scholarly journals Adsorption Isotherm Studies on Acid Orange-10 Dye Removal using Cerium Dioxide Nanoparticles

2014 ◽  
Vol 14 (3) ◽  
pp. 226-232 ◽  
Author(s):  
Harry Budiman ◽  
Oman Zuas
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Dye Removal ◽  
Isotherm Models ◽  
Batch Mode ◽  
Monolayer Adsorption ◽  
Equilibrium Data ◽  
Linear Transform ◽  
Optimum Reaction ◽  
Optimum Reaction Condition

The adsorption capacity of AO-10 from aqueous solution onto CeO2-NPs was investigated under various reaction parameters. Batch mode experiments were conducted to assess the potential of the CeO2-NPs as adsorbent for the removal of AO-10 dye from aqueous solution. Equilibrium isotherm studies were carried out under an optimum reaction condition (i.e., AO-10 dye concentration = 15 mg/L, CeO2-NPS dosage = 2 g/L, pH of dye solution = 2) obtained from this study. The equilibrium data obtained were fitted to Langmuir, Freundlich, and Redlich-Peterson isotherm models. The results shows that, the linear transform model provided the highest regression coefficient (R2 = 0.991) with the Langmuir model. The maximum monolayer adsorption capacity was found to be 33.33 mg/g at 30 °C, which is higher than some data from published literature.

ADSORPTION OF ACID ORANGE 7 BY CETYLPYRIDINIUM BROMIDE MODIFIED SUGARCANE BAGASSE

2016 ◽  
Vol 78 (1-2) ◽  
Author(s):  
Nik Ahmad Nizam Nik Malek ◽  
Nurain Mat Sihat ◽  
Mahmud A. S. Khalifa ◽  
Auni Afiqah Kamaru ◽  
Nor Suriani Sani
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Sugarcane Bagasse ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Acid Orange 7 ◽  
Cetylpyridinium Bromide ◽  
Batch Mode ◽  
Acid Orange ◽  
Adsorption Data

In the present study, the adsorption of acid orange 7 (AO7) dye from aqueous solution by sugarcane bagasse (SB) and cetylpyridinium bromide (CPBr) modified sugarcane bagasse (SBC) was examined. SBC was prepared by reacting SB with different concentrations (0.1, 1.0 and 4.0 mM) of cationic surfactant, CPBr. The SB and SBC were characterized using Fourier transform infrared (FTIR) spectroscopy. The adsorption experiments were carried out in a batch mode. The effect of initial AO7 concentrations (5-1000 mg/L), initial CPBr concentrations and pH of AO7 solution (2-9) on the adsorption capacity of SB and SBC were investigated. The experimental adsorption data were analyzed using Langmuir and Freundlich isotherm models. The adsorption of AO7 onto SB and SBC followed Freundlich and Langmuir isotherm models, respectively. The maximum uptake of AO7 was obtained by SBC4.0 (SB treated with 4.0 mMCPBr) with the adsorption capacity of 144.928 mg/g. The highest AO7 removal was found to be at pH 2 and 7 for SB and SBC, respectively. As a conclusion, sugarcane bagasse modified with CPBr can become an alternative adsorbent for the removal of anionic compounds in aqueous solution.

scholarly journals Batch Adsorption of Maxilon Red GRL from Aqueous Solution by Natural Sugarcane Stalks Powder

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Gamal Owes El-Sayed ◽  
Talaat Younis Mohammed ◽  
Ashraf Abd-Allah Salama
Keyword(s):  
Aqueous Solution ◽  
Dye Removal ◽  
Dye Adsorption ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Textile Dye ◽  
Initial Ph ◽  
Equilibrium Data ◽  
Pseudo Second Order

Sugarcane stalks powder was tested for its efficiency of removing a textile dye Maxilon Red GRL from aqueous solution. Different parameters affecting dye removal efficiency were studied. These parameters include contact time, initial dye concentration, adsorbent dose, ionic strength, pH, and temperature. Langmuir and Freundlich isotherm models were applied to the equilibrium data. The data fitted well with the Langmuir isotherm (). The maximum monolayer adsorption capacity () was found to be 20.96 mg/g at an initial pH of 7.2. The temperature variation study showed that dye adsorption is exothermic and spontaneous with increased randomness at the solid solution interface. The results indicated that sugarcane stalks could be an alternative for more costly adsorbents used for dye removal. The kinetic of the adsorption process followed the pseudo second-order kinetics model.

scholarly journals Application of Acacia karroo charcoal for desalinating Ni(II) and Zn(II) from aqueous solutions through batch mode

2013 ◽  
Vol 3 (3) ◽  
pp. 268-276
Author(s):  
Joginder Singh ◽  
Renu Sharma ◽  
Amjad Ali
Keyword(s):  
Aqueous Solution ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Solution Ph ◽  
Batch Mode ◽  
Acacia Karroo ◽  
Biosorption Process ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Heavy Metals Ions

Acacia karroo charcoal lumps were used for the biosorption of Ni(II) and Zn(II) from an aqueous solution using batch mode. The effect of various parameters viz., solution pH, adsorbent dose, contact time and initial metal concentrations were studied. Freundlich and Langmuir isotherm models were applied to the batch equilibrium data. The maximum biosorption capacity (qmax) for Ni(II) and Zn(II) was found to be 9.0 and 7.99 mg g−1 at pH 6.0 and 4.0 respectively. Experiments were performed to study the kinetics of Ni(II) and Zn(II) biosorption and the data obtained was best fitted to the pseudo-second-order kinetic model. Gibbs free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) changes were also calculated and the observed values supported the spontaneity of the biosorption process. The exhausted adsorbent was regenerated three times using 0.1 N NaOH and its regeneration capacity was evaluated. These results illustrate that A. karroo charcoal lumps hold good potential for removing heavy metals ions from aqueous solution and could be used for desalinating metal ions from industrial wastewater.

scholarly journals Biosorption Characteristics of Water Hyacinth (Eichhornia crassipes) in the Removal of Nickel (II) Ion under Isothermal Condition

2016 ◽  
Vol 59 (2) ◽  
pp. 118-120
Author(s):  
Chidi Obi ◽  
Sylvester Eigbiremonlen
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Water Hyacinth ◽  
Contact Time ◽  
Eichhornia Crassipes ◽  
Isothermal Condition ◽  
Initial Concentration ◽  
Monolayer Adsorption ◽  
Optimum Ph ◽  
Equilibrium Data

This study was taken to investigate the potentiality of water hyacinth (Eichhornia crassipes) as an alternative biosorbent for the removal of Ni (II) ion from aqueous solution. The optimum pH, contact time and concentration were found to be 6.0, 40 min and 1.0 mg/L under isothermal condition. The biosorption of Ni (II) ion was found to decrease with increasing pH, initial concentration and contact time. Results obtained were analysed with Langmuir and Freundlich biosorption models. The equilibrium data fitted well to the Langmuir biosorption model with correlation coefficient (R2) value of 0.98. The monolayer adsorption capacity was 0.29 mg/g. The removal of Ni (II) ion from aqueous solution using water hyacinth biomass followed a monolayer biosorption.

Adsorption Characteristics of Phenol in Aqueous Solution by Pinus massoniana Biochar

2013 ◽  
Vol 295-298 ◽  
pp. 1154-1160 ◽  
Author(s):  
Guo Zhi Deng ◽  
Xue Yuan Wang ◽  
Xian Yang Shi ◽  
Qian Qian Hong
Keyword(s):  
Aqueous Solution ◽  
Ph Value ◽  
Pinus Massoniana ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Adsorbent Dosage ◽  
Salt Ions ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

The objective of this paper is to investigate the feasibility of phenol adsorption from aqueous solution by Pinus massoniana biochar. Adsorption conditions, including contact time, initial phenol concentration, adsorbent dosage, strength of salt ions and pH, have been investigated by batch experiments. Equilibrium can be reached in 24 h for phenol from 50 to 250 mg• L-1. The optimum pH value for this kind of biochar is 5.0. The amount of phenol adsorbed per unit decreases with the increase in adsorbent dosage. The existence of salt ions makes negligible influence on the equilibrium adsorption capacity. The experimental data is analyzed by the Freundlich and Langmuir isotherm models. Equilibrium data fits well to the Freundlich model. Adsorption kinetics models are deduced and the pseudo-second-order kinetic model provides a good correlation for the adsorbent process. The results show that the Pinus massoniana biochar can be utilized as an effective adsorption material for the removal of phenol from aqueous solution.

scholarly journals Preparation and Characterization of Cationized Cellulose for the Removal of Anionic Dyes

2001 ◽  
Vol 19 (3) ◽  
pp. 197-210 ◽  
Author(s):  
A. Hashem ◽  
Reda M. El-Shishtawy
Keyword(s):  
Adsorption Capacity ◽  
Freundlich Isotherm ◽  
Structural Features ◽  
Isotherm Models ◽  
Acid Orange 7 ◽  
Anionic Dyes ◽  
Adsorption Parameters ◽  
Direct Blue ◽  
Equilibrium Data

The factors influencing the cationization of microcrystalline cellulose with 3-chloro-2-hydroxypropyl triethylammonium chloride in the presence of NaOH were investigated. The course of the reaction was followed by estimating the nitrogen content of the cationized product while its structural features were confirmed by IR analysis. The ability of cationized cellulose to adsorb anionic dyes, viz. Acid Orange 7, Direct Blue 75 and Direct Violet 31, was investigated at 25°C and 50°C. The equilibrium data obtained were fitted by the Langmuir and Freundlich isotherm models, allowing the corresponding adsorption parameters to be determined. The results showed that the adsorption capacity was dependent on the adsorbent, temperature, the nature of the dye and (to some extent) on van der Waals and hydrogen bonding. Cationized cellulose exhibited a much better adsorption capacity towards anionic dyes than cellulose.

Preparation of crosslinked chitosan magnetic membrane for cations sorption from aqueous solution

2017 ◽  
Vol 75 (9) ◽  
pp. 2034-2046 ◽  
Author(s):  
Adnan Khan ◽  
Samina Begum ◽  
Nauman Ali ◽  
Sabir Khan ◽  
Sajjad Hussain ◽  
...  
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Magnetic Particles ◽  
Isotherm Models ◽  
Chitosan Membrane ◽  
Dilute Aqueous Solution ◽  
Chitosan Membranes ◽  
The Fourier Transform ◽  
Time Required

A chitosan magnetic membrane was prepared in order to confer magnetic properties to the membrane, which could be used for the removal of cations from aqueous solution. The crosslinked magnetic membrane was compared with pristine chitosan membrane in term of stability, morphology and cation adsorption capacity. The fabricated magnetic materials are thermally stable as shown by thermogravimetric curves. The membrane containing nickel magnetic particles (CHNiF-G) shows high thermal stability compared to the other membranes. The Fourier transform infrared spectroscopy showed successful preparation of chitosan magnetic membrane. Scanning electron microscopy micrographs showed the rough surface of the membrane with increased porosity. The prepared chitosan membranes were applied to cations of copper, nickel and lead in dilute aqueous solution. The chitosan membrane showed the following adsorption order for metallic cations: Cu2+ > Ni2+ > Pb2+, while CHNiF-G showed higher capacity, 3.51 mmol g−1 for copper, reflecting the improvement in adsorption capacity, since the amount of copper on pristine chitosan gave 1.40 mmol g−1. The time required for adsorption to reach to the equilibrium was 6 h for the selected cations using different chitosan membranes. The kinetic study showed that adsorption followed pseudo-second order kinetics. The most commonly used isotherm models, Freundlich, Langmuir and Temkin, were applied to experimental data using linear regression technique. However, The Temkin model fits better to experimental data.

scholarly journals Study on the adsorption of methylene blue from aqueous solution using hydrogel glucomannan/graphene oxide

2021 ◽  
Vol 10 (1) ◽  
pp. 59-66
Author(s):  
Son Le Lam ◽  
Phu Nguyen Vinh ◽  
Hieu Le Trung ◽  
Tan Le Thua ◽  
Nhan Dang Thi Thanh ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Graphene Oxide ◽  
Adsorption Capacity ◽  
Organic Dyes ◽  
Dye Adsorption ◽  
Order Kinetic ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Glucomannan/graphene oxide (GM/GO) hydrogel was synthesized by using calcium hydroxide as the crosslinker. The synthesized material was characterized by using IR, XRD, SEM, EDX and RAMAN technology. The composite hydrogel was used for removal of organic dyes from aqueous solution. The results showed that the GM/GO hydrogel had a porous structure and a high adsorption capacity toward methylene blue (MB). The pseudo-second-order kinetic model could fit the rate equation of MB adsorption onto the GM/GO hydrogel. The adsorption of MB onto GM/GO hydrogel was a spontaneous process. In addition, the equilibrium adsorption isotherm data indicated that equilibrium data were fitted to the Langmuir isotherm and the maximum dye adsorption capacity was 198,69 mg.g-1. Moreover, the hydrogel was stable and easily recovered and adsorption capacity was around 97% of the initial saturation adsorption capacity after being used five times.

scholarly journals Modified/Unmodified Nanoparticle Adsorbents of Cellulose Origin With High Adsorptive Potential for Removal of Pb(II) From Aqueous Solution

2017 ◽  
Vol 13 (27) ◽  
pp. 425
Author(s):  
Azeh Yakubu ◽  
Gabriel Ademola Olatunji ◽  
Folahan Amoo Adekola
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Contact Time ◽  
Adsorption Process ◽  
Correlation Coefficients ◽  
Solution Temperature ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Kinetics Of Adsorption ◽  
Kinetics Of

This investigation was conducted to evaluate the adsorption capacity of nanoparticles of cellulose origin. Nanoparticles were synthesized by acid hydrolysis of microcrystalline cellulose/cellulose acetate using 64% H3PO4 and characterized using FTIR, XRD, TGA-DTGA, BET and SEM analysis. Adsorption kinetics of Pb (II) ions in aqueous solution was investigated and the effect of initial concentration, pH, time, adsorbent dosage and solution temperature. The results showed that adsorption increased with increasing concentration with removal efficiencies of 60% and 92.99% for Azeh2 and Azeh10 respectively for initial lead concentration of 3 mg/g. The effects of contact time showed that adsorption maximum was attained within 24h of contact time. The maximum adsorption capacity and removal efficiency were achieved at pH6. Small dose of adsorbent had better performance. The kinetics of adsorption was best described by the pseudo-second-Order model while the adsorption mechanism was chemisorption and pore diffusion based on intra-particle diffusion model. The isotherm model was Freundlich. Though, all tested isotherm models relatively showed good correlation coefficients ranging from 0.969-1.000. The adsorption process was exothermic for Azeh-TDI, with a negative value of -12.812 X 103 KJ/mol. This indicates that the adsorption process for Pb by Azeh-TDI was spontaneous. Adsorption by Azeh2 was endothermic in nature.

scholarly journals Adsorption of Mn2+ from Aqueous Solution Using Manganese Oxide-Coated Hollow Polymethylmethacrylate Microspheres (MHPM)

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Dhiraj Dutta ◽  
Jyoti Prasad Borah ◽  
Amrit Puzari
Keyword(s):  
Aqueous Solution ◽  
Manganese Oxide ◽  
Adsorption Capacity ◽  
High Surface ◽  
High Surface Area ◽  
Freundlich Isotherm ◽  
Ion Concentration ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Coated Sand

Results of investigation on adsorption of Mn2+ from aqueous solution by manganese oxide-coated hollow polymethylmethacrylate microspheres (MHPM) are reported here. This is the first report on Mn-coated hollow polymer as a substitute for widely used materials like green sand or MN-coated sand. Hollow polymethylmethacrylate (HPM) was prepared by using a literature procedure. Manganese oxide (MnO) was coated on the surface of HPM (MHPM) by using the electroless plating technique. The HPM and MHPM were characterized by using optical microscopy (OM), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). Optical and scanning micrographs were used to monitor the surface properties of the coated layer which revealed the presence of MnO on the surface of HPM. TGA showed the presence of 4-5% of MnO in MHPM. Adsorption isotherm studies were carried out as a function of pH, initial ion concentration, and contact time, to determine the adsorption efficiency for removal of Mn2+ from contaminated water by the synthesized MHPM. The isotherm results showed that the maximum adsorption capacity of MnO-coated HPM to remove manganese contaminants from water is 8.373 mg/g. The obtained R 2 values of Langmuir isotherm and Freundlich isotherm models were 1 and 0.87, respectively. Therefore, R 2 magnitude confirmed that the Langmuir model is best suited for Mn2+ adsorption by a monolayer of MHPM adsorbent. The material developed shows higher adsorption capacity even at a higher concentration of solute ions, which is not usually observed with similar materials of this kind. Overall findings indicate that MHPM is a very potential lightweight adsorbent for removal of Mn2+ from the aqueous solution because of its low density and high surface area.

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