Study on Interaction between Acid Phosphate and Friction Modifier in Sliding Surface Lubrication

During the design and synthesis of new chemotherapeutic agents for prostatic carcinoma based on phosphorylated agents which might be enzyme-activated to cytotoxicity, phosphorylcholine, [(CH3)3+NCH2CH2OPO3Ca]Cl-, has been indicated to be a very specific substrate for prostatic acid phosphatase (PAP). This phenomenon has led to the development of specific histochemical and ultracytochemical methods for PAP using modifications of the Gomori lead method for acid phosphatase. Comparative histochemical results in prostate and kidney of the rat have been published earlier with phosphorylcholine (PC) and β-glycerophosphate (βGP). We now report the ultracytochemical results.Minced tissues were fixed in 3% glutaraldehyde-0.1 M phosphate buffered (pH 7.4) for 1.5 hr and rinsed overnight in several changes of 0.05 M phosphate buffer (pH 7.0) containing 7.5% sucrose. Tissues were incubated 30 min to 2 hr in Gomori acid phosphatase medium (2) containing 0.1 M substrate, either PC or βGP.

Download Full-text

Locating Al in the DABCO catalyst before and after Al extraction

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100174461 ◽

1990 ◽

Vol 48 (4) ◽

pp. 265-267

Author(s):

Kathleen B. Reuter

Keyword(s):

Active Site ◽

Inverse Relationship ◽

Transverse Direction ◽

Reaction Rate ◽

Acid Phosphate ◽

Fracture Surfaces ◽

Al Content ◽

Before And After ◽

Relationship Of

The reaction rate and efficiency of piperazine to 1,4-diazabicyclo-octane (DABCO) depends on the Si/Al ratio of the MFI topology catalysts. The Al was shown to be the active site, however, in the Si/Al range of 30-200 the reaction rate increases as the Si/Al ratio increases. The objective of this work was to determine the location and concentration of Al to explain this inverse relationship of Al content with reaction rate.Two silicalite catalysts in the form of 1/16 inch SiO2/Al2O3 bonded extrudates were examined: catalyst A with a Si/Al of 83; and catalyst B, the acid/phosphate Al extracted form of catalyst A, with a Si/Al of 175. Five extrudates from each catalyst were fractured in the transverse direction and particles were obtained from the fracture surfaces near the center of the extrudate diameter. Particles were also obtained from the outside surfaces of five extrudates.

Download Full-text

Selection of Wear Resistive Nano coating in En8 Steel

Bulletin of Scientific Research ◽

10.34256/bsr1929 ◽

2019 ◽

Vol 1 (2) ◽

pp. 73-80

Author(s):

Ilangkumaran M ◽

Tiruvenkadam N ◽

Saranya M ◽

Thulsidharan R

Keyword(s):

Mild Steel ◽

Mechanical Action ◽

Medium Carbon Steel ◽

Solid Surfaces ◽

Material Surface ◽

Multi Criteria Decision Making ◽

Sliding Surface ◽

Medium Carbon ◽

Nano Coating ◽

Selection Of

Where is the abrasive or gradual removal of materials at solid surfaces? It is caused due to the interaction between the sliding surface by mechanical action. The abrasive wears can be recognised as scratches or grooves. To enhance the wear resistance suitable nanocoating is applied on the material surface for better tribological properties such as hardness and toughness. Wear resistant nanocoating is used to reduce or eradicate wear to extend the lifetime of the EN8 steel. EN8 is unalloyed medium carbon steel with better mechanical properties than mild steel and also readily machinable in any condition. The nanocoating materials such as Al2O3, TiO2, SiC, ZrO2, WS2, Si3N4 etc., are used to reduce wear and to enhance hardness and toughness on mild steel through various nanocoating techniques. This paper deals with selection of suitable nanocoating material through AHP (Analytical hierarchal process) - a multi-criteria decision-making method.

Download Full-text

Interaction of tungsten in dry sliding against steel under high density electric current

Voprosy Materialovedeniya ◽

10.22349/1994-6716-2019-97-1-101-109 ◽

2019 ◽

pp. 101-109 ◽

Cited By ~ 2

Author(s):

M. I. Aleutdinova ◽

V. V. Fadin ◽

Yu. P. Mironov

Keyword(s):

Electrical Contact ◽

Analysis Data ◽

Dry Sliding ◽

Sliding Surface ◽

X Ray ◽

Sliding Surfaces ◽

Quenched Steel ◽

Sliding Electrical Contact ◽

A Current ◽

Tungsten Steel

The possibility of creating a wear-resistant dry sliding electrical contact tungsten/steel was studied. It was shown that tungsten caused severe wear of the quenched steel counterbody due to unlimited plastic flow of its surface layer at a current density up to 150 A/cm2 . This indicated the impossibility of achieving satisfactory characteristics of such a contact. Low electrical conductivity and wear resistance of the contact tungsten/steel were presented in comparison with the known high copper/steel contact characteristics under the same conditions. X-ray phase analysis data of the steel sliding surfaces made it possible to state that the cause of the unsatisfactory sliding of tungsten was the absence of the necessary concentration of FeO oxide on the sliding surface of the steel.

Download Full-text

An Energy-Based Discrete Element Modeling Method Coupled with Time-Series Analysis for Investigating Deformations and Failures of Jointed Rock Slopes

Applied Sciences ◽

10.3390/app11125447 ◽

2021 ◽

Vol 11 (12) ◽

pp. 5447

Author(s):

Xiaona Zhang ◽

Gang Mei ◽

Ning Xi ◽

Ziyang Liu ◽

Ruoshen Lin

Keyword(s):

Time Series ◽

Iterative Process ◽

Discrete Element ◽

Jointed Rock ◽

Modeling Method ◽

Discrete Element Modeling ◽

Rock Slopes ◽

Sliding Surface ◽

Element Modeling ◽

Displacement Based

The discrete element method (DEM) can be effectively used in investigations of the deformations and failures of jointed rock slopes. However, when to appropriately terminate the DEM iterative process is not clear. Recently, a displacement-based discrete element modeling method for jointed rock slopes was proposed to determine when the DEM iterative process is terminated, and it considers displacements that come from rock blocks located near the potential sliding surface that needs to be determined before the DEM modeling. In this paper, an energy-based discrete element modeling method combined with time-series analysis is proposed to investigate the deformations and failures of jointed rock slopes. The proposed method defines an energy-based criterion to determine when to terminate the DEM iterative process in analyzing the deformations and failures of jointed rock slopes. The novelty of the proposed energy-based method is that, it is more applicable than the displacement-based method because it does not need to determine the position of the potential sliding surface before DEM modeling. The proposed energy-based method is a generalized form of the displacement-based discrete element modeling method, and the proposed method considers not only the displacement of each block but also the weight of each block. Moreover, the computational cost of the proposed method is approximately the same as that of the displacement-based discrete element modeling method. To validate that the proposed energy-based method is effective, the proposed method is used to analyze a simple jointed rock slope; the result is compared to that achieved by using the displacement-based method, and the comparative results are basically consistent. The proposed energy-based method can be commonly used to analyze the deformations and failures of general rock slopes where it is difficult to determine the obvious potential sliding surface.

Download Full-text

Effect of temperature on tribological performance of organic friction modifier and anti-wear additive: Insights from friction, surface (ToF-SIMS and EDX) and wear analysis

Tribology International ◽

10.1016/j.triboint.2021.106896 ◽

2021 ◽

Vol 157 ◽

pp. 106896

Author(s):

Febin Cyriac ◽

Tee Xin Yi ◽

Sendhil K. Poornachary ◽

Pui Shan Chow

Keyword(s):

Friction Surface ◽

Tribological Performance ◽

Effect Of Temperature ◽

Friction Modifier ◽

Wear Analysis ◽

Tof Sims

Download Full-text

New Time-Varying Sliding Surface for Switching Type Quasi-Sliding Mode Control

Energies ◽

10.3390/en14133811 ◽

2021 ◽

Vol 14 (13) ◽

pp. 3811

Author(s):

Katarzyna Adamiak ◽

Andrzej Bartoszewicz

Keyword(s):

Sliding Mode Control ◽

Continuous Time ◽

Sliding Mode ◽

Representative Point ◽

Time Varying ◽

Sliding Surface ◽

External Disturbances ◽

Mode Control ◽

Switching Type ◽

Time Systems

This study considers the problem of energetical efficiency in switching type sliding mode control of discrete-time systems. The aim of this work is to reduce the quasi-sliding mode band-width and, as follows, the necessary control input, through an application of a new type of time-varying sliding hyperplane in quasi-sliding mode control of sampled time systems. Although time-varying sliding hyperplanes are well known to provide insensitivity to matched external disturbances and uncertainties of the model in the whole range of motion for continuous-time systems, their application in the discrete-time case has never been studied in detail. Therefore, this paper proposes a sliding surface, which crosses the system’s representative point at the initial step and then shifts in the state space according to the pre-generated demand profile of the sliding variable. Next, a controller for a real perturbed plant is designed so that it drives the system’s representative point to its reference position on the sliding plane in each step. Therefore, the impact of external disturbances on the system’s trajectory is minimized, which leads to a reduction of the necessary control effort. Moreover, thanks to a new reaching law applied in the reference profile generator, the sliding surface shift in each step is strictly limited and a switching type of motion occurs. Finally, under the assumption of boundedness and smoothness of continuous-time disturbance, a compensation scheme is added. It is proved that this control strategy reduces the quasi-sliding mode band-width from O(T) to O(T3) order from the very beginning of the regulation process. Moreover, it is shown that the maximum state variable errors become of O(T3) order as well. These achievements directly reduce the energy consumption in the closed-loop system, which is nowadays one of the crucial factors in control engineering.

Download Full-text