorly understood and some contradictory results have been recently reported. Here, we first report that the SLP of SPNP MNFH agent shows strong concentration-dependent oscillation behavior. According to the experimentally and theoretically analyzed results, the energy competition among the magnetic dipole interaction energy, magnetic potential energy, and exchange energy, was revealed as the main physical reason for the oscillation behavior. Empirically demonstrated new finding and physically established model on the concentration-dependent SLP oscillation behavior is expected to provide biomedically crucial information in determining the critical dose of an agent for clinically safe and highly efficient MNFH in cancer clinics.


2019 ◽  
Vol 630 ◽  
pp. A90 ◽  
Author(s):  
Bertil Pettersson ◽  
Bo Reipurth

A deep objective-prism survey for Hα emission stars towards the Canis Major star-forming clouds was performed. A total of 398 Hα emitters were detected, 353 of which are new detections. There is a strong concentration of these Hα emitters towards the molecular clouds surrounding the CMa OB1 association, and it is likely that these stars are young stellar objects recently born in the clouds. An additional population of Hα emitters is scattered all across the region, and probably includes unrelated foreground dMe stars and background Be stars. About 90% of the Hα emitters are detected by WISE, of which 75% was detected with usable photometry. When plotted in a WISE colour–colour diagram it appears that the majority are Class II YSOs. Coordinates and finding charts are provided for all the new stars, and coordinates for all the detections. We searched the Gaia-DR2 catalogue and from 334 Hα emission stars with useful parallaxes, we selected a subset of 98 stars that have parallax errors of less than 20% and nominal distances in the interval 1050 to 1350 pc that surrounds a strong peak at 1185 pc in the distance distribution. Similarly, Gaia distances were obtained for 51 OB-stars located towards Canis Major and selected with the same parallax errors as the Hα stars. We find a median distance for the OB stars of 1182 pc, in excellent correspondence with the distance from the Hα stars. Two known runaway stars are confirmed as members of the association. Finally, two new Herbig-Haro objects are identified.


Author(s):  
Zhengwei Ge ◽  
Chun Yang

Microfluidic concentration of sample species is achieved using the temperature gradient focusing (TGF) in a microchannel with a step change in the cross-section under a pure direct current (DC) field or a combined alternating current (AC) and DC electric field. Experiments were carried out to study the effects of applied voltage, buffer concentration and channel size on sample concentration in the TGF processes. These effects were analyzed and summarized using a dimensionless Joule number that is introduced in this study. In addition, Joule number effect in the Poly-dimethylsiloxane (PDMS)/PDMS microdevice was compared with the PDMS/Glass microdevice. A more than 450-fold concentration enhancement was obtained within 75 seconds in the PDMS/PDMS microdevice. Results also showed that the high frequency AC electric field which contributes to produce the temperature gradient and reduces the required DC voltage for the sample concentration. The lower DC voltage has generated slower electroosmotic flow (EOF), which reduces the backpressure effect associated with the finite reservoir size. Finally, a more than 2500-fold concentration enhancement was obtained within 14 minutes in the PDMS/PDMS microdevice, which was a great achievement in this TGF technique using inherent Joule heating effects.


2011 ◽  
Vol 178-179 ◽  
pp. 421-426
Author(s):  
Jan Vobecký ◽  
Volodymyr Komarnitskyy ◽  
Vít Záhlava ◽  
Pavel Hazdra

Low-temperature diffusion of Cr, Mo, Ni, Pd, Pt, and V in silicon diodes is compared in the range 450 - 800 oC. Before the diffusion, the diodes were implanted with high-energy He2+ to assess, if the radiation defects enhance the concentration of metal atoms at electrically active sites and what is the application potential for carrier lifetime control. The devices were characterized using AES, XPS, DLTS, OCVD carrier lifetime and diode electrical parameters. The metal atoms are divided into two groups. The Pt, Pd and V form deep levels in increased extent at the presence of radiation defects above 600 oC, which reduces the excess carrier lifetime. It is shown as a special case that the co-diffusion of Ni and V from a NiV surface layer results fully in the concentration enhancement of the V atoms. The enhancement of the acceptor level V-/0 (EC 0.203 eV) and donor level V0/+ (EC 0.442 eV) resembles the behavior of substitutional Pts. The second group is represented by the Mo and Cr. They easily form oxides, which can make their diffusion into a bulk more difficult or impossible. Only a slight enhancement of the Cr-related deep levels by the radiation defects has been found above 700 oC.


2016 ◽  
Vol 37 (5Supl2) ◽  
pp. 3625 ◽  
Author(s):  
Willian Vilela Rocha ◽  
Valéria De Sá Jayme ◽  
Ana Lourdes Arrais de Alencar Mota ◽  
Wilia Marta Elsner Diederichsen de Brito ◽  
Glauciane Ribeiro de Castro Pires ◽  
...  

Bovine tuberculosis results in economic losses in livestock production and poses a risk to public health. This study aimed to characterize the epidemiological status of bovine tuberculosis in adult cows in the state of Goiás, Brazil. The state was divided into three sampling strata, corresponding to different livestock production circuits. A total of 18,659 animals were tested with the comparative cervical tuberculin test (CCT), in 300 randomly sampled bovine herds per stratum. An epidemiological questionnaire was used to identify health and management practices that may be associated with the presence of tuberculosis infection in the herd. In Stratum 1, dominated by beef cattle, no animals reacted to the CCT. In Stratum 2, which covers the main dairy regions of the state, the prevalence was estimated at 8.67% [5.73 to 12.74%] for herds and at 0.9% [0.21 to 1.58%] for animals. In Stratum 3, characterized by a mix of dairy, beef and dual-purpose herds, the prevalence was estimated at 1.00% [0.21 to 2.89] for herds and 0.30% [0.10 to 0.49 %] for animals. The overall prevalence in the state of Goiás was 3.43% [2.20 to 4.67%] for herds and 0.30% [0.10 to 0.49%] for animals. The multiple logistic regression analysis revealed that herd-level risk factors associated with the presence of the bovine tuberculosis are: the location of the herd in Stratum 2 (OR = 12.05 [3.52 to 41.28]) and the number of times a cow is milked per day (OR = 6.27 [2.72 to 14.44]). Regular veterinary care was identified as a protective factor (OR = 0.38 [0.15-0.94]). These results indicate that bovine tuberculosis is endemic in the state; its spatial distribution is heterogeneous with a strong concentration in dairy regions. The most intensive dairy farms are those with the highest risk, which is consistent with what other authors’ found elsewhere in Brazil. The epidemiological information generated by this study provides information for planning of risk-based surveillance actions, and justifies the adoption of free-herd certification programs for bovine tuberculosis in the main dairy regions of Goiás.


2005 ◽  
Vol 85 (2) ◽  
pp. 87-96 ◽  
Author(s):  
Dragana Matijevic

Principles of modern development of settlements are taking place under the strong influence of great urban agglomerations. Belgrade and its gravitational role have triggered huge spatial and populational changes with distinctive differences within its metropolitan area. In northern parts of Belgrade functional zone, there are zones of strong concentration of population and economy, as opposed to southern parts, where depopulation and dissection of economy and activities are present. As a part of Belgrade functional area, settlements network of Ljig municipality has been subject to considerable urban-geographic changes. This paper gives the analysis of all changes in settlements network which occurred as a consequence of gravitational impacts of the capital.


2017 ◽  
Vol 62 (25) ◽  
pp. 2941-2950 ◽  
Author(s):  
LiPing LEI ◽  
Hui ZHONG ◽  
ZhongHua HE ◽  
BoFeng CAI ◽  
ShaoYuan YANG ◽  
...  

2017 ◽  
Vol 44 ◽  
Author(s):  
Patrick-Yves Badillo ◽  
Dominique Bourgeois

Switzerland is a country where the press is key. Democracy is at the heart of the Swiss press, characterized by multilingualism, diversity of the press and a long tradition of newspapers readership. But the paid-for daily printed press has been faced with a crisis for the last decade with the development of the free press, the rise of Internet and a decline in advertising revenues. Consequently, the Swiss press model is evolving. With the help of various indicators, this paper highlights an increasingly strong concentration of the Swiss daily press between 2005 and 2014. Moreover, it analyses the strategies of the two main Swiss press groups, Tamedia and Ringier, towards profitable digital diversification. It shows that the Swiss press remains strong, contrarily to the French press, for example. Thus, the evolution of the Swiss press model is illustrative of a new economic model. However, the paper also emphasizes that the Swiss press is now faced with increasing competition from the world digital leaders, such as Google and Facebook. 


2015 ◽  
Vol 7 (2) ◽  
pp. 105-117
Author(s):  
Lizette Brenes Bonilla ◽  
Ligia Bermúdez Mesén ◽  
Carlos Andrés Campos Vargas

Poverty in Costa Rican has been analyzed from different perspectives for many years, however, the study of current behavior requires innovative approaches. We used detailed official maps to visualize relationships among business density, poverty, higher education and technological connectivity. We found a strong concentration of entrepreneur capacity in the Great Metropolitan Area around the capital, which has more than half of the country’s population in only 4% of the country’s territory. There is no entrepreneurial coordination among provinces and the greatest inequalities occur in the province of Heredia. Areas with less businesses are the poorest in the country and this needs to be addressed by national policies.


Author(s):  
Jean-François Gravel ◽  
Martin Allard ◽  
François Babin ◽  
François Chateauneuf ◽  
Eric Bergeron

While natural gas pipelines already benefit from airborne, remote detection of leaks [1, 2], oil pipeline leak detection has been for a long time reliant on SCADA systems limited in their capability to detect very small leaks, and/or visual inspection of the right of way (line flyers, pipeline employees or members of the public). This paper presents a novel and complementary way of detecting small leaks (i.e. sensitivity of 0.1 L/minute, 1 barrel/day) of oil (crude or refined products) using an optical detection system mounted on an airborne platform (UAV, plane or helicopter). The scope of this paper is based on the requirements provided by TransCanada, namely sensitivity (herein referred as LOD — Limit of Detection) and accuracy (herein referred as spatial resolution) as similar to their description in API 1130, while the topic of reliability is addressed in our noted concerns on the false alarms that may be generated in Infrared-DiAL based systems due to soil reflectivity. Robustness, as described in API 1130, was out of scope. Keeping in mind the requirement of airborne operation, three different approaches for the detection of leaks along long pipeline ROWs were studied. Infrared Differential Absorption lidar (IR-DiAL), UltraViolet Raman lidar (UV-Raman lidar) and UltraViolet Laser-Induced Fluorescence lidar (UV-LIF lidar) have been tested in realistic conditions. In the first round of tests, laboratory spectral measurements of vapors in a closed cell were performed. In the second round of tests, the breadboards were placed in a mobile laboratory and the light beams aimed at a large open at 40 to 50 meters and reflected off a sand target. Finally, the mobile laboratory with the breadboards was installed at ∼40 meters from a leak simulator. The leak simulator was made by using a large sand container in which petroleum products were leaked. Intermediate scale leak simulator tests showed that it is clearly a challenge to correlate a measured concentration to an actual leak size. Tests have also shown that there is a strong concentration gradient in the air above a leak. This indicates that a better overall detection performance should be obtained with a measurement using the air next to the ground, and that it is feasible to detect a leak of less than 1 barrel/day. UV-Raman tests performed in the outdoors suggested a Limit Of Detection (LOD) of the system below 1 500 ppm-m when detecting all hydrocarbons. Because of the hardware that would be needed to lower this detection limit, results suggest abandoning the Raman technique for remote leak detection from an airborne platform. IR-DiAL showed the best sensitivity for the detection of hydrocarbons (< 1 ppm-m of LOD). However the effective LOD will be reduced because of the soil spectral reflectance variations that may lead to a high false alarm rate for concentrations of hydrocarbons lower than 235 ppm-m. The UV-absorption approach was also briefly tested, suggesting a LOD for benzene of between 1.5 and 2.5 ppm-m. The UV absorption of benzene is not affected by ground spectral reflectance variations. This is an approach that will be investigated further.


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