scholarly journals NANOFIBRAS ELETROFIADAS E SUAS APLICAÇÕES: AVANÇOS NA ÚLTIMA DÉCADA

Química Nova ◽  
2021 ◽  
Author(s):  
Luiza Mercante ◽  
Rafaela Andre ◽  
Juliana Macedo ◽  
Adriana Pavinatto ◽  
Daniel Correa

ELECTROSPUN NANOFIBERS AND THEIR APPLICATIONS: ADVANCES IN THE LAST DECADE. In recent years there has been an increasing interest in the development of nanomaterials with improved properties compared to their counterparts at the micro- and macroscopic scale. In this context, nanofibers obtained by electrospinning technique are highly attractive due to the unique combination of high surface area/volume ratio, porosity, flexibility, mechanical performance, simple processing and relatively low cost. In addition, the possibility to buildup nanofibers with different compositions, structures and properties allows the design of nanostructures for a wide range of applications. In this review, we will discuss the advances of the last decade in the use of the electrospinning to obtain nanofibers with different compositions and morphologies for varied applications. Specifically, we are interested in providing an overview of the state of the art in relation to the application of nanofibers in different areas, including healthcare, environment, sensing and energy. Finally, we will discuss the real perspective in terms of industrial application and future trends that have been pursued to improve the performance of electrospun nanofibers. This review will help researchers to understand the evolution and challenges of the area and will also stimulate even more interest in the development of new devices based on electrospun nanofibers

Catalysts ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 9
Author(s):  
M. Olga Guerrero-Pérez

During the last two decades, electrospinning has become a very popular technique for the fabrication of nanofibers due to its low cost and simple handling. Nanofiber materials have found utilization in many areas such as medicine, sensors, batteries, etc. In catalysis, these materials also present important advantages, since they present a low resistance to internal diffusion and a high surface area to volume ratio. These advantages are mainly due to the diameter–length proportion. A bibliographic analysis on the applications of electrospun nanofibers in catalysis shows that there are two important groups of catalysts that are being investigated, based on TiO2 and in carbon materials. The main applications found are in photo- and in electro-catalysis. The present study contributes by reviewing these catalytic applications of electrospun nanofibers and demonstrating that they are promising materials as catalysts, underlining some works to prove the advantages and possibilities that these materials have as catalysts. On one hand, the possibilities of synthesis are almost infinite, since with coaxial electrospinning quite complex nanofibers with different layers can be prepared. On the other hand, the diameter and other properties can be controlled by monitoring the applied voltage and other parameters during the synthesis, being quite reproducible procedures. The main advantages of these materials can be grouped in two: one related to their morphology, as has been commented, relative to their low resistance and internal diffusion, that is, their fluidynamic behavior in the reactor; the second group involves advantages related to the fact that the active phases can be nanoscaled and dispersed, improving the activity and selectivity in comparison with conventional catalytic materials with the same chemical composition.


SURG Journal ◽  
2012 ◽  
Vol 5 (2) ◽  
pp. 63-73 ◽  
Author(s):  
Nishath Khan

Electrospinning is a technology that has been widely used as a novel method for the generation of nano scale fibres. Electrospun fibres are used in a wide range of applications from electronics to textile. The viability and popularity of this technology can be evidenced by its ease of use and the simplicity of the science behind building the electrospinning machine. The generated fibres have a high surface area- to- volume ratio, the fibrous mats are highly porous and display excellent mechanical properties when compared to other materials of the same scale. In the past decade, this technology has taken off with the use of biocompatible and biodegradable polymers. This review is a summary of the different ways in which electrospinning can be used in the biomedical field. This article analyzes the recent advances of this technology in tissue engineering, drug delivery and in enzyme immobilisation, which once again showcases the versatility of the electrospinning procedure.


Sensors ◽  
2019 ◽  
Vol 19 (16) ◽  
pp. 3587 ◽  
Author(s):  
Nahal Aliheidari ◽  
Nojan Aliahmad ◽  
Mangilal Agarwal ◽  
Hamid Dalir

Electrospinning is a simple, low-cost and versatile method for fabricating submicron and nano size fibers. Due to their large surface area, high aspect ratio and porous structure, electrospun nanofibers can be employed in wide range of applications. Biomedical, environmental, protective clothing and sensors are just few. The latter has attracted a great deal of attention, because for biosensor application, nanofibers have several advantages over traditional sensors, including a high surface-to-volume ratio and ease of functionalization. This review provides a short overview of several electrospun nanofibers applications, with an emphasis on biosensor applications. With respect to this area, focus is placed on label-free sensors, pertaining to both recent advances and fundamental research. Here, label-free sensor properties of sensitivity, selectivity, and detection are critically evaluated. Current challenges in this area and prospective future work is also discussed.


2021 ◽  
Vol 22 (12) ◽  
pp. 6357
Author(s):  
Kinga Halicka ◽  
Joanna Cabaj

Sensors and biosensors have found applications in many areas, e.g., in medicine and clinical diagnostics, or in environmental monitoring. To expand this field, nanotechnology has been employed in the construction of sensing platforms. Because of their properties, such as high surface area to volume ratio, nanofibers (NFs) have been studied and used to develop sensors with higher loading capacity, better sensitivity, and faster response time. They also allow to miniaturize designed platforms. One of the most commonly used techniques of the fabrication of NFs is electrospinning. Electrospun NFs can be used in different types of sensors and biosensors. This review presents recent studies concerning electrospun nanofiber-based electrochemical and optical sensing platforms for the detection of various medically and environmentally relevant compounds, including glucose, drugs, microorganisms, and toxic metal ions.


2021 ◽  
Author(s):  
Ashoka Gamage ◽  
Thiviya Punniamoorthy ◽  
Terrence Madhujith

Environmental pollution is becoming a major global issue with increasing anthropogenic activities that release massive toxic pollutants into the land, air, and water. Nanomaterials have gained the most popularity in the last decades over conventional methods because of their high surface area to volume ratio and higher reactivity. Nanomaterials including metal, metal oxide, zero-valent ions, carbonaceous nanomaterials, and polymers function as adsorbents, catalysts, photocatalysts, membrane (filtration), disinfectants, and sensors in the detection and removal of various pollutants such as heavy metals, organic pollutants, dyes, industrial effluents, and pathogenic microbial. Polymer-inorganic hybrid materials or nanocomposites are highly studied for the removal of various contaminants. Starch, a heteropolysaccharide, is a natural biopolymer generally incorporated with other metal, metal oxide, and other polymeric nanoparticles and has been reported in various environmental remediation applications as a low-cost alternative for petroleum-based polymers. Therefore, this chapter mainly highlights the various nanomaterials used in environmental remediation, starch-based hybrid nanomaterials, and their application and limitations.


Author(s):  
Ravindra Kumar Gautam ◽  
Shivani Soni ◽  
Mahesh Chandra Chattopadhyaya

Water pollution by anthropogenic activities is proving to be of critical concern as the heavy metals affect aquatic organisms and can quickly disperse to large distances. This poses a risk to both human health and the aquatic biota. Hence, there is a need to treat the wastewater containing toxic metals before they are discharged into the water bodies. During recent years, magnetic nanoparticles came to the foreground of scientific interest as a potential adsorbent of novel wastewater treatment processes. Magnetic nanoparticles have received much attention due to their unique properties, such as extremely small size, high surface-area-to-volume ratio, surface modifiability, multi functionality, excellent magnetic properties, low-cost synthesis, and great biocompatibility. The multi-functional magnetic nanoparticles have been successfully applied for the reduction of toxic metal ions up to ppb level in waste-treated water. This chapter highlights the potential application of magnetic nanoparticles for the removal of heavy metals.


Author(s):  
Ravindra Kumar Gautam ◽  
Shivani Soni ◽  
Mahesh Chandra Chattopadhyaya

Water pollution by anthropogenic activities is proving to be of critical concern as the heavy metals affect aquatic organisms and can quickly disperse to large distances. This poses a risk to both human health and the aquatic biota. Hence, there is a need to treat the wastewater containing toxic metals before they are discharged into the water bodies. During recent years, magnetic nanoparticles came to the foreground of scientific interest as a potential adsorbent of novel wastewater treatment processes. Magnetic nanoparticles have received much attention due to their unique properties, such as extremely small size, high surface-area-to-volume ratio, surface modifiability, multi functionality, excellent magnetic properties, low-cost synthesis, and great biocompatibility. The multi-functional magnetic nanoparticles have been successfully applied for the reduction of toxic metal ions up to ppb level in waste-treated water. This chapter highlights the potential application of magnetic nanoparticles for the removal of heavy metals.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
C. E. A. Botteon ◽  
L. B. Silva ◽  
G. V. Ccana-Ccapatinta ◽  
T. S. Silva ◽  
S. R. Ambrosio ◽  
...  

AbstractGold nanoparticles (AuNPs) are highlighted due to their low toxicity, compatibility with the human body, high surface area to volume ratio, and surfaces that can be easily modified with ligands. Biosynthesis of AuNPs using plant extract is considered a simple, low-cost, and eco-friendly approach. Brazilian Red Propolis (BRP), a product of bees, exhibits anti-inflammatory, anti-tumor, antioxidant, and antimicrobial activities. Here, we described the biosynthesis of AuNPs using BRP extract (AuNPextract) and its fractions (AuNPhexane, AuNPdichloromethane, AuNPethyl acetate) and evaluated their structural properties and their potential against microorganisms and cancer cells. AuNPs showed a surface plasmon resonance (SPR) band at 535 nm. The sizes and morphologies were influenced by the BRP sample used in the reaction. FTIR and TGA revealed the involvement of bioactive compounds from BRP extract or its fractions in the synthesis and stabilization of AuNPs. AuNPdichloromethane and AuNPhexane exhibited antimicrobial activities against all strains tested, showing their efficacy as antimicrobial agents to treat infectious diseases. AuNPs showed dose-dependent cytotoxic activity both in T24 and PC-3 cells. AuNPdichloromethane and AuNPextract exhibited the highest in vitro cytotoxic effect. Also, the cytotoxicity of biogenic nanoparticles was induced by mechanisms associated with apoptosis. The results highlight a potential low-cost green method using Brazilian red propolis to synthesize AuNPs, which demonstrated significant biological properties.


2016 ◽  
Vol 852 ◽  
pp. 1455-1462
Author(s):  
Jie Zhang ◽  
Yong Heng Zhu ◽  
Shi Zao Kang ◽  
Xiang Qing Li ◽  
Jia Qiang Xu

In this paper, different SBA-15 molecular sieves were prepared in a facile sol-gel method by using a low-cost sodium silicate as silicon source at different ripening temperature. The materials were characterized by small-angle XRD, TEM, nitrogen adsorption–desorption test. The results showed that ripening temperature can affect the pore size and mesostructure of SBA-15. High surface area SBA-15 can be obtained at low ripening temperature, and plugged mesostructure can be prepared at high temperature. The gravimetric humidity sensing property of the materials were tested based on a transducer of quartz crystal microbalance. The test results revealed that all the samples showed high response in the wide range of relative humidity. The sensors based on that prepared at 35°C show a good stability and linearity in the range of 11.3%RH to 98%RRH along with fast response (12s) and recovery time (8s), ultrahigh sensitivity and low hysteresis, implying that has a great potential for humidity detection.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2679
Author(s):  
Alessandra Toncelli

Electrospinning is an effective and inexpensive technique to grow polymer materials in nanofiber shape with exceptionally high surface-area-to-volume ratio. Although it has been known for about a century, it has gained much interest in the new millennium thanks to its low cost and versatility, which has permitted to obtain a large variety of multifunctional compositions with a rich collection of new possible applications. Rare-earth doped materials possess many remarkable features that have been exploited, for example, for diode pumped bulk solid-state lasers in the visible and near infrared regions, or for biomedical applications when grown in nanometric form. In the last few decades, electrospinning preparation of rare-earth-doped crystal nanofibers has been developed and many different materials have been successfully grown. Crystal host, crystal quality and nanosized shape can deeply influence the optical properties of embedded rare earth ions; therefore, a large number of papers has recently been devoted to the growth and characterization of rare earth doped nanofibers with the electrospinning technique and an up-to-date review of this rapidly developing topic is missing; This review paper is devoted to the presentation of the main results obtained in this field up to now with particular insight into the optical characterization of the various materials grown with this technique.


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