Entropy-based theory of thermomagnetic phenomena

Author(s):  
Andrei Sergeev ◽  
Michael Reizer

We show that in the linear response approximation only entropy provides coupling between thermal and electric phenomena. The dissipationless quantum currents — magnetization, superconducting, persistent and topological edge currents — do not produce and transfer entropy and may be excluded from final formulas for thermomagnetic coefficients. The magnetization energy flux, [Formula: see text], in crossed electric and magnetic fields strongly modifies the Poynting vector in magnetic materials and metamaterials, but do not contribute to the heat current. Calculating entropy fluxes of fluctuating Cooper pairs in pure and disordered superconductors, we obtained the fluctuation Nernst coefficient proportional to [Formula: see text] ([Formula: see text] is the Fermi energy). We also introduce the thermomagnetic entropy per unit charge and derive the Nernst coefficient proportional to the difference of the thermoelectric and thermomagnetic entropies. This explains the Sondheimer cancellation and high sensitivity of thermomagnetic phenomena to correlations. In 2D superconductors, the transport entropy transferred by a vortex moving through the background formed by vortex–antivortex pairs is the configuration entropy of [Formula: see text], which strongly exceeds the intrinsic entropy of vortex core. Beyond the linear response, the nonentropic forces can lead to phenomena unexpected from thermodynamics, such as vortex attraction to the moving hot spot. Quantum currents do not transfer entropy and may be used as ideal connectors to quantum nanodetectors.

2020 ◽  
Vol 12 (49) ◽  
pp. 55362-55371
Author(s):  
Tingting Zhao ◽  
Li Yuan ◽  
Tongkuai Li ◽  
Longlong Chen ◽  
Xifeng Li ◽  
...  

2020 ◽  
Vol 9 (5) ◽  
pp. 247-251
Author(s):  
Tilmann Sander ◽  
Anna Jodko-Władzińska ◽  
Stefan Hartwig ◽  
Rüdiger Brühl ◽  
Thomas Middelmann

AbstractThe electrophysiological activities in the human body generate electric and magnetic fields that can be measured noninvasively by electrodes on the skin, or even, not requiring any contact, by magnetometers. This includes the measurement of electrical activity of brain, heart, muscles and nerves that can be measured in vivo and allows to analyze functional processes with high temporal resolution. To measure these extremely small magnetic biosignals, traditionally highly sensitive superconducting quantum-interference devices have been used, together with advanced magnetic shields. Recently, they have been complemented in usability by a new class of sensors, optically pumped magnetometers (OPMs). These quantum sensors offer a high sensitivity without requiring cryogenic temperatures, allowing the design of small and flexible sensors for clinical applications. In this letter, we describe the advantages of these upcoming OPMs in two exemplary applications that were recently carried out at Physikalisch-Technische Bundesanstalt (PTB): (1) magnetocardiography (MCG) recorded during exercise and (2) auditory-evoked fields registered by magnetoencephalography.


2021 ◽  
pp. 112067212199663
Author(s):  
Kemal Turgay Özbilen ◽  
Tuncay Gündüz ◽  
Selva Nur Çukurova Kartal ◽  
Ali Ceyhun Gedik ◽  
Mefküre Eraksoy ◽  
...  

Purpose: Bruch’s membrane opening-minimum rim width (BMO-MRW) and RNFL measured using anatomic positioning system (APS-RNFL) are novel OCT methods and remained unexplored in MS patients. To investigate the novel parameters of spectral-domain OCT as an alternative biomarker in patients with multiple sclerosis (MS). Methods: Retrospective cohort study; participants consisted of relapsing-remitting MS (RRMS) patients and healthy controls (HC). Eyes were classified according to the presence of MS and previous optic neuritis (ON). Measurements of standard peripapillary RNFL (S-RNFL), BMO-MRW, and APS-RNFL were performed. Result: A total of 244 eyes of 122 participants (MS-patients: 63, HC: 59) were included in the study. Fifty-one eyes had a history of previous ON. In almost all measured parameters, neuroretinal rim thicknesses were observed the thinnest in eyes with ON history between all subgroups. S-RNFL and APS-RNFL techniques showed the difference in neuroretinal rim thickness in all three subjects (ON+, ON−, and HC). However, BMO-MRW, on the other hand, could not distinguish between ON(−) patients and HC. The relationship between OCT parameters and EDSS were observed only in eyes with an ON history in all three techniques. A meaningful model with 78% accuracy was obtained by using only the OCT parameters as risk factors. In the ROC analysis, no parameters were found to have acceptable high sensitivity and specificity. BMO-MRW was statistically weaker in every aspect than other RNFL techniques. Conclusion: The novel APS-RNFL technique appears to be a bit more reliable alternative to S-RNFL technique to support therapeutic decision-making in MS. BMO-MRW has not been found as a successful alternative to S-RNFL.


2021 ◽  
Author(s):  
Feng Gao ◽  
Xiaolong Tu ◽  
Yongfang Yu ◽  
Yansha Gao ◽  
Jin Zou ◽  
...  

Abstract Herein, an efficient electrochemical sensing platform is proposed for selective and sensitive detection of nitrite on the basis of Cu@C@Zeolitic imidazolate framework-8 (Cu@C@ZIF-8) heterostructure. Core-shell Cu@C@ZIF-8 composite was synthesized by pyrolysis of Cu-metal-organic framework@ZIF-8 (Cu-MOF@ZIF-8) in Ar atmosphere on account of the difference of thermal stability between Cu-MOF and ZIF-8. For the sensing system of Cu@C@ZIF-8, ZIF-8 with proper pore size allows nitrite diffuse through the shell, while big molecules cannot, which ensures high selectivity of the sensor. On the other hand, Cu@C as electrocatalyst promotes the oxidation of nitrite, thereby resulting high sensitivity of the sensor. Accordingly, the Cu@C@ZIF-8 based sensor presents excellent performance for nitrite detection, which achieves a wide linear response range of 0.1 µM to 300.0 µM, and a low limit of detection (LOD) of 0.033 µM. In addition, the Cu@C@ZIF-8 sensor possesses excellent stability and reproducibility, and was employed to quantify nitrite in sausage samples with recoveries of 95.45-104.80%.


1988 ◽  
Vol 136 (1) ◽  
pp. 351-361
Author(s):  
LEONA MATTSOFF ◽  
MIKKO NIKINMAA

We studied the effects of acute external acidification on the acid-base status and plasma and red cell ion concentrations of lampreys. Mortality was observed within 24 h at pH5 and especially at pH4. The main reason for the high sensitivity of lampreys to acid water appears to be the large drop in blood pH: 0.6 and 0.8 units after 24 h at pH5 and pH4, respectively. The drop of plasma pH is much larger than in teleost fishes exposed to similar pH values. The difference in the plasma pH response between lampreys and teleosts probably results from the low buffering capacity of lamprey blood, since red cells cannot participate in buffering extracellular acid loads. Acidification also caused a decrease in both Na+ and C− concentrations and an elevation in K+ concentration of plasma. The drop in plasma Na+ concentration occurred faster than the drop in plasma Cl− concentration which, in turn, coincided with the decrease in total CO2 concentration of the blood.


2019 ◽  
Author(s):  
Huilan Yao ◽  
Grant Wu ◽  
Subhasree Das ◽  
Crystal MacKenzie ◽  
Hua Gao ◽  
...  

AbstractHere we report on the development of a sensitive and cost-effective method to longitudinally trackESR1andPIK3CAmutations from cfDNA in patients with metastatic breast cancer (MBC) using a streamlined and de-centralized workflow. Hotspot mutations inESR1have been shown to cause resistance to aromatase inhibitor–based and anti-estrogenic therapies, whilePIK3CAmutations have high prevalence in MBC. As a result, their utility as circulating biomarkers to predict or monitor response in the clinical development of investigational compounds has been the focus of many studies. Six regions inESR1andPIK3CAgenes containing 20 hotspot mutations were pre-amplified, followed by optimized singleplex ddPCR assays to detect allele frequencies of individual mutations. Without pre-amplification, the limit of detection (LOD) and limit of linearity (LOL) of individual ddPCR assays were at 0.05-0.1% and 0.25% level, respectively. With pre-amplification, the LOD and LOL were slightly elevated at 0.1-0.25% and 0.25-0.5% levels, respectively. High concordance was achieved to the BEAMing assay (Sysmex Inostics) for mutation positive assays (r=0.98, P<0.0001). In conclusion, coupling pre-amplification and ddPCR assays allowed us for the detection of up to 20 hot spot mutations inESR1andPIK3CAwith high sensitivity and reproducibility.


In a previous paper it was shown that 0·0007 per cent, of 29 Cu and 0·0003 per cent, of 26 Fe could be detected in 30 Zn by atomic analysis by X-ray spectroscopy. This sensitivity is greater than that which was claimed by Noddack, Tacke, and Berg, who set the limit at about 0·1 per cent, for non-metals, and by Hevesy, who stated it to be about 0·01 per cent, for an element present in an alloy. It was later suggested by Hevesy that the high value of the sensitivity which we found might result from the fact that some of the alloys we had used were composed of elements of almost equal atomic number, and that the sensitivity would be smaller for a constituent of low atomic number mixed with a major constituent of high atomic number. To elucidate these disagreements we have made further observations of the sensitivity with elements of different atomic number and have investigated the conditions which can influence the sensitivity. The Factors Determining Sensitivity . The detection of one element in a mixture of elements depends upon the identification of its K or L lines in the general spectrum emitted by the mixture under examination. The intensity with which these lines are excited in the target (“excited intensity”) is proportional to the number of atoms of the constituent element excited, i. e ., to its concentration and to the volume of the target in which the cathode ray energy is absorbed. The depth of penetration of the cathode rays is determined by the density of the target material and by their velocity ( i. e ., by the voltage applied to the X-ray tube). Schonland has shown that the range of homogeneous cathode rays in different elements, expressed as a mass per unit area, is approximately constant and is independent of the atomic number of the absorbing element. When their velocity is increased, the cathode rays will penetrate to a greater depth, and therefore a greater number of atoms of all constituents will be ionised. This will increase the “excited intensity” of the lines due to the particular constituent sought equally with those lines of the other elements present. The intensity of a line further depends upon the difference between the voltage applied to the X-ray tube and that necessary to excite the series. For these reasons, a high applied voltage is required for a high sensitivity.


2020 ◽  
Vol 4 ◽  
pp. 65-71
Author(s):  
E.A. Veshkin ◽  
◽  
V.I. Postnov ◽  
V.V. Semenychev ◽  
E.V. Krasheninnikova ◽  
...  

The change in the microhardness over the thickness of samples made of EDT-69N binder cured in vacuum and at atmospheric pressure at temperatures from 130 to 170°C was investigated. It was found that the change in microhardness along the thickness of the samples occurs according to the parabolic law, with the maximum values being achieved in the middle of the sample cross-section along the thickness. With an increase in the molding temperature, the microhardness in the middle section of the sample increases from 222 MPa at a molding temperature of 130°C to 410 MPa during molding at 170°C. At the critical molding temperature (170°C), the microhardness in all zones of the specimen cross section (subsurface, semi-average, and core) levels off, while the parabolic dependence degenerates into a straight line. It is shown that the method of scratching (sclerometry) demonstrated a sufficiently high sensitivity to the state of samples cured at different temperatures. With an increase in the molding temperature, the width of the sclerometric grooves decreases. At a critical molding temperature of 170°C, the groove width is stabilized and becomes constant throughout the sample thickness. To characterize the difference in the values of the microhardness of the cured binder in the sample volume, it is proposed to use a dimensionless “coefficient of volume anisotropy,” which can take a positive, negative or zero value. With an increase in the curing temperature of the binder and, accordingly, with an increase in the microhardness of the sample, the coefficient of volume anisotropy decreases, and when the samples are molded at the critical temperature, it turns to zero, which indicates the absence of anisotropy.


2020 ◽  
Author(s):  
Lukasz Lelek ◽  
Joanna Kulczycka

Abstract The life cycle phase of fossil fuel extraction is mainly considered in the LCA when evaluating the energy production processes. It is then only one of many unit processes, which contribute to the blurring of mining-relevant results. There are few items in the literature focusing exclusively on the lignite mining phase and analysing the specific mining conditions and associated environmental impacts. The article focuses on the LCA of lignite mining pro-cesses on the basis of data coming from a Polish mine. The technology for opencast lignite mining is noted for its high production efficiency, high level of recovery and lower risk as regards the safety of workers when compared with underground mining systems. However, the need to remove large amounts of overburden to uncover the deposit contributes to a much greater degradation of the landscape. Analysing the results obtained, several key (hot spot) elements of the lignite mining operations were distinguished for modelling the environmental impact, i.e.: calorific value, the amount of electricity consumption, the manner in which waste and overburden are managed. As a result there is a high sensitivity of the final indicator to changes in these impacts.


2017 ◽  
Vol 4 (2) ◽  
pp. 286
Author(s):  
Jajang Nuryana ◽  
I Gede Hendrawan ◽  
Widiastuti Karim

National Ocean Atmospheric Administrations (NOAA) by the program coral reef Watch (CRW) has developed a method to estimate the potential of coral bleaching using Sea Surface Temperature (SST). The products are hot spot (HS) and degree heating week (DHW). HS is the SST 1°C (SSTL?1) above normal and DHW is the length of HS inhabits a place. The CRW product do not provided detail informations because it has a lower resolution. It is need a satellite image with a higher resolution to provide better informations. One of the satellite images that can be used is Moderate Resolution Imaging Spectroradiometer (MODIS) with a spatial resolution of 1 km. The purpose of this study was to know HS and DHW distribution patterns and status of coral bleaching in Bali waters seen from the analysis of HS and DHW. MODIS data is used daily, then do mosaicing process to get a weekly SPL (8 daily) and the monthly SST. Monthly SPL normally used to get maximum montly mean (MMM). HS obtained from the difference between 8 daily weekly SST and SST normal (MMM).).Location bleaching based on data Coral Triangle Center (CTC) and coralwatch.org.  SST results revealed difference of SPL in 2015 and 2016 amounted to 1.48°C. Highest DHW in Bali Hai, Nusa Penida is 10 465° C-weeks in April 2016. Based on the value HS and DHW coral reefs in Bali waters threatened bleaching level Alert 1 and Alert level 2.


Sign in / Sign up

Export Citation Format

Share Document