Ultrastructural aspects of fibre development during the stone groundwood process: New insights into derived pulp properties

Holzforschung ◽  
2007 ◽  
Vol 61 (5) ◽  
pp. 532-538 ◽  
Author(s):  
Dinesh Fernando ◽  
Peter Rosenberg ◽  
Erik Persson ◽  
Geoffrey Daniel
Keyword(s):  
Cell Wall ◽  
Juvenile Wood ◽  
Raw Materials ◽  
Microfibril Angle ◽  
Ultrastructural Level ◽  
Pilot Scale ◽  
Mature Wood ◽  
Thermomechanical Pulp ◽  
Fibre Development ◽  
Fibre Fraction

Abstract A study was performed on stone groundwood (SGW) pulps produced on a pilot scale. The behaviour of selected juvenile and mature Norway spruce wood samples was investigated. As revealed by standard tests, sheets formed from juvenile wood showed improved light scattering properties, improved tear and tensile strength, and higher sheet density compared to those formed from mature wood. Scanning electron microscopy indicated that the differences are likely related to the manner of fibre processing and development at the ultrastructural level. Mature wood fibres showed greater fibre end breakage, a smaller long-fibre fraction, enhanced S1 fibrillation and frequently open fibres. In contrast, juvenile fibres had a 14% higher long-fibre fraction and showed typical S2 fibrillation. Fibre development of juvenile wood showed fibrillation features similar to those previously reported for thermomechanical pulp fibres. In both cases, the structural hierarchy of the wood fibre cell wall and the microfibril angle of S2 and S1 layers govern cell-wall splitting and fibrillation progression. The superior quality of the fibre furnish prepared from juvenile fibres compared to mature fibres with SGW pulping may offer an alternative process for more effective utilisation of raw materials such as top logs rich in juvenile wood.

Microfibril Angle: Measurement, Variation and Relationships – A Review

IAWA Journal ◽  
2008 ◽  
Vol 29 (4) ◽  
pp. 345-386 ◽  
Author(s):  
Lloyd Donaldson
Keyword(s):  
Cell Wall ◽  
Large Scale ◽  
Juvenile Wood ◽  
Microfibril Angle ◽  
Basic Density ◽  
Angle Measurement ◽  
Axial Stiffness ◽  
Timber Species ◽  
Increment Core ◽  
X Ray

Microfibril angle (MFA) is perhaps the easiest ultrastructural variable to measure for wood cell walls, and certainly the only such variable that has been measured on a large scale. Because cellulose is crystalline, the MFA of the S2 layer can be measured by X-ray diffraction. Automated X-ray scanning devices such as SilviScan have produced large datasets for a range of timber species using increment core samples. In conifers, microfibril angles are large in the juvenile wood and small in the mature wood. MFA is larger at the base of the tree for a given ring number from the pith, and decreases with height, increasing slightly at the top tree. In hardwoods, similar patterns occur, but with much less variation and much smaller microfibril angles in juvenile wood. MFA has significant heritability, but is also influenced by environmental factors as shown by its increased values in compression wood, decreased values in tension wood and, often, increased values following nutrient or water supplementation. Adjacent individual tracheids can show moderate differences in MFA that may be related to tracheid length, but not to lumen diameter or cell wall thickness. While there has been strong interest in the MFA of the S2 layer, which dominates the axial stiffness properties of tracheids and fibres, there has been little attention given to the microfibril angles of S1 and S3 layers, which may influence collapse resistance and other lateral properties. Such investigations have been limited by the much greater difficulty of measuring angles for these wall layers. MFA, in combination with basic density, shows a strong relationship to longitudinal modulus of elasticity, and to longitudinal shrinkage, which are the main reasons for interest in this cell wall property in conifers. In hardwoods, MFA is of more interest in relation to growth stress and shrinkage behaviour.

scholarly journals Influence of juvenile and mature wood on anatomical and chemical properties of early and late wood from Chinese fir plantation

2021 ◽  
Vol 67 (1) ◽  
Author(s):  
Changqing Lu ◽  
Jun Wu ◽  
Qianqian Jiang ◽  
Yamei Liu ◽  
Liang Zhou ◽  
...  
Keyword(s):  
Juvenile Wood ◽  
Lignin Content ◽  
Microfibril Angle ◽  
Chemical Properties ◽  
Decisive Role ◽  
Chinese Fir ◽  
Mature Wood ◽  
Chemical Components ◽  
Late Wood ◽  
Significant Difference

AbstractThe proportion of juvenile wood affects the utilization of wood seriously, and the transition year of juvenile wood (JW) and mature wood (MW) plays a decisive role in the rotation and the modification of wood. To find out the demarcation of JW and MW, the tracheid length (TL) and microfibril angle (MFA) of early wood (EW) and late wood (LW) from four Chinese fir clones were measured by optical microscopy and X-ray diffraction. Then the data were analyzed by the k-means clustering method. The correlation and the differences among wood properties between JW and MW were compared. Results indicated that the LW showed better properties than that of EW, but the anatomical differences between EW and LW did not influence the demarcation of JW and MW. The cluster analysis of TL and MFA showed that the transition year was in the 16th year and the transition zone of EW and LW was different among clones. The MW has longer and wider tracheid, thicker cell walls, and smaller MFA. In terms of chemistry, MW had a higher content of holocellulose, α-cellulose, less content of extract, but no significant difference in lignin content compared with JW. The stabilization of chemical components was earlier than that of the anatomic properties. Correlation analysis showed that there were strong correlations between the chemical composition and anatomical characteristics in JW and MW. In general, compared with chemical components, anatomical indicators were more suitable for JW and MW demarcation. The differences and correlations between JW and MW properties provide a theoretical basis for wood rotation and planting.

scholarly journals Genetic control of transition from juvenile to mature wood with respect to microfibril angle in Norway spruce (Picea abies) and lodgepole pine (Pinus contorta)

2018 ◽  
Vol 48 (11) ◽  
pp. 1358-1365 ◽  
Author(s):  
Haleh Hayatgheibi ◽  
Nils Erik Gustaf Forsberg ◽  
Sven-Olof Lundqvist ◽  
Tommy Mörling ◽  
Ewa J. Mellerowicz ◽  
...  
Keyword(s):  
Picea Abies ◽  
Genetic Control ◽  
Norway Spruce ◽  
Pinus Contorta ◽  
Juvenile Wood ◽  
Lodgepole Pine ◽  
Microfibril Angle ◽  
Mature Wood ◽  
Direct Selection ◽  
Narrow Sense Heritability

Genetic control of microfibril angle (MFA) transition from juvenile wood to mature wood was evaluated in Norway spruce (Picea abies (L.) Karst) and lodgepole pine (Pinus contorta Douglas ex Loudon). Increment cores were collected at breast height (1.3 m) from 5664 trees in two 21-year-old Norway spruce progeny trials in southern Sweden and from 823 trees in two lodgepole pine progeny trials, aged 34–35 years, in northern Sweden. Radial variations in MFA from pith to bark were measured for each core using SilviScan. To estimate MFA transition from juvenile wood to mature wood, a threshold level of MFA 20° was considered, and six different regression functions were fitted to the MFA profile of each tree after exclusion of outliers, following three steps. The narrow-sense heritability estimates (h2) obtained for MFA transition were highest based on the slope function, ranging from 0.21 to 0.23 for Norway spruce and from 0.34 to 0.53 for lodgepole pine, while h2 were mostly non-significant based on the logistic function, under all exclusion methods. Results of this study indicate that it is possible to select for an earlier MFA transition from juvenile wood to mature wood in Norway spruce and lodgepole pine selective breeding programs, as the genetic gains (ΔG) obtained in direct selection of this trait were very high in both species.

scholarly journals VARIATION OF MICROFIBRIL ANGLE OF Pinus radiata D. Don IN RELATION TO TREE SPACING IN CHILEAN PLANTATIONS

2015 ◽  
Vol 39 (4) ◽  
pp. 751-758 ◽  
Author(s):  
Jerome Alteyrac
Keyword(s):  
Pinus Radiata ◽  
Juvenile Wood ◽  
Microfibril Angle ◽  
Radiata Pine ◽  
Mature Wood ◽  
X Ray Diffraction ◽  
X Ray

ABSTRACTFour stands of 28-year-old radiata pine (Pinus radiata D. Don) grown in the eighth region (Biobio) of Chile were sampled to determine the effect of tree spacing on the microfibril angle. The samples were taken at two different stem levels of the tree, 2.5 m and 7.5 m, with increment strip taken in the Nothern direction. The four experimental stands were characterized by the following spacing 2x2, 2x3, 3x4 and 4x4. The microfibril angle was measured by X-ray diffraction with the SilviScan technology at the FP-Innovation-Paprican Division in Vancouver, Canada. The results showed a significant effect of tree spacing on the microfibril angle in both juvenile wood and mature wood as well as at the two stem levels considered. The minimum (9.42º) was reached in 2x2 stand at 7.5 m in mature wood, while maximum microfibril angle (24.54º) was obtained in 2x3 stand at 2.5 m in juvenile wood. Regarding the effect of tree spacing, 4x4 stand had the lowest microfibril angle,except in mature wood at 7.5 m where 4x4 had the highest microfibril angle (11°) of the four stands.

Juvenile and mature wood characteristics of short and long rotation teak in Java

IAWA Journal ◽  
2015 ◽  
Vol 36 (4) ◽  
pp. 428-442 ◽  
Author(s):  
Wayan Darmawan ◽  
Dodi Nandika ◽  
Rita Kartika Sari ◽  
Annisah Sitompul ◽  
Istie Rahayu ◽  
...  
Keyword(s):  
Fiber Length ◽  
Juvenile Wood ◽  
Microfibril Angle ◽  
Wood Products ◽  
Mature Wood ◽  
Modulus Of Rupture ◽  
Radial Increment ◽  
Processing Technologies ◽  
Wood Processing ◽  
Teak Wood

Teak wood (Tectona grandis) as an important forest resource in Indonesia has been processed to wood furniture in large quantities to fulfill an increasing need of both local and international consumers. To satisfy the increasing demand for wood products, teak wood has been supplied from the State forests (Perhutani) and Community teak plantations. Community teak has been harvested at shorter age rotations (7–10 years) than Perhutani teak (40–60 years). This paper discusses the occurrence and characteristics of juvenile wood in Perhutani and Community teak based on density, shrinkage, bending strength (modulus of rupture - MOR, modulus of elasticity - MOE), fiber length, and microfibril angle (MFA). A segmented modeling approach was used to find the juvenile mature transition. Fiber length and MFA appear to be good anatomical indicators of radial increment demarcation between juvenile and mature wood, although maturation radial increment varies slightly between the fiber length and MFA. The use of radial increment density, shrinkage, MOR, and MOE were not appropriate, because of low coefficients of determination and a large range of radial increment for transition from juvenile to mature wood. The maturations were estimated to start at radial increments 10 and 14 cm from the pith by fiber length, and 11 and 15 cm from the pith by MFA for Perhutani and Community teak, respectively. The projected figures for the proportion of juvenile wood at breast height for Perhutani and Community teak were 65% and 100%, respectively. The results also indicate that short-rotation Community teak was not remarkably inferior in shrinkage, MOE and MOR compared to Perhutani teak, although it was less dense, less attractive and less durable due to lower heartwood content. Therefore, careful attention should be given to the use of the Community teak in some wood-processing technologies.

scholarly journals Influence of biological origin on the tensile properties of cellulose nanopapers

Cellulose ◽  
2021 ◽  
Author(s):  
Katri S. Kontturi ◽  
Koon-Yang Lee ◽  
Mitchell P. Jones ◽  
William W. Sampson ◽  
Alexander Bismarck ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Cell Wall ◽  
Bacterial Cellulose ◽  
Raw Materials ◽  
Cellulose Nanofibers ◽  
Nanofibrillated Cellulose ◽  
Primary Cell Wall ◽  
Biological Origin ◽  
Basic Principles ◽  
Fiber Mats

Abstract Cellulose nanopapers provide diverse, strong and lightweight templates prepared entirely from sustainable raw materials, cellulose nanofibers (CNFs). Yet the strength of CNFs has not been fully capitalized in the resulting nanopapers and the relative influence of CNF strength, their bonding, and biological origin to nanopaper strength are unknown. Here, we show that basic principles from paper physics can be applied to CNF nanopapers to illuminate those relationships. Importantly, it appeared that ~ 200 MPa was the theoretical maximum for nanopapers with random fibril orientation. Furthermore, we demonstrate the contrast in tensile strength for nanopapers prepared from bacterial cellulose (BC) and wood-based nanofibrillated cellulose (NFC). Endemic amorphous polysaccharides (hemicelluloses) in NFC act as matrix in NFC nanopapers, strengthening the bonding between CNFs just like it improves the bonding between CNFs in the primary cell wall of plants. The conclusions apply to all composites containing non-woven fiber mats as reinforcement. Graphic abstract

scholarly journals Process Modeling and Simulation of Tableting—An Agent-Based Simulation Methodology for Direct Compression

Pharmaceutics ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 996
Author(s):  
Niels Lasse Martin ◽  
Ann Kathrin Schomberg ◽  
Jan Henrik Finke ◽  
Tim Gyung-min Abraham ◽  
Arno Kwade ◽  
...  
Keyword(s):  
Raw Materials ◽  
Pilot Scale ◽  
Physical Models ◽  
Agent Based Simulation ◽  
Validation Data ◽  
Agent Based ◽  
Industrial Processing ◽  
Digital Twins ◽  
Product And Process ◽  
The Impact

In pharmaceutical manufacturing, the utmost aim is reliably producing high quality products. Simulation approaches allow virtual experiments of processes in the planning phase and the implementation of digital twins in operation. The industrial processing of active pharmaceutical ingredients (APIs) into tablets requires the combination of discrete and continuous sub-processes with complex interdependencies regarding the material structures and characteristics. The API and excipients are mixed, granulated if required, and subsequently tableted. Thereby, the structure as well as the properties of the intermediate and final product are influenced by the raw materials, the parametrized processes and environmental conditions, which are subject to certain fluctuations. In this study, for the first time, an agent-based simulation model is presented, which enables the prediction, tracking, and tracing of resulting structures and properties of the intermediates of an industrial tableting process. Therefore, the methodology for the identification and development of product and process agents in an agent-based simulation is shown. Implemented physical models describe the impact of process parameters on material structures. The tablet production with a pilot scale rotary press is experimentally characterized to provide calibration and validation data. Finally, the simulation results, predicting the final structures, are compared to the experimental data.

The Ultrastructure and Ontogeny of Pollen in Helleborus Foetidus L

1968 ◽  
Vol 3 (2) ◽  
pp. 161-174
Author(s):  
P. ECHLIN ◽  
H. GODWIN
Keyword(s):  
Cell Wall ◽  
Tapetal Cell ◽  
Pollen Grains ◽  
Ultrastructural Level ◽  
Low Molecular Weight ◽  
Cell Organelles ◽  
Helleborus Foetidus ◽  
Ubisch Bodies ◽  
Ubisch Body ◽  
Development Proceeds

The ontogeny of the tapetum and Ubisch bodies in Helleborus foetidus L. has been examined at the ultrastructural level, and their development has been closely linked with that of the sporogenous cell and pollen grains. During development the tapetum passes through successive phases of synthesis, maturity and senescence, ending in complete dissolution. During the anabolic phase of growth, precursors of the Ubisch bodies are formed as spheroidal vesicles of medium electron density within the tapetal cytoplasm; they are associated with a zone of radiating ribosomes, which, as development proceeds, can clearly be seen to be situated on strands of endoplasmic reticulum. The callose special wall round the microspores and the tapetal cell wall now disintegrate and the pro-Ubisch bodies are extruded through the cell membrance of the tapetal cells, where they remain on the surface of the anther cavity and soon become irregularly coated with sporopollenin. Deposition of sporopollenin continues on the Ubisch bodies at the same time as upon the exines of the developing pollen grains. In both cases, the later stages of sporopollenin deposition are associated with electron-transparent layers of unit-membrane dimensions appearing in section as white lines of uniform thickness. Continuing deposition of sporopollenin leads to the formation of compound or aggregate Ubisch bodies. It is conjectured that the sporopollenin is synthesized from the compounds of low molecular weight released into the anther loculus by the breakdown of the callose special wall and the tapetal cell wall. The final stages of tapetal autolysis involve the disappearance of all the cell organelles. An attempt is made to relate the findings to those described in other recent studies on Ubisch body formation and to combine them in a common ontogenetic pattern.

scholarly journals A study to set-up a technological process for purification of Zinc scraps by using liquation method

2021 ◽  
Vol 8 (1) ◽  
pp. 36-43
Author(s):  
Ngoc Vuong Tran ◽  
Manh Hung Luong ◽  
Dinh Dang Nguyen
Keyword(s):  
Zinc Oxide ◽  
Raw Materials ◽  
Time Factors ◽  
Pilot Scale ◽  
Raw Material ◽  
Optimal Time ◽  
Fe Content ◽  
Technology Process ◽  
Zn Content ◽  
Set Up

Zinc scrap is a source of raw material for zinc oxide production. However, to qualify the requirement of raw material for zinc oxide (99.5%) production, refining this source is needed. Many methods are considered such as rectification, chemical method, etc., but difficult to apply on an industrial scale. This workfocused on the investigation of the influence of temperature and time factors for asessing the possibility of applying liquation method for the purification of impurities from scrap zinc.The experiment results show that the optimum temperature of liquation to remove Pb,Fe from zinc scrap is in the range of 440-450°C, the optimal time of the process is 8h for the pot with 8cm in height and 6cm in diameter (the quantity of raw zinc sample is about 2kg / batch), then we can obtain about 80% of zinc metal with an average Zn content of about 97, 0%, both Pb and Fe content decreased to a range from 0.35 to 0.4%, and 1.0 to 1.1%, respectively, which meet the requirement of raw materials for the production of high quanlity ZnO ( 99,5 %). Based on the parameters obtained on lab-scale, a trial on pilot scale of 250 kg / batch was conducted, The result confirms that the quality of the products meets the requirement of raw materials for production of high quality ZnO (99.5%) and a technology process for refining zinc scrap by the liquation was proposed.

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