scholarly journals The Impact of Pore Structure on Kerogen Geomechanics

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Saad Alafnan

Production stimulation techniques such as the combination of hydraulic fracturing and lateral drilling have made exploiting unconventional formations economically feasible. Advancements in production aspects are not always in lockstep with our ability to predict and model the extent of a fracturing job. Shale is a clastic sedimentary rock composed of a complex mineralogy of clay, quartz, calcite, and fragments of an organic material known as kerogen. The latter, which consists of large chains of aromatic and aliphatic carbons, is highly elastic, a characteristic that impacts the geomechanics of a shale matrix. Following a molecular simulation approach, the objective of this work is to investigate kerogen’s petrophysics on a molecular level and link it to kerogen’s mechanical properties, considering some range of kerogen structures. Nanoporous kerogen structures across a range of densities were formed from single macromolecule units. Eight units were initially placed in a low-density cell. Then, a molecular dynamic protocol was followed to form a final structure with a density of 1.1 g/cc; the range of density values was consistent with what has been reported in the literature. The structures were subjected to petrophysical assessments including a helium porosity analysis and pore size distribution characterization. Mechanical properties such as Young’s modulus, bulk modulus, and Poisson ratio were calculated. The results revealed strong correlations among kerogen’s mechanical properties and petrophysics. The kerogen with the lowest porosity showed the highest degree of elasticity, followed by other structures that exhibited larger pores. The effect temperature and the fluid occupying the pore volume were also investigated. The results signify the impact of kerogen’s microscale intricacies on its mechanical properties and hence on the shale matrix. This work provides a novel methodology for constructing kerogen structures with different microscale properties that will be useful for delineating fundamental characteristics such as mechanical properties. The findings of this work can be used in a larger scale model for a better description of shale’s geomechanics.

2012 ◽  
Vol 535-537 ◽  
pp. 1881-1888 ◽  
Author(s):  
Gustavo Mendoza-Chavez ◽  
Luis Horacio Martínez-Mártinez ◽  
David Joaquin Delgado-Hernandez ◽  
David De León Escobedo ◽  
Elia Mercedes Alonso Guzmán ◽  
...  

In Mexico, since the early stages of the civilization, the stone masonry has assumed an important role in construction due to the wide availability of this kind of material. Masonry is a material composed by bricks, carved or even rubble stones jointed without (dry joint) or with mortar (mortar joints); which is principally formed with sand, water and cementitiuos materials. The research presented in this paper deals with the procedure of obtaining the mechanical properties of rocks placed on piers of four vehicular bridges located in the south of the state of Mexico, these mechanical properties are compressive strength, modulus of elasticity, Poisson ratio, Cohesion and Internal friction Angle of the rocks as independent units, also are reported the Density values. All of these properties are necessary to conduct further research regarding the mechanical behavior of the pier as a structure since this piece of research is part of an ongoing project concerning risk assessment of vehicular bridges developed in Mexico. The identified rocks in masonry were volcanic igneous materials such as dacites, basalts, rhyolites, andesites and rusted andesites. The materials with the highest and the lowest mechanical properties are the basalt and the dacite respectively. It is recommended to use the dacite’s properties in order to perform a conservative analysis of the mechanical behavior of any masonry structure, located near the selected sample studied herein.


2021 ◽  
Author(s):  
Clement Chekwube Afagwu ◽  
Saad Fahaid Al-Afnan ◽  
Mohamed Mahmoud

Abstract The advancements in production technologies have unlocked tremendous reserves of natural gas in shale formations. The ability to describe shale matrix dynamics during the production span is, however, at infancy stages. The complex mineralogy and the multiscale nature of shales require transport models beyond the classical Darcian framework. Shales primarily consist of clays, quartz, calcite, and some fragments of organic matters known as kerogen. The latter can be envisioned as naturally occurring nanoporous media where diffusion is believed to be the predominant transport mechanism. Moreover, kerogen exhibits different geo-mechanical behavior than typical clastic sedimentary rocks. Hence, kerogen responds to changes in the stress field differently during the production span and ultimately influences the transport. It is our aim in this paper to delineate the transport and geo-mechanical aspects of kerogen through molecular-based assessments. Realistic kerogen structures at some ranges of density were recreated on a computational platform for thorough investigations. The structures were analyzed for porosity, pore size distribution, and mechanical properties such as bulk modulus, shear modulus, Young's modulus, and Poisson ratio. The adsorption alongside self-diffusion calculations were performed on the configurations. Moreover, the assessment of diffusivity was linked to pore compressibility to address the impact of effective stress changes on the transport throughout typical production span. An effective diffusion model for kerogen was proposed, validated with molecular simulation data in the literature, and compared with the MD diffusion data of this study. The results revealed critical dependency of pore size distribution, and porosity on the effective stress, which severely alters the diffusive permeability. This work provides a novel methodology for linking kerogen microscale intricacies to some fundamental transport and mechanical properties to better describe the transport of natural gas from kerogen.


2020 ◽  
Vol 14 (2) ◽  
pp. 6734-6742
Author(s):  
A. Syamsir ◽  
S. M. Mubin ◽  
N. M. Nor ◽  
V. Anggraini ◽  
S. Nagappan ◽  
...  

This study investigated the combine effect of 0.2 % drink cans and steel fibers with volume fractions of 0%, 0.5%, 1%, 1.5%, 2%, 2.5% and 3% to the mechanical properties and impact resistance of concrete. Hooked-end steel fiber with 30 mm and 0.75 mm length and diameter, respectively was selected for this study.  The drinks cans fiber were twisted manually in order to increase friction between fiber and concrete. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the strength performance of concrete, especially the compressive strength, flexural strength and indirect tensile strength. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the compressive strength, flexural strength and indirect tensile strength by 2.3, 7, and 2 times as compare to batch 1, respectively. Moreover, the impact resistance of fiber reinforced concrete has increase by 7 times as compared to non-fiber concretes. Moreover, the impact resistance of fiber reinforced concrete consistently gave better results as compared to non-fiber concretes. The fiber reinforced concrete turned more ductile as the dosage of fibers was increased and ductility started to decrease slightly after optimum fiber dosage was reached. It was found that concrete with combination of 2% steel and 0.2% drink cans fibers showed the highest compressive, split tensile, flexural as well as impact strength.    


2016 ◽  
Vol 8 (15) ◽  
pp. 47-54
Author(s):  
Haspiadi Haspiadi

The purpose of this research is to know the influence of pressure and use of conplast against mechanical properties which are a Modulus of Elasticity (MOE) and Modulus of Rupture (MOR) of plasterboard. The study is done because still low quality of plasterboard made from a mixture of ashes of oil-palm shell especially of the mechanical properties compared to the controls. The method of this reserach used variation of printed pressure and the addition of conplast. Test result is obtained that the highest value of Modulus of Elasticity (MOE) 90875.94 Kg/cm2, Modulus of Rupture (MOR) 61.16 Kg/cm2 and density values in generally good printed at the pressure 60 g/cm3 and the addition of conplast 25% as well as the composition of the ash of palm shell oil 40%: limestone 40%: cement 15%: fiber 5% and 300 mL of water. ABSTRAK Tujuan dari penelitian ini adalah untuk mengetahui pengaruh tekanan dan penggunaan conplast terhadap sifat mekanik yaitu kuat lentur dan keteguhan patah eternit berbahan dasar abu cangkang sawit. Penelitian ini dilakukan karena masi rendahnya mutu eternit berbahan campuran abu cangkang sawit dari bolier khususnya sifat mekanik dibandingkan dengan kontrol. Metode penelitian yang digunakan adalah dengan variasi tekanan cetak dan penambahan conplast. Hasil uji diperoleh bahwa kuat lentur tertinggi sebesar 90875,94 Kg/cm2 dan keteguhan patah sebesar 61,16 Kg/cm2, yang dicetak pada tekanan 60 g/cm3 dan penambahan conplast 25% dengan komposisi  abu cangkang sawit 40 %: kapur 40 % : semen 15 %: serat 5 % dan air 300 mL.Kata Kunci :  Abu cangkang sawit, conplast, kuat lentur, keteguhan patah.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2323
Author(s):  
Yubing Du ◽  
Zhiqing Zhao ◽  
Qiang Xiao ◽  
Feiting Shi ◽  
Jianming Yang ◽  
...  

To explore the basic mechanical properties and size effects of recycled aggregate concrete (RAC) with different substitution ratios of coarse recycled concrete aggregates (CRCAs) to replace natural coarse aggregates (NCA), the failure modes and mechanical parameters of RAC under different loading conditions including compression, splitting tensile resistance and direct shear were compared and analyzed. The conclusions drawn are as follows: the failure mechanisms of concrete with different substitution ratios of CRCAs are similar; with the increase in substitution ratio, the peak compressive stress and peak tensile stress of RAC decrease gradually, the splitting limit displacement decreases, and the splitting tensile modulus slightly increases; with the increase in the concrete cube’s side length, the peak compressive stress of RAC declines gradually, but the integrity after compression is gradually improved; and the increase in the substitution ratio of the recycled aggregate reduces the impact of the size effect on the peak compressive stress of RAC. Furthermore, an influence equation of the coupling effect of the substitution ratio and size effect on the peak compressive stress of RAC was quantitatively established. The research results are of great significance for the engineering application of RAC and the strength selection of RAC structure design.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3140
Author(s):  
Kamil Dydek ◽  
Anna Boczkowska ◽  
Rafał Kozera ◽  
Paweł Durałek ◽  
Łukasz Sarniak ◽  
...  

The main aim of this work was the investigation of the possibility of replacing the heavy metallic meshes applied onto the composite structure in airplanes for lightning strike protection with a thin film of Tuball single-wall carbon nanotubes in the form of ultra-light, conductive paper. The Tuball paper studied contained 75 wt% or 90 wt% of carbon nanotubes and was applied on the top of carbon fibre reinforced polymer before fabrication of flat panels. First, the electrical conductivity, impact resistance and thermo-mechanical properties of modified laminates were measured and compared with the reference values. Then, flat panels with selected Tuball paper, expanded copper foil and reference panels were fabricated for lightning strike tests. The effectiveness of lightning strike protection was evaluated by using the ultrasonic phased-array technique. It was found that the introduction of Tuball paper on the laminates surface improved both the surface and the volume electrical conductivity by 8800% and 300%, respectively. The impact resistance was tested in two directions, perpendicular and parallel to the carbon fibres, and the values increased by 9.8% and 44%, respectively. The dynamic thermo-mechanical analysis showed higher stiffness and a slight increase in glass transition temperature of the modified laminates. Ultrasonic investigation after lightning strike tests showed that the effectiveness of Tuball paper is comparable to expanded copper foil.


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1128
Author(s):  
Sylwia Członka ◽  
Anna Strąkowska ◽  
Agnė Kairytė

In this study, coir fibers were successfully modified with henna (derived from the Lawsonia inermis plant) using a high-energy ball-milling process. In the next step, such developed filler was used as a reinforcing filler in the production of rigid polyurethane (PUR) foams. The impact of 1, 2, and 5 wt % of coir-fiber filler on structural and physico-mechanical properties was evaluated. Among all modified series of PUR composites, the greatest improvement in physico-mechanical performances was observed for PUR composites reinforced with 1 wt % of the coir-fiber filler. For example, on the addition of 1 wt % of coir-fiber filler, the compression strength was improved by 23%, while the flexural strength increased by 9%. Similar dependence was observed in the case of dynamic-mechanical properties—on the addition of 1 wt % of the filler, the value of glass transition temperature increased from 149 °C to 178 °C, while the value of storage modulus increased by ~80%. It was found that PUR composites reinforced with coir-fiber filler were characterized by better mechanical performances after the UV-aging.


2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Mathilde Tiennot ◽  
Davide Iannuzzi ◽  
Erma Hermens

AbstractIn this investigation on the mechanical behaviour of paint films, we use a new ferrule-top nanoindentation protocol developed for cultural heritage studies to examine the impact of repeated relative humidity variations on the viscoelastic behaviour of paint films and their mechanical properties in different paint stratigraphies through the changes in their storage and loss moduli. We show that the moisture weathering impact on the micromechanics varies for each of these pigment-oil systems. Data from the nanoindentation protocol provide new insights into the evolution of the viscoelastic properties dsue to the impact of moisture weathering on paint films.


Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 779
Author(s):  
Mohamed Gomah ◽  
Guichen Li ◽  
Salah Bader ◽  
Mohamed Elkarmoty ◽  
Mohamed Ismael

The awareness of the impact of high temperatures on rock properties is essential to the design of deep geotechnical applications. The purpose of this research is to assess the influence of heating and cooling treatments on the physical and mechanical properties of Egyptian granodiorite as a degrading factor. The samples were heated to various temperatures (200, 400, 600, and 800 °C) and then cooled at different rates, either slowly cooled in the oven and air or quickly cooled in water. The porosity, water absorption, P-wave velocity, tensile strength, failure mode, and associated microstructural alterations due to thermal effect have been studied. The study revealed that the granodiorite has a slight drop in tensile strength, up to 400 °C, for slow cooling routes and that most of the physical attributes are comparable to natural rock. Despite this, granodiorite thermal deterioration is substantially higher for quick cooling than for slow cooling. Between 400:600 °C is ‘the transitional stage’, where the physical and mechanical characteristics degraded exponentially for all cooling pathways. Independent of the cooling method, the granodiorite showed a ductile failure mode associated with reduced peak tensile strengths. Additionally, the microstructure altered from predominantly intergranular cracking to more trans-granular cracking at 600 °C. The integrity of the granodiorite structure was compromised at 800 °C, the physical parameters deteriorated, and the rock tensile strength was negligible. In this research, the temperatures of 400, 600, and 800 °C were remarked to be typical of three divergent phases of granodiorite mechanical and physical properties evolution. Furthermore, 400 °C could be considered as the threshold limit for Egyptian granodiorite physical and mechanical properties for typical thermal underground applications.


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