Hyperbaric Testing of an Alternative Approach to Remove Carbon Dioxide From Underwater Life Support Equipment

Author(s):  
M. Nuckols ◽  
S. Kolaczkowski ◽  
S. Awdry ◽  
T. Smith ◽  
D. Thomas

Traditional CO2 absorption methods for underwater life support equipment use alkali metal hydroxide chemical beds — mostly calcium hydroxide — that have been shown to have poor absorption efficiencies at cold temperatures, and must be replaced at considerable trouble and expense on a frequent basis. With chemical utilizations as low as 20% in water temperatures of 2°C, these hydroxides do not lend themselves to applications requiring extended durations in cold water due to the inability to carry sufficient quantities of expendables. A joint research effort between Duke University and the University of Bath has verified the feasibility in laboratory trials of an alternative carbon dioxide removal method that intimately mixes seawater with breathing circuit gases within a packed bed of Dixon rings. Based on the results of these laboratory trials, two multi-path scrubber prototypes were designed and fabricated for unmanned testing. In March 2013, the hyperbaric performance of these prototype scrubbers was characterized over a wide range of gas and water flow rates when operating the scrubbers in counter-current (water flowing in the opposite direction as gas flow) and co-current (water flowing in the same direction as gas flow) fashion. Significant findings from these tests included the following: • Both scrubber prototypes were found to be capable of delivering exit CO2 levels below 0.5 vol% (surface equivalent) at respiratory rates up to 22.5 liters per minute and at depths ranging from 0 to 40 meters of seawater (MSW). • Negligible collateral O2 absorption was observed at surface pressure (exit O2 levels were typically above 20.2 vol%), and exit O2 levels were typically above 18.4% during testing at 10 MSW. • At surface pressure, both prototypes had significantly lower breathing resistances than design goals established by the U. S. Navy.

2021 ◽  
Vol 2 (3) ◽  
Author(s):  
Arash Esmaeili ◽  
◽  
Zhibang Liu ◽  
Yang Xiang ◽  
Jimmy Yun ◽  
...  

A high pressure carbon dioxide (CO2) absorption from a specific gas in a conventional column has been evaluated by the Aspen HYSYS simulator using a wide range of single absorbents and blended solutions to estimate the outlet CO2 concentration, absorption efficiency and CO2 loading to choose the most proper solution in terms of CO2 capture for environmental concerns. The property package (Acid Gas-Chemical Solvent) which is compatible with all applied solutions for the simulation in this study, estimates the properties based on an electrolyte non-random two-liquid (E- NRTL) model for electrolyte thermodynamics and Peng-Robinson equation of state for the vapor and liquid hydrocarbon phases. Among all the investigated single amines as well as blended solutions, piperazine (PZ) and the mixture of piperazine and monoethanolamine (MEA) have been found as the most effective absorbents respectively for CO2 absorption with high reactivity based on the simulated operational conditions.


Science ◽  
2013 ◽  
Vol 342 (6154) ◽  
pp. 91-95 ◽  
Author(s):  
Hyo Won Kim ◽  
Hee Wook Yoon ◽  
Seon-Mi Yoon ◽  
Byung Min Yoo ◽  
Byung Kook Ahn ◽  
...  

Graphene is a distinct two-dimensional material that offers a wide range of opportunities for membrane applications because of ultimate thinness, flexibility, chemical stability, and mechanical strength. We demonstrate that few- and several-layered graphene and graphene oxide (GO) sheets can be engineered to exhibit the desired gas separation characteristics. Selective gas diffusion can be achieved by controlling gas flow channels and pores via different stacking methods. For layered (3- to 10-nanometer) GO membranes, tunable gas transport behavior was strongly dependent on the degree of interlocking within the GO stacking structure. High carbon dioxide/nitrogen selectivity was achieved by well-interlocked GO membranes in high relative humidity, which is most suitable for postcombustion carbon dioxide capture processes, including a humidified feed stream.


Author(s):  
Evgeny Pererva

Introduction. The paper is devoted to the examination of craniological materials of the late middle age originating from the Shareniy Bugor archaeological complex. Methods and materials. A complete series which includes 33 individual remains is now kept by the Research Institute and the Museum of Anthropology of Moscow State University. The access to scientific information on the series has been opened for the first time. The series consists of 24 male skulls, 4 female brain capsules, two childrens and 3 adolescent craniums. Analysis. The standard assessment program of pathological conditions on postcranial skeleton and skull bones developed by A.P. Buzhilova (1995, 1998) was applied in the course of examination of the anthropological material. Results. A wide range of cranium anomalies, various dentition diseases, endocrine disease markers, signs of exposure to low temperatures, episodic stress traces and numerous injuries were recorded as a result of the examination of the bone material. Conclusions. The series under consideration does not meet the paleopopulation criteria, i.e. cannot be a prototype of a really existing group of medieval urban population. Signs of unintentional artificial deformity of the occipital type were recorded on the skulls of the studied sample. The identified stress markers indicate that the urban population of the Volga Delta was exposed to the pressure of negative factors due to the natural and social environment including cold temperatures, hunger, war, etc. The population group originating from Shareniy Bugor settlement probably specialized in living in the river area, which led to a specific diet and the appearance of cases of diseases typical for people spending a long time in a cold water environment. Extremely high rates of injuries, including combat near-death and lethal ones, wounds to the skull facial area characterize the studied part of the population as a group that actively participated in hostilities. A series of skulls originating from Shareniy Bugor settlement probably belongs to a specific social stratum or the handicraft part of the population of the Golden Horde city of Khadzhi-Tarkhan which was engaged in river fishing and whose appearance (hairstyle and constantly worn headdress) was very different from most townspeople; they probably actively defended the city during the raids of enemies.


Sensors ◽  
2020 ◽  
Vol 20 (13) ◽  
pp. 3613
Author(s):  
Michele Bellancini ◽  
Laura Cercenelli ◽  
Stefano Severi ◽  
Guido Comai ◽  
Emanuela Marcelli

Measurement of carbon dioxide (CO2) in medical applications is a well-established method for monitoring patient’s pulmonary function in a noninvasive way widely used in emergency, intensive care, and during anesthesia. Even in extracorporeal-life support applications, such as Extracorporeal Carbon Dioxide Removal (ECCO2R), Extracorporeal Membrane Oxygenation (ECMO), and cardiopulmonary by-pass (CPB), measurement of the CO2 concentration in the membrane oxygenator exhaust gas is proven to be useful to evaluate the treatment progress as well as the performance of the membrane oxygenator. In this paper, we present a new optical sensor specifically designed for the measurement of CO2 concentration in oxygenator exhaust gas. Further, the developed sensor allows measurement of the gas flow applied to the membrane oxygenator as well as the estimation of the CO2 removal rate. A heating module is implemented within the sensor to avoid water vapor condensation. Effects of temperature on the sensor optical elements of the sensors are disclosed, as well as a method to avoid signal–temperature dependency. The newly developed sensor has been tested and compared against a reference device routinely used in clinical practice in both laboratory and in vivo conditions. Results show that sensor accuracy fulfills the requirements of the ISO standard, and that is suitable for clinical applications.


1987 ◽  
Vol 98 ◽  
Author(s):  
F. W. Giacobbe

ABSTRACTA series of powder feeders, developed during the course of an experimental study involving the synthesis of carbon monoxide from pure carbon and carbon dioxide, have been described in detail. The most efficient and reliable of these powder feeders was capable of continuously producing uniform mixtures of powdered carbon entrained in carbon dioxide gas. This device was also capable of producing a relatively wide range of solid/ gas mixture ratios (from about 0.8 to 3.2 g/l) at carbon dioxide gas flow rates between 75 and 200 1/min. In addition, it was relatively easy to vary and control solid/gas mixture ratios and gas flow rates using this powder feeder. Similar powder feeders may be useful in other thermal plasma synthesis or processing applications as well as in other applications requiring accurately blended mixtures of gases and powdered solids


Materials ◽  
2020 ◽  
Vol 13 (13) ◽  
pp. 2931
Author(s):  
Soumya Banerjee ◽  
Ek Adhikari ◽  
Pitambar Sapkota ◽  
Amal Sebastian ◽  
Sylwia Ptasinska

Atmospheric pressure plasma (APP) deposition techniques are useful today because of their simplicity and their time and cost savings, particularly for growth of oxide films. Among the oxide materials, titanium dioxide (TiO2) has a wide range of applications in electronics, solar cells, and photocatalysis, which has made it an extremely popular research topic for decades. Here, we provide an overview of non-thermal APP deposition techniques for TiO2 thin film, some historical background, and some very recent findings and developments. First, we define non-thermal plasma, and then we describe the advantages of APP deposition. In addition, we explain the importance of TiO2 and then describe briefly the three deposition techniques used to date. We also compare the structural, electronic, and optical properties of TiO2 films deposited by different APP methods. Lastly, we examine the status of current research related to the effects of such deposition parameters as plasma power, feed gas, bias voltage, gas flow rate, and substrate temperature on the deposition rate, crystal phase, and other film properties. The examples given cover the most common APP deposition techniques for TiO2 growth to understand their advantages for specific applications. In addition, we discuss the important challenges that APP deposition is facing in this rapidly growing field.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Karolina Kula ◽  
Agnieszka Kącka-Zych ◽  
Agnieszka Łapczuk-Krygier ◽  
Radomir Jasiński

Abstract The large and significant increase in carbon dioxide concentration in the Earth’s atmosphere is a serious problem for humanity. The amount of CO2 is increasing steadily which causes a harmful greenhouse effect that damages the Earth’s climate. Therefore, one of the current trends in modern chemistry and chemical technology are issues related to its utilization. This work includes the analysis of the possibility of chemical consumption of CO2 in Diels-Alder processes under non-catalytic and catalytic conditions after prior activation of the C=O bond. In addition to the obvious benefits associated with CO2 utilization, such processes open up the possibility of universal synthesis of a wide range of internal carboxylates. These studies have been performed in the framework of Molecular Electron Density Theory as a modern view of the chemical reactivity. It has been found, that explored DA reactions catalyzed by Lewis acids with the boron core, proceeds via unique stepwise mechanism with the zwitterionic intermediate. Bonding Evolution Theory (BET) analysis of the molecular mechanism associated with the DA reaction between cyclopentadiene and carbon dioxide indicates that it takes place thorough a two-stage one-step mechanism, which is initialized by formation of C–C single bond. In turn, the DA reaction between cyclopentadiene and carbon dioxide catalysed by BH3 extends in the environment of DCM, indicates that it takes place through a two-step mechanism. First path of catalysed DA reaction is characterized by 10 different phases, while the second by eight topologically different phases.


2001 ◽  
Vol 19 (4) ◽  
pp. 579-595 ◽  
Author(s):  
D. MOSHER ◽  
B.V. WEBER ◽  
B. MOOSMAN ◽  
R.J. COMMISSO ◽  
P. COLEMAN ◽  
...  

High-sensitivity interferometry measurements of initial density distributions are reviewed for a wide range of gas-puff nozzles used in plasma radiation source (PRS) z-pinch experiments. Accurate gas distributions are required for determining experimental load parameters, modeling implosion dynamics, understanding the radiation properties of the stagnated pinch, and for predicting PRS performance in future experiments. For a number of these nozzles, a simple ballistic-gas-flow model (BFM) has been used to provide good physics-based analytic fits to the measured r, z density distributions. These BFM fits provide a convenient means to smoothly interpolate radial density distributions between discrete axial measurement locations for finer-zoned two-dimensional MHD calculations, and can be used to determine how changes in nozzle parameters and load geometry might alter implosion dynamics and radiation performance. These measurement and analysis techniques are demonstrated for a nested-shell nozzle used in Double Eagle and Saturn experiments. For this nozzle, the analysis suggests load modifications that may increase the K-shell yield.


2007 ◽  
Vol 344 ◽  
pp. 143-150 ◽  
Author(s):  
Gianluca Buffa ◽  
Livan Fratini ◽  
Marion Merklein ◽  
Detlev Staud

Tight competition characterizing automotive industries in the last decades has determined a strong research effort aimed to improve utilized processes and materials in sheet stamping. As far as the latter are regarded light weight alloys, high strength steels and tailored blanks have been increasingly utilized with the aim to reduce parts weight and fuel consumptions. In the paper the mechanical properties and formability of tailored welded blanks made of a precipitation hardenable aluminum alloy but with different sheet thicknesses, have been investigated: both laser welding and friction stir welding have been developed to obtain the tailored blanks. For both welding operations a wide range of the thickness ratios has been considered. The formability of the obtained blanks has been characterized through tensile tests and cup deep drawing tests, in order to show the formability in dependency of the stress condition; what is more mechanical and metallurgical investigations have been made on the welded joints.


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