New Activated Carbon from Mine Coal for Adsorption of Dye in Simulated Water or Multiple Heavy Metals in Real Wastewater

Nano-activated carbon (NAC) prepared from El-Maghara mine coal were modified with nitric acid solution. Their physico-chemical properties were investigated in terms of methylene blue (MB) adsorption, FTIR, and metal adsorption. Upon oxidation of the ACS with nitric acid, surface oxide groups were observed in the FTIR spectra by absorption peaks at 1750–1250 cm−1. The optimum processes parameters include HNO3/AC ratio (wt./wt.) of 20, oxidation time of 2 h, and the concentration of HNO3 of 10% reaching the maximum adsorption capacity of MB dye. Also, the prepared NAC was characterized by SEM, EDX, TEM, Raman Spectroscopy, and BET analyses. The batch adsorption of MB dye from solution was used for monitoring the behavior of the most proper produced NAC. Equilibrium isotherms of MB dye adsorption on NAC materials were acquired and the results discussed in relation to their surface chemistry. Langmuir model recorded the best interpretation of the dye adsorption data. Also, NAC was evaluated for simultaneous adsorption of six different metal ions (Fe2+, Ni2+, Mn2+, Pb2+, Cu2+, and Zn2+) that represented contaminates in petrochemical industrial wastewater. The results indicated that the extracted NAC from El-Maghara mine coal is considered as an efficient low-cost adsorbent material for remediation in both basic dyes and metal ions from the polluted solutions.

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Application of treated eggplant peel as a low-cost adsorbent for water treatment toward elimination of Pb2+: Kinetic modeling and isotherm study

Adsorption Science & Technology ◽

10.1177/0263617417753784 ◽

2018 ◽

Vol 36 (3-4) ◽

pp. 1112-1143 ◽

Cited By ~ 11

Author(s):

Mohammad Hossein Karimi Darvanjooghi ◽

Seyyed Mohammadreza Davoodi ◽

Arzu Y Dursun ◽

Mohammad Reza Ehsani ◽

Iman Karimpour ◽

...

Keyword(s):

Contact Time ◽

Low Cost ◽

Standard Free Energy ◽

Chemical Properties ◽

Entropy Change ◽

Batch Adsorption ◽

Maximum Adsorption Capacity ◽

Standard Entropy ◽

Adsorption Parameters ◽

Adsorbent Dose

In this study, treated eggplant peel was used as an adsorbent to remove Pb2+ from aqueous solution. For this purpose batch adsorption experiments were performed for investigating the effect of contact time, pH, adsorbent dose, solute concentrations, and temperature. In order to assess adsorbent’s physical and chemical properties, Fourier transform infrared spectroscopy, scanning electron microscopy, and energy dispersive X-ray spectroscopy were used. The results showed that the adsorption parameters for reaching maximum removal were found to be contact time of 110 min, adsorbent dose of 0.01 g/ml, initial lead(II) concentration of 70 ppm, pH of 4, and temperature of 25°C. Moreover, for the experiments carried out at pH > 4 the removal occurred by means of significant precipitation as well as adsorption. Furthermore, these results indicated that the adsorption followed pseudo-second-order kinetics model implying that during the adsorption process strong bond between lead(II) and chemical functional groups of adsorbent surface took place. The process was described by Langmuir model (R2 = 0.99; maximum adsorption capacity 88.33 mg/g). Also thermodynamics of adsorption was studied at various temperatures and the thermodynamic parameters including equilibrium constant (K), standard enthalpy change, standard entropy change, and standard free energy changes were obtained from experimental data.

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Characterization of the Corallina Elongata Alga and Study of its Biosorption Properties for Methylene Blue

Journal of the chemical society of pakistan ◽

10.52568/000712/jcsp/41.01.2019 ◽

2019 ◽

Vol 41 (1) ◽

pp. 62-62

Author(s):

Farida Bouremmad Farida Bouremmad ◽

Abdennour Bouchair Abdennour Bouchair ◽

Sorour Semsari Parapari Sorour Semsari Parapari ◽

Shalima Shawuti and Mehmet Ali Gulgun Shalima Shawuti and Mehmet Ali Gulgun

Keyword(s):

Methylene Blue ◽

Activated Carbon ◽

Adsorption Capacity ◽

Low Cost ◽

Mediterranean Coast ◽

Batch Adsorption ◽

Maximum Adsorption Capacity ◽

Aquatic Biomass ◽

Equilibrium Data

Biosorbents can be an alternative to activated carbon. They are derived from agricultural by-products or aquatic biomass. They are low cost and they may have comparable performances to those of activated carbon. The present study focuses on the characterization of the Corallina Elongata (CE) alga and its adsorption performance for Methylene Blue (MB), this alga is found in abundance at the Mediterranean coast of the city of Jijel in eastern Algeria. The dried alga was characterized using various characterization techniques such as DTA, TG, FTIR, XRD, SEM and EDX, which showed that the material consists essentially of a calcite containing magnesium. Batch adsorption studies were carried out and the effect of experimental parameters Such as pH, initial dye concentration, temperature, adsorbent dose and contact time, on the adsorption of MB was studied. The kinetic experimental data were found to conform to the pseudo-second-order model with good correlation and equilibrium data were best fitted to The Langmuir model, with a maximum adsorption capacity of 34.4 mg/g. The adsorption isotherms at various temperatures allowed the determination of certain thermodynamic parameters (ΔG, ΔH and ΔS). Finally, the adsorption results showed a good affinity between CE and MB with a high adsorption capacity.

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Comparison of sulfamethoxazole adsorption by activated carbon and biochar in seawater

E3S Web of Conferences ◽

10.1051/e3sconf/202125102065 ◽

2021 ◽

Vol 251 ◽

pp. 02065

Author(s):

Wei Meng ◽

Mengying Shao ◽

Mei Shi

Keyword(s):

Activated Carbon ◽

Emerging Contaminants ◽

Removal Rate ◽

Low Cost ◽

Marine Ecosystem ◽

Batch Adsorption ◽

Maximum Adsorption Capacity ◽

Adsorption Characteristics ◽

Theoretical Support ◽

Coconut Shell Activated Carbon

Antibiotics, a type of emerging contaminants in marine environment, have posed serious threats to human health and ecological function. Biochar has been widely used in the remediation of multiple pollutants due to low cost and good adsorption characteristics. However, the adsorption characteristics of biochar for antibiotics in seawater are still unclear. Therefore, a coconut shell activated carbon (AC) and a sludge biochar produced at 700 °C (SB700) were selected to carry out batch adsorption experiments of sulfamethoxazole (SMX) under different adsorbent dosage and different initial concentration of SMX. These results showed that the maximum removal rate (R) of AC and SB700 was 99.9% and 97.9%, the maximum adsorption capacity (Qe) was 13.7 mg g-1 and 1.6 mg g-1, and the maximum adsorption coefficient (Kd) was 2142 L g-1 and 5.1 L g-1, respectively. Compared with SB700, AC showed the excellent performance in SMX adsorption. This study provided theoretical support and experimental basis for the development of highly efficient antibiotic adsorbents in marine ecosystem.

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Porous Activated Carbon from Lignocellulosic Agricultural Waste for the Removal of Acetampirid Pesticide from Aqueous Solutions

Molecules ◽

10.3390/molecules25102339 ◽

2020 ◽

Vol 25 (10) ◽

pp. 2339 ◽

Cited By ~ 1

Author(s):

Somaia G. Mohammad ◽

Sahar M. Ahmed ◽

Abd El-Galil E. Amr ◽

Ayman H. Kamel

Keyword(s):

Activated Carbon ◽

Aqueous Solutions ◽

Adsorption Process ◽

Low Cost ◽

Agricultural Waste ◽

Batch Adsorption ◽

Maximum Adsorption Capacity ◽

Equilibration Time ◽

Freundlich Isotherms ◽

Before And After

A facile eco-friendly approach for acetampirid pesticide removal is presented. The method is based on the use of micro- and mesoporous activated carbon (TPAC) as a natural adsorbent. TPAC was synthesized via chemical treatment of tangerine peels with phosphoric acid. The prepared activated carbon was characterized before and after the adsorption process using Fourier- transform infrared (FTIR), X-ray diffraction (XRD), particle size and surface area. The effects of various parameters on the adsorption of acetampirid including adsorbent dose (0.02–0.2 g), pH 2–8, initial adsorbate concentration (10–100 mg/L), contact time (10–300 min) and temperature (25–50 °C) were studied. Batch adsorption features were evaluated using Langmuir and Freundlich isotherms. The adsorption process followed the Langmuir isotherm model with a maximum adsorption capacity of 35.7 mg/g and an equilibration time within 240 min. The adsorption kinetics of acetamiprid was fitted to the pseudo-second-order kinetics model. From the thermodynamics perspective, the adsorption was found to be exothermic and spontaneous in nature. TPAC was successfully regenerated and reused for three consecutive cycles. The results of the presented study show that TPAC may be used as an effective eco-friendly, low cost and highly efficient adsorbent for the removal of acetamiprid pesticides from aqueous solutions.

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Parameters Affecting Dye Adsorption - Using Graphene Coated Sand (GSC)

International Journal of Science and Engineering Invention ◽

10.23958/ijsei/vol04-i02/01 ◽

2018 ◽

Vol 4 (02) ◽

Author(s):

Seroor Atalah Khaleefa Alia ◽

Dr. Mohammed Ibrahimb ◽

Hussein Ali Hussein

Keyword(s):

Heavy Metals ◽

Contact Time ◽

Organic Dyes ◽

Low Cost ◽

Dye Adsorption ◽

Contaminated Water ◽

Maximum Adsorption Capacity ◽

Engineering Designs ◽

Heavy Metals Ions ◽

Coated Sand

Adsorption is most commonly applied process for the removal of pollutants such as dyes and heavy metals ions from wastewater. The present work talks about preparing graphenic material attached sand grains called graphene sand composite (GSC) by using ordinary sugar as a carbon source. Physical morphology and chemical composition of GSC was examined by using (FTIR, SEM, EDAX and XRD). Efficiency of GSC in the adsorption of organic dyes from water was investigated using reactive green dye with different parameters such as (ph, temperature, contact time and dose). Adsorption isotherm was also studied and the results showed that the maximum adsorption capacity of dye is 28.98 mg/g. This fast, low-cost process can be used to manufacture commercial filters to treat contaminated water using appropriate engineering designs.

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Kinetics and isotherm modeling of Pb(II) and Cd(II) sequestration from polluted water onto tropical ultisol obtained from Enugu Nigeria

Applied Water Science ◽

10.1007/s13201-021-01402-8 ◽

2021 ◽

Vol 11 (4) ◽

Author(s):

Theresa C. Umeh ◽

John K. Nduka ◽

Kovo G. Akpomie

Keyword(s):

Metal Ions ◽

Low Cost ◽

Water Environment ◽

Standard Technique ◽

Soil Surface ◽

Cost Effective ◽

Polluted Water ◽

Batch Adsorption ◽

Lead And Cadmium ◽

Pseudo Second Order

AbstractDeterioration in soil–water environment severely contributed by heavy metal bioavailability and mobility on soil surface and sub-surface due to irrational increase in wastewater discharge and agrochemical activities. Therefore, the feasibility of adsorption characteristics of the soil is paramount in curbing the problem of micropollutant contamination in the farming vicinity. Soil from a farming site in a populated area in Enugu, Nigeria was collected and tested to measure the lead and cadmium contents using atomic absorption spectrophotometer (AAS). The adsorption potency of the ultisol soil was estimated for identifiable physicochemical properties by standard technique. The mean activity concentration of Pb2+ and Cd2+ was 15.68 mg/kg and 3.01 mg/kg. The pH, temperature, metal concentration and contact time adsorptive effect on the Pb2+ and Cd2+ uptake was evaluated by batch adsorption technique. The Langmuir, Freundlich and Temkin models were fitted into equilibrium adsorption data and the calculated results depict a better and satisfactory correlation for Langmuir with higher linear regression coefficients (Pb2+, 0.935 and Cd2+, 0.971). On the basis of sorption capacity mechanism of the soil, pseudo-second-order model best described the kinetics of both metal ions retention process. The results of the present study indicated that the soil being a low cost-effective adsorbent can be utilized to minimize the environmental risk impact of these metal ions.

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Removal of Chromium(III) and Cadmium(II) Heavy Metal Ions from Aqueous Solutions Using Treated Date Seeds: An Eco-Friendly Method

Molecules ◽

10.3390/molecules26123718 ◽

2021 ◽

Vol 26 (12) ◽

pp. 3718

Author(s):

Mohammad Azam ◽

Saikh Mohammad Wabaidur ◽

Mohammad Rizwan Khan ◽

Saud I. Al-Resayes ◽

Mohammad Shahidul Islam

Keyword(s):

Metal Ions ◽

Adsorption Capacity ◽

Low Cost ◽

Maximum Adsorption Capacity ◽

Solution Ph ◽

Surface Analysis Techniques ◽

Adsorption Processes ◽

Ft Ir ◽

Metal Elution ◽

Date Pits

The aim of the research was to prepare low-cost adsorbents, including raw date pits and chemically treated date pits, and to apply these materials to investigate the adsorption behavior of Cr(III) and Cd(II) ions from wastewater. The prepared materials were characterized using SEM, FT-IR and BET surface analysis techniques for investigating the surface morphology, particle size, pore size and surface functionalities of the materials. A series of adsorption processes was conducted in a batch system and optimized by investigating various parameters such as solution pH, contact time, initial metal concentrations and adsorbent dosage. The optimum pH for achieving maximum adsorption capacity was found to be approximately 7.8. The determination of metal ions was conducted using atomic adsorption spectrometry. The experimental results were fitted using isotherm Langmuir and Freundlich equations, and maximum monolayer adsorption capacities for Cr(III) and Cd(II) at 323 K were 1428.5 and 1302.0 mg/g (treated majdool date pits adsorbent) and 1228.5 and 1182.0 mg/g (treated sagai date pits adsorbent), respectively. It was found that the adsorption capacity of H2O2-treated date pits was higher than that of untreated DP. Recovery studies showed maximal metal elution with 0.1 M HCl for all the adsorbents. An 83.3–88.2% and 81.8–86.8% drop in Cr(III) and Cd(II) adsorption, respectively, were found after the five regeneration cycles. The results showed that the Langmuir model gave slightly better results than the Freundlich model for the untreated and treated date pits. Hence, the results demonstrated that the prepared materials could be a low-cost and eco-friendly choice for the remediation of Cr(III) and Cd(II) contaminants from an aqueous solution.

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Removal of Ni (II) from Aqueous Solution by Adsorption onto Activated Carbon Prepared from Lapsi (Choerospondias axillaris) Seed Stone

Journal of the Institute of Engineering ◽

10.3126/jie.v9i1.10680 ◽

2014 ◽

Vol 9 (1) ◽

pp. 166-174 ◽

Cited By ~ 9

Author(s):

Rajeshwar M. Shrestha ◽

Margit Varga ◽

Imre Varga ◽

Amar P. Yadav ◽

Bhadra P. Pokharel ◽

...

Keyword(s):

Aqueous Solution ◽

Activated Carbon ◽

Activated Carbons ◽

Low Cost ◽

Chemical Characterization ◽

Maximum Adsorption Capacity ◽

Adsorption Data ◽

Optimum Ph ◽

Nickel Adsorption

Activated carbons were prepared from Lapsi seed stone by the treatment with H2SO4 and HNO3 for the removal of Ni (II) ions from aqueous solution. Two activated carbon have been prepared from Lapsi seed stones by treating with conc.H2SO4 and a mixture of H2SO4 and HNO3 in the ratio of 1:1 by weight for removal of Ni(II) ions. Chemical characterization of the resultant activated carbons was studied by Fourier Transform Infrared Spectroscopy and Boehm titration which revealed the presence of oxygen containing surface functional groups like carboxyl, lactones and phenols in the carbons. The optimum pH for nickel adsorption is found to be 5. The adsorption data were better fitted with the Langmuir equations than Freundlich adsorption equation to describe the equilibrium isotherms. The maximum adsorption capacity of Ni (II) on the resultant activated carbons was 28.25.8 mg g-1 with H2SO4 and 69.49 mg g-1 with a mixture of H2SO4 and HNO3. The waste material used in the preparation of the activated carbons is inexpensive and readily available. Hence the carbons prepared from Lapsi seed stones can act as potential low cost adsorbents for the removal of Ni (II) from water. DOI: http://dx.doi.org/10.3126/jie.v9i1.10680Journal of the Institute of Engineering, Vol. 9, No. 1, pp. 166–174

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Batch Sorption Experiments: Langmuir and Freundlich Isotherm Studies for the Adsorption of Textile Metal Ions onto Teff Straw (Eragrostis tef) Agricultural Waste

Journal of Thermodynamics ◽

10.1155/2013/375830 ◽

2013 ◽

Vol 2013 ◽

pp. 1-6 ◽

Cited By ~ 147

Author(s):

Mulu Berhe Desta

Keyword(s):

Heavy Metals ◽

Metal Ions ◽

Contact Time ◽

Metal Ion ◽

Low Cost ◽

Agricultural Waste ◽

Equilibrium Concentration ◽

Eragrostis Tef ◽

Batch Adsorption ◽

Textile Effluents

Adsorption of heavy metals (Cr, Cd, Pb, Ni, and Cu) onto Activated Teff Straw (ATS) has been studied using batch-adsorption techniques. This study was carried out to examine the adsorption capacity of the low-cost adsorbent ATS for the removal of heavy metals from textile effluents. The influence of contact time, pH, Temperature, and adsorbent dose on the adsorption process was also studied. Results revealed that adsorption rate initially increased rapidly, and the optimal removal efficiency was reached within about 1 hour. Further increase in contact time did not show significant change in equilibrium concentration; that is, the adsorption phase reached equilibrium. The adsorption isotherms could be fitted well by the Langmuir model. The value in the present investigation was less than one, indicating that the adsorption of the metal ion onto ATS is favorable. After treatment with ATS the levels of heavy metals were observed to decrease by 88% (Ni), 82.9% (Cd), 81.5% (Cu), 74.5% (Cr), and 68.9% (Pb). Results indicate that the freely abundant, locally available, low-cost adsorbent, Teff straw can be treated as economically viable for the removal of metal ions from textile effluents.

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