Emerging Materials Challenges in Microelectronics Packaging

MRS Bulletin ◽  
2003 ◽  
Vol 28 (1) ◽  
pp. 68-74 ◽  
Author(s):  
D. R. Frear ◽  
S. Thomas

IntroductionThe trend for microelectronic devices has historically been, and will continue to be, toward a smaller feature size, faster speeds, more complexity, higher power, and lower cost. The driving force behind these advances has traditionally been microprocessors. With the tremendous growth of wireless telecommunications, rf applications are beginning to drive many areas of microelectronics that traditionally were led by developments in microprocessors. An increasingly dominant factor in rf microelectronics is electronic packaging, and the materials needed to create the package, because the package materials strongly affect the performance of the electronics. Many challenges remain for the packaging of microprocessors as well. These challenges include increased speed, the number of input/output interconnects, decreased pitch, and decreased cost. This article highlights the key issues facing the packaging of high-performance digital and rf electronics.

1993 ◽  
Vol 323 ◽  
Author(s):  
H. M. Clearfleld ◽  
B. K. Furman ◽  
A. Callegari ◽  
T. Graham ◽  
S. Purushothaman

AbstractDurability of metal/polymer interfaces is essential for the long-term reliability of high performance microelectronics packages. Such interfaces undergo stresses during production and in service. In this work, we report on the durability of interfaces formed between reactive metals and polyimides (PI) that have been subjected to stresses simulating both types of environment. The P1 surfaces were treated by Ar RF plasmas prior to metal deposition, and durability was determined by measuring the 90 degree peel strength as a function of environmental exposure. The durability of Cr and Ti/PMDA-ODA interfaces through processing stresses (i.e., large thermal excursions) depends on the PI surface modification and the metal reactivity. For both, we observed interfacial degradation due to oxidation of the metal–the cause is water absorbed by the polyimide. These studies, coupled with water transport measurements, suggest that the physical structure of the interface is the dominant factor. To determine the durability under service environmental stresses (e.g., temperature/humidity), we correlated peel strengths with interfacial chemistry and water uptake. In this case, Ar and O2 plasmas were used. For Ta/BPDA-PDA, the durability depends on the type of plasma treatment. Ar-treated specimens maintain strength through 500 hours T/H stressing whereas those treated by O2 plasma alone fail at 165 hours. The differences here can be explained by the interfacial chemistry–Ta/Ar-etched surfaces form a stable TaG-like structure whereas the Ta/O2-etched surfaces form a metastable, sub-oxide structure that transforms to Ta2O5 during stressing. Ta/PMDA-ODA interfaces fail readily under these conditions due to the increased water uptake of the PI.


2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Iñigo Bretos ◽  
Ricardo Jiménez ◽  
Monika Tomczyk ◽  
Enrique Rodríguez-Castellón ◽  
Paula M. Vilarinho ◽  
...  

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 409
Author(s):  
Xiaofei Tang ◽  
Rui Zhu ◽  
Tianjing Shi ◽  
Yu Wang ◽  
Xiaochen Niu ◽  
...  

High energy density materials (HEDM) are the subject of an extensive research effort in relation to the use of these compounds as components of rocket propellants, powders, and formulations of high-performance explosives. Hexanitrohexaazaisowurtzitane (HNIW, i.e., CL-20) has received much attention in these research fields for its specific impulse, burning rate, ballistics, and detonation velocity. In this paper, the development and performances of the explosives from the first to the fourth generation are briefly summarized, and the synthesis status of the fourth-generation explosive, HNIW, is reviewed. The key issues that restrict the development of industrial amplification synthesis of HNIW are analyzed, and the potential directions of development are proposed. It is pointed out that to synthesize new and efficient catalysts is the key to making the cost-effective manufacturing of CL-20 a reality.


2017 ◽  
Vol 5 (24) ◽  
pp. 12330-12339 ◽  
Author(s):  
Norah Balahmar ◽  
Abdul Salam Al-Jumialy ◽  
Robert Mokaya

The direct conversion of biomass to activated carbons in a simple and lower cost one step process, which negates the need for hydrothermal carbonisation or pyrolysis, generates activated carbons with properties and CO2 uptake comparable or superior to those of conventionally prepared activated carbons.


2016 ◽  
Vol 2016 (DPC) ◽  
pp. 000631-000649
Author(s):  
Matthew A Thorseth ◽  
Mark Scalisi ◽  
Inho Lee ◽  
Sang-Min Park ◽  
Yil-Hak Lee ◽  
...  

Increasing market demand for portable high-performance electronic devices is requiring an increase in the I/O density in the chip packaging used to make these products. Flip-chip interconnects that enable advanced packaging utilize a C4 bumping process with lead-free solder to make the chip interconnection. However, with the decreasing chip size and tighter I/O pitch requirements that are needed to realize high-performance, Cu pillar plating has emerged as an enabling technology to meet the technical demands. Cu pillars, capped with a lead-free solder, allow for increased I/O density while still maintaining the standoff needed for proper thermal and electrical performance of stacked chips. With this realized performance, there is expected to be a significant increase in capacity of Cu pillar in the industry, requiring electrolytic Cu plating products with fast deposition rates in order to decrease wafer plating time and increase throughput. In this paper, Cu electroplating products are evaluated for plating performance at increased deposition rates for Cu pillar applications ranging from micropillar (<20 μm feature size), to standard pillar (20 – 75 μm feature size), redistribution layer (RDL) wiring, and the emerging fan-out wafer level packaging (FO-WLP), which encompasses megapillars (>150 μm feature sizes) as well as stacked via RDL designs. The chief performance criteria for evaluation is the ability to increase deposition rates while maintaining feature height uniformity, smooth and uniform feature morphology, and ability to plate a wide variety of feature sizes and shapes. Additionally, performance of these products is assessed on their ability to plate highly pure Cu deposits which enable void-free integration with lead-free solder without the need of (but is compatible with) a cost-added barrier layer.


2017 ◽  
Vol 2017 (1) ◽  
pp. 000491-000496
Author(s):  
Mario Magaña ◽  
Basab Chatterjee ◽  
Rey Javier

Abstract TI's commitment to meeting customer requirements has resulted in the development of package technologies and process to improve performance and higher power at lower cost for wire-bonded packages and automotive products are requiring more stringent reliability requirements. Some of the strategies we have adopted include using thinner metal and low-K ILD for lower parasitics and higher performance, thick copper routings for higher power and larger wafer diameters and smaller scribe streets for lower cost and using Copper (Cu) wire. Cu wire is a key enabler due to higher electrical conductivity and lower cost than gold), but also poses integration challenges due to hardness, CTE mismatch and corrosion susceptibility. The hardness of the copper wire imposes significant challenges for wire-bonding on pads w thin metal and low-k ILD. This required co-design of die bond pad structure for enhanced reliability as well as Cu wire process development requires comprehensive approach encompassing multiple areas including ball and stitch parameters, capillary design, bonding processes like segmented bonding and validation of process margins using ‘hammer’ test. Copper wire also requires metrology and test/detection tools like Nomarski, stitch pull test in addition to the traditional wire pull at mid span and neck, rapid-bake test, measuring intermetallics & Al remaining under ball, and Al-splash. The susceptibility of Cu wire to corrosion required us to introduce new materials like PCC and Au-flash PCC, tight environmental controls in the form of forming gas, monitoring of Ph and ion-trappers in BOM, wire oxidation check at outgoing/incoming inspection as SERA (Sequential Electrochemical Reduction Analysis), and paying close attention to handling and non-process gases. More stringent qualification requirements like AEC-006 is driving additional changes to lead frame design and finish, selection of EMC and Die attach, to reduce delamination and epoxy bleed-out. The demands for lower cost is driving us to use larger sized wafers (like 300mm) and narrower scribe width, while packing more functionality into smaller dies thereby driving higher metal densities. Additional requirements for thinner and 3D packages requiring post backgrind thickness as low as 50–75um imposing challenges in terms of warpage and saw. The demand for higher power applications is requiring us to use thick copper routings. We have developed test structures and redesigned layout of the scribe street and scribe seal and pursuing new saw methods. We have also learned many lessons in terms of handling and corrosion risks and implemented safeguards in terms of process and material selection.


Author(s):  
Stuart J. Barnes ◽  
Eusebio Scornavacca

The growth and convergence of wireless telecommunications and ubiquitous networks has created a tremendous potential platform for providing business services. In consumer markets, mobile marketing is likely to be a key growth area. The immediacy, interactivity, and mobility of wireless devices provide a novel platform for marketing. The personal and ubiquitous nature of devices means that interactivity can, ideally, be provided anytime and anywhere. However, as experience has shown, it is important to keep the consumer in mind. Mobile marketing permission and acceptance are core issues that marketers have yet to fully explain or resolve. This chapter provides direction in this area. After briefly discussing some background on mobile marketing, the chapter conceptualises key characteristics for mobile marketing permission and acceptance. The chapter concludes with predictions on the future of mobile marketing and some core areas of further research.


2018 ◽  
Vol 6 (16) ◽  
pp. 7027-7033 ◽  
Author(s):  
Mikko Nisula ◽  
Maarit Karppinen

We demonstrate that the high-capacity organic electrode material, p-benzoquinone, is able to sustain ultrahigh redox reaction rates without any conductive additives when applied as ultrathin layers in an all-solid-state thin-film battery setup, viable for e.g. high-performance power sources in microelectronic devices.


Author(s):  
Maria Christina Meyers ◽  
Nicky Dries ◽  
Giverny De Boeck

It is assumed that employees display favorable attitudes (e.g., high organizational commitment) and behaviors (e.g., high work effort) when identified as organizational talent. If they did not, the idea that talent management creates value by making disproportionate investments into organizational talent would need to be reconsidered. We reviewed the literature to explore whether the assumed favorable reactions among talent are valid and the results are not straightforward. Many studies found evidence for the assumption; however, several studies revealed that talent designation bears considerable risks: Being identified as talent creates (overly optimistic) expectations of receiving rewards and benefits from the organization and it increases the felt pressure to meet high performance standards. We discuss the findings in the light of social exchange theory, psychological contract theory, and others commonly used in talent-management research, highlighting key issues regarding talent designation and identifying avenues for future research.


Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 593 ◽  
Author(s):  
Tao Wan ◽  
Xiaojun Yin ◽  
Chengjun Pan ◽  
Danqing Liu ◽  
Xiaoyan Zhou ◽  
...  

Single-walled carbon nanotubes (SWCNTs) incorporated with π-conjugated polymers, have proven to be an effective approach in the production of advanced thermoelectric composites. However, the studied polymers are mainly limited to scanty conventional conductive polymers, and their performances still remain to be improved. Herein, a new planar moiety of platinum acetylide in the π-conjugated system is introduced to enhance the intermolecular interaction with the SWCNTs via π–π and d–π interactions, which is crucial in regulating the thermoelectric performances of SWCNT-based composites. As expected, SWCNT composites based on the platinum acetylides embedded polymers displayed a higher power factor (130.7 ± 3.8 μW·m−1·K−2) at ambient temperature than those without platinum acetylides (59.5 ± 0.7 μW·m−1·K−2) under the same conditions. Moreover, the strong interactions between the platinum acetylide-based polymers and the SWCNTs are confirmed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) measurements.


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