The photolysis of hexafluoroacetone
1956 ◽
Vol 234
(1199)
◽
pp. 476-488
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Keyword(s):
The photolytic decomposition of hexafluoroacetone has been studied over a wide range of temperatures and pressures using light of wavelength 3130 Å. The initial step involves the production of CF 3 radicals, and the only products are C 2 F 6 and CO. The reaction is an excellent source of CF 3 radicals. The quantum yield diminishes with increasing pressure. A mechanism is suggested involving the participation of an electronically excited molecule of comparatively long lifetime, and the effect of various inert gases on the stability of this species is discussed.
2019 ◽
2018 ◽
Keyword(s):
2020 ◽
Vol 21
(3)
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pp. 211-220
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Keyword(s):
2021 ◽
Vol 10
(1)
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pp. 9