scholarly journals Dissolved Concentrations, Sources, and Risk Evaluation of Selected Metals in Surface Water from Mangla Lake, Pakistan

2014 ◽  
Vol 2014 ◽  
pp. 1-12 ◽  
Author(s):  
Muhammad Saleem ◽  
Javed Iqbal ◽  
Munir H. Shah
Keyword(s):  
Surface Water ◽  
Water Conservation ◽  
Hazard Quotient ◽  
Hazard Index ◽  
Water Reservoir ◽  
Principal Component ◽  
Atomic Absorption Spectrophotometry ◽  
Conservation Strategy ◽  
Flame Atomic Absorption ◽  
Metal Levels

The present study is carried out for the assessment of water quality parameters and selected metals levels in surface water from Mangla Lake, Pakistan. The metal levels (Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, Pb, Sr, and Zn) were determined by flame atomic absorption spectrophotometry. Average levels of Cd, Co, Cr, Ni, and Pb were higher than the allowable concentrations set by national and international agencies. Principal component analysis indicated significant anthropogenic contributions of Cd, Co, Cr, Ni, and Pb in the water reservoir. Noncarcinogenic risk assessment was then evaluated using Hazard QuotientHQing/dermand Hazard IndexHIing/dermfollowing USEPA methodology. For adults and children, Cd, Co, Cr, and PbHQing>1emerged as the most important pollutants leading to noncarcinogenic concerns via ingestion route, whereas there was no risk via dermal contact of surface water. This study helps in establishing pollutant loading reduction goal and the total maximum daily loads, and consequently contributes to preserve public health and develop water conservation strategy.

scholarly journals Trace Metal Contamination Characteristics and Health Risks Assessment ofCommelina africanaL. and Psammitic Sandflats in the Niger Delta, Nigeria

2016 ◽  
Vol 2016 ◽  
pp. 1-14 ◽  
Author(s):  
Nsikak U. Benson ◽  
Paul A. Enyong ◽  
Omowunmi H. Fred-Ahmadu
Keyword(s):  
Trace Metal ◽  
Niger Delta ◽  
Anthropogenic Activities ◽  
Hazard Quotient ◽  
Risk Index ◽  
Sediment Quality ◽  
Hazard Index ◽  
Adult Males ◽  
Metal Concentrations ◽  
Metal Levels

The purpose of this study was to investigate and quantify trace metal concentrations inCommelina africanaL. and psammitic sandflats from an intertidal coastal ecosystem in Niger Delta, Nigeria, and to evaluate their spatial distribution, degree of contamination, and source apportionment. The environmental risks associated with soil contamination were elaborately assessed using potential ecological risk index, sediment quality guidelines, and enrichment relative to background levels. The mean concentrations of Cd, Cr, Ni, Pb, and Zn in sandflat soil samples are0.76±9.0×10-2,7.39±8.7×10-1,2.28±0.35,0.024±4.0×10-3, and74.51±2.55 mg/kg, respectively. Metal levels indicate strong variability with sampling sites. The order of trace metal concentrations in theCommelina africanaL. samples isZn>Ni>Cr>Pb>Cd. The concentrations varied with the sample locations; and the levels of Pb (0.05 to 0.08 mg/kg) at all locations are found to be significantly below permissible level of 0.3 mg/kg. Potential sources of metal loadings may be associated with localised or diffused anthropogenic activities. The average carcinogenic risks are below1.0×10-6threshold values, and the sandflat soils are not considered to pose significant health effects to children and adult males and females. However, the carcinogenicity and noncarcinogenicity risks ranking decrease following the orderchildren>adult  males>adult  females. Comparatively, the hazard quotient and hazard index indicate that the psammitic sandflats might pose a health risk to children in future.

Potentially toxic metals and metalloids in surface water intended for human consumption and other uses in the Mantaro River watershed, Peru

2020 ◽  
Vol 15 (No. 4) ◽  
pp. 237-245
Author(s):  
María Custodio ◽  
Daniel Álvarez ◽  
Walter Cuadrado ◽  
Raúl Montalvo ◽  
Salomé Ochoa
Keyword(s):  
Surface Water ◽  
Toxic Metals ◽  
Atomic Absorption Spectrophotometry ◽  
Water Bodies ◽  
Human Consumption ◽  
Potentially Toxic Metals ◽  
Metals And Metalloids ◽  
Flame Atomic Absorption ◽  
Mine Wastewater ◽  
High Concentrations

The concentration of Cu, Fe, Pb, Zn and As in the surface water intended for human consumption and other uses in the Mantaro River basin were analysed using multivariate methods. The water samples were collected from seven water bodies in the Junín region in June 2019, in the low discharge period. In each body of water, a sector with six sampling sites was established. The Cu, Fe, Pb, Zn and As contents were determined by the flame atomic absorption spectrophotometry method. The correlation analysis revealed positive and significant correlations (P < 0.05) for the Zn/Pb, Pb/Fe and Zn/Fe pairs with a good association, higher than 0.80 and for the Pb/Cu, Fe/Cu, As/Pb and As/Zn pairs a weak degree of association (P < 0.05). The analysis of the main components showed three components with their own values > 1. The hierarchical grouping analysis classified the evaluated water bodies into three groups according to the concentration of the Cu, Fe, Pb, Zn and As. The high concentrations of heavy metals and arsenic recorded in the CIMIRM and MERIS irrigation channels reveal that the Mantaro River continues to be a sink for mine wastewater discharges and runoff from mining liabilities at the headwaters of the Mantaro basin. It is, therefore, necessary to implement urgent management policies to control and reduce the levels of contamination by potentially toxic metals and metalloids in the Mantaro River.

scholarly journals Non-carcinogenic and Carcinogenic Risk Assessment of Heavy Metals Exposure to Indoor Dust in Kathmandu, Nepal

2021 ◽  
Vol 42 (1) ◽  
pp. 16-28
Author(s):  
Sulakshya Bhandari ◽  
Sudarshana Shakya ◽  
Bijaya Adhikari ◽  
Mahesh Shrestha ◽  
Bindra Devi Shakya ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Land Use ◽  
Hazard Quotient ◽  
Heavy Traffic ◽  
Hazard Index ◽  
Carcinogenic Risk ◽  
Indoor Dust ◽  
Metal Exposure ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer

The present study was carried out to assess the contamination of heavy metals in indoor household dust of Kathmandu, Nepal, and its adverse effect on the indoor environment and human health. The concentrations of four heavy metals (Cd, Cr, Ni, and Pb) in a total of ninety-three (N = 93) indoor dust samples collected from four different types of land use zones viz., commercial, heavy traffic, residential, and control (undisturbed) of Kathmandu were determined by the flame atomic absorption spectrophotometer (FAAS). The mean concentrations of Cd, Cr, Ni, and Pb in indoor dust samples over the study zones were 0.89, 158.1, 113.3, and 65.3 mg kg−1, respectively. The land use zones showed the various degree of metal contamination in indoor dust ranging from moderate to considerable level. PLI showed a high pollution load in the monitored locations, indicating an alarming condition and the urgent need for immediate remedial actions. Hazard quotient (HQ) values indicated ingestion as the major pathway of indoor dust heavy metal exposure to children while the inhalation pathway remained dominant in adults. Hazard index (HI) values showed no probable non-carcinogenic risk of the heavy metals present in the indoor dust of Kathmandu. For carcinogenic health risk, TLCR values were found within the acceptable safe limit indicating no cancer risk for both the receptor groups.

scholarly journals Human Health Risk Assessment of Trace Metals in Surface Water Due to Leachate from the Municipal Dumpsite by Pollution Index: A Case Study from Ndawuse River, Abuja, Nigeria

2018 ◽  
Vol 16 (1) ◽  
pp. 214-227 ◽  
Author(s):  
Ibironke Titilayo Enitan ◽  
Abimbola Motunrayo Enitan ◽  
John Ogony Odiyo ◽  
Muhammad Mamman Alhassan
Keyword(s):  
Heavy Metals ◽  
Surface Water ◽  
Health Risk ◽  
Human Health ◽  
Heavy Metal Contamination ◽  
Hazard Quotient ◽  
Phase 1 ◽  
Human Health Risk ◽  
Hazard Index ◽  
Cumulative Exposure

AbstractThe study assessed the level of heavy metals in surface water across Ndawuse River near the dumpsite at Phase 1 District of the Federal Capital Territory (FCT), Abuja, Nigeria. The results indicated that oxygen demand, turbidity and heavy metals were above the standard limits set for drinking water. Multivariate analysis using principal component analysis and hierarchical cluster analysis revealed natural and anthropogenic activities as sources of heavy metal contamination. The estimated non-carcinogenic effects using hazard quotient toxicity potential, cumulative hazard index and daily human exposure dose of surface water through ingestion pathway were less than a unity. The estimated carcinogenic risks (CRing) exceeded the suggested potential risk limits, with lead (Pb) having the highest CRing value for all age groups. However, children were found to be more susceptible to heavy metals over a period of time according to the estimated values. The concentration of heavy metals in the investigated river could pose an adverse health risk to several communities that rely on this receiving water bodies for domestic purposes. Therefore, there is need for strict enforcement of environmental laws to protect aquatic ecosystem and to avoid long term cumulative exposure risk that heavy metals may pose on human health.

scholarly journals Anomalous Fluctuation of Halogens in Relation to the Pollution Status along Lake Mariout, Egypt

2020 ◽  
Vol 2020 ◽  
pp. 1-20
Author(s):  
Ghada F. El-Said ◽  
Gehan M. El Zokm ◽  
Abeer A. El Sayed ◽  
Ahmed A. El Ashmawy ◽  
Mohamed A. Shreadah
Keyword(s):  
Multivariate Analysis ◽  
Surface Water ◽  
Human Health ◽  
Pore Water ◽  
Hazard Quotient ◽  
Saturation Index ◽  
Hazard Index ◽  
Dermal Absorption ◽  
Pore Waters ◽  
Pollution Status

This paper aimed to study the anomalous fluctuation of halogens with respect to the pollution status in surface water (w), pore water (p), and sediments (s) of Lake Mariout. It provided a framework for understanding the distribution of dissolved and precipitated halogen salts related to the pollution status of the lake. The study cleared out that bromide was only the most abundant halogen in the three studied partitions. On contrast, sediment’s partition contained the lowest chloride content. Fluoride minerals, especially, fluorapatites and carbonate-fluorapatite (FAP and CFAP), had high Saturation Index (SI) values in surface water (42.77–51.95 and 16.04–60.89, respectively) and in pore water (51.26–54.60 and 17.52–78.33, respectively). Bromide and chloride were mainly found in the soluble forms in the surface water and pore waters. Iodide salts, (Ca(IO3)2 and Ca(IO3)2.6H2O), were moderately precipitated in surface and pore waters. Thus, SI content reflected that halogens, especially fluoride and iodide, played a vital role in reducing lake pollution. Fluorite (CaF2) and sellaïte (MgF2) could only be formed in pore water, while calcite and aragonite could be deposited from surface water. In addition, Cl was mainly found in the forms of NaCl, CaCl2, MgCl2, and KCl in surface and pore waters. The multivariate analysis revealed that fluoride precipitate may serve in decreasing the dissolved salt pollution. Multivariate analysis showed that in the long run, the fluoride precipitation in FAP and CFAP can significantly adsorb and absorb various pollutants and can protect the lake from pollution. The ecological risk assessment conducted by calculating the enrichment factor (EF) showed that the lake was still unpolluted. Regarding human health risks, at appropriate levels of human health and safety, the hazard quotient (HQ) and hazard index (HI) of halogens found to be lower than these reported levels. Hence, ingestion and dermal absorption routes of halogens by surface water and sediments did not pose any adverse effects to population reflecting uncontaminated status of Lake Mariout.

scholarly journals Human Risk from Exposure to Heavy Metals and Arsenic in Water from Rivers with Mining Influence in the Central Andes of Peru

Water ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1946
Author(s):  
María Custodio ◽  
Walter Cuadrado ◽  
Richard Peñaloza ◽  
Raúl Montalvo ◽  
Salomé Ochoa ◽  
...  
Keyword(s):  
Heavy Metals ◽  
High Risk ◽  
Hazard Quotient ◽  
Adult Population ◽  
Hazard Index ◽  
Central Andes ◽  
Anthropogenic Pressure ◽  
Flame Atomic Absorption ◽  
Risk Of Cancer ◽  
Heavy Metals And Arsenic

Water pollution by heavy metals is one of the leading environmental concerns as a result of intense anthropogenic pressure on the aquatic environment. This constitutes a significant limitation to the human right of access to drinking water. In this context, the risk to humans from exposure to heavy metals and arsenic in water from rivers subject to mining influence in the Central Andes of Peru was assessed. Water samples were collected from seven rivers at 63 sampling sites, and concentrations of Cu, Fe, Pb, Zn, and As were determined using flame atomic absorption spectrophotometry. Cluster analysis was used to group 21 sampling sites into four groups with similar chemical characteristics, and principal component analysis was used to simplify the complex relationship between the toxic elements by generating two main components with a total percentage of variation of 86%. Fe, Zn, and As had higher percentages of contribution in the Mantaro, Cunas, and Chia rivers. The hazard quotient was highest for children and adults. The hazard index for ingestion of all the studied heavy metals and As was higher than the threshold value (HIing > 1). HIing in 43% of the rivers indicated that the adult population is at risk of non-carcinogenic effects, and HIing in 14% of the rivers revealed a very high health risk. The risk of cancer by ingestion for children varied from medium to high risk and for adults from low to high risk.

Levels of lead, aluminum, and zinc in occupationally exposed workers of North-Western India

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Preeti Singh ◽  
Prasenjit Mitra ◽  
Taru Goyal ◽  
Shailja Sharma ◽  
Purvi Purohit ◽  
...  
Keyword(s):  
Atomic Absorption ◽  
Atomic Absorption Spectrophotometry ◽  
Western India ◽  
Absorption Spectrophotometry ◽  
Flame Atomic Absorption ◽  
Wide Range ◽  
Metal Levels ◽  
Exposed Workers ◽  
Occupationally Exposed ◽  
North Western

Abstract Objectives Metals including lead (Pb), aluminum (Al), and zinc (Zn) are widely used in factories such as welding, handicrafts, and paint. Occupational exposure to such metals causes a wide range of biological effects, depending upon the metal levels and duration of exposure. Accumulation of these metals may lead to several adverse health effects such as neurodegenerative diseases and cancer. The study aimed to evaluate Pb, Al, and Zn levels in occupationally exposed workers of North-Western India and create awareness about its toxicity and adverse outcomes. Methods The study included 120 factory workers (exposed) and 100 healthy controls (nonexposed); age ranged 18–78 years. Blood Pb and serum Al was estimated by graphite furnace atomic absorption spectrophotometry and serum Zn was estimated by flame atomic absorption spectrophotometry (ICE 3000, Thermo Fisher Scientific). Results Results indicated significantly higher levels of Pb, Al, and Zn in the exposed than the nonexposed. No significant difference was observed in metal levels, based on age and duration of exposure. Painters showed higher blood Pb, whereas welders were found to have higher serum Al and Zn levels. Conclusions To conclude, workers showed higher levels of metals and it may cause deleterious effects on the health of workers occupationally exposed to these metals. Appropriate maintenance regarding worker’s safety and hygiene is required to protect them from the harmful effects of these toxic metals.

scholarly journals Assessment of Health Risk Associated with Heavy Metal Contamination of Edible Vegetables in Cement Contaminated Area

2019 ◽  
pp. 1-11
Author(s):  
Edmund Richard Egbe ◽  
Augusta Chinyere Nsonwu-Anyanwu ◽  
Sunday Jeremiah Offor ◽  
Chinyere Adanna Opara Usoro ◽  
Maise Henrietta Etukudo
Keyword(s):  
Heavy Metal ◽  
Heavy Metal Contamination ◽  
Hazard Quotient ◽  
Hazard Index ◽  
Atomic Absorption Spectrophotometry ◽  
Cross Sectional ◽  
Cement Production ◽  
Cement Factory ◽  
Increased Risk ◽  
Safe Limits

Aim: Heavy metal (HM) content of some vegetables in the vicinity of a cement factory can be a useful index for assessment of HM contamination of the environment associated with cement production. Study Design: This cross sectional study was conducted at the United Cement Company at Mfamosing, Akamkpa local government area, Cross River State, Nigeria between February to November 2016. Methods: One hundred and forty edible vegetables of Telfairia occidentalis (fluted pumpkin), Vernonia amygdalina (bitter leaf), Amaranthus viriditis (green leaf), Talinum triangulare (water leaf), Lavantheca africanum, Heinsia crinata and Gnatum africana were collected at varying distances and directions from the cement factory site and an area remote to the site serving as control. The lead (Pb), copper (Cu), manganese (Mn), iron (Fe), cadmium (Cd), selenium (Se), chromium (Cr), zinc (Zn) and arsenic (As) content of the vegetable samples were determined using atomic absorption spectrophotometry. Data were analyzed using analysis of variance at P = .05. Results: The Pb, Cu, Mn, Fe, Cd, Se and Zn content of vegetables in all the locations studied were within the safe limits except for Cr and As levels of some vegetables from location closest to the factory which were higher than the safe limits. The HM content of all vegetables from location closest to the factory were significantly higher than those from other locations (P <0.001). The hazard quotient (HQ) of all HM in all the vegetables were <1 except for Mn in T. occidentalis which was >1. The hazard index (ƩHQ) for all HM in all the vegetables were >1. Conclusion: Cement production is associated with chromium and arsenic contamination of edible vegetables and increase in hazard index of HM levels in vegetables closest to the factory which may be implicated in increased risk for development of deleterious health consequences to consumers.

Study on Toxic Metal Levels in Food Supplements

2017 ◽  
Vol 68 (6) ◽  
pp. 1298-1301
Author(s):  
Sonia Amariei ◽  
Gheorghe Gutt ◽  
Mircea Oroian
Keyword(s):  
Hazard Quotient ◽  
Daily Intake ◽  
Hazard Index ◽  
Toxic Metal ◽  
Heavy Metal Concentration ◽  
Food Supplements ◽  
Chemical Toxicology ◽  
Icp Ms ◽  
Metal Levels ◽  
Average Body

The objective of this study was to evaluate the chronic-toxic risks posed by individual metals via food supplements consumption by computing the hazard quotient (HQ), considering the average daily metal intake ADD (mg/kg�day), daily intake reference dose RfD (mg/kg� day) suggested by the European Food Safety Authority (EFSA), heavy metal concentration C in food supplements (mg/kg), food supplements rate IR (kg/person�day), and the average body weight BW (kg). For this study we took into consideration that the food supplements analyzed are consumed daily at maximum dose. Samples were digested with concentrated nitric and hydrochloric acid and analysed for their inorganic elemental compositions by ICP/MS. The hazard index (HI) was used to estimate total chronic-toxic risks of multiple metals on the assumption of dose additivity. Cd hazard index is over one and it can be considered a great issue due to its chemical toxicology. The Cd hazard index is much greater in the case of animal and mineral food supplements than vegetal supplements. In the case of the other heavy metals analyzed (Cr, Cu, Zn, As, Hg and Pb) the hazard index is very low so their toxicological potential is negligible.

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