scholarly journals Impedance spectroscopic study on hybrid phthalocyanine/lead sulphide nanocomposite film

2019 ◽  
Vol 23 (11n12) ◽  
pp. 1622-1628
Author(s):  
Zahra Khozaee ◽  
Isabelle Chambrier ◽  
L. Sosa Vargas ◽  
Andrew N. Cammidge ◽  
Asim K. Ray
Keyword(s):  
Indium Tin Oxide ◽  
Low Cost ◽  
Localized States ◽  
Lead Sulphide ◽  
Cbh Model ◽  
Universal Power Law ◽  
The Matrix ◽  
Pbs Quantum Dots ◽  
Model Point ◽  
Ac Conduction

A unique organic/inorganic nanocomposite of non-aggregated lead sulphide (PbS) quantum dots (QDs) dispersed within a spun film of non-peripherally octakis(hexyl)-substituted metal-free phthalocyanine (C[Formula: see text]H[Formula: see text]Pc) has been prepared at room temperature by a simple and low-cost method. The frequency response of alternating current (AC) conduction in a 130 nm thick C[Formula: see text]H[Formula: see text]Pc /PbS film sandwiched between the indium-tin-oxide (ITO) and aluminum (Al) electrodes is found to obey the universal power-law. The cryogenic study of AC conduction reveals that the correlated barrier hopping (CBH) model closely fits to the experimental data at temperatures below 240 K. The parameters obtained by fitting the CBH model point out that the hopping process cannot take place directly between neighboring PbS QDs but involves the localized states within the matrix.

scholarly journals Room-Temperature Solution-Processed 0D/1D Bilayer Electrodes for Translucent CsPbBr3 Perovskite Photovoltaics

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1489
Author(s):  
Bhaskar Parida ◽  
Saemon Yoon ◽  
Dong-Won Kang
Keyword(s):  
Solar Cells ◽  
Indium Tin Oxide ◽  
High Performance ◽  
Room Temperature ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Ambient Air ◽  
Plasma Damage ◽  
Temperature Solution ◽  
Ito Nanoparticles

Materials and processing of transparent electrodes (TEs) are key factors to creating high-performance translucent perovskite solar cells. To date, sputtered indium tin oxide (ITO) has been a general option for a rear TE of translucent solar cells. However, it requires a rather high cost due to vacuum process and also typically causes plasma damage to the underlying layer. Therefore, we introduced TE based on ITO nanoparticles (ITO-NPs) by solution processing in ambient air without any heat treatment. As it reveals insufficient conductivity, Ag nanowires (Ag-NWs) are additionally coated. The ITO-NPs/Ag-NW (0D/1D) bilayer TE exhibits a better figure of merit than sputtered ITO. After constructing CsPbBr3 perovskite solar cells, the device with 0D/1D TE offers similar average visible transmission with the cells with sputtered ITO. More interestingly, the power conversion efficiency of 0D/1D TE device was 5.64%, which outperforms the cell (4.14%) made with sputtered-ITO. These impressive findings could open up a new pathway for the development of low-cost, translucent solar cells with quick processing under ambient air at room temperature.

scholarly journals Direct measurement of the thermoelectric properties of electrochemically deposited Bi2Te3 thin films

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jose Recatala-Gomez ◽  
Pawan Kumar ◽  
Ady Suwardi ◽  
Anas Abutaha ◽  
Iris Nandhakumar ◽  
...  
Keyword(s):  
Thin Films ◽  
Thermoelectric Properties ◽  
Bismuth Telluride ◽  
Indium Tin Oxide ◽  
Seed Layer ◽  
Room Temperature ◽  
Low Cost ◽  
Temperature Dependent ◽  
Temperature Heat ◽  
Electrochemically Deposited

Abstract The best known thermoelectric material for near room temperature heat-to-electricity conversion is bismuth telluride. Amongst the possible fabrication techniques, electrodeposition has attracted attention due to its simplicity and low cost. However, the measurement of the thermoelectric properties of electrodeposited films is challenging because of the conducting seed layer underneath the film. Here, we develop a method to directly measure the thermoelectric properties of electrodeposited bismuth telluride thin films, grown on indium tin oxide. Using this technique, the temperature dependent thermoelectric properties (Seebeck coefficient and electrical conductivity) of electrodeposited thin films have been measured down to 100 K. A parallel resistor model is employed to discern the signal of the film from the signal of the seed layer and the data are carefully analysed and contextualized with literature. Our analysis demonstrates that the thermoelectric properties of electrodeposited films can be accurately evaluated without inflicting any damage to the films.

FOAMING AND MOISTURE CROSSLINKING OF VINYL TRIETHOXY SILANE GRAFTED ETHYLENE–PROPYLENE–DIENE TERPOLYMER

2022 ◽  
Author(s):  
Zhengwei Lin ◽  
Qinghong Zhang ◽  
Gongliang Wang ◽  
Jie Mao ◽  
Martin Hoch ◽  
...  
Keyword(s):  
High Efficiency ◽  
Low Cost ◽  
Side Reaction ◽  
High Energy ◽  
Expansion Ratio ◽  
Ethylene Propylene ◽  
Foaming Process ◽  
The Matrix ◽  
High Energy Absorption ◽  
Ethylene Propylene Diene Terpolymer

ABSTRACT Moisture crosslinking of polyolefins has attracted increasing attention because of its high efficiency, low cost, and easy processing. However, the crucial shortcoming of moisture crosslinking is that the side reaction of peroxide scorch (precrosslinking) simultaneously occurs in silane grafting. It has been recognized that making peroxide precrosslinking useful is an effective way to broaden the application of moisture crosslinking. A novel foaming process combined with moisture crosslinking is proposed. The matrix of ethylene–propylene–diene terpolymer grafted with silane vinyl triethoxysilane (EPDM-g-VTES) was prepared by melt grafting, with dicumyl peroxide as initiator. Foaming was then carried out with azodicarbonamide (AC) as the blowing agent by making use of precrosslinking. Subsequently, the EPDM-g-VTES foams were immersed in a water bath to achieve moisture crosslinking with dibutyl tin dilaurate as the catalyst. The results showed that VTES was grafted onto EPDM and the EPDM-g-VTES foams were successfully crosslinked by moisture. The EPDM-g-VTES compounds with AC obtained great cells by compression molding with the help of precrosslinking. The mechanical property of the EPDM-g-VTES foam was improved by moisture crosslinking. The moisture-cured foam with 4 wt% AC had an expansion ratio of about three times, which could bear large deformation and showed a high energy-absorption effect.

Effects of Chemical Modification of Indium-Tin-Oxide with Benzene Derivates on the Performance of Organic Photovoltaic Cells of ITO/CuPc/C60/BCP/Al

2011 ◽  
Vol 1288 ◽  
Author(s):  
Khayankhyarvaa Sarangerel ◽  
Altantsetseg Delgerjargal ◽  
Byambasuren Delgertsetseg ◽  
Chimed Ganzorig
Keyword(s):  
Chemical Modification ◽  
Tin Oxide ◽  
Indium Tin Oxide ◽  
Copper Phthalocyanine ◽  
Low Cost ◽  
Photovoltaic Cells ◽  
Organic Photovoltaic ◽  
Organic Thin Film ◽  
Organic Pv ◽  
20 Nm

ABSTRACTOrganic thin film photovoltaic (PV) cells have attracted attention because of their ease of fabrication and potential for low cost production. In this paper, we study the effects of chemical modification of indium-tin-oxide (ITO) on the performance of organic PV cells. The organic PV cells are fabricated, with the cell configuration of ITO/copper phthalocyanine (CuPc) (20 nm)/fullerene (C60) (40 nm)/Al with and without bathocuproine (BCP) (10 nm) between C60 and Al. By the use of para-substituted benzenesulfonyl chlorides with different terminal groups of H- and Cl-, the energy offset at the ITO/CuPc interface is tuned widely depending upon the interface dipoles and thus the correlation between the change in the ITO work function and the performance of the PV cells by chemical modification is examined.

scholarly journals Practical Implementation of an Indoor Robot Localization and Identification System using an Array of Anchor Nodes

2020 ◽  
Vol 16 (1) ◽  
pp. 1-8 ◽  
Author(s):  
Israa AL-Forati ◽  
Abdulmuttalib Rashid
Keyword(s):  
Search Algorithm ◽  
Low Cost ◽  
Binary Search ◽  
Practical Implementation ◽  
Identification System ◽  
Robot Localization ◽  
Light Emitting ◽  
The Matrix ◽  
Anchor Nodes ◽  
Binary Search Algorithm

This paper proposes a low-cost Light Emitting Diodes (LED) system with a novel arrangement that allows an indoor multi-robot localization. The proposed system uses only a matrix of low-cost LED installed uniformly on the ground of an environment and low-cost Light Dependent Resistor (LDR), each equipped on bottom of the robot for detection. The matrix of LEDs which are driven by a modified binary search algorithm are used as active beacons. The robot localizes itself based on the signals it receives from a group of neighbor LEDs. The minimum bounded circle algorithm is used to draw a virtual circle from the information collected from the neighbor LEDs and the center of this circle represents the robot’s location. The propose system is practically implemented on an environment with (16*16) matrix of LEDs. The experimental results show good performance in the localization process.

Fabrication of Low Cost 1D CdSe Nanowires using Near-field Electrospinning

2011 ◽  
Vol 1302 ◽  
Author(s):  
Leroy Magwood ◽  
Binil Starly
Keyword(s):  
Quantum Dots ◽  
Fluorescence Microscopy ◽  
Fiber Diameter ◽  
Low Cost ◽  
Near Field ◽  
Light Attenuation ◽  
Dimethyl Formamide ◽  
Cdse Quantum Dot ◽  
The Matrix ◽  
Cdse Nanowires

ABSTRACTWell-aligned, 1D CdSe quantum dot (QD) fibers (0.3μm to 2.5μm) containing up to 20wt% fluorescent quantum dots (QDs) were prepared by near-field electrospinning (NFES) process. Electrospun solutions were prepared using PVAc as the matrix polymer, dimethyl formamide (DMF) solvent and colloidal QDs in chloroform (CHCl3). The diameter of the fibers decreased as the ratio of DMF/CHCl3 is varied. QDs showed good dispersion and a linear relationship between QD loading and fiber diameter, as determined by the morphology measurements taken using TEM and SEM, respectively. Fluorescence microscopy shows that there is light attenuation throughout the fibers. Results also show that the NFES process may be used as a method to create aligned, 1D fibers of QDs and potentially other nanofibers.

AC CONDUCTION PHENOMENON OF Li2O–WO3–B2O3 GLASSES DOPED WITH V2O5

2013 ◽  
Vol 06 (03) ◽  
pp. 1350032 ◽  
Author(s):  
LINGANABOINA SRINIVASA RAO ◽  
NALLURI VEERAIAH ◽  
TUMU VENKATAPPA RAO
Keyword(s):  
High Temperatures ◽  
Ac Conductivity ◽  
Conduction Mechanism ◽  
Glass Composition ◽  
Melt Quenching ◽  
Frequency Exponent ◽  
Spreading Factor ◽  
Cbh Model ◽  
Tan Δ ◽  
Ac Conduction

The glass composition 40 Li 2 O –5 WO 3–(55−x) B 2 O 3: x V 2 O 5 for x = 0.2, 0.4, 0.6 and 0.8 is chosen for the present study. The glass samples were synthesized by conventional melt-quenching technique. The dielectric properties such as constant (ε′), loss (tan δ) and ac conductivity (σac) are carried out as a function of temperature (30–270°C) and frequency (102–105 Hz). The glass sample (at x = 0.6) exhibited highest ac conductivity (σac) and spreading factor (β) among all the samples. All glasses exhibited mixed conduction (both electronic and ionic) at high temperatures. The frequency exponent s denotes the ac conduction mechanism is associated with both QMT model (at low temperatures) and CBH model (at high temperatures).

Fabrication of Organic Small Molecular Thin Films based on Ultrasonic Spray-Assisted Vapor-Deposition Method

2012 ◽  
Vol 1400 ◽  
Author(s):  
Jinchun Piao ◽  
Shigetaka Katori ◽  
Takumi Ikenoue ◽  
Shizuo Fujita
Keyword(s):  
Thin Films ◽  
Indium Tin Oxide ◽  
Vapor Deposition ◽  
Low Cost ◽  
Device Fabrication ◽  
Deposition Method ◽  
Material Loss ◽  
Good Surface ◽  
Low Leakage ◽  
Molecular Thin Films

ABSTRACTSmall molecular thin films using solution-based method is a challengeable subject in organic optical and electronic devices. In our previous research, we successfully deposited aluminum tris(8-hydroxyquinoline) (Alq3) films on glass substrate. In this paper, aiming at future exploration of electroluminescent devices, we deposited N, N ’-Bis(3-methylphenyl)-N,N’- diphenylbenzidine) (TPD) films on indium-tin-oxide (ITO) substrates using the vapor-deposition method. Photoluminescence characteristics evidenced the actual formation of TPD thin films. Together with the good surface morphology and low leakage current of the films, the results are promising for actual device fabrication at low cost and low material loss.

Low-cost semi-transparent copper sulfide electrode for indium-tin-oxide-free perovskite solar cells

2018 ◽  
Vol 662 ◽  
pp. 90-96 ◽  
Author(s):  
Juan Tirado ◽  
Daniel Ramirez ◽  
Rafael Betancur ◽  
Franklin Jaramillo
Keyword(s):  
Solar Cells ◽  
Tin Oxide ◽  
Indium Tin Oxide ◽  
Copper Sulfide ◽  
Low Cost ◽  
Perovskite Solar Cells

New Generation Transparent Conducting Electrode Materials for Solar Cell Technologies

2021 ◽  
pp. 86-128
Keyword(s):  
Electrical Conductivity ◽  
Solar Cell ◽  
Indium Tin Oxide ◽  
Carbon Nanomaterials ◽  
Electrode Materials ◽  
Low Cost ◽  
Optical Transparency ◽  
Metal Mesh ◽  
Transparent Conducting ◽  
New Generation

Transparent conducting electrodes (TCEs) play a vital role for the fabrication of solar cells and pivoted almost 50% of the total cost. Recently several materials have been identified as TCEs in solar cell applications. Still, indium tin oxide (ITO) based TCEs have dominated the market due to their outstanding optical transparency and electrical conductivity. However, inadequate availability of indium has increased the price of ITO based TCEs, which attracts the researchers to find alternative materials to make solar technology economical. In this regard, various kinds of conducting materials are available and synthesized worldwide with high electrical conductivity and optical transparency in order to find alternative to ITO based electrodes. Especially, new generation nanomaterials have opened a new window for the fabrication of cost effective TCEs. Carbon nanomaterials such as graphene, carbon nanotubes (CNTs), metal nanowires (MNWs) and metal mesh (MMs) based electrodes especially attracted the scientific community for fabrication of low cost photovoltaic devices. In addition to it, various conducting polymers such as poly (3, 4-ethylene dioxythiophene): poly (styrenesulfonate) (PEDOT:PSS) based TCEs have also showed their candidacy as an alternative to ITO based TCEs. Thus, the present chapter gives an overview on materials available for the TCEs and their possible use in the field of solar cell technology

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