scholarly journals Types and Micromorphology of Authigenic Carbonates in the Kolyma Yedoma Ice Complex, Northeast Siberia

2021 ◽  
Vol 9 ◽  
Author(s):  
Victor V. Rogov ◽  
Anna N. Kurchatova ◽  
Natalia A. Taratunina
Keyword(s):  
Pore Space ◽  
Component Part ◽  
Initial Reaction ◽  
Mineral Surfaces ◽  
Secondary Phases ◽  
Replica Technique ◽  
Authigenic Carbonates ◽  
Nucleation Sites ◽  
Molecular Compounds ◽  
Ice Complex

The study focuses on authigenic carbonates that are widespread in different deposition environments and are a component part of the terrestrial biogeochemical cycle of carbon. Samples from the Kolyma Yedoma Ice Complex that formed during the Sartan Cryochrone (MIS 2), the coldest period of the Late Pleistocene, in the northeastern Siberian lowlands, have been studied utilizing scanning electron microscopy and energy-dispersive spectroscopy with replica technique. The samples bear signatures of irreversible multistage cryogenic changes in structure and composition, with the formation of authigenic minerals. Authigenic carbonates as secondary phases in the Ice Complex deposits are remarkable by local changes in chemical, physical, and other properties, which induce gradual changes in the lattice and conversion of one mineral species to another. As a result, the sediments may contain stable and metastable minerals. Crystalline species like calcite or aragonite precipitate from aqueous solutions and their presence are restricted to free pore space in segregation ice. Metastable phases may be produced as an initial reaction product between the CO2 and the aqueous phase, while mineral surfaces and small pores act as possible nucleation sites. Organic matter is also an important agent in the cryometamorphism of sediments, including precipitation of authigenic phases due to the freezing of colloids and high-molecular compounds.

scholarly journals Mechanical Properties of New Ni-Mn-Based Braze Alloys for the Fast Epitaxial Braze Repair of Single-Crystalline Ni-Base Superalloys

2011 ◽  
Vol 278 ◽  
pp. 479-484
Author(s):  
Britta Laux ◽  
Joachim Rösler
Keyword(s):  
Base Material ◽  
Repair Process ◽  
Isothermal Solidification ◽  
High Temperature Strength ◽  
Secondary Phases ◽  
Single Crystalline ◽  
Nucleation Sites ◽  
Diffusion Controlled ◽  
Wide Gap ◽  
Stray Grains

Diffusion brazing is a widely-used technology for the repair of cracks in hot section turbine components, mostly fabricated from single-crystalline Ni-based superalloys. Typically, braze alloys with a composition similar to the base material, enhanced by fast diffusing melting point depressants like B are used. If single-crystalline (SX) components are repaired, an epitaxial healing can be achieved, however, the filling of wide cracks in the range of 100-300 μm is difficult, since the process is completely diffusion controlled which means that wide cracks require very long hold times. If the temperature is lowered before a complete isothermal solidification has been awaited, the poor solubility of B in Ni leads to the precipitation of borides, serving as nucleation sites for stray grains. Thus, especially for the repair of wide cracks, new Ni-Mn-based braze alloys were developed which allow a very fast epitaxial healing. As B is replaced by Mn, the repair process can be significantly shortened since the epitaxial solidification is no longer diffusion controlled but can be enforced by cooling. This is due to the fact that Ni and Mn are almost completely miscible which means that the precipitation of secondary phases during solidification is eliminated. The Ni-Mn-based braze alloys were enhanced by Al, Cr and Ti to provide a sufficient high temperature strength and an appropriate oxidation behavior. Furthermore, heat treatment cycles have been developed producing a γ / γ’-microstructure very similar to the base material. In this work, results from mechanical testing of wide-gap samples which were filled with the new braze alloys are presented and discussed.

scholarly journals A novel route for identifying starch diagenetic products in the archaeological record

PLoS ONE ◽  
2021 ◽  
Vol 16 (11) ◽  
pp. e0258779
Author(s):  
Thomas Oldenburg ◽  
Melisa Brown ◽  
Jamie Inwood ◽  
Jagoš Radović ◽  
Ryan Snowdon ◽  
...  
Keyword(s):  
Maillard Reaction ◽  
Chemical Structure ◽  
Maillard Reaction Products ◽  
Ion Cyclotron Resonance ◽  
Mineral Surfaces ◽  
Reaction Products ◽  
Chemical Complexity ◽  
Fticr Ms ◽  
Molecular Compounds ◽  
Amino Acid Glycine

This work introduces a novel analytical chemistry method potentially applicable to the study of archaeological starch residues. The investigation involved the laboratory synthesis of model Maillard reaction mixtures and their analysis through Fourier-Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS). Thus, starch from sixteen plant species were matured while reacting it with the amino acid glycine. The FTICR-MS analysis revealed > 5,300 molecular compounds, with numerous unique heteroatom rich compound classes, ranging from 20 (Zea mays) to 50 (Sorghum bicolor). These classes were investigated as repositories of chemical structure retaining source and process-specific character, linked back to botanical provenance. We discussed the Maillard reaction products thus generated, a possible pathway for the preservation of degraded starch, while also assessing diagenetic recalcitrance and adsorption potential to mineral surfaces. In some cases, hydrothermal experimentation on starches without glycine reveals that the chemical complexity of the starch itself is sufficient to produce some Maillard reaction products. The article concludes that FTICR-MS offers a new analytical window to characterize starchy residue and its diagenetic products, and is able to recognize taxonomic signals with the potential to persist in fossil contexts.

scholarly journals Hydrate—A Mysterious Phase or Just Misunderstood?

Energies ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 880 ◽  
Author(s):  
Bjørn Kvamme ◽  
Jinzhou Zhao ◽  
Na Wei ◽  
Navid Saeidi
Keyword(s):  
Pure Water ◽  
Hydrate Formation ◽  
Free Water ◽  
Mineral Surfaces ◽  
Dual Roles ◽  
Hydrate Reservoir ◽  
Nucleation Sites ◽  
Stability Limits ◽  
Real Stability ◽  
Non Equilibrium

Hydrates that form during transport of hydrocarbons containing free water, or water dissolved in hydrocarbons, are generally not in thermodynamic equilibrium and depend on the concentration of all components in all phases. Temperature and pressure are normally the only variables used in hydrate analysis, even though hydrates will dissolve by contact with pure water and water which is under saturated with hydrate formers. Mineral surfaces (for example rust) play dual roles as hydrate inhibitors and hydrate nucleation sites. What appears to be mysterious, and often random, is actually the effects of hydrate non-equilibrium and competing hydrate formation and dissociation phase transitions. There is a need to move forward towards a more complete non-equilibrium way to approach hydrates in industrial settings. Similar challenges are related to natural gas hydrates in sediments. Hydrates dissociates worldwide due to seawater that leaks into hydrate filled sediments. Many of the global resources of methane hydrate reside in a stationary situation of hydrate dissociation from incoming water and formation of new hydrate from incoming hydrate formers from below. Understanding the dynamic situation of a real hydrate reservoir is critical for understanding the distribution characteristics of hydrates in the sediments. This knowledge is also critical for designing efficient hydrate production strategies. In order to facilitate the needed analysis we propose the use of residual thermodynamics for all phases, including all hydrate phases, so as to be able to analyze real stability limits and needed heat supply for hydrate production.

A Replica Technique for the Inside Surfaces of Small Diameter Pipes and Tubes

1967 ◽  
Vol 25 ◽  
pp. 352-353
Author(s):  
T. G. Gregory
Keyword(s):  
Polyvinyl Chloride ◽  
Small Diameter ◽  
Replica Technique ◽  
Tube Size ◽  
Inside Diameter ◽  
Complete Inspection ◽  
Operating Limits

A nondestructive replica technique permitting complete inspection of bore surfaces having an inside diameter from 0.050 inch to 0.500 inch is described. Replicas are thermally formed on the outside surface of plastic tubing inflated in the bore of the sample being studied. This technique provides a new medium for inspection of bores that are too small or otherwise beyond the operating limits of conventional inspection methods.Bore replicas may be prepared by sliding a length of plastic tubing completely through the bore to be studied as shown in Figure 1. Polyvinyl chloride tubing suitable for this replica process is commercially available in sizes from 0.037- to 0.500-inch diameter. A tube size slightly smaller than the bore to be replicated should be used to facilitate insertion of the plastic replica blank into the bore.

Surface Structure of Nucleated Animal Cells: Carbon Replicas

1967 ◽  
Vol 25 ◽  
pp. 120-121
Author(s):  
Robert M. Glaeser ◽  
Thea B. Scott
Keyword(s):  
Cell Surface ◽  
Surface Structure ◽  
Particle Diameter ◽  
Cellular Functions ◽  
Animal Cells ◽  
Replica Technique ◽  
Carbon Replica ◽  
Characteristic Particle ◽  
Cell Surface Structure ◽  
Carbon Replicas

The carbon-replica technique can be used to obtain information about cell-surface structure that cannot ordinarily be obtained by thin-section techniques. Mammalian erythrocytes have been studied by the replica technique and they appear to be characterized by a pebbly or “plaqued“ surface texture. The characteristic “particle” diameter is about 200 Å to 400 Å. We have now extended our observations on cell-surface structure to chicken and frog erythrocytes, which possess a broad range of cellular functions, and to normal rat lymphocytes and mouse ascites tumor cells, which are capable of cell division. In these experiments fresh cells were washed in Eagle's Minimum Essential Medium Salt Solution (for suspension cultures) and one volume of a 10% cell suspension was added to one volume of 2% OsO4 or 5% gluteraldehyde in 0.067 M phosphate buffer, pH 7.3. Carbon replicas were obtained by a technique similar to that employed by Glaeser et al. Figure 1 shows an electron micrograph of a carbon replica made from a chicken erythrocyte, and Figure 2 shows an enlarged portion of the same cell.

Studies of Circular DNA Using a New Electron Microscopic Technique

1973 ◽  
Vol 31 ◽  
pp. 596-597
Author(s):  
C. N. Gordon
Keyword(s):  
Electron Microscopy ◽  
Aqueous Salt Solution ◽  
Contour Length ◽  
Cleavage Surface ◽  
Mica Substrate ◽  
Electron Microscopic ◽  
Replica Technique ◽  
Circular Dna ◽  
Transmission Electron ◽  
Electron Microscopic Technique

Gordon and Kleinschmidt have described a new preparative technique for visualizing DNA by electron microscopy. This procedure, which is a modification of Hall's “mica substrate technique”, consists of the following steps: (a) K+ ions on the cleavage surface of native mica are exchanged for Al3+ ions by ion exchange. (b) The mica, with Al3+ in the exchange sites on the surface, is placed in a dilute aqueous salt solution of DNA for several minutes; during this period DNA becomes adsorbed on the surface. (c) The mica with adsorbed DNA is removed from the DNA solution, rinsed, dried and visualized for transmission electron microscopy by Hall's platinum pre-shadow replica technique.In previous studies of circular DNA by this technique, most of the molecules seen were either broken to linears or extensively tangled; in general, it was not possible to obtain suitably large samples of open extended molecules for contour length measurements.

Microanalysis of precipitates in a ferritic steel

1978 ◽  
Vol 36 (1) ◽  
pp. 618-619
Author(s):  
J.M. Titchmarsh
Keyword(s):  
Ferritic Steel ◽  
Particle Identification ◽  
Energy Dispersive ◽  
Objective Lens ◽  
Ferritic Steels ◽  
Replica Technique ◽  
X Ray ◽  
Large Numbers ◽  
Scanning Transmission ◽  
Made In

The advances in recent years in the microanalytical capabilities of conventional TEM's fitted with probe forming lenses allow much more detailed investigations to be made of the microstructures of complex alloys, such as ferritic steels, than have been possible previously. In particular, the identification of individual precipitate particles with dimensions of a few tens of nanometers in alloys containing high densities of several chemically and crystallographically different precipitate types is feasible. The aim of the investigation described in this paper was to establish a method which allowed individual particle identification to be made in a few seconds so that large numbers of particles could be examined in a few hours.A Philips EM400 microscope, fitted with the scanning transmission (STEM) objective lens pole-pieces and an EDAX energy dispersive X-ray analyser, was used at 120 kV with a thermal W hairpin filament. The precipitates examined were extracted using a standard C replica technique from specimens of a 2¼Cr-lMo ferritic steel in a quenched and tempered condition.

Scanning Electron Microscope Study of Bacteria on Mineral Surfaces

1976 ◽  
Vol 34 ◽  
pp. 130-131
Author(s):  
V.K. Berry
Keyword(s):  
Oxidation Reaction ◽  
Electron Microscope Study ◽  
Elemental Sulfur ◽  
Thiobacillus Ferrooxidans ◽  
Physical Contact ◽  
Metal Sulfides ◽  
Low Grade ◽  
Mineral Surfaces ◽  
Mineral Surface ◽  
Scanning Electron Microscope Study

There are two strains of bacteria viz. Thiobacillus thiooxidansand Thiobacillus ferrooxidanswidely mentioned to play an important role in the leaching process of low-grade ores. Another strain used in this study is a thermophile and is designated Caldariella .These microorganisms are acidophilic chemosynthetic aerobic autotrophs and are capable of oxidizing many metal sulfides and elemental sulfur to sulfates and Fe2+ to Fe3+. The necessity of physical contact or attachment by bacteria to mineral surfaces during oxidation reaction has not been fairly established so far. Temple and Koehler reported that during oxidation of marcasite T. thiooxidanswere found concentrated on mineral surface. Schaeffer, et al. demonstrated that physical contact or attachment is essential for oxidation of sulfur.

Electron Energy Analysis of Germanium and Silica Layers on Silicon Substrates

1975 ◽  
Vol 33 ◽  
pp. 96-97
Author(s):  
R. W. Ditchfield ◽  
A. G. Cullis
Keyword(s):  
Epitaxial Growth ◽  
Electron Energy ◽  
Silicon Substrates ◽  
Secondary Phases ◽  
Si Substrates ◽  
Transmission Electron ◽  
Layer Structures ◽  
Si Films ◽  
Electron Energy Loss ◽  
Growth Centres

An energy analyzing transmission electron microscope of the Möllenstedt type was used to measure the electron energy loss spectra given by various layer structures to a spatial resolution of 100Å. The technique is an important, method of microanalysis and has been used to identify secondary phases in alloys and impurity particles incorporated into epitaxial Si films.Layers Formed by the Epitaxial Growth of Ge on Si Substrates Following studies of the epitaxial growth of Ge on (111) Si substrates by vacuum evaporation, it was important to investigate the possible mixing of these two elements in the grown layers. These layers consisted of separate growth centres which were often triangular and oriented in the same sense, as shown in Fig. 1.

Three-Dimensional Immunoelectron Microscopy of Yeast Cells by a New High-Resolution Replica Method

1985 ◽  
Vol 43 ◽  
pp. 562-563
Author(s):  
Hirano T. ◽  
M. Yamaguchi ◽  
M. Hayashi ◽  
Y. Sekiguchi ◽  
A. Tanaka
Keyword(s):  
High Resolution ◽  
Plasma Polymerization ◽  
Three Dimensional ◽  
Freeze Fracture ◽  
Replica Method ◽  
Yeast Cells ◽  
Dynamic Aspect ◽  
Replica Technique ◽  
Gaseous Hydrocarbon ◽  
Transmission Electron

A plasma polymerization film replica method is a new high resolution replica technique devised by Tanaka et al. in 1978. It has been developed for investigation of the three dimensional ultrastructure in biological or nonbiological specimens with the transmission electron microscope. This method is based on direct observation of the single-stage replica film, which was obtained by directly coating on the specimen surface. A plasma polymerization film was deposited by gaseous hydrocarbon monomer in a glow discharge.The present study further developed the freeze fracture method by means of a plasma polymerization film produces a three dimensional replica of chemically untreated cells and provides a clear evidence of fine structure of the yeast plasma membrane, especially the dynamic aspect of the structure of invagination (Figure 1).

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