scholarly journals Effects of B on the Structure and Properties of Lead-Tin Bronze Alloy and the Mechanism of Strengthening and Toughening

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7806
Author(s):  
Xiaoyan Ren ◽  
Guowei Zhang ◽  
Hong Xu ◽  
Zhaojie Wang ◽  
Yijun Liu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Wear Resistance ◽  
High Performance ◽  
Toughening Mechanism ◽  
Bronze Alloy ◽  
Main Research ◽  
Tin Bronze ◽  
The Matrix ◽  
High Lead

High lead–tin bronze is widely used in the selection of wear-resistant parts such as bearings, bearing bushes, aerospace pump rotors, turbines, and guide plates because of its excellent wear resistance, thermal conductivity, fatigue resistance, and strong load-bearing capacity. At present, high lead–tin bronze is used as a material for bimetal cylinders, which cannot meet the requirements of high-strength, anti-wear in actual working conditions under high temperature, high speed, and heavy load conditions, and is prone to de-cylinder, cylinder holding, copper sticking, etc. The reason for the failure of cylinder body parts is that the strength of copper alloy materials is insufficient, the proportion of lead in the structure is serious, and the wear resistance of the material is reduced. Therefore, it has important theoretical significance and application value to carry out research on the comprehensive properties of high-performance lead–tin bronze materials and reveal the strengthening and toughening mechanism. In this paper, The ZCuPb20Sn5 alloy is taken as the main research object, and the particle size, microstructure, mechanical properties, and friction of lead particles in ZCuPb20Sn5 alloy are systematically studied after single addition of B in ZCuPb20Sn5 alloy liquid. This paper takes ZCuPb20Sn5 alloy as the research object to study the effect of adding B on the morphology, microstructure, mechanical properties, and friction and wear properties of ZCuPb20Sn5 alloy lead particles, and discusses the strengthening and toughening mechanism of ZCuPb20Sn5 alloy under the action of B, and prepares a double high-performance lead–tin bronze alloy for metal cylinders. The main research results are as follows: The addition of B elements has an obvious refining effect on the α (Cu) equiaxed grains and lead particles in ZCuPb20Sn5 alloy. The average size of lead particles decreases from 30.0 µm to 24.8 µm as the B content increases from 0 wt.% to 0.1 wt.%. The reason for grain refinement is that B is easily concentrated at the grain boundary during the ZCuPb20Sn5 alloy solidification process, which affects the diffusion of solute atoms at the solidification interface, inhibits the grain growth, refines the grain, and hinders the sinking and homogenizes distribution between dendrites of lead; the tensile strength of the ZCuPb20Sn5 alloy improves. Relatively without B, when the addition of P is 0.1 wt.%, the tensile strength is the largest at 244.04 MPa, which enhances 13%; the maximum hardness gets 75.0 HB, which enhances 13.6%, as well as elongation get the maximum value at 17.2%. The main mechanism is that the addition of B forms a high melting point submicron Ni4B3 phase in the lead–tin bronze alloy. The Ni4B3 phase is dispersed in the matrix and strengthens the matrix. With the increase in B content (more than 0.1 wt.%), the Ni4B3 phase changes from sub-micron degree granular to micron degree block-like, and some defects such as shrinkage and porosity appear in the structure, resulting in a decrease in mechanical properties.

scholarly journals Optimizing The Addition of TiB to Improve Mechanical Properties of the ADC 12/SiC Composite Through Stir Casting Process

2019 ◽  
Vol 130 ◽  
pp. 01005
Author(s):  
Cindy Retno Putri ◽  
Anne Zulfia Syahrial ◽  
Salahuddin Yunus ◽  
Budi Wahyu Utomo
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Wear Resistance ◽  
Aluminum Alloy ◽  
Casting Process ◽  
Stir Casting ◽  
Automotive Application ◽  
Alloying Element ◽  
Brake Shoe ◽  
The Matrix

The goal of this research is to improve the mechanical properties such as strength, hardness and wear resistance for automotive application such as brake shoe and bearings due to high cycle, load and impact during their usage. Therefore, another alloying element or reinforcement addition is necessary. In this work, the composites are made by ADC 12 (Al-Si aluminum alloy) as the matrix and reinforced with micro SiC through stir casting process and TiB is added various from (0.04, 0.06, 0.15, 0.3 and 0.5) wt.% that act as grain refiners and 5 wt.% of Mg is added to improve the wettability of the composites. The addition of TiB improves the mechanical properties because the grain becomes finer and uniform, and the addition of Mg makes the matrix and reinforce have better adhesion. The results obtained that the optimum composition was found by adding 0.15 wt.% of TiB with tensile strength improve from 98 MPa to 136.3 MPa, hardness from 35 to 53 HRB and wear rate reduced from 0.006 2 mm3 s−1 to 0.002 3 mm3 s−1 respectively.

Experimental Study of Cu-Al-Ni-Fe-Mn Aluminum Bronze Strengthen by Ce

2013 ◽  
Vol 721 ◽  
pp. 177-183
Author(s):  
Jia Ming Ji ◽  
Guo Cui Meng ◽  
Yuan Yong Lu ◽  
Jing Wu
Keyword(s):  
Mechanical Properties ◽  
Experimental Study ◽  
Tensile Strength ◽  
Wear Resistance ◽  
Rare Earth ◽  
Grain Boundary ◽  
Aluminum Bronze ◽  
Bronze Alloy ◽  
Alloy Material ◽  
Ce Content

Cu-Ce intermediate alloy was added to aluminum bronze alloy which contains Al, Ni, Fe and Mn to form a novel aluminum-bronze material of Cu-Al-Ni-Fe-Mn. The influence of the different concentrations of rare earth cerium on the mechanical properties, wear resistance and microstructures of as cast Cu-Al-Ni-Fe alloy has been investigated. The results indicate that the addition of an appropriate Ce content can effectively refine the microstructure and improve the tensile strength, ductility and wear resistance. When the alloy is added by 0.15% Ce, the grain is small, sleek and uniform distribution, the tensile strength, ductility and wear resistance of the alloy material can reach to the best performance, in which tensile strength is 731Mpa and elongation is 34%. However, when the rare earth cerium add to more than 0.20%, the block shape and shred of organization becomes large, which leads to the grain boundary roughening. The tensile strength, ductility and wear resistance are declining.

Study on the Preparation Method of Nanoparticle Reinforced Copper Alloy and Mechanical Test

2013 ◽  
Vol 631-632 ◽  
pp. 568-571
Author(s):  
Lan Ying Wu ◽  
Jian Meng Chen
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Yield Strength ◽  
Copper Alloy ◽  
Preparation Method ◽  
Mechanical Test ◽  
Centrifugal Casting ◽  
Vacuum Melting ◽  
Bronze Alloy ◽  
Tin Bronze

In this paper,on the basis of a certain kind of Tin bronze alloy,a new nanoparticle reinforced copper alloy with additions of some alloy is produced by using vacuum melting and centrifugal casting technology.The mechanical properties of the alloy have increased significantly than the Tin bronze alloy.The tensile strength, yield strength,elongation of as-cast nanoparticle reinforced copper alloy are 477~535MPa,221~280MPa,28.0~35.6%,respectively.Compared with the conventional Tin bronze alloy, the strength and plastic of the nanoparticle reinforced copper alloy are obviously improved.

Investigation of tribological and mechanical properties of aluminium boron carbide composites using response surface methodology and desirability analysis

2018 ◽  
Vol 70 (2) ◽  
pp. 301-315 ◽  
Author(s):  
X. Canute ◽  
M.C. Majumder
Keyword(s):  
Mechanical Properties ◽  
Wear Resistance ◽  
Wear Rate ◽  
Boron Carbide ◽  
High Performance ◽  
Content Type ◽  
Mechanical And Tribological Properties ◽  
The Matrix ◽  
Desirability Analysis ◽  
Carbide Particles

Purpose Aluminium metal matrix composites are used in automotive and aerospace industries because of their high performance and weight reduction benefits. The current investigation aims to focus on the development of the stir cast aluminium-boron carbide composites with enhanced mechanical and tribological properties. Design/methodology/approach The aluminium-boron carbide composites are produced by stir casting process. Aluminium alloy A356 is chosen as the matrix material and three sets of composites are produced with different weight fractions of boron carbide particles. Higher particle size (63 µm) of boron carbide is chosen as the reinforcement material. Aluminium-boron carbide composites are tested for mechanical and tribological properties. The effect of process parameters like load, speed and percentage of reinforcement on the wear rate are studied using the pin-on-disc method. The interaction of the process parameters with the wear rate is analysed by DesignExpert software using RSM methodology and desirability analysis. The coded levels for parameters for independent variables used in the experimental design are arranged according to the central composite design. The worn surface of the pin is examined using a scanning electron microscope. The phases and reaction products of the composites are identified by X-ray diffraction (XRD) analysis. Findings Aluminium-boron carbide composites reveal better mechanical properties compared to monolithic aluminium alloys. Mechanical properties improved with the addition of strontium-based master alloy Al10Sr. The ultimate tensile strength, hardness and compressive strength increase with an increase in the reinforcement content. The wettability of the boron carbide particles in the matrix improved with the addition of potassium flurotitanate to the melt. Uniform dispersion of particles into the alloy during melting is facilitated by the addition of magnesium. Wear resistance is optimal at 8 per cent of boron carbide with a load 20 N and sliding speed of 348 RPM. The wear rate is optimized by the numerical optimization method using desirability analysis. The amount of wear is less in Al-B4C composites when compared to unreinforced aluminium alloy. The wear rate increases with an increase in load and decreases with the sliding speed. The wear resistance increases with an increase in the weight fraction of the boron carbide particles. Practical implications The produced Al-B4C composites can retain properties at high temperature. It is used in nuclear and automotive products owing its high specific strength and stiffness. The main applications are neutron absorbers, armour plates, high-performance bicycles, brake pads, sand blasting nozzles and pump seals. Originality/value Al/B4C composites have good potential in the development of wear-resistant products.

Morphology of High-Performance Rigid-Rod Polymer Fibers and Molecular Composites

1989 ◽  
Vol 47 ◽  
pp. 338-339
Author(s):  
W.W. Adams ◽  
S. J. Krause
Keyword(s):  
Tensile Strength ◽  
High Performance ◽  
Liquid Crystalline ◽  
Molecular Level ◽  
Synergistic Effects ◽  
Tensile Modulus ◽  
Commercial Development ◽  
The Matrix ◽  
Molecular Composites ◽  
Rigid Rod

Rigid-rod polymers such as PBO, poly(paraphenylene benzobisoxazole), Figure 1a, are now in commercial development for use as high-performance fibers and for reinforcement at the molecular level in molecular composites. Spinning of liquid crystalline polyphosphoric acid solutions of PBO, followed by washing, drying, and tension heat treatment produces fibers which have the following properties: density of 1.59 g/cm3; tensile strength of 820 kpsi; tensile modulus of 52 Mpsi; compressive strength of 50 kpsi; they are electrically insulating; they do not absorb moisture; and they are insensitive to radiation, including ultraviolet. Since the chain modulus of PBO is estimated to be 730 GPa, the high stiffness also affords the opportunity to reinforce a flexible coil polymer at the molecular level, in analogy to a chopped fiber reinforced composite. The objectives of the molecular composite concept are to eliminate the thermal expansion coefficient mismatch between the fiber and the matrix, as occurs in conventional composites, to eliminate the interface between the fiber and the matrix, and, hopefully, to obtain synergistic effects from the exceptional stiffness of the rigid-rod molecule. These expectations have been confirmed in the case of blending rigid-rod PBZT, poly(paraphenylene benzobisthiazole), Figure 1b, with stiff-chain ABPBI, poly 2,5(6) benzimidazole, Fig. 1c A film with 30% PBZT/70% ABPBI had tensile strength 190 kpsi and tensile modulus of 13 Mpsi when solution spun from a 3% methane sulfonic acid solution into a film. The modulus, as predicted by rule of mixtures, for a film with this composition and with planar isotropic orientation, should be 16 Mpsi. The experimental value is 80% of the theoretical value indicating that the concept of a molecular composite is valid.

EFFECT OF ZINC DITHIOCARBAMATES AND THIAZOLE-BASED ACCELERATORS ON THE VULCANIZATION OF NATURAL RUBBER

2012 ◽  
Vol 85 (1) ◽  
pp. 120-131 ◽  
Author(s):  
Md. Najib Alam ◽  
Swapan Kumar Mandal ◽  
Subhas Chandra Debnath
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
High Performance Liquid Chromatography ◽  
Liquid Chromatography ◽  
Reaction Mechanism ◽  
Natural Rubber ◽  
High Performance ◽  
Binary Systems ◽  
Synergistic Activity ◽  
Tetramethylthiuram Disulfide

Abstract Several zinc dithiocarbamates (ZDCs) as accelerator derived from safe amine has been exclusively studied in the presence of thiazole-based accelerators to introduce safe dithiocarbamate in the vulcanization of natural rubber. Comparison has been made between conventional unsafe zinc dimethyldithiocarbamate (ZDMC) with safe novel ZDC combined with thizole-based accelerators in the light of mechanical properties. The study reveals that thiuram disulfide and 2-mercaptobenzothiazole (MBT) are always formed from the reaction either between ZDC and dibenzothiazyledisulfide (MBTS) or between ZDC and N-cyclohexyl-2-benzothiazole sulfenamide (CBS). It has been conclusively proved that MBT generated from MBTS or CBS reacts with ZDC and produces tetramethylthiuram disulfide. The observed synergistic activity has been discussed based on the cure and physical data and explained through the results based on high-performance liquid chromatography and a reaction mechanism. Synergistic activity is observed in all binary systems studied. The highest tensile strength is observed in the zinc (N-benzyl piperazino) dithiocarbamate-accelerated system at 3:6 mM ratios. In respect of tensile strength and modulus value, unsafe ZDMC can be successfully replaced by safe ZDCs in combination with thiazole group containing accelerator.

scholarly journals Influence of Alumina Nanofibers Sintered by the Spark Plasma Method on Nickel Mechanical Properties

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 548 ◽  
Author(s):  
Leonid Agureev ◽  
Valeriy Kostikov ◽  
Zhanna Eremeeva ◽  
Svetlana Savushkina ◽  
Boris Ivanov ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Elastic Modulus ◽  
Strength Properties ◽  
Alumina Nanoparticles ◽  
Metal Powders ◽  
Wide Range ◽  
The Matrix ◽  
Spark Plasma ◽  
Average Size

The article presents the study of alumina nanoparticles’ (nanofibers) concentration effect on the strength properties of pure nickel. The samples were obtained by spark plasma sintering of previously mechanically activated metal powders. The dependence of the grain size and the relative density of compacts on the number of nanofibers was investigated. It was found that with an increase in the concentration of nanofibers, the average size of the matrix particles decreased. The effects of the nanoparticle concentration (0.01–0.1 wt.%) on the elastic modulus and tensile strength were determined for materials at 25 °C, 400 °C, and 750 °C. It was shown that with an increase in the concentration of nanofibers, a 10–40% increase in the elastic modulus and ultimate tensile strength occurred. A comparison of the mechanical properties of nickel in a wide range of temperatures, obtained in this work with materials made by various technologies, is carried out. A description of nanofibers’ mechanisms of influence on the structure and mechanical properties of nickel is given. The possible impact of impurity phases on the properties of nickel is estimated. The tendency of changes in the mechanical properties of nickel, depending on the concentration of nanofibers, is shown.

scholarly journals Composites from Thermoplastic Natural Rubber Reinforced Rubberwood Sawdust: Effects of Sawdust Size and Content on Thermal, Physical, and Mechanical Properties

2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Chatree Homkhiew ◽  
Surasit Rawangwong ◽  
Worapong Boonchouytan ◽  
Wiriya Thongruang ◽  
Thanate Ratanawilai
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Natural Rubber ◽  
High Density Polyethylene ◽  
High Performance ◽  
Physical And Mechanical Properties ◽  
Modulus Of Rupture ◽  
Shore Hardness ◽  
Thermoplastic Natural Rubber ◽  
Plastic Content

The aim of this work is to investigate the effects of rubberwood sawdust (RWS) size and content as well as the ratio of natural rubber (NR)/high-density polyethylene (HDPE) blend on properties of RWS reinforced thermoplastic natural rubber (TPNR) composites. The addition of RWS about 30–50 wt% improved the modulus of the rupture and tensile strength of TPNR composites blending with NR/HDPE ratios of 60/40 and 50/50. TPNR composites reinforced with RWS 80 mesh yielded better tensile strength and modulus of rupture than the composites with RWS 40 mesh. The TPNR/RWS composites with larger HDPE content gave higher tensile, flexural, and Shore hardness properties and thermal stability as well as lower water absorption. The TPNR/RWS composites with larger plastic content were therefore suggested for applications requiring high performance of thermal, physical, and mechanical properties.

The Investigation on Aluminium Alloys Automobile Wheel with Low-Titanium Content Produced by Electrolysis

2005 ◽  
Vol 475-479 ◽  
pp. 317-320 ◽  
Author(s):  
Jing Pei Xie ◽  
Ji Wen Li ◽  
Zhong Xia Liu ◽  
Ai Qin Wang ◽  
Yong Gang Weng ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Aluminium Alloys ◽  
Solution Treatment ◽  
A356 Alloy ◽  
Aging Treatment ◽  
Titanium Content ◽  
The Matrix ◽  
Automobile Wheel

The in-situ Ti alloying of aluminium alloys was fulfilled by electrolysis, and the material was made into A356 alloy and used in automobile wheels. The results show that the grains of the A356 alloy was refined and the second dendrites arm was shortened due to the in-situ Ti alloying. Trough 3-hour solution treatment and 2-hour aging treatment for the A356 alloy, the microstructures were homogeneous, and Si particles were spheroid and distribute in the matrix fully. The outstanding mechanical properties with tensile strength (σb≥300Mpa) and elongation values (δ≥10%) have been obtained because the heat treatment was optimized. Compared with the traditional materials, tensile strength and elongation were increased by 7.6~14.1% and 7.4~44.3% respectively. The qualities of the automobile wheels were improved remarkably.

scholarly journals Preparation and Mechanical Properties of Graphene Oxide: Cement Nanocomposites

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Fakhim Babak ◽  
Hassani Abolfazl ◽  
Rashidi Alimorad ◽  
Ghodousi Parviz
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Graphene Oxide ◽  
Cement Mortar ◽  
Cement Matrix ◽  
Cement Composites ◽  
Xrd Diffraction ◽  
Calcium Silicate Hydrates ◽  
The Matrix ◽  
Scanning Electron

We investigate the performance of graphene oxide (GO) in improving mechanical properties of cement composites. A polycarboxylate superplasticizer was used to improve the dispersion of GO flakes in the cement. The mechanical strength of graphene-cement nanocomposites containing 0.1–2 wt% GO and 0.5 wt% superplasticizer was measured and compared with that of cement prepared without GO. We found that the tensile strength of the cement mortar increased with GO content, reaching 1.5%, a 48% increase in tensile strength. Ultra high-resolution field emission scanning electron microscopy (FE-SEM) used to observe the fracture surface of samples containing 1.5 wt% GO indicated that the nano-GO flakes were well dispersed in the matrix, and no aggregates were observed. FE-SEM observation also revealed good bonding between the GO surfaces and the surrounding cement matrix. In addition, XRD diffraction data showed growth of the calcium silicate hydrates (C-S-H) gels in GO cement mortar compared with the normal cement mortar.

Sign in / Sign up

Export Citation Format

Share Document