scholarly journals Corn and Rice Starch-Based Bio-Plastics as Alternative Packaging Materials

Fibers ◽  
2019 ◽  
Vol 7 (4) ◽  
pp. 32 ◽  
Author(s):  
Marichelvam ◽  
Jawaid ◽  
Asim
Keyword(s):  
Citric Acid ◽  
Thermogravimetric Analysis ◽  
Water Absorption ◽  
Tensile Properties ◽  
Water Solubility ◽  
Thermoplastic Starch ◽  
Rice Starch ◽  
Packaging Materials ◽  
Commercial Applications ◽  
Thickness Testing

Due to the negative environmental impacts of synthetic plastics, the development of biodegradable plastics for both industrial and commercial applications is essential today. Researchers have developed various starch-based composites for different applications. The present work investigates the corn and rice starch-based bioplastics for packaging applications. Various samples of bioplastics are produced, with different compositions of corn and rice starch, glycerol, citric acid, and gelatin. The tensile properties were improved after adding rice starch. However, water absorption and water solubility were reduced. On the basis of these results, the best sample was analyzed for thickness testing, biodegradability properties, SEM, hydrophilicity, thermogravimetric analysis, and sealing properties of bioplastic. The results show the suitability of rice and corn-based thermoplastic starch for packaging applications.

Reduced Graphene Oxide/Carboxymethyl Cellulose Nanocomposites: Novel Conductive Films

2019 ◽  
Vol 19 (6) ◽  
pp. 3544-3550 ◽  
Author(s):  
Jutamas Ampaiwong ◽  
Pranee Rattanawaleedirojn ◽  
Kanokwan Saengkiettiyut ◽  
Nadnudda Rodthongkum ◽  
Pranut Potiyaraj ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Graphene Oxide ◽  
Water Absorption ◽  
Tensile Properties ◽  
Reduced Graphene Oxide ◽  
Carboxymethyl Cellulose ◽  
Water Solubility ◽  
Cellulose Film ◽  
Cellulose Films ◽  
Reduced Graphene

Herein, carboxymethyl cellulose nanocomposite films incorporated with graphene oxide and reduced graphene oxide were successfully prepared by a novel approach for the first time, and their alternative properties compared with the original carboxymethyl cellulose films were disclosed. For carboxymethyl cellulose/reduced graphene oxide film preparation, sodium borohydride was used as a chemical reducing agent. The carboxymethyl cellulose films were prepared by using a solvent casting method, followed by an acid treatment to decrease the water solubility (98%) while enhancing the tensile strength (15%) and elastic modulus (32%) of the original carboxymethyl cellulose films. Overall, the addition of 1.0 wt% graphene oxide and reduced graphene oxide to the treated films increased the water solubility, water absorption, tensile properties and electrical conductivity. Particularly, the electrical conductivity was predominantly enhanced 1.3×105 times with graphene oxide and 2.2×105 times with reduced graphene oxide compared to the treated carboxymethyl cellulose film. The electrical conductivity of the treated carboxymethyl cellulose film also increased with an increase in reduced graphene oxide. The effects of reduced graphene oxide on the water solubility, water absorption, tensile properties and electrical conductivity of the treated carboxymethyl cellulose film were more pronounced than those of graphene oxide, especially for the electrical conductivity. In conclusion, graphene oxide and reduced graphene oxide might be alternative nanofillers for improving the carboxymethyl cellulose film properties. For the future applications, carboxymethyl cellulose/reduced graphene oxide films prepared by using this approach might be employed as alternative materials in electronic packagings and electrochemical biosensors.

Effect of Rice Flour Types on the Properties of Nonwoven Pineapple Leaf Fiber and Thermoplastic Rice Starch Composites

2021 ◽  
Vol 904 ◽  
pp. 221-225
Author(s):  
Thapanee Wongpreedee ◽  
Nanthaya Kengkhetkit
Keyword(s):  
Tensile Properties ◽  
Rice Flour ◽  
Thermoplastic Starch ◽  
Rice Starch ◽  
Slight Improvement ◽  
Pineapple Leaf Fiber ◽  
Glutinous Rice ◽  
Reinforcing Agent ◽  
Sem Micrograph ◽  
Rice Flours

Thermoplastic starches and a nonwoven pineapple leaf sheet (NPALF) were prepared. Two types of flours were used to prepare thermoplastic starches (TPSs) which were Rice flour thermoplastic starch (RTPS) and Glutinous rice flour thermoplastic starch (GTPS). Two layers of thermoplastic starches and NPALF layer were sandwiched and pressed by a hot pressing machine at 150°C with 1500 psi for 15 min. All composites were investigated their densities and tensile properties. The density of all composite types had a lower density than each neat TPSs and types of rice flours did not affect their densities. The tensile property results confirmed NPALF could be used as a reinforcing agent both in GTPS and RTPS composites but their tensile improvement effectiveness in both systems are different. NPALF composite with RTPS did not affect the tensile strength but provided a slight improvement in modulus. Remarkably, NPALF composite using GTPS explored the great improvement performance both in strength and modulus which were increased up to 174% and 308% comparing with neat GTPS. SEM micrograph evidence clearly showed good wetting between GTPS and the reinforcement layer in the composite. This is resulting in the NPALF-GTPS composite showed a strong improvement in tensile properties.

scholarly journals Functionalization of Enzymatically Treated Apple Pomace from Juice Production by Extrusion Processing

Foods ◽  
2021 ◽  
Vol 10 (3) ◽  
pp. 485
Author(s):  
Vera Schmid ◽  
Antje Trabert ◽  
Judith (Schäfer) Keller ◽  
Mirko Bunzel ◽  
Heike P. Karbstein ◽  
...  
Keyword(s):  
Water Absorption ◽  
Dietary Fiber ◽  
Water Solubility ◽  
Apple Pomace ◽  
Raw Material ◽  
Food Ingredients ◽  
Insoluble Dietary Fiber ◽  
Extrusion Processing ◽  
The Impact ◽  
Treated Apple

Food by-products can be used as natural and sustainable food ingredients. However, a modification is needed to improve the technofunctional properties according to the specific needs of designated applications. A lab-scale twin-screw extruder was used to process enzymatically treated apple pomace from commercial fruit juice production. To vary the range of the thermomechanical treatment, various screw speeds (200, 600, 1000 min−1), and screw configurations were applied to the raw material. Detailed chemical and functional analyses were performed to develop a comprehensive understanding of the impact of the extrusion processing on apple pomace composition and technofunctional properties as well as structures of individual polymers. Extrusion at moderate thermomechanical conditions increased the water absorption, swelling, and viscosity of the material. An increase in thermomechanical stress resulted in a higher water solubility index, but negatively affected the water absorption index, viscosity, and swelling. Scanning electron microscopy showed an extrusion-processing-related disruption of the cell wall. Dietary fiber analysis revealed an increase of soluble dietary fiber from 12.6 to 17.2 g/100 g dry matter at maximum thermo-mechanical treatment. Dietary fiber polysaccharide analysis demonstrated compositional changes, mainly in the insoluble dietary fiber fraction. In short, pectin polysaccharides seem to be susceptible to thermo-mechanical stress, especially arabinans as neutral side chains of rhamnogalacturonan I.

scholarly journals Lignin-Containing Coatings for Packaging Materials—Pilot Trials

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1595
Author(s):  
Asif Javed ◽  
Peter Rättö ◽  
Lars Järnström ◽  
Henrik Ullsten
Keyword(s):  
High Speed ◽  
Water Solubility ◽  
Transmission Rate ◽  
Kraft Lignin ◽  
Packaging Materials ◽  
Water Contact ◽  
Pilot Trials ◽  
Significant Difference ◽  
Ph Level ◽  
Ammonium Zirconium Carbonate

One severe weakness of most biopolymers, in terms of their use as packaging materials, is their relatively high solubility in water. The addition of kraft lignin to starch coating formulations has been shown to reduce the water solubility of starch in dry coatings. However, lignin may also migrate into aqueous solutions. For this paper, kraft lignin isolated using the LignoBoost process was used in order to examine the effect of pH level on the solubility of lignin with and without ammonium zirconium carbonate (AZC). Machine-glazed (MG) paper was coated in a pilot coating machine, with the moving substrate at high speed, and laboratory-coated samples were used as a reference when measuring defects (number of pinholes). Kraft lignin became soluble in water at lower pH levels when starch was added to the solution, due to the interactions between starch and lignin. This made it possible to lower the pH of the coating solutions, resulting in increased water stability of the dry samples; that is, the migration of lignin to the model liquids decreased when the pH of the coating solutions was reduced. No significant difference was observed in the water vapor transmission rate (WVTR) between high and low pH for the pilot-coated samples. The addition of AZC to the formulation reduced the migration of lignin from the coatings to the model liquids and led to an increase in the water contact angle, but also increased the number of pinholes in the pilot-coated samples.

scholarly journals Ecofriendly Preparation and Characterization of a Cassava Starch/Polybutylene Adipate Terephthalate Film

Processes ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 329
Author(s):  
Tan Yi ◽  
Minghui Qi ◽  
Qi Mo ◽  
Lijie Huang ◽  
Hanyu Zhao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Contact Angle ◽  
Water Vapor ◽  
Composite Film ◽  
Water Absorption ◽  
Composite Films ◽  
Thermoplastic Starch ◽  
Light Transmittance ◽  
Infrared Spectrometry ◽  
Nano Zno

Composite films of polybutylene adipate terephthalate (PBAT) were prepared by adding thermoplastic starch (TPS) (TPS/PBAT) and nano-zinc oxide (nano-ZnO) (TPS/PBAT/nano-ZnO). The changes of surface morphology, thermal properties, crystal types and functional groups of starch during plasticization were analyzed by scanning electron microscopy, synchronous thermal analysis, X-ray diffraction, infrared spectrometry, mechanical property tests, and contact Angle and transmittance tests. The relationship between the addition of TPS and the tensile strength, transmittance, contact angle, water absorption, and water vapor barrier of the composite film, and the influence of nano-ZnO on the mechanical properties and contact angle of the 10% TPS/PBAT composite film. Experimental results show that, after plasticizing, the crystalline form of starch changed from A-type to V-type, the functional group changed and the lipophilicity increased; the increase of TPS content, the light transmittance and mechanical properties of the composite membrane decreased, while the water vapor transmittance and water absorption increased. The mechanical properties of the composite can be significantly improved by adding nano-ZnO at a lower concentration (optimum content is 1 wt%).

scholarly journals Investigation of an Electrostatic Discharge Protective Biodegradable Packaging Foam in the Logistic Chain

2014 ◽  
Vol 5 (1) ◽  
pp. 25-33 ◽  
Author(s):  
Ákos Mojzes ◽  
Barnabás Tóth ◽  
Péter Csavajda
Keyword(s):  
Electrostatic Discharge ◽  
Technological Development ◽  
Environmental Parameters ◽  
Thermoplastic Starch ◽  
Vital Role ◽  
Packaging Materials ◽  
Negative Effects ◽  
Packaging System ◽  
Product Packaging ◽  
The One

Abstract Since the beginning of the 20th century, logistics has undergone a huge technological development, which has, however, resulted in many negative effects as well. The industry, particularly in the packaging industry has been a massive waste producer, although recently it has forced the use of new materials and it started to focus on environmentally friendly technologies. During the transportation of finished and semi-finished Electrostatic Discharge (ESD) sensitive products, the product packaging system has a vital role. These kind of packaging materials must be suitable to both logistic (protection against mechanical and environmental stresses) and special ESD protection requirements. During the transportation of printed-circuit electronic products, ESD defense is then of primary significance. However there is a huge disadvantage for the use of various shield bags. Namely, this kind of associated packaging is particularly pollutant, it causes a lot of inconvenience in the form of waste. In order to rule out these materials from the packaging system, new innovative solutions have to be found. The investigated TPS (thermoplastic starch biodegradable foam) is subjected to a validation, a long process to certify that this material unites properties of two types of packaging materials at the same time. On the one hand, this packaging foam has to meet the requirements product defense. On the other hand, the material must be anti-static under the logistic stress effects. In case it is found suitable, it can be an alternative of the conventional materials. In this article, we investigate the ESD characteristic of TPS foam. As this material sensitive for environmental parameters during transportation, we make the relevant Surface Resistance (Rs) tests on different temperature and humidity conditions. Based on result, the decision of the application can be done, as an ESD packaging material.

scholarly journals Effect of Different Extrusion Processing Parameters on Physical Properties of Soy White Flakes and High Protein Distillers Dried Grains-Based Extruded Aquafeeds

2014 ◽  
Vol 3 (6) ◽  
pp. 107 ◽  
Author(s):  
Sushil K. Singh ◽  
K. Muthukumarappan
Keyword(s):  
Physical Properties ◽  
Water Absorption ◽  
Bulk Density ◽  
Water Solubility ◽  
Expansion Ratio ◽  
High Protein ◽  
Regression Equations ◽  
Process Variables ◽  
Distillers Dried Grains ◽  
Durability Index

<p>Nutritionally balanced ingredient blends for catla (<em>Catla catla</em>), belonging to the family Cyprinidae, were extruded using single screw extruder. The extrusion was carried out at five levels of soy white flakes content (21%, 29%, 40%, 52%, and 59% db), five levels of moisture content (15, 19, 25, 31, and 35% db) and five levels of barrel temperature (100, 110, 125, 140, and 150 ºC) using three different die nozzles (having L/D ratios 3.33, 5.83, and 7.25). Blends with net protein content of 32.5% contains soy white flakes, along with high protein distillers dried grains (HP-DDG), corn flour, corn gluten meal, fish meal, vitamin, and mineral mix. A central composite rotatable design (CCRD) and  response surface methodology (RSM) was used to investigate the significance of independent and interaction effects of the extrusion process variables on the extrudates physical properties namely pellet durability index, bulk density, water absorption and solubility indices and expansion ratio. Quadratic polynomial regression equations were developed to correlate the product responses and process variables as well as to obtain the response surfaces plots. The independent variables had significant (<em>P </em>&lt; 0.05) effects on physical properties of extrudates: (i) higher soy white flakes content increased the pellet durability index and water absorption index, but decreased the water solubility index, (ii) higher temperature decreased pellet durability index, bulk density and water solubility index, (iii) increased L/D ratio from 3.33 to 7.25 increased the pellet durability index, expansion ratio but decreased the bulk density of the extrudates.</p>

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