scholarly journals Facile and low-cost synthesis of pure hematite (α-Fe2O3) nanoparticles from naturally occurring laterites and their superior adsorption capability towards acid-dyes

RSC Advances ◽  
2019 ◽  
Vol 9 (37) ◽  
pp. 21249-21257 ◽  
Author(s):  
D. M. S. N. Dissanayake ◽  
M. M. M. G. P. G. Mantilaka ◽  
T. C. Palihawadana ◽  
G. T. D. Chandrakumara ◽  
R. T. De Silva ◽  
...  

High purity hematite nanoparticles have been synthesized by a facile method using naturally occurring laterites for industrial dye effluent treatment applications.

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1003
Author(s):  
Pantharee Kongsat ◽  
Sakprayut Sinthupinyo ◽  
Edgar A. O’Rear ◽  
Thirawudh Pongprayoon

Several types of hematite nanoparticles (α-Fe2O3) have been investigated for their effects on the structure and properties of fly ash (FA) blended cement. All synthesized nanoparticles were found to be of spherical shape, but of different particle sizes ranging from 10 to 195 nm depending on the surfactant used in their preparation. The cement hydration with time showed 1.0% α-Fe2O3 nanoparticles are effective accelerators for FA blended cement. Moreover, adding α-Fe2O3 nanoparticles in FA blended cement enhanced the compressive strength and workability of cement. Nanoparticle size and size distribution were important for optimal filling of various size of pores within the cement structure.


Author(s):  
Robyn E. Wootton ◽  
Hannah J. Jones ◽  
Hannah M. Sallis

AbstractThe successful prevention of mental illness relies upon the identification of causal, modifiable risk factors. However, observational evidence exploring such risk factors often produces contradictory results and randomised control trials are often expensive, time-consuming or unethical to conduct. Mendelian randomisation (MR) is a complementary approach that uses naturally occurring genetic variation to identify possible causal effects between a risk factor and an outcome in a time-efficient and low-cost manner. MR utilises genetic variants as instrumental variables for the risk factor of interest. MR studies are becoming more frequent in the field of psychiatry, warranting a reflection upon both the possibilities and the pitfalls. In this Perspective, we consider several limitations of the MR method that are of particular relevance to psychiatry. We also present new MR methods that have exciting applications to questions of mental illness. While we believe that MR can make an important contribution to the field of psychiatry, we also wish to emphasise the importance of clear causal questions, thorough sensitivity analyses, and triangulation with other forms of evidence.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Yan Sang ◽  
Xi Cao ◽  
Gaofei Ding ◽  
Zixuan Guo ◽  
Yingying Xue ◽  
...  

Electrolysis of water to produce high-purity hydrogen is a very promising method. The development of green, high-efficiency, long-lasting and low-cost dual function electrocatalysts for oxygen evolution reaction (OER) and hydrogen...


1995 ◽  
Vol 22 (1) ◽  
pp. 106-120
Author(s):  
Roberto M. Narbaitz ◽  
Frances Z. Parsons ◽  
Tsong-Yih Tzeng

Point-of-entry systems with granular activated carbon filters have been used extensively to provide safe water to rural homes with wells contaminated with synthetic organic chemicals. Because of the low cost of these systems, their design is generally based on the equilibrium column model, the isotherm data from the literature, and a scale-up factor. This paper analyzes the necessary scale-up factors for point-of-entry adsorbers based on fumigant adsorption data gathered through an extensive literature review. The fumigants evaluated are 1,2-dichloropropane, 1,2-dibromo-3-chloropropane, and ethylene dibromide. It was impossible to thoroughly assess the scale-up factors for 1,2-dichloropropane because of the limited data. Column data for the other two fumigants were sufficient to generate column loading lines, which can be used directly without resorting to scale-up factors. Column data showed that the scale-up factors are greatly affected by competitive adsorption with the naturally occurring background organic matter and by preloading of these organic matter. As these phenomena are not well understood, it is presently impossible to accurately predict the appropriate scale-up factors. A recommended design approach is outlined. Key words: adsorption, activated carbon, fumigants, point-of-entry.


2019 ◽  
Vol 45 (3) ◽  
pp. 3101-3110 ◽  
Author(s):  
Shuaibo Gao ◽  
Xin Li ◽  
Shuai Wang ◽  
Pengfei Xing ◽  
Jian kong ◽  
...  

Author(s):  
Ke Xue ◽  
Shuyi Lv ◽  
Chunlei Zhu

Naturally-occurring saturated fatty acids (NSFAs) have emerged as a class of promising biomaterials due to their low cost, chemical stability, well-defined melting points, large heat of fusion, reversible solid-liquid phase...


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Hakan Çelebi ◽  
Gülden Gök ◽  
Oğuzhan Gök

Abstract Recently, the search for low-cost eco-friendly adsorbents has become one of the main objectives of researchers. The aim of this study was to test the removal of four heavy metals, namely lead (Pb), zinc (Zn), nickel (Ni) and cadmium (Cd), from a simulated watery solution using brewed tea waste as a potentially suitable adsorbent. The effects of pH levels (2.0–6.0), adsorbent amount (0.1–5.0 g), contact times (1–150 min.) were examined throughout the adsorption process. The results of the experiments showed that the heavy metals elimination yields had an inverse relationship with pH and a linear relationship between the other parameters. The optimum pH for the removal of the heavy metals was between 4.0 and 5.0 in the case of the brewed tea waste. Equilibrium times of 2, 10, 30 and 5 min were required for the adsorption of Pb, Zn, Ni, Cd onto Camellia sinensis, respectively. Based on the results of this study it can be said that brewed tea waste has a high potential to remove heavy metals from aqueous solutions. The maximum adsorption capacities were calculated as 1.197, 1.457, 1.163 and 2.468 mg/g, for Pb, Zn, Ni and Cd, respectively, by fitting the equilibrium data to the Langmuir isotherm model.


2020 ◽  
Vol 200 ◽  
pp. 110744 ◽  
Author(s):  
Hengli Xiang ◽  
Genkuan Ren ◽  
Xiushan Yang ◽  
Dehua Xu ◽  
Zhiye Zhang ◽  
...  

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2308 ◽  
Author(s):  
Kefeng Pan ◽  
Ying Li ◽  
Jiawei Zhang ◽  
Qing Zhao

As one of the critical raw materials, very pure gallium is important for the semiconductor and photoelectric industry. Unfortunately, refining gallium to obtain a purity that exceeds 99.99999% is very difficult. In this paper, a new, facile and efficient continuous partial recrystallization method to prepare gallium of high purity is investigated. Impurity concentrations, segregation coefficients, and the purification effect were measured. The results indicated that the contaminating elements accumulated in the liquid phase along the crystal direction. The order of the removal ratio was Cu > Mg > Pb > Cr > Zn > Fe. This corresponded to the order of the experimentally obtained segregation coefficients for each impurity: Cu < Mg < Pb < Cr < Zn < Fe. The segregation coefficient of the impurities depended strongly on the crystallization rate. All observed impurity concentrations were substantially reduced, and the purity of the gallium obtained after our refinement exceeded 99.99999%.


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