scholarly journals Water-rock interaction of the Jilh and Tawil aquifers in the Wadi Sirhan Basin, NW Saudi Arabia

2019 ◽  
Vol 98 ◽  
pp. 01047
Author(s):  
Fahad Souid ◽  
Peter Birkle ◽  
Fred Worrall
Keyword(s):  
Saudi Arabia ◽  
Host Rock ◽  
Principal Component ◽  
Chemical Constituent ◽  
Elemental Abundance ◽  
Rock Interaction ◽  
Rock Samples ◽  
Reducing Conditions ◽  
Groundwater Samples ◽  
Host Rocks

A total of 79 groundwater samples from the Upper Silurian-Lower Devonian Tawil and Triassic Jilh aquifers in NW Saudi Arabia were analysed for hydrochemical and strontium isotopic composition. A sequential extraction and 87Sr/86Sr analysis were conducted on 32 cutting samples from the groundwater host rocks and the underlying shale bed. The chemical composition of the groundwater was distinct from that of the host rock lithologies in terms of elemental abundance (i.e., Na+ was dominant in the groundwater and K and Ca were the main constituents of the aquifer units). Principal component analysis (PCA) of water samples showed a positive loading of Na+ and negative loadings of Ca2+ and SO42-. The replacement of gypsiferous waters by Na+-rich waters is suggested by this ion exchange. The shale rock samples showed Na to be the dominant chemical constituent. 87Sr/86Sr ratios of the groundwater (0.707673-0.711577) and host rock samples (0.707930-0.712477) suggest that groundwater inherits the Sr signature of the rock from the exchangeable, carbonate, and the oxides phase, reflecting reducing conditions in Tawil aquifer. The elevated groundwater 87Sr/86Sr ratios were found in deeper sections of the aquifers, which coincided with the radiogenic 87Sr/86Sr of the deeper aquifer lithologies and the underlying shale bed.

scholarly journals Characterizing mineralogy and redox reactivity in potential host rocks for a UK geological disposal facility

2015 ◽  
Vol 79 (6) ◽  
pp. 1353-1367 ◽  
Author(s):  
J. Quirke ◽  
C. M. B. Henderson ◽  
R. A. D. Pattrick ◽  
K. M. Rosso ◽  
A. Dent ◽  
...  
Keyword(s):  
Iron Content ◽  
Host Rock ◽  
Azo Dye ◽  
Total Iron ◽  
Geological Disposal ◽  
Potential Host ◽  
Fine Grained ◽  
Reducing Conditions ◽  
Redox Reactivity ◽  
Host Rocks

AbstractGeological disposal facilities (GDF) are intended to isolate and contain radioactive waste within multiple protective barriers, deep underground, to ensure that no harmful quantities of radioactivity reach the surface environment. The last line of defense in a multi-barrier GDF is the geosphere, where iron is present in the host rock mineralogy as either Fe(II) or Fe(III), and in groundwater as Fe(II) under reducing conditions. The mobility of risk-driving radionuclides, including uranium and technetium, in the environment is affected significantly by their valence state. Due to its low redox potential, Fe(II) can mediate reduction of these radionuclides from their oxidized, highly mobile, soluble state to their reduced, insoluble state, preventing them from reaching the biosphere. Here a study of five types of potential host rocks, two granitoids, an andesite, a mudstone and a clay-rich carbonate, is reported. The bulk rocks and their minerals were analysed for iron content, Fe(II/III) ratio, and for the speciation and fine-grained nature of alteration product minerals that might have important controls on groundwater interaction. Total iron content varies between 0.9% in clays to 5.6% in the andesite. X-ray absorption spectroscopy reveals that Fe in the granitoids and andesite is predominantly Fe(II), and in mudstones, argillaceous limestone and terrestrial sandstone is predominantly Fe(III). The redox reactivity of the potential host rocks both in the presence and absence of Fe(II)-containing 'model' groundwater was investigated using an azo dye as a probe molecule. Reduction rates as determined by reactivity with the azo dye were correlated with the ability of the rocks to uptake Fe(II) from groundwater rather than with initial Fe(II) content. Potential GDF host rocks must be characterized in terms of mineralogy, texture, grain size and bulk geochemistry to assess how they might interact with groundwater. This study highlights the importance of redox reactivity, not just total iron and Fe(II)/(III) ratio, when considering the host rock performance as a barrier material to limit transport of radionuclides from the GDF.

scholarly journals Water quality assessment and geochemical processes in the unconfined coastal Boa Viagem Aquifer, Recife, NE Brazil

2021 ◽  
pp. 56-77
Author(s):  
Thyego Silva ◽  
Mariucha Lima ◽  
Teresa Leitão ◽  
Tiago Martins ◽  
Mateus Albuquerque
Keyword(s):  
Water Quality ◽  
Quality Assessment ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Water Quality Assessment ◽  
Multivariate Statistical Analyses ◽  
Multivariate Statistical ◽  
Rock Interaction ◽  
Groundwater Samples ◽  
Water Rock Interaction

A hydrochemical study was conducted on the Quaternary Aquifer, in Recife, Brazil. Groundwater samples were collected in March–April 2015, at the beginning of the rainy season. Conventional graphics, ionic ratios, saturation indices, GIS mapping, and geostatistical and multivariate statistical analyses were used to water quality assessment and to characterize the main hydrochemical processes controlling groundwater’s chemistry. Q-mode hierarchical cluster analysis separated the samples into three clusters and five sub-clusters according to their hydrochemical similarities and facies. Principal Component Analysis (PCA) was employed to the studied groundwater samples where a three-factor model explains 80% of the total variation within the dataset. The PCA results revealed the influence of seawater intrusion, water-rock interaction, and nitrate contamination. The physico-chemical parameters of ~30% groundwaters exceed the World Health Organization (WHO) guidelines for drinking water quality. Nitrate was found at a concentration >10 mg NO3−/L in ~21% of the wells and exceeded WHO reference values in one. The integrated approach indicates the occurrence of the main major hydrogeochemical processes occurring in the shallow marine to alluvial aquifer as follow: 1) progressive freshening of remaining paleo-seawater accompanying cation exchange on fine sediments, 2) water-rock interaction (i.e., dissolution of silicates), and 3) point and diffuse wastewater contamination, and sulfate dissolution. This study successfully highlights the use of classical geochemical methods, GIS techniques, and multivariate statistical analyses (hierarchical cluster and principal component analyses) as complementary tools to understand hydrogeochemical processes and their influence on groundwater quality status to management actions, which could be used in similar alluvial coastal aquifers.

scholarly journals A micro X-ray computed tomography dataset of fossil echinoderms in an ancient obrution bed: a robust method for taphonomic and palaeoecologic analyses

GigaScience ◽  
2018 ◽  
Vol 8 (3) ◽  
Author(s):  
Mhairi Reid ◽  
Emese M Bordy ◽  
Wendy L Taylor ◽  
Stephan G le Roux ◽  
Anton du Plessis
Keyword(s):  
Host Rock ◽  
Three Dimensional ◽  
Rock Samples ◽  
3D Space ◽  
Depositional Processes ◽  
Mechanical Preparation ◽  
Minimal Damage ◽  
X Ray Computed ◽  
Scan Data ◽  
Host Rocks

Abstract Background Taphonomic and palaeoecologic studies of obrution beds often employ conventional methods of investigation such as physical removal and extraction of fossils from their host rock (matrix) by mechanical preparation. This often-destructive method is not suitable for studying mold fossils, which are voids left in host rocks due to dissolution of the original organism in post-depositional processes. Findings Microcomputed tomography (µCT) scan data of 24 fossiliferous rock samples revealed thousands of Paleozoic echinoderms. Digitally "stitching" together individually µCT scanned rock samples within three-dimensional (3D) space allows for quantifiable taphonomic data on a fossil echinoderm-rich obrution deposit from the Devonian (Emsian) of South Africa. Here, we provide a brief step-by-step guide on creating, segmenting, and ultimately combining sections of richly fossiliferous beds to create virtual models suited for the quantitative and qualitative taphonomic analyses of fossil invertebrate assemblages. Conclusions Visualizing the internal features of fossiliferous beds in 3D is an invaluable taphonomic tool for analyzing delicate fossils, accounting for all specimens irrespective of their preservation stages and with minimal damage. This technique is particularly useful for analyzing fossiliferous deposits with mold fossils that prove to be difficult to study with traditional methods, because the method relies on the large density contrast between the mold and host rock.

scholarly journals Groundwater quality variations in Precambrian hard rock aquifers: a case study from Kerala, India

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
P. Nandakumaran ◽  
K. Balakrishnan
Keyword(s):  
Groundwater Quality ◽  
Analytical Data ◽  
Principal Component ◽  
Anthropogenic Sources ◽  
Exchange Reactions ◽  
Rock Interaction ◽  
Fractured Aquifers ◽  
Groundwater Samples ◽  
Hard Rock Aquifers ◽  
Hydrochemical Composition

Abstract Analytical data of groundwater samples collected from weathered and deep fractured zones in the Precambrian charnockite aquifers in Kerala, India, have been studied to understand their hydrochemical variations and reasons thereof. Concentrations of the majority of the constituents analyzed were found to increase with increasing depth of aquifers, with the exception of nitrate. Studies indicate that various processes such as ion exchange reactions, carbonate weathering and silicate weathering are active in both the aquifers which influence the hydrochemical composition of groundwater in them. The prevailing groundwater quality in the aquifers is dependent on the dominance of each process in relation to others. Principal component analysis of the data suggests that contamination from anthropogenic sources has a major role in determining the hydrochemical characteristics of groundwater in the weathered zone unlike in the case of fractured aquifers where water–rock interaction is the major factor responsible. The study also indicates limited hydraulic connection between the weathered and fractured aquifers at the local scale.

scholarly journals Magma Mixing Genesis of the Mafic Enclaves in the Qingshanbao Complex of Longshou Mountain, China: Evidence from Petrology, Geochemistry, and Zircon Chronology

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 195 ◽  
Author(s):  
Wenheng Liu ◽  
Xiaodong Liu ◽  
Jiayong Pan ◽  
Kaixing Wang ◽  
Gang Wang ◽  
...  
Keyword(s):  
Host Rock ◽  
Inductively Coupled Plasma ◽  
Magma Mixing ◽  
Coarse Grained ◽  
Calc Alkaline ◽  
Quartz Crystals ◽  
Alkaline Rocks ◽  
Mafic Enclaves ◽  
Normal Zoning ◽  
Host Rocks

The Qingshanbao complex, part of the uranium metallogenic belt of the Longshou-Qilian mountains, is located in the center of the Longshou Mountain next to the Jiling complex that hosts a number of U deposits. However, little research has been conducted in this area. In order to investigate the origin and formation of mafic enclaves observed in the Qingshanbao body and the implications for magmatic-tectonic dynamics, we systematically studied the mineralogy, petrography, and geochemistry of these enclaves. Our results showed that the enclaves contain plagioclase enwrapped by early dark minerals. These enclaves also showed round quartz crystals and acicular apatite in association with the plagioclase. Electron probe analyses showed that the plagioclase in the host rocks (such as K-feldspar granite, adamellite, granodiorite, etc.) show normal zoning, while the plagioclase in the mafic enclaves has a discontinuous rim composition and shows instances of reverse zoning. Major elemental geochemistry revealed that the mafic enclaves belong to the calc-alkaline rocks that are rich in titanium, iron, aluminum, and depleted in silica, while the host rocks are calc-alkaline to alkaline rocks with enrichment in silica. On Harker diagrams, SiO2 contents are negatively correlated with all major oxides but K2O. Both the mafic enclaves and host rock are rich in large ion lithophile elements such as Rb and K, as well as elements such as La, Nd, and Sm, and relatively poor in high field strength elements such as Nb, Ta, P, Ti, and U. Element ratios of Nb/La, Rb/Sr, and Nb/Ta indicate that the mafic enclaves were formed by the mixing of mafic and felsic magma. In terms of rare earth elements, both the mafic enclaves and the host rock show right-inclined trends with similar weak to medium degrees of negative Eu anomaly and with no obvious Ce anomaly. Zircon LA-ICP-MS (Laser ablation inductively coupled plasma mass spectrometry) U-Pb concordant ages of the mafic enclaves and host rock were determined to be 431.8 5.2 Ma (MSWD (mean standard weighted deviation)= 1.5, n = 14) and 432.8 4.2 Ma (MSWD = 1.7, n = 16), respectively, consistent with that for the zircon U-Pb ages of the granite and medium-coarse grained K-feldspar granites of the Qingshanbao complex. The estimated ages coincide with the timing of the late Caledonian collision of the Alashan Block. This comprehensive analysis allowed us to conclude that the mafic enclaves in the Qingshanbao complex were formed by the mixing of crust-mantle magma with mantle-derived magma due to underplating, which caused partial melting of the ancient basement crust during the collisional orogenesis between the Alashan Block and Qilian rock mass in the early Silurian Period.

scholarly journals High-Arsenic Groundwater in Paleochannels of the Lower Yellow River, China: Distribution and Genesis Mechanisms

Water ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 338
Author(s):  
Chuanshun Zhi ◽  
Wengeng Cao ◽  
Zhen Wang ◽  
Zeyan Li
Keyword(s):  
Yellow River ◽  
The Yellow River ◽  
Rock Interaction ◽  
Lower Yellow River ◽  
The Lower Yellow River ◽  
Groundwater Samples ◽  
Groundwater Systems ◽  
Different Sources ◽  
High Arsenic ◽  
High Arsenic Groundwater

High–arsenic (As) groundwater poses a serious threat to human health. The upper and middle reaches of the Yellow River are well–known areas for the enrichment of high–arsenic groundwater. However, little is known about the distribution characteristics and formation mechanism of high-As groundwater in the lower reach of the Yellow River. There were 203 groundwater samples collected in different groundwater systems of the lower Yellow River for the exploration of its hydrogeochemical characteristics. Results showed that more than 20% of the samples have arsenic concentrations exceeding 10 μg/L. The high-As groundwater was mainly distributed in Late Pleistocene–Holocene aquifers, and the As concentrations in the paleochannels systems (C2 and C4) were significantly higher than that of the paleointerfluve system (C3) and modern Yellow River affected system (C5). The high-As groundwater is characterized by high Fe2+ and NH4+ and low Eh and NO3−, indicating that reductive dissolution of the As–bearing iron oxides is probably the main cause of As release. The arsenic concentrations strikingly showed an increasing tendency as the HCO3− proportion increases, suggesting that HCO3− competitive adsorption may facilitate As mobilization, too. In addition, a Gibbs diagram showed that the evaporation of groundwater could be another significant hydrogeochemical processes, except for the water–rock interaction in the study area. Different sources of aquifer medium and sedimentary structure may be the main reasons for the significant zonation of the As spatial distribution in the lower Yellow River.

Compositional variation in the chevkinite group: new data from igneous and metamorphic rocks

2009 ◽  
Vol 73 (5) ◽  
pp. 777-796 ◽  
Author(s):  
R. Macdonald ◽  
H. E. Belkin ◽  
F. Wall ◽  
B. Baginski
Keyword(s):  
Electron Microprobe ◽  
Host Rock ◽  
Metamorphic Rocks ◽  
Compositional Variation ◽  
Temperature Range ◽  
Wide Range ◽  
Host Rocks ◽  
Cation Sites ◽  
Dominant Cation

AbstractElectron microprobe analyses are presented of chevkinite-group minerals from Canada, USA, Guatemala, Norway, Scotland, Italy and India. The host rocks are metacarbonates, alkaline and subalkaline granitoids, quartz-bearing pegmatites, carbonatite and an inferred K-rich tuff. The analyses extend slightly the range of compositions in the chevkinite group, e.g. the most MgO-rich phases yet recorded, and we report two further examples where La is the dominant cation in the A site. Patchily- zoned crystals from Virginia and Guatemala contain both perrierite and chevkinite compositions. The new and published analyses are used to review compositional variation in minerals of the perrierite subgroup, which can form in a wide range of host rock compositions and over a substantial pressure- temperature range. The dominant substitutions in the various cation sites and a generalized substitution scheme are described.

Competence and lithostratigraphy of host rocks govern kimberlite pipe morphology

2018 ◽  
Vol 55 (2) ◽  
pp. 130-137
Author(s):  
David E. Newton ◽  
Amy G. Ryan ◽  
Luke J. Hilchie
Keyword(s):  
Host Rock ◽  
Sedimentary Rock ◽  
Kimberlite Pipe ◽  
Crystalline Rock ◽  
Experimental Results ◽  
Compressed Air ◽  
Unconsolidated Sediments ◽  
Final Shape ◽  
Class 1 ◽  
Host Rocks

We use analogue experimentation to test the hypothesis that host rock competence primarily determines the morphology of kimberlite pipes. Natural occurrences of kimberlite pipes are subdivided into three classes: class 1 pipes are steep-sided diatremes emplaced into crystalline rock; class 2 pipes have a wide, shallow crater emplaced into sedimentary rock overlain by unconsolidated sediments; class 3 pipes comprise a steep-sided diatreme with a shallow-angled crater emplaced into competent crystalline rock overlain by unconsolidated sediments. We use different configurations of three analogue materials with varying cohesions to model the contrasting geological settings observed in nature. Pulses of compressed air, representing the energy of the gas-rich head of a kimberlitic magma, are used to disrupt the experimental substrate. In our experiments, the competence and configuration of the analogue materials control the excavation processes as well as the final shape of the analogue pipes: eruption through competent analogue strata results in steep-sided analogue pipes; eruption through weak analogue strata results in wide, shallow analogue pipes; eruption through intermediate strength analogue strata results in analogue pipes with a shallow crater and a steep-sided diatreme. These experimental results correspond with the shapes of natural kimberlite pipes, and demonstrate that variations in the lithology of the host rock are sufficient to generate classic kimberlite pipe shapes. These findings are consistent with models that ascribe the pipe morphologies of natural kimberlites to the competence of the host rocks in which they are emplaced.

scholarly journals Heavy minerals in the Wajid Sandstone from Abha-Khamis Mushayt area, southwestern Saudi Arabia: implications on provenance and regional tectonic setting

GeoArabia ◽  
2004 ◽  
Vol 9 (4) ◽  
pp. 77-102 ◽  
Author(s):  
Mahbub Hussain ◽  
Lameed O. Babalola ◽  
Mustafa M. Hariri
Keyword(s):  
Saudi Arabia ◽  
Tectonic Setting ◽  
Principal Component ◽  
Heavy Mineral ◽  
Heavy Minerals ◽  
Coarse Grained ◽  
Distribution Data ◽  
The South ◽  
Quartz Content ◽  
The North

ABSTRACT The Wajid Sandstone (Ordovician-Permian) as exposed along the road-cut sections of the Abha and Khamis Mushayt areas in southwestern Saudi Arabia, is a mediun to coarse-grained, mineralogically mature quartz arenite with an average quartz content of over 95%. Monocrystalline quartz is the dominant framework grain followed by polycrystalline quartz, feldspar and micas. The non-opaque heavy mineral assemblage of the sandstone is dominated by zircon, tourmaline and rutile (ZTR). Additional heavy minerals, constituting a very minor fraction of the heavies, include epidote, hornblende, and kyanite. Statistical analysis showed significant correlations between zircon, tourmaline, rutile, epidote and hornblende. Principal component R-mode varimax factor analysis of the heavy mineral distribution data shows two strong associations: (1) tourmaline, zircon, rutile, and (2) epidote and hornblende suggesting several likely provenances including igneous, recycled sedimentary and metamorphic rocks. However, an abundance of the ZTR minerals favors a recycled sedimentary source over other possibilities. Mineralogical maturity coupled with characteristic heavy mineral associations, consistent north-directed paleoflow evidence, and the tectonic evolutionary history of the region indicate a provenance south of the study area. The most likely provenances of the lower part (Dibsiyah and Khusayyan members) of the Wajid Sandstone are the Neoproterozoic Afif, Abas, Al-Bayda, Al-Mahfid, and Al-Mukalla terranes, and older recycled sediments of the infra-Cambrian Ghabar Group in Yemen to the south. Because Neoproterozic (650-542 Ma) rocks are not widespread in Somalia, Eritrea and Ethiopia, a significant source further to the south is not likely. The dominance of the ultrastable minerals zircon, tourmaline and rutile and apparent absence of metastable, labile minerals in the heavy mineral suite preclude the exposed arc-derived oceanic terrains of the Arabian Shield in the west and north as a significant contributor of the sandstone. An abundance of finer-grained siliciclastic sequences of the same age in the north, is consistent with a northerly transport direction and the existence of a deeper basin (Tabuk Basin?) to the north. The tectonic and depositional model presented in this paper differs from the existing model that envisages sediment transportation and gradual basin filling from west to east during the Paleozoic.

scholarly journals Radiological characterization of the phosphate deposit in Al-Jalamid phosphate mining area, Saudi Arabia

Nukleonika ◽  
2021 ◽  
Vol 66 (1) ◽  
pp. 35-44
Author(s):  
Abdulsalam M. Alhawsawi ◽  
E. I. Shababa ◽  
Maher M. T. Qutub ◽  
Essam M. Banoqitah ◽  
A. A. Kinsara
Keyword(s):  
Saudi Arabia ◽  
Scintillation Counter ◽  
Mining Area ◽  
Energy Agency ◽  
Phosphate Mining ◽  
Groundwater Samples ◽  
Public Company ◽  
Phosphate Deposit ◽  
Average Activity ◽  
Dose Levels

AbstractIt is a known fact that phosphate rocks have high levels of natural radioactivity due to the presence of large concentrations of radionuclides. This work aims to estimate radiation exposure and dose levels at Al-Jalamid site in northern Saudi Arabia. Al-Jalamid area is one of the largest reserves of phosphate worldwide. Ma’aden, a Saudi Government public company, owns the mine and is responsible for all mining activities. Phosphate and soil samples collected from Al-Jalamid phosphate mining area have been analysed for their uranium and thorium content by an α-spectrometer using radiochemical techniques. The quantity of radon gas was measured both in groundwater and in the atmosphere (indoor and outdoor) at the site using a portable radiation survey instrument. Groundwater samples collected from wells surrounding the mining area were analysed using a liquid scintillation counter in addition to an α-spectrometer. Finally, it is found that phosphate rock concentrate products cannot be utilized economically based on the standards set by the International Atomic Energy Agency (IAEA), since the average activity concentration does not reach the limit set by IAEA and hence are not commercially feasible.

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