Chemical properties of black cottonwood and balsam poplar

1986 ◽  
Vol 16 (3) ◽  
pp. 497-501 ◽  
Author(s):  
E. P. Swan ◽  
R. M. Kellogg
Keyword(s):  
Lignin Content ◽  
Chemical Properties ◽  
Species Group ◽  
Core Material ◽  
Chemical Components ◽  
Extractive Content ◽  
Black Cottonwood ◽  
Balsam Poplar ◽  
Dimension Lumber ◽  
Fraser Valley

Taxonomically, black cottonwood and balsam poplar are varieties of the same species. However, black cottonwood is excluded from the "northern aspen" species group embraced by the National Lumber Grading Agency grading rules for dimension lumber and from the use as core material in softwood plywood. This study examines the chemical properties of these two species varieties to assess whether continuing differentiation in their utilization is justified. Black cottonwood was sampled at three sites in British Columbia (Fraser Valley, Squamish Valley, Kingcome Inlet) and balsam poplar was sampled at three sites in Alberta (Lodgepole, Slave Lake, Lac La Biche). Representative subsamples of wood and bark meal were prepared from each original sample. Black cottonwood and balsam poplar did not differ significantly in lignin content. Within each species, the heartwood had higher lignin contents than the sapwood. The mean extractive content of the female trees is higher than that of the male trees, but this was statistically significant for only the benzene–alcohol extractive content of the black cottonwood sapwood. The pH and acidity did not differ significantly between species. However, there was a large difference between heart-wood and sapwood pH values in both species; sufficient to provide a basis for their differentiation. Acidity values were higher for both sapwoods than for heartwoods. The chemical component contents of black cottonwood and balsam poplar bark were the same, except for the benzene–alcohol extractive content, which was twice as great in balsam poplar. However, the same chemical components were found in each extractive mixture. Results do not provide any basis for separate commercial utilization of these two varieties of the same species.

Physical properties of black cottonwood and balsam poplar

1986 ◽  
Vol 16 (3) ◽  
pp. 491-496 ◽  
Author(s):  
R. M. Kellogg ◽  
E. P. Swan
Keyword(s):  
Specific Gravity ◽  
Fiber Length ◽  
Bending Strength ◽  
Tree Height ◽  
Strength Properties ◽  
Species Group ◽  
Core Material ◽  
Black Cottonwood ◽  
Balsam Poplar ◽  
Dimension Lumber

The objective of this study was to characterize selected properties of black cottonwood and balsam poplar to determine whether these species should be distinguished in their utilization. At present, black cottonwood is excluded from the "northern aspen" species group embraced by the National Lumber Grading Agency grading rules for dimension lumber and from use as core material in softwood plywood. Samples of black cottonwood were obtained from three sites in British Columbia. Samples of balsam poplar were obtained from three sites in Alberta. Ten tres were randomly selected from each site and a single 130 cm long bolt was collected immediately above breast height (1.36 m) from each tree. From two trees on each site, three additional bolts of the same length were collected immediately above the height positions located at 25, 50, and 75% of total tree height. The average basic specific gravity of the two species did not differ significantly (black cottonwood, 0.338; balsam poplar, 0.337) in this study. However, differences do exist between site averages, at least for black cottonwood. The initial green moisture contents differ significantly (black cottonwood, 160.5%; balsam poplar, 120.6%) and may be expected to affect their drying requirements differentially. For both species, the specific gravity increases and the green moisture content decreases with increasing height position in the tree. The average fiber length of black cottonwood is significantly longer than that of balsam poplar. The bending properties of strength and stiffness for black cottonwood were found to be significantly greater than for balsam poplar. Variation of these properties with height position in the tree was studied. Fiber length was found to decrease with increasing height position, while the bending strength properties were not affected by height position.

Comparison of Pineapple Leaf and Cassava Peel by Chemical Properties and Morphology Characterization

2014 ◽  
Vol 974 ◽  
pp. 384-388 ◽  
Author(s):  
Zawawi Daud ◽  
Halizah Awang ◽  
Angzzas Sari Mohd Kassim ◽  
Mohd Zainuri Mohd Hatta ◽  
Ashuvila Mohd Aripin
Keyword(s):  
Lignin Content ◽  
Paper Industry ◽  
Chemical Properties ◽  
Green Technology ◽  
Test Method ◽  
Chemical Components ◽  
Chemical Compositions ◽  
Cassava Peels ◽  
Pineapple Leaves ◽  
Cassava Peel

Proper waste management in Malaysia is needed for the organic wastes such as pineapple leaf and cassava peel where affects the increase the amount of solid waste dump into landfill. Thus, to overcome this problem agro waste material can be constructed in many production industries to commercialize the use of alternative fibre for the paper industry. The main objective of this study is to demonstrate the use of fibrous in pineapple leaf and cassava peel by production of alternative fibre based on chemical properties and surface morphology characteristic. This study conducted for the chemical composition by analysed by TAPPI Test method, Chlorination method and Kuchner-Hoffner method. Every chemical components analyse; Cellulose (Kuchner-Hoofner), Holocellulose (Chlorination method), Hemicellulose (Chlorination method), Hemicellulose, Ash content (T211-om-93), Lignin content (T222-om-98) and Sodium Hydroxide soluble (T203-om-88). The scanning electron microscopy (SEM) was used to observe and determine the morphological characteristic of both crops. The result indicates that pineapple leaf more suitable for becoming an alternative fibre than cassava peels. Pineapple leaves have a high Holocellulose content (85.7%), cassava peels 66%, followed by Cellulose pineapple leaf (66.2%), cassava peels (37.9%). However, hemicellulose content in pineapple leaf (19.5%) less than cassava peels (37.0%). Lignin content of pineapple leaf is lower (4.2%) compared to cassava peels (7.52%) in this study. From SEM images, cassava peel contained abundance fibre such as hemicellulose and cellulose that is held by the lignin in it and Pineapple leaves give a condensed composition of fibre structure. The chemical compositions and morphology study of pineapple leaf and cassava indicate pineapple leaf have a high percentage to be used as an alternative pulp in paper making industry, promoting the green technology. However, cassava peels make some of properties that can also be through for the paper industry.

scholarly journals Influence of juvenile and mature wood on anatomical and chemical properties of early and late wood from Chinese fir plantation

2021 ◽  
Vol 67 (1) ◽  
Author(s):  
Changqing Lu ◽  
Jun Wu ◽  
Qianqian Jiang ◽  
Yamei Liu ◽  
Liang Zhou ◽  
...  
Keyword(s):  
Juvenile Wood ◽  
Lignin Content ◽  
Microfibril Angle ◽  
Chemical Properties ◽  
Decisive Role ◽  
Chinese Fir ◽  
Mature Wood ◽  
Chemical Components ◽  
Late Wood ◽  
Significant Difference

AbstractThe proportion of juvenile wood affects the utilization of wood seriously, and the transition year of juvenile wood (JW) and mature wood (MW) plays a decisive role in the rotation and the modification of wood. To find out the demarcation of JW and MW, the tracheid length (TL) and microfibril angle (MFA) of early wood (EW) and late wood (LW) from four Chinese fir clones were measured by optical microscopy and X-ray diffraction. Then the data were analyzed by the k-means clustering method. The correlation and the differences among wood properties between JW and MW were compared. Results indicated that the LW showed better properties than that of EW, but the anatomical differences between EW and LW did not influence the demarcation of JW and MW. The cluster analysis of TL and MFA showed that the transition year was in the 16th year and the transition zone of EW and LW was different among clones. The MW has longer and wider tracheid, thicker cell walls, and smaller MFA. In terms of chemistry, MW had a higher content of holocellulose, α-cellulose, less content of extract, but no significant difference in lignin content compared with JW. The stabilization of chemical components was earlier than that of the anatomic properties. Correlation analysis showed that there were strong correlations between the chemical composition and anatomical characteristics in JW and MW. In general, compared with chemical components, anatomical indicators were more suitable for JW and MW demarcation. The differences and correlations between JW and MW properties provide a theoretical basis for wood rotation and planting.

scholarly journals Effects of Age and Height on Chemical Properties of Yushania Alpina Grown at Injibara District, Amhara Region, Ethiopia

2019 ◽  
Vol 4 (1) ◽  
pp. 32-36
Author(s):  
Amsalu Tolessa ◽  
Fikremariam Haile ◽  
Abraham Dilnesa ◽  
Buzayehu Desisa ◽  
Tegene Tantu ◽  
...  
Keyword(s):  
Lignin Content ◽  
Chemical Constituents ◽  
Chemical Properties ◽  
Industrial Sector ◽  
Chemical Components ◽  
Cellulose Content ◽  
Mean Values ◽  
Comprehensive Knowledge ◽  
American Society ◽  
Chemical Testing

This paper studied the chemical composition of cultivated 3, 4 and 5 year-old highland bamboo (Y. alpina) which were classified into three position (top, medium and bottom) to determined the main compositions especially cellulose, lignin, extractive and ash content. From all culms representative samples were converted to the required size of wood chips to prepared sample for chemical testing. Then the specimens prepared from bottom, middle and top portions for the three ages were used to determine the chemical properties in accordance to American Society for Testing and Materials (ASTM) standards except for cellulose test determined according to Kurschner and Hoffer method. All parameters in the experiment were expressed by percent based on dry basis. From this research, we have found small but significant increases in mean cellulose content from the base to the top of the culm at all three ages. The lignin content in Y. alpina species of bamboo is in the ranged of 23.04 to 30.03%. The mean values of the chemical constituents in 3, 4 and 5- year-old culms were 51.83, 54.94 and 49.78% for cellulose content, 28.28, 24.99 and 24.53% for lignin content, 7.8, 10.09, and 9.54% for alcohol-toluene extractive, respectively. In general, the comprehensive knowledge of the chemical components in the bamboo species will facilitate the use of the materials in the forestry industrial sector and help to enhance their utilization in the chemical and bio-chemical related industry.

scholarly journals Assessment of Pellets from Three Forest Species: From Raw Material to End Use

Forests ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 447
Author(s):  
Miguel Alfonso Quiñones-Reveles ◽  
Víctor Manuel Ruiz-García ◽  
Sarai Ramos-Vargas ◽  
Benedicto Vargas-Larreta ◽  
Omar Masera-Cerutti ◽  
...  
Keyword(s):  
Chemical Properties ◽  
Ash Content ◽  
Hot Water ◽  
Raw Material ◽  
Chemical Components ◽  
Energy Yield ◽  
Cellulose Content ◽  
Fixed Carbon ◽  
End Use ◽  
The Impact

This study aimed to evaluate and compare the relationship between chemical properties, energy efficiency, and emissions of wood and pellets from madroño Arbutus xalapensis Kunth, tázcate Juniperus deppeana Steud, and encino colorado Quercus sideroxyla Humb. & Bonpl. in two gasifiers (top-lit-up-draft (T-LUD) and electricity generation wood camp stove (EGWCS)) in order to determine the reduction of footprint carbon. In accordance with conventional methodologies, we determined the extracts and chemical components (lignin, cellulose, holocellulose), and the immediate analyses were carried out (volatile materials, fixed carbon, ash content and microanalysis of said ash), as well as the evaluation of emission factors (total suspended particulate matter (PM2.5), CO, CO2, CH4, black carbon (BC), elemental carbon (EC), and organic carbon (OC)). The results were statistically analyzed to compare each variable among species and gasifiers. The raw material analyzed showed how the pH ranged from 5.01 to 5.57, and the ash content ranged between 0.39 and 0.53%. The content values of Cu, Zn, Fe, Mg, and Ca ranged from 0.08 to 0.22, 0.18 to 0.19, 0.38 to 0.84, 1.75 to 1.90, and 3.62 to 3.74 mg kg−1, respectively. The extractive ranges from cyclohexane were 2.48–4.79%, acetone 2.42–4.08%, methanol 3.17–7.99%, and hot water 2.12–4.83%. The range of lignin was 18.08–28.60%. The cellulose content ranged from 43.30 to 53.90%, and holocellulose from 53.50 to 64.02%. The volatile material range was 81.2–87.42%, while fixed carbon was 11.30–17.48%; the higher heating value (HHV) of raw material and pellets presented the ranges 17.68–20.21 and 19.72–21.81 MJ kg−1, respectively. Thermal efficiency showed statistically significant differences (p < 0.05) between pellets and gasifiers, with an average of 31% Tier 3 in ISO (International Organization for Standardization) for the T-LUD and 14% (ISO Tier 1) for EGWCS, with Arbutus xalapensis being the species with the highest energy yield. The use of improved combustion devices, as well as that of selected raw material species, can reduce the impact of global warming by up to 33% on a cooking task compared to the three-stone burner.

Design of Laboratory Studies to Develop the Chemical Formulation for Surfactant-Polymer Flooding

2021 ◽  
Author(s):  
Dmitry Gospodarev ◽  
Igor Lymar ◽  
Aleksandra Rakutko ◽  
Anastasia Antuseva ◽  
Dmitry Tkachev
Keyword(s):  
Thermal Stability ◽  
Physical Simulation ◽  
Research Work ◽  
Polymer Flooding ◽  
Core Material ◽  
Chemical Components ◽  
Laboratory Studies ◽  
Static Adsorption ◽  
Reservoir Models ◽  
Surfactant Solutions

Abstract Nowadays, chemical EOR methods are becoming more and more relevant, among which the alkali-surfactant-polymer flooding is of particular interest. The efficiency of this technology largely depends on the correct choice of the components of chemical formulation, which should be based on a set of laboratory experiments carried out in a given sequence. This paper presents a methodological approach to laboratory studies in order to develop an optimal surfactant-polymer formulation, taking into account the geological and physical characteristics of the target field and the properties of reservoir fluids. The experimental part of the research work was carried out in several stages, involving the analysis of the physicochemical characteristics of reservoir oil, the screening studies of surfactant and polymer samples, as well as a series of coreflood tests with a selected chemical formulation on the terrigenous reservoir models. During screening studies, the solubility and compatibility of the chemical components, the phase behavior of surfactant solutions with oil at different salinity values and water-oil ratios, static adsorption of chemicals on the rock and their thermal stability at reservoir temperature were investigated. Optimization of the chemical formulation was based on the results of IFT measurements of the surfactant solutions and rheological studies of the polymer solutions. At the stage of coreflood tests, physical simulation of the surfactant-polymer flooding was carried out on reservoir models using natural core material in order to optimize the composition and slug size of the developed chemical formulation. The obtained results of the displacement experiment were matched by numerical 1D simulation. Based on the results of the studies performed, an effective surfactant-polymer formulation has been designed, which provides the ultra-low IFT (2.8·10−4 mN/m) values and the ability to form stable middle-phase microemulsions when interacting with oil. The findings of thermal stability and static adsorption experiments confirmed a feasibility of selected chemicals for practical application. Within the framework of the study, the key technical parameters of proposed formulation were determined, which are required for up-scaled simulation study of the chemical flooding process at pilot site.

Effect of High-Temperature Defibration on the Chemical Structure of Hardwood

Holzforschung ◽  
2002 ◽  
Vol 56 (1) ◽  
pp. 51-59 ◽  
Author(s):  
P. Widsten ◽  
J.E. Laine ◽  
P. Qvintus-Leino ◽  
S. Tuominen
Keyword(s):  
High Temperature ◽  
Lignin Content ◽  
Bulk Composition ◽  
Chemical Properties ◽  
Water Extract ◽  
Fiber Surface ◽  
Phenolic Hydroxyl ◽  
Hydroxyl Groups ◽  
Surface Chemical ◽  
Alkyl Aryl

Summary The present paper aims at elucidating the effect of high-temperature defibration at different temperatures on the bulk and surface chemical properties of defibrated birch, aspen and eucalypt. The results indicate that defibration of these hardwoods results in partial depolymerization of fiber lignin via (homolytic) cleavage of interunit alkyl-aryl (β-O-4) ether bonds. This increases the phenolic hydroxyl content and produces relatively stable (phenoxy) radicals. Syringyl-type lignin is more extensively depolymerized than guaiacyl-type lignin. Defibration generates water-extractable material, which is enriched in hemicellulose-derived carbohydrates and has a substantial content of aromatic compounds rich in phenolic hydroxyl groups. The amount of water-extract and the extent of lignin interunit ether bond cleavage increase with an increase in defibration temperature. The differences between various hardwood species in this respect are small. The surface chemical composition of the fibers differs considerably from their bulk composition, but is not significantly influenced by variations in defibration temperature. Lipophilic extractives cover a large portion of the fiber surface, while the lignin content of lipophilic extractives-free fiber surfaces is 2–3 times as high as the bulk lignin content of the fibers.

scholarly journals Chemical composition of germinating Tunisian almond (Prunus Amygdalus Mill.) seedlings oil

2021 ◽  
Vol 48 (2) ◽  
Author(s):  
Refka Dhouibi ◽  
◽  
Hanen Oueslati ◽  
Senda Bahri ◽  
Khaled Jabou ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Unsaturated Fatty Acids ◽  
Lipolytic Activity ◽  
Chemical Properties ◽  
Dry Mass ◽  
Chemical Components ◽  
Prunus Amygdalus ◽  
Almond Oil ◽  
Physico Chemical ◽  
Total Fatty Acids

Almonds (Prunus amygdalus) are a rich source of many essential nutrients. However, there is a lack of enough information on almond varieties' biochemical composition, especially at the germination stage. Therefore, this study was conducted to determine the chemical components of the germinating Tunisian almonds. The study included determining the content of oils, proteins, fatty acids, and triglycerides during germination. Results indicated that the oleaginous seeds are rich in oil (55 to 65% of the dry mass) and crude protein (21.825 mg/mL). The dominant polyunsaturated fatty acids are oleic and linoleic acids which represent 64.53% and 24.38%, respectively, while palmitic acid is the most dominant saturated fatty acid with 7.65% of the total fatty acids. Also, the primary molecular types of triglycerides detected by L.C. analysis are triolein (32.3%) and dioleolinolein (24.0%), followed by palmitodiolein (12.5%) and oleodilinolein (12.6%.). The physico-chemical properties study revealed that almond oil remains stable, thus preserving its quality and nutritional value, even during transition from dormancy to germination. On the other hand, we also detected the presence of a lipolytic activity which is maximum on the 3rd day of germination (4.66 mUI). Our results indicate that almond oil plays an important role in human nutrition due to the presence of unsaturated fatty acids, and it is more stable than other oils.

scholarly journals A Strategy to Synthesize Multilayer Graphene in Arc-Discharge Plasma in a Semi-Opened Environment

Materials ◽  
2019 ◽  
Vol 12 (14) ◽  
pp. 2279 ◽  
Author(s):  
Hai Tan ◽  
Deguo Wang ◽  
Yanbao Guo
Keyword(s):  
Discharge Plasma ◽  
Arc Discharge ◽  
Chemical Reduction ◽  
Chemical Properties ◽  
Chemical Vapor ◽  
Chemical Components ◽  
Multilayer Graphene ◽  
Whole Process ◽  
Hazardous Chemical ◽  
Physical And Chemical

Graphene, as the earliest discovered two-dimensional (2D) material, possesses excellently physical and chemical properties. Vast synthetic strategies, including chemical vapor deposition, mechanical exfoliation, and chemical reduction, are proposed. In this paper, a method to synthesize multilayer graphene in a semi-opened environment is presented by introducing arc-discharge plasma technology. Compared with previous technologies, the toxic gases and hazardous chemical components are not generated in the whole process. The synthesized carbon materials were characterized by transmission electron microscopy, atomic force microscopy, X-ray diffraction, and Raman spectra technologies. The paper offers an idea to synthesize multilayer graphene in a semi-opened environment, which is a development to produce graphene with arc-discharge plasma.

scholarly journals Aerosol hygroscopic growth, contributing factors, and impact on haze events in a severely polluted region in northern China

2019 ◽  
Vol 19 (2) ◽  
pp. 1327-1342 ◽  
Author(s):  
Jun Chen ◽  
Zhanqing Li ◽  
Min Lv ◽  
Yuying Wang ◽  
Wei Wang ◽  
...  
Keyword(s):  
Water Vapor ◽  
Chemical Properties ◽  
Water Vapor Content ◽  
Growth Effect ◽  
Chemical Components ◽  
Hygroscopic Growth ◽  
Contributing Factors ◽  
Total Particulate Matter ◽  
Size Category ◽  
The Impact

Abstract. This study investigates the impact of the aerosol hygroscopic growth effect on haze events in Xingtai, a heavily polluted city in the central part of the North China Plain (NCP), using a large array of instruments measuring aerosol optical, physical, and chemical properties. Key instruments used and measurements made include the Raman lidar for atmospheric water vapor content and aerosol optical profiles, the PC-3016A GrayWolf six-channel handheld particle and mass meter for atmospheric total particulate matter (PM) that has diameters less than 1 and 2.5 µm (PM1 and PM2.5, respectively), the aerosol chemical speciation monitor (ACSM) for chemical components in PM1, and the hygroscopic tandem differential mobility analyzer (H-TDMA) for aerosol hygroscopicity. The changes in PM1 and PM2.5 agreed well with that of the water vapor content due to the aerosol hygroscopic growth effect. Two cases were selected to further analyze the effects of aerosol hygroscopic growth on haze events. The lidar-estimated hygroscopic enhancement factor for the aerosol backscattering coefficient during a relatively clean period (Case I) was lower than that during a pollution event (Case II) with similar relative humidity (RH) levels of 80 %–91 %. The Kasten model was used to fit the aerosol optical hygroscopic growth factor (GF) whose parameter b differed considerably between the two cases, i.e., 0.1000 (Case I) versus 0.9346 (Case II). The aerosol acidity value calculated from ACSM data for Case I (1.35) was less than that for Case II (1.50) due to different amounts of inorganics such as NH4NO3, NH4HSO4, and (NH4)2SO4. Model results based on H-TDMA data showed that aerosol hygroscopic growth factors in each size category (40, 80, 110, 150, and 200 nm) at different RH levels (80 %–91 %) for Case I were lower than those for Case II. For similar ambient RH levels, the high content of nitrate facilitates the hygroscopic growth of aerosols, which may be a major factor contributing to heavy haze episodes in Xingtai.

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