DECOLOURIZATION AND COD REMOVAL OF WASEWATER FROM ETHANOL PRODUCTION PROCESS FROM MOLASSES BY COAGULANTION USING INORGANIC ALUM

2010 ◽  
Vol 13 (3) ◽  
pp. 92-102
Author(s):  
Trung Duc Le

The industrial production of ethanol by fermentation using molasses as main material that generates large quantity of wastewater. This wastewater contains high levels of colour and chemical oxygen demand (COD), that may causes serious environmental pollution. Most available treatment processes in Vietnam rely on biological methods, which often fail to treat waste water up to discharge standard. As always, it was reported that quality of treated wastewater could not meet Vietnameses discharge standard. So, it is necessary to improve the treatment efficiency of whole technological process and therefore, supplemental physico-chemical treatment step before biodegradation stage should be the appropriate choice. This study was carried out to assess the effect of coagulation process on decolourization and COD removal in molasses-based ethanol production wastewater using inorganic coaglutant under laboratory conditions. The experimental results showed that the reductions of COD and colour with the utilization of Al2(SO4)3 at pH 9.5 were 83% and 70%, respectively. Mixture FeSO4 – Al2(SO4)3 at pH 8.5 reduced 82% of colour and 70% of COD. With the addition of Polyacrylamide (PAM), the reduction efficiencies of colour, COD and turbidity by FeSO4 – Al2(SO4)3 were 87%, 73.1% and 94.1% correspondingly. It was indicated that PAM significantly reduced the turbidity of wastewater, however it virtually did not increase the efficiencies of colour and COD reduction. Furthermore, the coagulation processes using PAM usually produces a mount of sludge which is hard to be deposited.

Author(s):  
Vijay A. Juwar ◽  
Ajit P. Rathod

Abstract The present study deals with the treatment of complex waste (WW) treated for removal of chemical oxygen demand (COD) of the food industry by a sono-Fenton process using a batch reactor. The response surface methodology (RSM) was employed to investigate the five independent variables, such as reaction time, the molar ratio of H2O2/Fe2+, volume ratio of H2O2/WW, pH of waste, and ultrasonic density on COD removal. The experimental data was optimized. The optimization yields the conditions: Reaction time of 24 min, HP:Fe molar ratio of 2.8, HP:WW volume ratio of 1.9 ml/L, pH of 3.6 and an ultrasonic density of 1.8 W/L. The predicted value of COD was 91% and the experimental result was 90%. The composite desirability value (D) of the predicted percent of COD removal at the optimized level of variables was close to one (D = 0.991).


Author(s):  
Gilbert K. Gaboutloeloe ◽  
Gugu Molokwe ◽  
Benedict Kayombo

The impact of partially treated wastewater on the water quality of Notwane river stretch in the Gaborone region of Botswana was investigated. Water samples collected at effluent discharge point and three other sampling sites downstream were analyzed for pH, temperature, Biological Oxygen Demand (BOD5), Ammonia-nitrogen (Ammonia-N) and Nitrate-nitrogen (Nitrate-N). Sampling was conducted bi-weekly between February 2013 and April 2013. The ranges of measured parameters were:  pH (7.6-8.5), temperature (22-23ºC), BOD5 (11.2-27.0 mg/l), Ammonia-N (2.4-60.5 mg/l), Nitrate-N (20.6-28.6 mg/l). Analysis of variance, Games-Howel multiple comparisons and Pearson correlation were used to separate variable means. The results signal river non-point pollution due to runoff inflow of organics mainly from land use and domestic waste dumping by nearby dwellings. Temperature, BOD5, and pH range values were all within the Botswana Bureau of Standards (BOBS) limit while the maximum Ammonia-N and Nitrate-N were above BOBS limit by 50.5 mg/l and 6.6 mg/l, respectively. Regulations on indiscriminate waste dumping and discharge standards adherence should be enforced.


2021 ◽  
Author(s):  
Nebojša Đ. Pantelic ◽  
◽  
Jana S. Štrbacki ◽  
Goran Markovic ◽  
Jelena B. Popovic-Đorđevic ◽  
...  

The water samples collected from four localities of the middle course of the Zapadna Morava River during 2020 were analyzed via the selected physico-chemical parameters with the aim to estimate the quality of surface water. According to the results of selected physico-chemical parameters (pH, conductivity, dissolved oxygen, chemical oxygen demand, biochemical oxygen demand), analyzed surface water show a good chemical status, while the values of nutrient content (nitrate, nitrite, ammonium ion, total phosphorus) indicated the poor chemical status especially at the locality 4 probably due to the outflow of wastewater from the city of Čačak as well as from the influence of the polluted water of the Čemernica River.


2012 ◽  
Vol 2 (2) ◽  
pp. 84-91 ◽  
Author(s):  
Isabelli N. Dias ◽  
Ana C. Cerqueira ◽  
Geraldo L. Sant'Anna ◽  
Marcia Dezotti

Oil refinery wastewater was sequentially treated in a moving-bed biofilm reactor (MBBR) and a slow-rate sand filter (SF) in order to obtain an effluent with adequate characteristics for downstream reverse osmosis (RO) operation. Experiments were conducted in bench scale units and the results showed that the MBBR was able to remove 90% chemical oxygen demand (COD), 75% NH4+, 95% phenols, operating with a hydraulic retention time (HRT) of 9 h. Additional removal of COD (15–40%) and ammonia (30–60%) was achieved in the slow-rate SF that was also effective for removing microorganisms. The silt density index (SDI) of the treated wastewater (4.5) was below the maximum limit recommended for RO operation. The quality of the effluent from the combined treatment system (MBBR+SF) was already adequate for cooling tower make-up. The RO produced an effluent with quality compatible with that required for use in boilers.


Water ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 2376 ◽  
Author(s):  
Petr Praus

The quality of raw and treated wastewater was evaluated using the principal component weighted index (PCWI) which was defined as a sum of principal component scores weighted according to their eigenvalues. For this purpose, five principal components (PCs) explaining 88% and 83% of the total variability of raw and treated wastewater samples, respectively, were extracted from 11 original physico-chemical parameters by robust principal component analysis (PCA). The PCWIs of raw and treated wastewater were analyzed in terms of their statistical distributions, temporal changes, mutual correlations, correlations with original parameters, and common water quality indexes (WQI). The PCWI allowed us to monitor temporal wastewater quality by one parameter instead of several. Unlike other weighted indexes, the PCWI is composed of independent variables with minimal information noise and objectively determined weights.


1993 ◽  
Vol 27 (7-8) ◽  
pp. 321-329 ◽  
Author(s):  
B. Fattal ◽  
Y. Puyesky ◽  
G. Eitan ◽  
I. Dor

Wastewater effluent in Israel was sampled in six reservoirs during different seasons. All the reservoirs were tested for biological oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSS), light transmission, temperature, pH, dissolved oxygen (DO), chlorophyll - a, phytoplankton, Zooplankton, as well as microbiological indicators (E.coli. enterococci, heterotrophic bacteria and F+ bacteriophages). The mean reduction of COD, BOD and TSS was 72%, 76% and 45%, respectively and the mean levels at the entrances to the reservoirs were 380 mg/l, 230 mg/l, and 265 mg/l, respectively. The percent reduction of the various microorganisms tested at the entrance to the reservoir and in the reservoir itself ranged between 83.2% and 99.98%. Significant correlation coefficients were found between the concentrations of the various microbiological indicators tested, as well as between the number of indicator microorganisms and pollution parameters (BOD, COD and TSS). A good correlation was found between BOD vs. COD, BOD vs. TSS, and TSS vs. COD. From this preliminary study it may be concluded that a) storage of wastewater in the reservoirs improves the quality of the effluent, and b) changes in physico-chemical parameters and the concentration of enteric microorganisms are significantly correlated.


2016 ◽  
Vol 8 (1) ◽  
pp. 58-65
Author(s):  
Sadhana Pradhanang

The assessment of water quality of Karra River in Hetauda, Nepal was carried out by determining the changes in the concentration levels of eight physico-chemical parameters (pH, Electric conductivity (EC), bicarbonate, dissolved oxygen (DO), silica, chemical oxygen demand (COD), phosphate and nitrate). The samples were collected from upstream, industrial belt and downstream of the Karra River. The Karra River is the dumping ground for industrial effluents of Hetauda industrial district (HID). On analysis, the concentrations of most of the physico-chemicals parameters were found to be above the prescribed limits for industrial wastewater into inland surface waters. Dissolved Oxygen was found to be in the range of 0.49- 8.47 mg/L while COD, nitrate and phosphate were recorded in the range of 8.3-367 mg/L, 0.35- 78.22 mg/L and 0.01-1.64 mg/L, respectively. Concentrations of most of these parameters were within the prescribed limits in the samples collected from upstream and downstream, revealing the river still in good condition at these points indicating less human interference at the head water region and good self-purification capacity at downstream. However the concentrations of the pollutants’ parameters are higher at the sample points just after effluent discharge.Journal of Hydrology and Meteorology, Vol. 8(1) p.58-65


2022 ◽  
Author(s):  
A Rajendran ◽  
C. Mansiya ◽  
M. Shanmuganathan

Abstract Although flood hit the entire part of Chennai, Tamil nadu some three years ago, the quality of water is still found to be worse because of major inundation in these areas. The current inspection deals with the physico-chemical analysis of the ground water samples collected from ten locations in Neelangarai and Triplicane area in Chennai, Tamil Nadu and assessed using Heber Water Quality Index (HWQI) in the post tsunami circumstances. The factors examined were pH, fecal coliform, total dissolved solids (TDS), dissolved oxygen (DO), temperature biochemical oxygen demand (BOD) and turbidity. In addition to these parameters, pointers like electrical conductivity and salinity were also taken into consideration. The over all HWQI outcomes for all the trials in Neelangarai area were determined between 65.02 and 72.25 and Triplicane area was 66.64 - 70.71, which suggest that all the samples are medium to good in quality and could used for human consumption.


2019 ◽  
Vol 34 (01) ◽  
Author(s):  
Vishal Goyal ◽  
M. R. Meena ◽  
Sukhdev Kumar

Vinasse produced by fermentation of molasses has to be paid particular attention due to its potentially huge impacts. The chemical composition of vinasse differs depending upon the soil, sugarcane variety, harvesting method and industrial method of ethanol production. For obvious reasons, as per the Indian Law, there are restrictions on its disposal in water bodies. Detailed and extensive studies and field experiments on soil and crop mostly show that vinasse is excellent manure which not only positively affects the physico-chemical properties of the soil but also helps in increasing the sugarcane yield. But due to some objectionable characteristics (low pH, high biochemical oxygen demand etc.), its judicious use is essential.


2019 ◽  
Vol 4 (4) ◽  
pp. 115-123
Author(s):  
Mona Mohamed Amin Abdel Fatah ◽  
Ghada A. Al Bazedi

The Chemically enhanced process is considered to be a physicochemical technology for domestic wastewater treatment. The objective of this paper is to improve the efficiency of primary treatment processes and reducing the Hazardous Material and cost of the secondary treatment stage either by eliminating a biological treatment, where conditions and standards allow or by reducing the secondary treatment requirements. Analysis of physicochemical parameters as well as the treatment efficiency of aluminum sulfate (alum), ferric chloride (FeCl3), lime (CaO), and seawater was used. The effect of pH and the coagulant dosages were studied as well as mixing and settling time. Conditions were optimized according to the removal efficiencies measured in terms of reduction in the concentration of total suspended solids (TSS), biological oxygen demand (BOD5), and chemical oxygen demand (COD). The optimum COD removal % was achieved at a settling time of 20 minutes, while at pH~6, alum gave a high turbidity % removal of approximately 90% at the dose of 70 mg/l. FeCl3 gave a high turbidity % removal of approximately 95% at the dose of 40 mg/l. Turbidity removal and TSS removal gave a similar pattern at a settling time of 10-20 minutes, where best results were achieved. The results also showed that at pH~4, FeCl3 gave high COD% removal of approximately 90% at the dose of 40 mg/l. By studying the effect of stirrers’ speed (rpm), the results showed that an increase in the mixing intensity, above 80 rpm decreases the removals of COD, Turbidity and TSS when using alum as a coagulant.


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