scholarly journals VIS-NIR/SWIR Spectral Properties of H2O Ice Depending on Particle Size and Surface Temperature

Minerals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1328
Author(s):  
Katrin Stephan ◽  
Mauro Ciarniello ◽  
Olivier Poch ◽  
Bernard Schmitt ◽  
David Haack ◽  
...  
Keyword(s):  
Particle Size ◽  
Spectral Signature ◽  
Particle Sizes ◽  
Icy Satellites ◽  
Spectral Parameters ◽  
Spectral Changes ◽  
Large Particles ◽  
Band Depth ◽  
Increasing Temperature ◽  
Particle Shapes

Laboratory measurements were performed to study the spectral signature of H2O ice between 0.4 and 4.2 µm depending on varying temperatures between 70 and 220 K. Spectral parameters of samples with particle sizes up to ~1360 µm, particle size mixtures, and different particle shapes were analyzed. The band depth (BD) of the major H2O-ice absorptions at 1.04, 1.25, 1.5, and 2 µm offers an excellent indicator for varying particle sizes in pure H2O ice. The spectral changes due to temperature rather, but not exclusively, affect the H2O-ice absorptions located at 1.31, 1.57, and 1.65 µm and the Fresnel reflection peaks at 3.1 and 3.2 µm, which strongly weaken with increasing temperature. As the BDs of the H2O-ice absorptions at 1.31, 1.57, and 1.65 µm increase, the band centers (BCs) of the H2O-ice absorptions at 1.25 and 1.5 µm slightly shift to shorter wavelengths. However, the BCs of the strong H2O-ice absorptions can also be affected by saturation in the case of large particles. The collected spectra provide a useful spectral library for future investigations of icy satellites such as Ganymede and Callisto, the major targets of ESA’s JUICE mission.

scholarly journals Investigation of the kinetics of spontaneous combustion of the major coal seam in Dahuangshan mining area of the Southern Junggar coalfield, Xinjiang, China

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Li Shen ◽  
Qiang Zeng
Keyword(s):  
Particle Size ◽  
High Temperature ◽  
Coal Seam ◽  
Spontaneous Combustion ◽  
Heating Temperature ◽  
Characteristic Temperature ◽  
Mining Area ◽  
Particle Sizes ◽  
Coal Oxidation ◽  
Increasing Temperature

AbstractIn the present paper, with using diverse methods (including the SEM, the XRD, the TPO, the FTIR, and the TGA) , the authors analysed samples of the major coal seam in Dahuangshan Mining area with different particle sizes and with different heated temperatures (from 50 to 800 °C at regular intervals of 50 °C). The results from SEM and XRD showed that high temperature and high number of pores, fissures, and hierarchical structures in the coal samples could facilitate oxidation reactions and spontaneous combustion. A higher degree of graphitization and much greater number of aromatic microcrystalline structures facilitated spontaneous combustion. The results from TPO showed that the oxygen consumption rate of the coal samples increased exponentially with increasing temperature. The generation rates of different gases indicated that temperatures of 90 °C or 130 °C could accelerate coal oxidation. With increasing temperature, the coal oxidation rate increased, and the release of gaseous products was accelerated. The FTIR results showed that the amount of hydroxide radicals and oxygen-containing functional groups increased with the decline in particle size, indicating that a smaller particle size may facilitate the oxidation reaction and spontaneous combustion of coal. The absorbance and the functional group areas at different particle sizes were consistent with those of the heated coal samples, which decreased as the temperature rose. The results from TGA showed that the characteristic temperature T3 declined with decreasing particle size. After the sample with 0.15–0.18 mm particle size was heated, its carbon content decreased, and its mineral content increased, inhibiting coal oxidation. This result also shows that the activation energy of the heated samples tended to increase at the stage of high-temperature combustion with increasing heating temperature.

scholarly journals Synthesis and Optical Performances of a Waterborne Polyurethane-Based Polymeric Dye

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Xianhai Hu ◽  
Xingyuan Zhang ◽  
Jin Liu
Keyword(s):  
Molecular Weight ◽  
Particle Size ◽  
Waterborne Polyurethane ◽  
Average Particle ◽  
Particle Sizes ◽  
Hypsochromic Shift ◽  
Absorption Bands ◽  
Polymeric Dye ◽  
Emulsion Particle ◽  
Increasing Temperature

A waterborne polyurethane-based polymeric dye (WPU-CFBB) was synthesized by anchoring 1, 4-bis(methylamino)anthraquinone (CFBB) to waterborne polyurethane chains. The number molecular weight, glass transition temperature, and average emulsion particle size for the polymeric dye were determined, respectively. This polymeric dye exhibited intriguing optical behaviors. The polymeric dye engendered two new absorption bands centered at about 520 nm and 760 nm if compared with CFBB in UV-vis spectra. The 760 nm peak showed hypsochromic shift with the decrease of average particle sizes. The polymeric dye dramatically demonstrated both hypsochromic and bathochromic effects with increasing temperature. The fluorescence intensity of the polymeric dye was much higher than that of CFBB. It was found that the fluorescence intensities would be enhanced from 20°C to 40°C and then decline from 40°C to 90°C. The fluorescence of the polymeric dye emulsion was very stable and was not sensitive to quenchers.

scholarly journals THE EFFECT OF CAVITATION TREATMENT ON THE EXTINGUISHING OF PARTICLES OF OILS IN FUEL BOILERS

2019 ◽  
Vol 20 (9-10) ◽  
pp. 52-59
Author(s):  
M. A. Taymarov ◽  
R. V. Akhmetova ◽  
S. M. Margulis ◽  
L. I. Kasimova
Keyword(s):  
Particle Size ◽  
Combustion Zone ◽  
Consumption Rate ◽  
Fuel Oil ◽  
Particle Sizes ◽  
Oil Consumption ◽  
Boiler Efficiency ◽  
Large Particles ◽  
Oil Particles

The difficulties of burning the watered fuel oil used at the TPP as a reserve fuel for boilers are associated with its preparation by heating to reduce viscosity and the choice of a method of spraying with nozzles into the combustion zone. The quality of the preparation of fuel oil for combustion affecting the boiler efficiency is estimated by the length of the flame, the presence of burning large particles of fuel oil, the injection of coke and unburned particles onto screen and other heat-receiving surfaces. One of the ways to prepare fuel oil for combustion is cavitation treatment, which results in an emulsion consisting of fine micronsized particles. Heating of fuel oil particles after the nozzle in contact with the combustion zone is due to the flow of radiation from the burning torch. Therefore, in this article, the values of the flux density from the torch during the combustion of fuel oil are experimentally determined. The influence of particle size on the burning rate of the fuel oil M100 with the different density of the thermal radiation of the flame. It is found that the effect of cavitation treatment of fuel oil on the combustion rate is most significantly manifested in particle sizes less than 10 microns. For this purpose, the use of hydrodynamic cavitators are preferred at high fuel oil consumption rate.

scholarly journals Streaming instability of multiple particle species in protoplanetary disks

2018 ◽  
Vol 618 ◽  
pp. A75 ◽  
Author(s):  
Noemi Schaffer ◽  
Chao-Chin Yang ◽  
Anders Johansen
Keyword(s):  
Particle Size ◽  
Size Distribution ◽  
Protoplanetary Disks ◽  
Single Species ◽  
Stokes Number ◽  
Dust Particles ◽  
Particle Sizes ◽  
Particle Species ◽  
Streaming Instability ◽  
Large Particles

The radial drift and diffusion of dust particles in protoplanetary disks affect both the opacity and temperature of such disks, as well as the location and timing of planetesimal formation. In this paper, we present results of numerical simulations of particle-gas dynamics in protoplanetary disks that include dust grains with various size distributions. We have considered three scenarios in terms of particle size ranges, one where the Stokes number τs = 10−1−100, one where τs = 10−4−10−1, and finally one where τs = 10−3−100. Moreover, we considered both discrete and continuous distributions in particle size. In accordance with previous works we find in our multispecies simulations that different particle sizes interact via the gas and as a result their dynamics changes compared to the single-species case. The larger species trigger the streaming instability and create turbulence that drives the diffusion of the solid materials. We measured the radial equilibrium velocity of the system and find that the radial drift velocity of the large particles is reduced in the multispecies simulations and that the small particle species move on average outwards. We also varied the steepness of the size distribution, such that the exponent of the solid number density distribution, dN∕da ∝ a−q, is either q = 3 or q = 4. Overall, we find that the steepness of the size distribution and the discrete versus continuous approach have little impact on the results. The level of diffusion and drift rates are mainly dictated by the range of particle sizes. We measured the scale height of the particles and observe that small grains are stirred up well above the sedimented midplane layer where the large particles reside. Our measured diffusion and drift parameters can be used in coagulation models for planet formation as well as to understand relative mixing of the components of primitive meteorites (matrix, chondrules and CAIs) prior to inclusion in their parent bodies.

Die Gelchromatographie großer Partikel und ihre Grenzen / Limitation of Particles Size in Gel Chromatography

1970 ◽  
Vol 25 (11) ◽  
pp. 1235-1239 ◽  
Author(s):  
Wolfram Gerlich ◽  
Helmut Determann ◽  
Theodor Wieland
Keyword(s):  
Particle Size ◽  
Brownian Motion ◽  
Rat Liver ◽  
Liver Mitochondria ◽  
Rat Liver Mitochondria ◽  
Gel Chromatography ◽  
Particle Sizes ◽  
E Coli ◽  
Large Particles ◽  
Cellulose Gel

The behaviour of molecules and particles of 2 - 400 nm radius in gel chromatography was investigated using sephadex, agarose, and pearl shaped cellulose gel of different porosity. Correlations between elution volumes and particle sizes are given in Fig. 1. We found that particles from ca. 400 nm diameter upwards were more or less irreversibly adsorbed depending on the particle size. So only 15% of rat liver mitochondria and 5% of E. coli bacteria could be eluted from the loose cellulose Cu3. It is assumed that this adsorption is due to the absence of Brownian motion of large particles, which therefore are more or less subject to the gravity and to adsorption forces of the gel.

EFFECTS OF CHANGES IN ATTRIBUTES OF RETICULAR CONTRACTION ON FECAL PARTICLE SIZES IN CATTLE

1990 ◽  
Vol 70 (1) ◽  
pp. 159-166 ◽  
Author(s):  
E. K. OKINE ◽  
G. W. MATHISON ◽  
R. T. HARDIN
Keyword(s):  
Particle Size ◽  
High Weight ◽  
Geometric Mean ◽  
Latin Square ◽  
Design Experiment ◽  
Particle Sizes ◽  
Low Weight ◽  
Large Particles ◽  
Mean Size ◽  
Period Duration

A 3 × 3 Latin square design experiment was conducted with three ruminally-cannulated Hereford steers (605 ± SD 98 kg) to determine the effects of changes in reticular contraction characteristics on the distribution of fecal particle size of cattle fed at maintenance. Addition of 0 (control; C) 9 (low weight; LW) or 18 (high weight; HW) kg weight to ventral sac of the rumen of steers linearly increased (P = 0.03) the geometric mean size of fecal particles. During the 1.5-h feeding period, duration and amplitude of reticular contractions linearly increased (P = 0.04) and decreased (P = 0.08), respectively, with the addition of weights. Frequency of reticular contractions increased linearly (P = 0.05) and quadratically (P = 0.07), reaching a maximum of 1.7 min−1 in LW steers, 1.6 min−1 and 1.4 min−1 in HW and C steers, respectively. Duration of reticular contractions, but not amplitude or frequency, was linearly related to the proportion of large particles and to the geometric mean size of fecal particles (r = 0.90, P = 0.002; and r = 0.61, P = 0.08, respectively). It was concluded that the increase in fecal geometric mean and the change in the distribution of fecal particle sizes with increasing weights in the rumen was associated with increases in the duration of reticular contractions rather than changes in frequency or amplitude. Key words: Steers, reticular contractions, fecal particle size, rumen, weight

On the Sintering Activation Energy of α-Al2O3

2008 ◽  
Vol 368-372 ◽  
pp. 686-687 ◽  
Author(s):  
Wei Quan Shao ◽  
Shaou Chen ◽  
Da Li ◽  
Ping Qi ◽  
Yong Wan ◽  
...  
Keyword(s):  
Activation Energy ◽  
Particle Size ◽  
Temperature Interval ◽  
High Purity ◽  
Powder Compact ◽  
Isothermal Condition ◽  
Particle Sizes ◽  
Higher Temperature ◽  
Lower Temperature ◽  
Increasing Temperature

The sintering activation energy of high-purity alumina powders with different particle sizes was evaluated under non-isothermal condition. It was found that, during sintering, the activation energy for the lower temperature stage is higher than that for higher temperature stage. The value of the activation energies for the powder compact with larger particle size was higher than that for the powder compact with smaller particle size. If the selected temperature interval for calculation was narrow enough, the evaluated activation energy values varied with the increasing temperature continuously.

scholarly journals Effects of Particle Shapes and Sizes on the Minimum Void Ratios of Sand

2019 ◽  
Vol 2019 ◽  
pp. 1-12
Author(s):  
Zhaoyang Xu ◽  
Ning Xu ◽  
Haibo Wang
Keyword(s):  
Particle Size ◽  
Void Ratio ◽  
Relational Model ◽  
Particle Sizes ◽  
Size Distributions ◽  
Particle Size Distributions ◽  
Fines Content ◽  
Minimum Value ◽  
Alternative Materials ◽  
Particle Shapes

The minimum void ratio is an important parameter for evaluating soil properties. It is closely related to the compressive properties, permeability, and shear strength of soil, and it is affected by particle size distributions and particle shapes. However, existing research generally focuses on modeling the minimum void ratio with the effect of particle size distributions, ignoring the influences of particle shapes on the minimum void ratio. This paper analyzes the influences of particle size distributions and particle shapes on the minimum void ratio using four types of sand and alternative materials. The experiments showed that the minimum void ratio first decreased and then increased with the increase of the fines content. The minimum void ratio reached a minimum value when the proportion of fines content was approximately 40%. The more irregular the particle shapes, the more complicated the contact between particles, the more the void existed between the particles, and the larger the minimum void ratio. Based on the experimental data, a relational model between the minimum value of the minimum void ratio and the particle sizes ratio was derived with binary mixtures of different particle sizes and shapes. This proposed model required only one parameter T, which was closely related to the sphericity of the particles, to predict the minimum value of the minimum void ratio with various fines contents. The experiment results showed that the predicted value was very close to the actual measured value.

Surface energy of cellulosic materials: The effect of particle morphology, particle size, and hydroxyl number

TAPPI Journal ◽  
2015 ◽  
Vol 14 (9) ◽  
pp. 565-576 ◽  
Author(s):  
YUCHENG PENG ◽  
DOUGLAS J. GARDNER
Keyword(s):  
Particle Size ◽  
Surface Energy ◽  
Particle Morphology ◽  
Nanofibrillated Cellulose ◽  
Particle Sizes ◽  
Hydroxyl Number ◽  
Small Individual ◽  
Dispersion Component ◽  
Commercial Applications ◽  
Lower Temperature

Understanding the surface properties of cellulose materials is important for proper commercial applications. The effect of particle size, particle morphology, and hydroxyl number on the surface energy of three microcrystalline cellulose (MCC) preparations and one nanofibrillated cellulose (NFC) preparation were investigated using inverse gas chromatography at column temperatures ranging from 30ºC to 60ºC. The mean particle sizes for the three MCC samples and the NFC sample were 120.1, 62.3, 13.9, and 9.3 μm. The corresponding dispersion components of surface energy at 30°C were 55.7 ± 0.1, 59.7 ± 1.3, 71.7 ± 1.0, and 57.4 ± 0.3 mJ/m2. MCC samples are agglomerates of small individual cellulose particles. The different particle sizes and morphologies of the three MCC samples resulted in various hydroxyl numbers, which in turn affected their dispersion component of surface energy. Cellulose samples exhibiting a higher hydroxyl number have a higher dispersion component of surface energy. The dispersion component of surface energy of all the cellulose samples decreased linearly with increasing temperature. MCC samples with larger agglomerates had a lower temperature coefficient of dispersion component of surface energy.

scholarly journals Effect of particle size on phytochemical composition and antioxidant properties of Sargassum cristaefolium ethanol extract

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
E. S. Prasedya ◽  
A. Frediansyah ◽  
N. W. R. Martyasari ◽  
B. K. Ilhami ◽  
A. S. Abidin ◽  
...  
Keyword(s):  
Antioxidant Activity ◽  
Particle Size ◽  
Antioxidant Activities ◽  
Antioxidant Properties ◽  
Ethanol Extract ◽  
Total Phenolic ◽  
Particle Sizes ◽  
Epicatechin Gallate ◽  
Particle Size Reduction ◽  
Phytochemical Composition

AbstractSample particle size is an important parameter in the solid–liquid extraction system of natural products for obtaining their bioactive compounds. This study evaluates the effect of sample particle size on the phytochemical composition and antioxidant activity of brown macroalgae Sargassum cristaefolium. The crude ethanol extract was extracted from dried powders of S.cristeafolium with various particle sizes (> 4000 µm, > 250 µm, > 125 µm, > 45 µm, and < 45 µm). The ethanolic extracts of S.cristaefolium were analysed for Total Phenolic Content (TPC), Total Flavonoid Content (TFC), phenolic compound concentration and antioxidant activities. The extract yield and phytochemical composition were more abundant in smaller particle sizes. Furthermore, the TPC (14.19 ± 2.08 mg GAE/g extract to 43.27 ± 2.56 mg GAE/g extract) and TFC (9.6 ± 1.8 mg QE/g extract to 70.27 ± 3.59 mg QE/g extract) values also significantly increased as particle sizes decreased. In addition, phenolic compounds epicatechin (EC), epicatechin gallate (ECG), epigallocatechin (EGC), and Epigallocatechin gallate (EGCG) concentration were frequently increased in samples of smaller particle sizes based on two-way ANOVA and Tukey’s multiple comparison analysis. These results correlate with the significantly stronger antioxidant activity in samples with smaller particle sizes. The smallest particle size (< 45 µm) demonstrated the strongest antioxidant activity based on DPPH, ABTS, hydroxyl assay and FRAP. In addition, ramp function graph evaluates the desired particle size for maximum phytochemical composition and antioxidant activity is 44 µm. In conclusion, current results show the importance of particle size reduction of macroalgae samples to increase the effectivity of its biological activity.

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