scholarly journals Element Distribution and Migration Behavior in the Copper Slag Reduction and Separation Process

2021 ◽  
Vol 9 ◽  
Author(s):  
Zongliang Zuo ◽  
Yan Feng ◽  
Siyi Luo ◽  
Xinjiang Dong ◽  
Xiaoteng Li ◽  
...  

Copper slag is a solid pollutant with high recyclability. Reduction and separation are regarded as effective disposal methods. However, during the melting process, the separation and migration behavior of elements in the copper slag is complicated. Thus, the formation of pollutants cannot be controlled merely by optimizing the operation parameters. The elemental distribution and migration behavior are discussed in this work. In reduction experiments, the copper slag smelting liquid was divided into three layers: a reduction slag layer, a reactive boundary layer, and an iron ingot layer. Reduction slag and ingot iron were on the top and bottom of the liquid, respectively. Residual carbon oozed at the interface. C can react with reducible “O” atoms, which exist in 2FeO·SiO2, Fe3O4, and CuO. Meanwhile, CO was generated and overflowed from the liquid layer. After reduction by C or CO, metallic iron and copper were produced and migrated to the iron ingot layer. In the liquid, S gradually diffused into the upper layer. Some of the ZnO and CuS spilled from the liquid into the flume. After reduction, CaO·SiO2 was generated and moved to the upper layer.

2021 ◽  
Vol 11 (4) ◽  
pp. 1446
Author(s):  
Jacopo Orsilli ◽  
Anna Galli ◽  
Letizia Bonizzoni ◽  
Michele Caccia

Among the possible variants of X-Ray Fluorescence (XRF), applications exploiting scanning Macro-XRF (MA-XRF) are lately widespread as they allow the visualization of the element distribution maintaining a non-destructive approach. The surface is scanned with a focused or collimated X-ray beam of millimeters or less: analyzing the emitted fluorescence radiation, also elements present below the surface contribute to the elemental distribution image obtained, due to the penetrative nature of X-rays. The importance of this method in the investigation of historical paintings is so obvious—as the elemental distribution obtained can reveal hidden sub-surface layers, including changes made by the artist, or restorations, without any damage to the object—that recently specific international conferences have been held. The present paper summarizes the advantages and limitations of using MA-XRF considering it as an imaging technique, in synergy with other hyperspectral methods, or combining it with spot investigations. The most recent applications in the cultural Heritage field are taken into account, demonstrating how obtained 2D-XRF maps can be of great help in the diagnostic applied on Cultural Heritage materials. Moreover, a pioneering analysis protocol based on the Spectral Angle Mapper (SAM) algorithm is presented, unifying the MA-XRF standard approach with punctual XRF, exploiting information from the mapped area as a database to extend the comprehension to data outside the scanned region, and working independently from the acquisition set-up. Experimental application on some reference pigment layers and a painting by Giotto are presented as validation of the proposed method.


2017 ◽  
Vol 726 ◽  
pp. 316-320 ◽  
Author(s):  
Jie Gao ◽  
You Jun Lu ◽  
Jun Feng Hou ◽  
Zhen Xia Yuan ◽  
Wen Luo ◽  
...  

The Mo powder and Nb powder was used as raw material, the Mo-10Nb alloy target was prepared by different sintering condition (non-pressure sintering and hot pressing sintering). The density, phase composition, microstructure and elemental distribution of Mo-10Nb alloy targets were determined by X-ray diffraction and scanning electron microscopy. The results showed that prepared by hot pressing Mo-10Nb alloy target density of 9.618 g/cm3, grain size 20 ~ 30μm, Mo and Nb element distribution.


2006 ◽  
Vol 73 (23) ◽  
Author(s):  
Yuta Sato ◽  
Takashi Yumura ◽  
Kazu Suenaga ◽  
Koki Urita ◽  
Hiromichi Kataura ◽  
...  

2021 ◽  
Author(s):  
Zhenxing Zhou ◽  
Suxia Guo ◽  
Weiwei Zhou ◽  
Naoyoki Nomura

Abstract It is very challenging to fabricate spherical refractory material powders for additive manufacturing (AM) because of their high melting points and complex compositions. In this study, a novel technique, freeze-dry pulsated orifice ejection method (FD-POEM), was developed to fabricate spherical MoSiBTiC particles without a melting process. Elemental nanopowders were dispersed in water to prepare a high-concentration slurry, which was subsequently extruded from an orifice by diaphragm vibration and frozen instantly in liquid nitrogen. After a freeze-drying process, spherical composite particles with arbitrary composition ratios were obtained. The FD-POEM particles had a narrow size range and uniform elemental distribution. Mesh structures were formed within the FD-POEM particles, which was attributed to the sublimation of ice crystals. Furthermore, owing to their spherical morphology, the FD-POEM particles had a low avalanche angle of 42.6°, exhibiting good flowability. Consequently, the combination of FD-POEM and additive manufacturing has great potential for developing complex refractory components used in industrial applications.


2021 ◽  
Vol 1 (4) ◽  
pp. 20-32
Author(s):  
Anastasia Sokolova ◽  
Olga Kalachikova

The aim of this article is to investigate the connection between behavioral economy and migration processes. Behavioral economics is a relatively new phenomenon in science and the fact that some research in this area has earned the Nobel Prize makes its contribution significant in the consideration of economic processes. The analysis of sources shows that in the field of Russian studies there is practically no mention of the fact that migration behavior can be explained by the behavioral economics theses. In this article, we explore several key ideas in this area: nudge theory, prospect theory, evolutionary game theory, cognitive distortion, and hedonistic adaptation. In this article, we put forward a hypothesis that migration processes can not only be explained from the standpoint of behavioral economics but can also be regulated using the tools of this direction. Behavioral economics can be the key for discovering the dynamics and true motives of migration. The analysis of information in this area shows, that a person makes decisions mainly based not on the laws of logic and rationalism. Paradoxes such as cognitive biases, etc. reduce the effectiveness of an individual's actions and provide an incentive for the scientific community to expand the number of empirical studies of migration processes within the framework of behavioral economics theories.


2022 ◽  
Vol 276 ◽  
pp. 125334
Author(s):  
Z.A.Y. Abdalla ◽  
E.G. Njoroge ◽  
M. Mlambo ◽  
S.V. Motloung ◽  
J.B. Malherbe ◽  
...  

IUBMB Life ◽  
2019 ◽  
Vol 71 (12) ◽  
pp. 1929-1936
Author(s):  
Sadaf Ghanaatgar‐Kasbi ◽  
Forouzan Amerizadeh ◽  
Farzad Rahmani ◽  
Seyed Mahdi Hassanian ◽  
Majid Khazaei ◽  
...  

2019 ◽  
Vol 2019 ◽  
pp. 1-13 ◽  
Author(s):  
Yunlong Ding ◽  
Jialian Shi ◽  
Dongying Ju

In this study, magnesium alloy AZ91, which was cast by double roll casting system, was rolled by a rolling mill. Then, rolled magnesium alloy and magnesium alloy without being rolled were, respectively, welded with aluminum alloy 6061 by diffusion bonding method. Furthermore, annealing process was applied to refine the microstructure and improve mechanical property. The microstructure and elemental distribution of diffusion zone were investigated with a scanning electron microscope (SEM), an electron probe micro analyzer (EPMA), and a transmission electron microscope (TEM). In addition, hardness and tensile strength were measured. When cast magnesium alloy was used, the width of diffusion layers was wider than that with rolled magnesium alloy. And the width increased with the increasing annealing temperatures. Element distribution of specimens with annealing was more uniform than that did not undergo annealing process. Furthermore, tensile strength turns to be strongest after annealing at 250°C. And the strength of the specimens with rolled magnesium alloy was stronger than that with cast magnesium alloy which was not rolled.


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