A new surface finish for the electronics industry: Electroless nickel/immersion silver

Author(s):  
Lenora M. Toscano ◽  
Ernest Long
2011 ◽  
Vol 2011 (1) ◽  
pp. 000516-000520 ◽  
Author(s):  
John Ganjei ◽  
Ernest Long ◽  
Lenora Toscano

The continuing drive for ever increasing performance enhancement in the electronics industry, in combination with the recent, very significant increase in precious metal costs have left fabricators and OEMs questioning what the best, most cost effective, surface finish is for high reliability applications. Currently, the IC substrate market relies heavily on electrolytic nickel and gold as a solderable and superior wire bondable surface. The use of this finish has allowed manufacturers to avoid the reliability concerns However, this choice also results in significant design restraints being imposed. Many in the industry are now investigating the use of electroless nickel/electroless palladium/immersion gold (ENEPIG) to achieve both high reliability and performance, without the negative design restraints imparted by the use of electrolytic processes. However, over the last year alone, the industry has watched the price of gold increase by 50% and that of palladium double [1]. With this in mind, and considering the historic precedent set in the mid 1990’s when ENEPIG was also evaluated as a surface finish for printed circuit boards, when coincidentally, the cost of palladium also reached an all time high, it should be remembered that the electronics industry quickly moved to evaluate alternate, more cost sustainable, surface finishes. This paper details the use of lower cost, alternate surface finishes for IC substrate applications, with particular experimental focus on gold wire bonding capabilities and BGA solderability of the finishes described. The paper also discusses related process cycle advantages and the significantly reduced operating costs associated with these new finishes.


Author(s):  
Adam Pearl ◽  
Michael Osterman

Electroless Nickel/Electroless Palladium/Immersion Gold (ENEPIG), which has been used in component packaging, has been gaining attention as a surface finish for printed wiring boards. The primary role of a printed wiring board surface finish is to provide a solderable surface for assembly, creating a reliable solder interconnect. With regards to reliability, the increased use of mobile electronics has resulted in the need to consider the ability of interconnects to withstand repeated mechanical shocks. This paper examines the drop reliability of both SnPb and SAC305 interconnects formed on ENEPIG finished printed wiring boards. For comparison, the drop reliability test results for similar boards with Immersion Silver (ImAg) board finish are included. Test boards include BGA and resistor packages. The boards are dropped 500 times to achieve failure across the components. Failure analysis revealed that the dominant failure mode for BGA packages on the ENEPIG finish was cracking in the solder balls at the component interface, while for the ImAg finish the dominant failure mode was cratering in the board laminate below the solder pad. For the resistor packages, cracking through the solder joint at the component interface was the dominant failure mode for both the ENEPIG and ImAg finishes. The drop results indicate that both finishes are suitable for systems that could experience mechanical shock due to drop, with components soldered onto ENEPIG with a SAC 305 solder having the highest survivability. The combination of SnPb and ImAg was found to be superior to SAC 305 and ImAg.


2016 ◽  
Vol 2016 (1) ◽  
pp. 000117-000122 ◽  
Author(s):  
Cong Zhao ◽  
Thomas Sanders ◽  
Zhou Hai ◽  
Chaobo Shen ◽  
John L. Evans

Abstract This paper investigates the effect of long term isothermal aging and thermal cycling on the reliability of lead-free solder mixes with different solder compositions, PCB surface finishes, and isothermal aging conditions. A variety of surface mount components are considered, including ball grid arrays (BGAs), quad flat no-lead packages (QFNs) and 2512 Surface Mount Resistors (SMRs). 12 lead-free solder pastes are tested; for BGA packages these are reflowed with lead-free solder spheres of SAC105, SAC305 and matched doped solder spheres (“matched” solder paste and sphere composition). Three surface finishes are tested: Organic Solderability Preservative (OSP), Immersion Silver (ImAg), and Electroless Nickel Immersion Gold (ENIG). All test components are subjected to isothermal aging at 125°C for 0 or 12 months, followed by accelerated thermal cycle testing from −40°C to 125°C. Data from the first 1500 cycles is presented here, with a focus on the effect of surface finish on package reliability. Current results demonstrate that the choice of surface finish has a strong effect on reliability. However, different solder materials appear to show different reliability trends with respect to the surface finishes, and the reliability trends of BGA and SMR packages also diverge.


2019 ◽  
Vol 796 ◽  
pp. 183-188
Author(s):  
Jaidi Zolhafizi ◽  
Osman Saliza Azlina

Surface finish is coating layer plated on a bare copper board of printed circuit board (PCB). Among PCB surface finishes, Electroless Nickel/Immersion Gold (ENIG) finish is a top choice among electronic packaging manufacturer due to its excellent properties for PCB. However, the use of gold element in ENIG is very high cost and the black pad issue have not been resolved. Thus, by introducing an Electroless Nickel/Immersion Silver (ENImAg) as alternative surface finish hopefully can reduce the cost and offer better properties. The aim of this study is to investigate the effect of bismuth on interfacial reaction during reflow soldering between Sn-2.5Ag (SA25), Sn-3.4Ag-4.8Bi (SAB3448) and ENIMAG surface finish. Solder balls with sizes of 500μm diameters were used. The characteristics of intermetallic compound (IMC) were analyzed by using scanning electron microscopy (SEM), optical microscope and energy dispersive x-ray (EDX). After reflow soldering, the result revealed that only the irregular circle-shape of (Cu,Ni)6Sn5IMC layer was formed at the interface and change to an irregular rod-like shape meanwhile the irregular needle-shape (Ni,Cu)3Sn4was appeared after aging treatment. The result also indicated that, the grain size and thickness of IMC for SAB3448 is smaller and thinner compared to the SA25. The IMC thickness is proportional to the aging duration and IMC morphology for both solder are became thicker, larger and coarser after isothermal aging. No bismuth particle has been detected on SAB3448 solder during top surface examination. In addition, the Bi has been observed can reduce the grain size and the growth rate of IMC. Keywords: ENIMAG, reflow soldering, lead-free solder, intermetallic compound, bismuth


2015 ◽  
Vol 2015 (DPC) ◽  
pp. 001531-001563
Author(s):  
Arnd Kilian ◽  
Gustavo Ramos ◽  
Rick Nichols ◽  
Robin Taylor ◽  
Vanessa Smet ◽  
...  

One constant in electronic system integration is the continuous trend towards smaller devices with increased functionality, driven by emerging mobile and high-performance applications. This brings the need for higher bandwidth at lower power, translating into increased I/O density, to enable highly-integrated systems with form factor reduction. These requirements result in the necessity of interconnection pitch-scaling, below 30 μm in the near future, and substrates with high wiring densities, leading to routing with sub 5 μm L/S where standard surface finishes (ENIG, ENEPIG) are no longer applicable. Copper pillar with solder caps technology is currently the prevalent solution for off-chip interconnections at fine pitch, dominating the high performance and mobile market with pitches as low as 40 μm in production. However, this technology faces many fundamental limitations in pitch scaling below 30 μm, due to solder bridging, IMC-solder interfacial stress management, and poor power handling capability of solders. All-copper interconnections without solder are very sought after by the semiconductor industry and have been applied to 3D-IC stacking, however no cost effective, manufacturable and scalable solution has been proposed to date for HVM and application to non CTE matched package structures. The low temperature Cu-Cu interconnection technology without solder recently patented by Georgia Tech PRC is one of the most promising solutions to this problem. The main bottleneck of copper oxidation is dealt with by application of ENIG on the Cu bumps and pads, enabling formation of a reliable metallurgical bond by thermocompression bonding (TCB) at temperatures below 200°C, in air, with cycle-times compatible with HVM targets. However, to ensure a bump collapse of 3 μm to overcome non-coplanarities and warpage, a pressure of 300MPa is used in the Process-of-Record (PoR) conditions, limiting the scalability of this technology. This paper introduces a novel Electroless Palladium / Autocatalytic Gold (EPAG) surface finish process, to enable the next generation of high density substrates and interconnections. With circa 100nm-thin Pd and Au layers, the EPAG finish can be applied to fine L/S wiring, with no risk of bridging adjacent Cu traces, even with spacing below 5 μm. Further, the EPAG finish is compatible with current interconnection processes; such as wire bonding, and the Cu pillar and solder cap technology for fine-pitch applications. For further pitch reduction, the EPAG surface finish was coupled to GT PRC's low-temperature Cu-interconnections, in an effort to reduce the bonding load for enhanced manufacturability without degrading the metallurgical bond or reliability. This paper is the first demonstration of such interconnections. The effect of the surface finish thickness and composition on the bonding load, assembly yield, quality of the metallurgical bond was extensively evaluated based on analysis of the metal interface microstructures and the chemical composition of the joints. The current PoR using Electroless Nickel / Immersion Gold (ENIG) coated Cu pillars and pads was used as reference. A novel surface finish is introduced, which allows formation of Cu-Cu interconnections without solder at lower pressure, between a silicon die and glass, organic or silicon substrate at fine pitch, allowing the performance improvements demanded by the IC Packaging Industry.


2013 ◽  
Vol 2013 (CICMT) ◽  
pp. 000283-000287
Author(s):  
Allan Beikmohamadi ◽  
Steve Stewart ◽  
Jim Parisi ◽  
Mark McCombs ◽  
Michael Smith ◽  
...  

Low Temperature Co-fired Ceramic (LTCC) technology provides an attractive packaging platform for microwave and millimeter wave circuits and systems due to its unique properties. Generally, thick film gold or silver conductors are used as metallizations on LTCC substrates along with occasional use of copper thick films. This paper reports methods and results of extensive process development experiments DuPont Microcircuit Materials has undertaken to establish a commercially viable plating process for the market leading DuPont™ GreenTape™ 9K7 LTCC system. Both Electroplating and Electroless plating processes are investigated in this work. These techniques provide certain advantages when used in isolation or in combination with standard thick film metallizations, helping to extend their applicability. Electroplating of copper on LTCC provides a means of using copper as the external conductor without having to use complicated firing processes in oxygen-free atmosphere as required for copper thick film. This approach leads to a much more cost effective approach if copper is required as the external metal. Electroless Nickel/Gold plating (ENIG) of both silver and copper (electroplated and/or thick film) provides an industry standard, highly reliable, robust surface finish. Such surface finish enables easy integration of both soldering and wire bonding processes.


Author(s):  
Gnyaneshwar Ramakrishna ◽  
Donghyun Kim ◽  
Mudasir Ahamad ◽  
Lavanya Gopalakrishnan ◽  
Mason Hu ◽  
...  

Large Flip Chip BGA (FCBGA) packages are needed in high pin out applications (>1800), e.g., ASIC's and are typically used in high reliability and robustness applications. Hence understanding the package reliability and robustness becomes one of paramount importance for efficient product design. There are various aspects to the package that need to be understood, to ensure an effective design. The focus of this paper is to understand the BGA reliability of the package with particular reference to comparison of the surface finish, vis-a`-vis, between Electroless Nickel Immersion Gold (ENIG) and Solder On Pad (SOP) on the substrate side of the package, which are the typical solutions for large plastic FC-BGA packages. Tests, which include board level temperature cycling, monotonic bend and shock testing have been conducted to compare the two surface finish options. The results of these tests demonstrate that the mechanical strength of the interface exceeds by a factor of two for the SOP surface finish, while BGA design parameters play a key role in ensuring comparative temperature cycle reliability in comparison with ENIG packages.


2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Rabiatul Adawiyah Mohamed Anuar ◽  
Saliza Azlina Osman

Purpose The surface finish is an essential step in printed circuit boards design because it provides a solderable surface for electronic components. The purpose of this study to investigate the effects of different surface finishes during the soldering and ageing process. Design/methodology/approach The solder joints of Sn-4.0Ag-0.5Cu/Cu and Sn-4.0Ag-0.5Cu/electroless nickel/immersion silver (ENImAg) were investigated in terms of intermetallic (IMC) thickness, morphology and shear strength. The microstructure and compositions of solder joints are observed, and analyzed by using scanning electron microscopy (SEM-EDX) and optical microscope (OM). Findings Compounds of Cu6Sn5 and (Cu, Ni)6Sn5 IMC were formed in SAC405/Cu and SAC405/ENImAg, respectively, as-reflowed. When the sample was exposed to ageing, new layers of Cu3Sn and (Ni, Cu)3Sn5 were observed at the interface. Analogous growth in the thickness of the IMC layer and increased grains size commensurate with ageing time. The results equally revealed an increase in shear strength of SAC405/ENImAg because of the thin layer of IMC and surface finish used compared to SAC405/Cu. Hence, a ductile fracture was observed at the bulk solder. Overall, the ENImAg surface finish showed excellent performance of solder joints than that of bare Cu. Originality/value The novel surface finish (ENImAg) has been developed and optimized. This alternative lead-free surface finish solved the challenges in electroless nickel/immersion gold and reduced cost without affecting the performance.


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