scholarly journals Elimination of Congo Red Dye from Industrial Wastewater Using Teucrium polium L. as a Low-Cost Local Adsorbent

2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Nasser A. Alamrani ◽  
Hatem A. AL-Aoh
Keyword(s):  
Industrial Wastewater ◽  
Low Cost ◽  
Positive Influence ◽  
Isotherm Models ◽  
Heat Absorber ◽  
Leaf Powder ◽  
Teucrium Polium ◽  
Teucrium Polium L ◽  
Cr Concentration ◽  
Red Dye

A novel adsorbent prepared from the leaf powder of Teucrium polium L. (TPLLP) was characterized and its ability for adsorption of Cong red (CR) was inspected. Influences of CR concentration, adsorbent dosage, time of agitation, pH of solution, and temperature on the performance of this adsorption were also examined. Three models of kinetic along with three different isotherm models were applied for analyzing the empirical data of this adsorption. Additionally, the thermodynamic constants of were decided. The surface area, pore volume, pore size, and pHZPC of Zn/Cu-TPLLP were found to be 2.6436 m2.g-1, 0.013317 cm3.g-1, 527.393 Å, and 8.8, respectively. The achieved outcomes indicate the positive influence of temperature, concentration of CR in the range of 20 to 900 mg/L, adsorbent mass in the range of 0.005 to 0.02 g, time of adsorption from 0 to 120 min, and pH from 5.5 to 8.5. Models of the 2nd order with R 2 ≥ 0.995 and Langmuir with R 2 ≥ 0.990 were the best among the other kinetic and isotherm models applied in this research. Moreover, superior capacities of 526.32, 666.67, and 909.09 (mg.g-1) were stemmed at 27, 42, and 57°C, respectively. The outcomes of the thermodynamic evidenced that this adsorption is spontaneous and a heat absorber.

scholarly journals Fabrication and Application of Zeolite/Acanthophora Spicifera Nanoporous Composite for Adsorption of Congo Red Dye from Wastewater

Nanomaterials ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 2441
Author(s):  
Ahmed Hamd ◽  
Asmaa Ragab Dryaz ◽  
Mohamed Shaban ◽  
Hamad AlMohamadi ◽  
Khulood A. Abu Al-Ola ◽  
...  
Keyword(s):  
Congo Red ◽  
Industrial Wastewater ◽  
Low Cost ◽  
Industrial Effluent ◽  
Dye Adsorption ◽  
Field Testing ◽  
Field Trials ◽  
Anionic Dyes ◽  
Intra Particle Diffusion ◽  
Red Dye

Systematic investigations involving laboratory, analytical, and field trials were carried out to obtain the most efficient adsorbent for the removal of congo red (CR) dye from industrial effluent. Modification of the zeolite (Z) by the Acanthophora Spicifera algae (AS; marine algae) was evaluated in terms of adsorption capability of the zeolite to remove CR dye from aqueous solution. The zeolite/algae composite (ZAS) was fabricated using the wet impregnation technique. The AS, Z, and the synthesized ZAS composite were analyzed utilizing various characterization techniques. The newly synthesized ZAS composite has an adsorption capacity that is significantly higher than that of Z and AS, particularly at low CR concentrations. Batch experiments were carried out to explore the effects of different experimental factors, as well as the dye adsorption isotherms and kinetics. Owing to the presence of intermolecular interactions, the computational analysis showed that the adsorption of the CR molecule on zeolite surfaces is exothermic, energetically favorable, and spontaneous. Furthermore, growing the zeolite surface area has no discernible effect on the adsorption energies in all configurations. The ZAS composite may be used as a low-cost substitute adsorbent for the removal of anionic dyes from industrial wastewater at lower dye concentrations, according to the experimental results. Adsorption of CR dye onto Z, AS, and ZAS adsorbents was adequately explained by pseudo-second-order kinetics and the Langmuir isotherm. The sorption mechanism was also evaluated using Weber’s intra-particle diffusion module. Finally, field testing revealed that the newly synthesized adsorbent was 98.0% efficient at extracting dyes from industrial wastewater, proving the foundation of modern eco-friendly materials that aid in the reuse of industrial wastewater.

Kinetic, isotherm and thermodynamic aspects of Cu2+ biosorption onto Rosa damascena leaf as a low-cost biosorbent: Optimization of process variables by Response Surface Methodology

2021 ◽  
Author(s):  
Mustafa A. Fawzy ◽  
Hatim M. Al-Yasi ◽  
Tarek M. Galal ◽  
Reham Z. Hamza ◽  
Esmat F. Ali ◽  
...  
Keyword(s):  
Response Surface Methodology ◽  
Aqueous Solutions ◽  
Response Surface ◽  
Structural Characteristics ◽  
Low Cost ◽  
High Surface ◽  
Isotherm Models ◽  
Rosa Damascena ◽  
Before And After ◽  
Leaf Powder

Abstract In this study, the Rosa damascena leaf powder was evaluated as a biosorbent for copper removal from aqueous solutions. Optimized conditions of 4.0 g/L biosorbent dosage, pH of 5.5 and initial copper concentration of 55 mg/L obtained by Response Surface Methodology were employed for Cu2+ biosorption by R. damascena leaves and up to 88.7 % Cu2+ was removed. The biosorption data were well fitted to the pseudo-second order and Elovich kinetic models. The Langmuir and Dubinin-Radushkevich isotherm models were also best fit the experimental data showing monolayer isotherm with qmax value of 25.13 mg/g obtained at optimum conditions. Thermodynamic parameters showed the spontaneity, feasibility and exothermic nature of adsorption. Scanning electron microscopy, Energy-Dispersive X-Ray, and Fourier transform infrared spectroscopy were used to characterize the biosorbent before and after Cu2+ biosorption, revealing outstanding structural characteristics and high surface functional groups availability. In addition, immobilized R. damascena leaves adsorbed 90.7 % of copper from aqueous solution, which is greater than free biosorbent (85.3 %). It can be concluded that R. damascena might be employed as a low-cost biosorbent for removing heavy metals from aqueous solutions.

Étude de la phytodiversité et caractérisation de l’habitat de Teucrium polium L. (Lamiaceae) du mont de Tessala (Algérie occidentale)

2016 ◽  
Vol 42 (2) ◽  
pp. 21-39
Author(s):  
Nadjia Fertout-Mouri ◽  
Ali Latrèche ◽  
Zoheir Mehdadi ◽  
Soror Akli-Djaaboub ◽  
Adel Akli
Keyword(s):  
Teucrium Polium ◽  
Teucrium Polium L

scholarly journals Spent Coffee Ground as Low-Cost Adsorbent for Congo Red Dye Removal from Aqueous Solution

2021 ◽  
Vol 765 (1) ◽  
pp. 012089
Author(s):  
R Taufik ◽  
M Mohamad ◽  
R Wannahari ◽  
N F Shoparwe ◽  
WHW Osman ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Congo Red ◽  
Dye Removal ◽  
Low Cost ◽  
Congo Red Dye ◽  
Spent Coffee Ground ◽  
Coffee Ground ◽  
Red Dye

scholarly journals Removal of Cadmium(II) from Water using Modified Citrus limettioides Peels: Thermodynamic and Isotherm Studies

2019 ◽  
Vol 32 (1) ◽  
pp. 73-78
Author(s):  
P. Janaki ◽  
R. Sudha ◽  
T.S. Sribharathi ◽  
P. Anitha ◽  
K. Poornima ◽  
...  
Keyword(s):  
Adsorption Process ◽  
Low Cost ◽  
Raw Material ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Adsorption Method ◽  
Chemically Modified ◽  
Adsorption Performance ◽  
Monolayer Adsorption ◽  
Isotherm Equations

The adsorption performance of sulphuric acid treated low cost adsorbent synthesized by using Citrus limettioides peel as an effective raw material for the removal of cadmium(II) from water. The batch adsorption method was carried out to optimize some parameters like contact time, pH and adsorbent dose. The nonlinear isotherm equations were used to calculate the different isotherm constant of five isotherm models namely Freundlich, Langmuir, Dubinin-Radushkevich, Redlich-Peterson and Sips. The Langmuir monolayer adsorption capacity of chemically modified Citrus limettioides peel was found to be 287.60 mg g-1. The negative values of ΔGº and ΔHº showed that the adsorption process is spontaneous and exothermic.

Removal of Ni(II) from aqueous solution byLycopersicum esculentum(Tomato) leaf powder as a low-cost biosorbent

2014 ◽  
Vol 54 (1) ◽  
pp. 200-208 ◽  
Author(s):  
Yuvaraja Gutha ◽  
Venkata Subbaiah Munagapati ◽  
Mu. Naushad ◽  
Krishnaiah Abburi
Keyword(s):  
Aqueous Solution ◽  
Low Cost ◽  
Tomato Leaf ◽  
Leaf Powder

scholarly journals Effect of Intercalation Structure of Organo-Modified Montmorillonite/Polylactic Acid on Wheat Straw Fiber/Polylactic Acid Composites

Polymers ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 896 ◽  
Author(s):  
Qiqi Fan ◽  
Guangping Han ◽  
Wanli Cheng ◽  
Huafeng Tian ◽  
Dong Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermogravimetric Analysis ◽  
Wheat Straw ◽  
Polylactic Acid ◽  
Low Cost ◽  
Interlayer Spacing ◽  
Positive Influence ◽  
X Ray Diffraction ◽  
Ft Ir ◽  
Ir Analysis

In this work, an easy way to prepare the polylactic acid (PLA)/wheat straw fiber (WSF) composite was proposed. The method involved uses either the dopamine-treated WSF or the two-step montmorillonite (MMT)-modified WSF as the filler material. In order to achieve the dispersibility and exfoliation of MMT, it was modified by 12-aminododecanoic acid using a two-step route. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were performed to characterize the modified MMT and the coated WSF. As for the properties of PLA/WSF composites, some thermal (using Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis) and mechanical properties (flexural, tensile, and impact) were analyzed. The results showed that the dopamine was successfully coated onto the WSF. Furthermore, Na-MMT was successfully transformed to organo-montmorillonite (OMMT) and formed an exfoliated structure. In addition, a better dispersion of MMT was obtained using the two-step treatment. The interlayer spacing of modified MMT was 4.06 nm, which was 123% higher than that of the unmodified MMT. Additionally, FT-IR analysis suggested that OMMT diffused into the PLA matrix. The thermogravimetric analysis (TGA) showed that a higher thermal stability of PLA/WSF composites was obtained for the modified MMT and dopamine. The results also showed that both the dopamine treated WSF and the two-step-treated MMT exhibited a positive influence on the mechanical properties of PLA/WSF composites, especially on the tensile strength, which increased by 367% compared to the unmodified precursors. This route offers researchers a potential scheme to improve the thermal and mechanical properties of PLA/WSF composites in a low-cost way.

scholarly journals Dynamic control of nutrient-removal from industrial wastewater in a sequencing batch reactor, using common and low-cost online sensors

2015 ◽  
Vol 73 (4) ◽  
pp. 740-745 ◽  
Author(s):  
Jan Dries
Keyword(s):  
Activated Sludge ◽  
Nutrient Removal ◽  
Industrial Wastewater ◽  
Sequencing Batch Reactor ◽  
Batch Reactor ◽  
Low Cost ◽  
Dynamic Control ◽  
Oxygen Demand ◽  
Oxidation Reduction ◽  
Oxidation Reduction Potential

On-line control of the biological treatment process is an innovative tool to cope with variable concentrations of chemical oxygen demand and nutrients in industrial wastewater. In the present study we implemented a simple dynamic control strategy for nutrient-removal in a sequencing batch reactor (SBR) treating variable tank truck cleaning wastewater. The control system was based on derived signals from two low-cost and robust sensors that are very common in activated sludge plants, i.e. oxidation reduction potential (ORP) and dissolved oxygen. The amount of wastewater fed during anoxic filling phases, and the number of filling phases in the SBR cycle, were determined by the appearance of the ‘nitrate knee’ in the profile of the ORP. The phase length of the subsequent aerobic phases was controlled by the oxygen uptake rate measured online in the reactor. As a result, the sludge loading rate (F/M ratio), the volume exchange rate and the SBR cycle length adapted dynamically to the activity of the activated sludge and the actual characteristics of the wastewater, without affecting the final effluent quality.

scholarly journals Teaching and Learning Physics with Smartphones

2015 ◽  
Vol 17 (1) ◽  
pp. 31-50 ◽  
Author(s):  
M. Á. González ◽  
Manuel Á. González ◽  
M. Esther Martín ◽  
César Llamas ◽  
Óscar Martínez ◽  
...  
Keyword(s):  
Mobile Applications ◽  
Teaching And Learning ◽  
Low Cost ◽  
Positive Influence ◽  
Mobile Technologies ◽  
Traditional Learning ◽  
Know How ◽  
Measurement Devices ◽  
The One ◽  
Physics Experiments

The use of mobile technologies is reshaping how to teach and learn. In this paper the authors describe their research on the use of these technologies to teach physics. On the one hand they develop mobile applications to complement the traditional learning and to help students learn anytime and anywhere. The use of this applications has proved to have very positive influence on the students' engagement. On the other hand, they use smartphones as measurement devices in physics experiments. This opens the possibility of designing and developing low cost laboratories where expensive material can be substituted by smartphones. The smartphones' sensors are reliable and accurate enough to permit good measurements. However, as it is shown with some examples, special care must be taken here if one does not know how these apps used to access the sensors' data are programmed.

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