scholarly journals Composite Binder Containing Industrial By-Products (FCCCw and PSw) and Nano SiO2

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1604
Author(s):  
Vilma Banevičienė ◽  
Jurgita Malaiškienė ◽  
Jiri Zach ◽  
Karel Dvorak

This article analyzes the integrated effect of industrial by-products (spent fluidized bed catalytic cracking catalyst waste (FCCCw) and paper sludge waste (PSw) generated in paper manufacturing) combined with nano-SiO2 (NS) on the properties of cement binder, when a certain part of the binder is replaced with the said by-products in the cement mix. Standard testing methods were used to analyze the physical and mechanical properties of cement-based materials. For structure analysis, we used X-ray diffraction (XRD), derivative thermogravimetry (DTG), mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM). It was found that the replacement of cement by a combined additive of FCCCw, PSw and NS is important not only for ecological reasons (abatement of CO2 emissions and recovery of waste through secondary raw materials), but also in order to enhance the properties of cement-based binders. Presumably, higher amounts of calcium silicate hydrate (CSH) and calcium alumina silicate hydrate (CASH) in the compound binder are the result of the low content of portlandite and alite in the test specimens. The specimens modified with all three additives had the highest density (~2100 kg/m3), ultrasonic pulse velocity (UPV) (~4160 m/s) and compressive strength (~105 MPa), which was ~40% higher than in the control specimens. The average pore diameter of the complex binder decreased by 21%, whereas the median pore diameter decreased by 47%.

2021 ◽  
Vol 54 (4) ◽  
Author(s):  
Francesca Autiero ◽  
Meera Ramesh ◽  
Miguel Azenha ◽  
Marco Di Ludovico ◽  
Andrea Prota ◽  
...  

AbstractThe study aims at defining and characterizing a specific restoration mortar for archaeological masonry structures made with traditional materials and to assess the suitability of the mixture compared to other mortars; such a goal is crucial to develop and define interventions in the archaeological sites. The mixture was defined to ensure compatibility with ancient materials and following frequently adopted recommendations at the site, specifically by using: (1) raw materials as similar as possible to the ancient ones; (2) traditional mix design. Therefore, the mixture was made with commercial lime putty CL 90-S type and natural Phlegrean pozzolan, i.e. volcanoclastic material collected from the volcanic area located in the West of Naples in Italy. The precious and limitedly available natural pozzolan used in the experiments resulted in an exclusive mortar which is very similar to the archaeological ones. The mortar has a binder to aggregate ratio 1:3 by volume, according to traditional techniques typically encountered in the ancient Roman city of Pompeii and Vesuvius surrounding area. The evolution of the flexural and compressive strength, elastic modulus, bulk density, open porosity and ultrasonic pulse velocity has been monitored for up to 200 days, based on standard procedures. Moreover, the hardening process was monitored with Differential Thermal Analysis up to 90 days, through the evaluation of phase transitions associated with dehydroxylation and decarboxylation, considering different depths from the external surface of the mortar. The achieved mechanical properties were compatible with those of lime-based mixtures for repair interventions of ancient masonry structures. Moreover, the mortar was found to be well-suited to mitigate cracking, showing a low ratio between its stiffness and load capacity compared to other typologies of mortars used for masonry restoration. Ultrasonic pulse velocity test proved to be a reasonable complementary method to monitor the evolution of the hardened properties of the mortar. Carbonation was found to be still progressing at 90 days. The data presented provide useful and reliable information to approach the complex process of restoration in archeological sites.


2021 ◽  
Vol 12 (2) ◽  
pp. 39
Author(s):  
Tuba Bahtli ◽  
Nesibe Sevde Ozbay

Studies in the literature show that the physical and mechanical properties of concrete could be improved by the incorporation of different kinds of industrial waste, including waste tire rubber and tire steel. Recycling of waste is important for economic gain and to curb environmental problems. In this study, finely ground CuAl10Ni bronze is used to improve the physical and mechanical properties, and freeze-thaw resistances of C30 concrete. The density, cold crushing strength, 3-point bending strength, elastic modulus, toughness, and freeze-thaw resistances of concrete are determined. In addition, the Schmidt Rebound Hammer (SRH) and the ultrasonic pulse velocity (UPV) tests, which are non-destructive test methods, are applied. SEM/EDX analyses are also carried out. It is noted that a more compacted structure of concrete is achieved with the addition of bronze sawdust. Then higher density and strength values are obtained for concretes that are produced by bronze addition. In addition, concretes including bronze sawdust generally show higher toughness due to high plastic energy capacities than pure concrete.


2018 ◽  
Vol 789 ◽  
pp. 150-154
Author(s):  
Victor Hugo Blancas-Herrera ◽  
Jorge Alberto Pacheco-Segovia ◽  
Wilfrido Martínez-Molina ◽  
Hugo Luis Chávez García ◽  
Mauricio Arreola-Sanchez ◽  
...  

The use of dehydrated fibres of cactus, Opuntia ficus-indica (FN), and starch (corn starch,Zea Mays (MZ)) as partial substitutes for the total mass of Portland Cement (CP) in the making ofmortar, aims at modifying its physical and mechanical properties, reducing the amount of cementand the CO2 emission. Four mixtures of CP mortar were designed incorporating a superplasticizeradditive with a water/cement weight ratio of 0.68. To compare the results, there was a controlmortar; two mixtures with partial substitutions using fibres of FN, 0.5 and 1.5% (in weight of CP)respectively; and a substituted mixture with 2% of corn starch plus 0.5% of cactus fibre (MZ - FN).The test age was 180 days. The specimens were subjected to an accelerated attack of sodiumsulphate, quantifying the electric resistivity (ER) and the ultrasonic pulse velocity (UPV). Theresults indicate that the substitution of the materials, remarkably densify the cement matrix, whichresults in the improvement of the physical properties and the durability.


Ultrasonics ◽  
2015 ◽  
Vol 60 ◽  
pp. 33-40 ◽  
Author(s):  
Emilia Vasanelli ◽  
Donato Colangiuli ◽  
Angela Calia ◽  
Maria Sileo ◽  
Maria Antonietta Aiello

Energies ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1974 ◽  
Author(s):  
Viviana Letelier ◽  
Bastián I. Henríquez-Jara ◽  
Miguel Manosalva ◽  
Camila Parodi ◽  
José Marcos Ortega

Glass waste used in mortars or concretes behaves similar to cement, with resulting environmental benefits. In this light, the behavior of glass powder of various particle sizes has been analyzed as a cement replacement in mortars, in an attempt to minimize the loss of strength and durability, and maximize the amount of materials replaced. The dry density, water accessible porosity, water absorption by immersion, capillary absorption coefficient, ultrasonic pulse velocity and both compressive and flexural strengths were studied in the mortars. Furthermore, a statistical analysis of the obtained results and a greenhouse gases assessment were also performed. In view of the results obtained, glass powder of 38 microns allows up to 30% of the cement to be replaced, due to the filler effect combined with its pozzolanic activity. Moreover, it has been observed that glass powder size is one of the factors with the greatest influence among the properties of porosity, absorption and capillarity. On the other hand, in the mechanical properties, this factor does not contribute significantly more than the amount of glass powder. Finally, the greenhouse gasses analysis shows that the incorporation of glass powder reduces the CO2 emissions associated with mortar up to 29.47%.


2013 ◽  
Vol 15 (4) ◽  
pp. 578-584 ◽  

<p>An experimental investigation was carried out to compare the compressive strength of zero slump and high slump concrete with high volume fly ash. 40% to 70% replacements of OPC (by weight) with class F fly ash have been incorporated. Superplasticizer was added at 1% of binder (cement + fly ash) to the zero slump mixture to get a slump in the range of 140 to 180mm and cubes were cast without compaction. The results showed that the apparent porosity and water absorption were higher for zero slump concrete than high slump concrete. Zero slump concrete showed better compressive strengths than superplasticized concrete with 40 to 60% fly ash addition for all curing times tested (3,7 and 28 days). Ultrasonic pulse velocity results categorized all mixes as of &lsquo;EXCELLENT&rsquo; concrete quality. Based on the present experimental investigation, it can be concluded that high volume fly ash concrete is suitable for general construction applications.</p>


2019 ◽  
Vol 11 (0) ◽  
pp. 1-5
Author(s):  
Deividas Augutis ◽  
Džigita Nagrockienė

Materials used for the study: Portland cement CEM I 42,5 R, 0/4 fraction sand, 4/16 fraction gravel, biofuel fly ash, superplastizer ViscoCrete D187 (V) and water. Seven compositions of concrete were designed by replacing 0%, 5%, 10%, 15%, 20%, 25% and 30% of cement with biofuel fly ash. The article analyses the effect of biofuel fly ash content on the properties of concrete. Studies have shown that the increase of biofuel fly ash content up to 15% increases concrete density and compressive strengh after 28 days of curing, compressive strength, ultrasonic pulse velocity, closed porosity, concrete forecasted freeze-thaw cycles and decreases water absorbtion, open porosity.


2017 ◽  
Vol 80 (1) ◽  
Author(s):  
Ruhal Pervez Memon ◽  
Lemar Achekzai ◽  
Abdul Rahman Mohd. Sam ◽  
A. S. M. Abdul Awal ◽  
Uroosa Memon

The aim of this study was to shows the behavior of sawdust concrete at elevated temperature. Sawdust is considered as waste material but nowadays this waste material is utilized in the construction of the building as sawdust concrete. Sawdust is a by-product of wood which is generally used in the production of lightweight concrete, possessing low thermal conductivity. In this study sawdust concrete was made at three different proportions of cement and sawdust 1:1, 1:2, 1:3 by volume. At these proportions, the physical and mechanical properties such as density, workability, strength, fire resistance, mass loss, ultrasonic pulse velocity and residual strength were investigated after 28 days of curing. It was found that with the increment in the amount of sawdust, the workability and strength decreases, however in terms of fire resistance, concrete with lower amount of sawdust performed well. Considering the overall physical and mechanical properties, sawdust concrete can be used in building construction. 


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