scholarly journals Cement-fly ash mortars durability, with fly ash from fluidized bed boilers and conventional combustion, exposed to aggressive environment influence

2018 ◽  
Vol 174 ◽  
pp. 02006 ◽  
Author(s):  
Elżbieta Janowska-Renkas ◽  
Jolanta Kowalska ◽  
Grzegorz Janus ◽  
Agnieszka Kaliciak

The study shows results of research on the aggressive environment impact (1, 3 and 5% HCl solution) on durability of cement mortars with fraction from 30 to 45% by mass of fly ashes from the fluidized bed combustion (FBC fly ash) and conventional fly ashes used separately and in the form of a mixture. The impact of aggressive environments on durability of cement and ash mortars was tested for aperiod of 365 days, by testing the compressive strength, linear changes, mass loss and porosity. It was demonstrated that mortars with the content of FBC fly ashes, after 365 days of tests showed the higher resistance to aggressive environment impact. It is confirmed by e.g. their higher compressive strength, and thus the reduced total porosity. Reduction of total porosity content (<50 nm) was accompanied by the increased compressive strength, which in the aqueous environment was in favour of cement mortars, and in the aggressive environment in favour of cement and ash mortars. It was demonstrated that the content of pores < 200 nm was lower for mortars with FBC fly ashes and mixtures of ashes regardless of environment the mortars were stored in. A beneficial impact of FBC fly ashes was found on physical properties of mortars, i.e. reduction of the shrinkage, lower mass loss and reduced destruction of mortars in the acid corrosion environment. That effect was especially beneficial for the mortar with higher (45% by mass) content of FBC fly ashes, regardless of aggressive character of the environment.

Author(s):  
Iwona Wilińska ◽  
Barbara Pacewska ◽  
Wojciech Kubissa

Utilization of fluidized fly ash in cement composite is problematic, e.g. because of its changeable chemical composition and increased water demand of the mixture. However, this kind of by-product shows some self-cementing properties, which may be beneficial for low-cement mixtures. The article compares the impact of various kinds of fly ashes, i.e. fluidized fly ash and conventional one, and their mixtures on hydration of fly ash–cement compositions in relation to properties of final material. The amount of fly ash in the binder was 50 wt%. Calorimetry, thermal analysis (TG/DTG) and infrared spectroscopy were used. Compressive strength and water absorption of hardened composites were also registered. It was found that both fly ashes exhibit delay effect in fly ash-cement pastes which causes extension of initial setting time and lower heat released compared to the reference without fly ash. At later hydration days, fluidized fly ash develops higher pozzolanic activity than conventional one. Compositions with fluidized fly ash show better compressive strength compared to those containing conventional one. Mixing of different materials of high and low activity (fluidized and conventional fly ash in this case) seems to be a good way for creation of new cement replacement material.


2017 ◽  
Vol 26 (2) ◽  
pp. 234-240
Author(s):  
Jakub Jura ◽  
Małgorzata Ulewicz

Paper presents the possibility of using fly ash from the combustion of two types biomass in fluidized bed boiler to modifications cement mortars composition. The influence of the use of ashes on their mechanical and physical properties (compressive strength, frost resistance, water absorption) of cement mortars. In research part of standarized sand was replaced by fly ash from the combustion of wood with coconut husks and wood with sunflower in the amount of 10, 20 and 30% by weight of cement. The addition of ash, depending on the composition, increase the compressive strength about 17%, decrease a reduction compressive strength after frost resistance tests to 0,5% and slightly increases weight loss and absorbency.


Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 753
Author(s):  
Jacek Śliwiński ◽  
Artur Łagosz ◽  
Tomasz Tracz ◽  
Radosław Mróz ◽  
Jan Deja

This paper presents the results of an extensive experimental study on the effect of the addition of two types of fly ash produced during fluidized bed combustion of bituminous coal and lignite, which differ substantially in their chemical and mineral compositions, on the compressive strength of concrete. Concretes with water/binder ratios of 0.65, 0.55 and 0.45 made with CEM I 42.5 R Portland cement and gravel aggregate were tested. The analyzed amounts of fly ash added to the binder were 0, 15% and 30% by weight. Based on the results of compressive strength testing after 28 and 90 days of curing, the relationships with the water/binder ratio and fly ash content in the binder were determined. The fly ashes used were highly active and capable of pozzolanic reaction. The relationships established allow the compressive strength of concretes based on composite cement-fly ash binder to be predicted with sufficient accuracy. The results presented in this study are an important contribution to the knowledge of concretes with combined binders. They have the exploratory value of establishing the dependence of compressive strength at 28 and 90 days on binder composition and water-binder ratio. In addition, they could be used almost directly in practical applications.


2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Yu Zhang ◽  
Peixin Shi ◽  
Lijuan Chen ◽  
Qiang Tang

The electroplating sludge may pose serious threat to human health and surrounding environment without safe treatment. This paper investigated the feasibility of using electroplating sludge as subgrade backfill materials, by evaluating the mechanical properties and environmental risk of the cement-coal fly ash solidified sludge. In this study, Portland cement and coal fly ash are used to solidify/stabilize the sludge. After curing for 7, 14, and 28 days, the stabilization/solidification sludge specimens were subject to a series of mechanical, leaching, and microcosmic tests. It was found that the compressive strength increased with the increase of cement content, curing time, and the cement replacement by coal fly ash besides water content. Among these factors, the impact of water content on the compressive strength is most noticeable. It was observed that the compressive strength declined by 87.1% when the water content increased from 0% to 10%. Besides, leaching tests showed that the amount of leaching heavy metals were under the standard limit. These results demonstrated utilization of electroplating sludge in subgrade backfill material may provide an alternative for the treatment of electroplating sludge.


Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 487 ◽  
Author(s):  
Gabriela Rutkowska ◽  
Piotr Wichowski ◽  
Małgorzata Franus ◽  
Michał Mendryk ◽  
Joanna Fronczyk

This article focuses on the impact of fly ash from the combustion of municipal sewage sludge (FAMSS) as a cement additive in the amounts of 5%, 10%, 15%, 20% and 25% (by mass) on selected concrete properties. In the course of the experimental work, water penetration depth and compressive strength measurements were made at various periods of curing (from 2 to 365 days). In addition, the potential impact of FAMSS on the natural environment was examined by determining the leachability of heavy metals. FAMSS-modified concretes showed small values of water penetration depth (lower than 50 mm), as well as good compressive strength (reaching minimum class C30/37 after 130 days of maturing)—similar to the compressive strength obtained for conventional concrete. In addition, the partial replacement of cement with FAMSS has environmental benefits, expressed as a reduction in CO2 emissions. In addition, study has shown that compliance with environmental requirements is associated with heavy metal leaching.


2019 ◽  
Vol 296 ◽  
pp. 173-179 ◽  
Author(s):  
Matěj Lédl ◽  
Lucie Galvánková ◽  
Rostislav Drochytka

This paper is focused on the effect of treatment of fly ash after selective non-catalytic reduction (SNCR) with tannin on autoclaved aerated concrete (AAC) production in order to reduce or stop ammonia leakage from the fresh mixture due to its alkalinity. A pure form of tannin and a tannin-based product „Farmatan“ were used as a treatment in dosage ranging from 0,5 g – 3 g of agent per 1 kg of fly ash. Efficient dosage was determined at 2 wt.% of fly ash by the speed of an indicator change due to gaseous ammonia diluted in water. The rheological properties of fresh mixtures were observed by consistency test in Viskomat showing that Farmatan causes delay of hydration. The results of bulk density and compressive strength testing revealed that Farmatan causes an increase of bulk density and at higher amount decreases the compressive strength because of thermal crack formation due to combined effect of delayed hydration and thixotropy. Using x-ray diffraction (XRD) analysis there were no differences in phase composition observed.


Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 141
Author(s):  
Zhengzhen Yao ◽  
Zhonghui Xu ◽  
Qin Shuai ◽  
Xiaoyue Chen ◽  
Zao Jiang ◽  
...  

This study aims to explore the solidification performance of municipal solid waste incineration fly ash (MSWIFA) through co-mechanical treatment with circulation fluidized bed combustion fly ash (CFBCFA). The mineral characterization, physical properties, and leaching resistance of the solidified bodies are investigated by X-ray diffraction spectroscopy (XRD), Fourier transform infrared spectroscopy (FT-IR), Thermogravimetry-differential thermal analysis (TG-DTA), compressive strength, porosity, and leaching test, respectively. C–S–H, ettringite (AFt), and Friedel’s salt (FS) are the predominant hydrate products in the CFBCFA based solidified bodies, which are similar to the cement based solidified bodies. However, CFBCFA based solidified bodies exhibit higher compressive strength (36.7 MPa) than cement based solidified bodies (11.28 MPa), attributing to the three reasons: lower porosity and more compact internal structure of CFBCFA based solidified bodies; large amounts of Ca(OH)2 originating from MSWIFA are conducive to promoting the hydration reaction extent and compressive strength of the CFBCFA based solidified bodies; excessive Ca(OH)2 would cause compressive strength deterioration for the cement based solidified bodies. The heavy metals (Zn, Cu, Cr, Cd, and Pb) concentrations in the extraction solution of the CFBCFA based solidified bodies are far below the requirements of Chinese National Standard GB 5085.3-2007. The solidification of MSWIFA through co-mechanical treatment could be an ideal substitute for cement solidification technology.


2018 ◽  
Vol 276 ◽  
pp. 110-115
Author(s):  
Martin Ťažký ◽  
Martin Labaj ◽  
Rudolf Hela

The by-products of energy industry are nowadays often affected by new limits governing the production of harmful gases discharged into the air. These stricter and stricter criteria are often met by electricity producers by changing the combustion process in thermal power plants itself. Nowadays, the SNCR (selective non-catalytic reduction) application is quite common in the combustion process in order to help reduce the nitrogen oxide emission. This article deals with the primary measures of thermal power plants, which in particular consist of a modified treatment of raw materials (coal) entering the combustion process. These primary measures then often cause the formation of fly ash with unsuitable fineness for the use in concrete according to EN 450. The paper presents the comparison of the physico-mechanical parameters of several fly ashes with a different fineness values. The primary task is to assess the impact of non-suitable granulometry in terms of EN 450 on the other physico-mechanical parameters of fly ashes sampled within the same thermal power plant. Several fly ashes produced in the Czech Republic and surrounding countries were evaluated in this way.


1988 ◽  
Vol 137 ◽  
Author(s):  
H. H. Patel ◽  
P. L. Pratt ◽  
L. J. Parrott

AbstractThe changes in porosity of OPC and an OPC-fly ash blended cement during hydration have been studied at water/solids ratios of 0.35, 0.47 and 0.59, cured for times of up to 1 year at 25°C. The porosity was measured indirectly by methanol exchange and methanol adsorption techniques and, directly, by quantitative image analysis using backscattered electron imaging in the scanning electron microscope. Measurements of porosity and of remaining anhydrous material by image analysis showed good correlation with indirect methods. Measurement of the diffusion of methanol and of the compressive strength were made in parallel with the determination of the porosity during hydration and attempts were made to relate the properties to the microstructure. For both binders the reduction of total porosity with increased reaction was small. The major change in pore structure was the subdivision of coarse pores by gel to form finer pores. Compressive strength and diffusion properties were dominated by the relative volume of coarse pores.


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