scholarly journals Polymer Composites Filled with Metal Derivatives: A Review of Flame Retardants

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1701
Author(s):  
R. A. Ilyas ◽  
S. M. Sapuan ◽  
M. R. M. Asyraf ◽  
D. A. Z. N. Dayana ◽  
J. J. N. Amelia ◽  
...  
Keyword(s):  
Polymer Composites ◽  
Fire Resistance ◽  
Flame Retardants ◽  
Safety Concern ◽  
Industrial Applications ◽  
Metal Particles ◽  
Thermoplastic Composites ◽  
Flame Resistance ◽  
Metal Derivatives ◽  
Resistance Performance

Polymer composites filled with metal derivatives have been widely used in recent years, particularly as flame retardants, due to their superior characteristics, including high thermal behavior, low environmental degradation, and good fire resistance. The hybridization of metal and polymer composites produces various favorable properties, making them ideal materials for various advanced applications. The fire resistance performance of polymer composites can be enhanced by increasing the combustion capability of composite materials through the inclusion of metallic fireproof materials to protect the composites. The final properties of the metal-filled thermoplastic composites depend on several factors, including pore shape and distribution and morphology of metal particles. For example, fire safety equipment uses polyester thermoplastic and antimony sources with halogenated additives. The use of metals as additives in composites has captured the attention of researchers worldwide due to safety concern in consideration of people’s life and public properties. This review establishes the state-of-art flame resistance properties of metals/polymer composites for numerous industrial applications.

Study on the Data-Bases for Fire Engineering Design of Structural Steels Members

2012 ◽  
Vol 628 ◽  
pp. 156-160
Author(s):  
In Kyu Kwon ◽  
Hyung Jun Kim ◽  
Heung Youl Kim ◽  
Bum Yean Cho ◽  
Kyung Suk Cho
Keyword(s):  
Bearing Capacity ◽  
Fire Resistance ◽  
Engineering Method ◽  
Fire Tests ◽  
Structural Members ◽  
Data Bases ◽  
Load Bearing Capacity ◽  
Load Bearing ◽  
In Fire ◽  
Resistance Performance

Structural steel has been used since the early 1970’s in Korea as primary structural members such as columns, beams, and trusses. The materials have much higher strength such as fast construction, high load bearing capacity, high construction quality but those have a fatal weakness as well. Load-bearing capacity is going down when the structural members are contained in fire condition. Therefore, to protect the structural members made of steels from the heat energy the fire resistance performance required. Generally, the fire resistance performance have evaluated from the exact fire tests in fire furnaces. But the evaluation method takes much more time and higher expenses so, the engineering method requires. The engineering method not only adopts a science but also an engineering experience. In this paper, to make various data-bases for evaluation of structural members such as columns(H-section, RHS), beams, loaded fire tests were conducted and derived not only each limiting temperature but also fire resistance respectively.

scholarly journals Sequential Laser–Mechanical Drilling of Thick Carbon Fibre Reinforced Polymer Composites (CFRP) for Industrial Applications

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2136
Author(s):  
Sharizal Ahmad Sobri ◽  
Robert Heinemann ◽  
David Whitehead
Keyword(s):  
Carbon Fibre ◽  
Polymer Composites ◽  
Weight Ratio ◽  
High Strength ◽  
Industrial Applications ◽  
Fibre Laser ◽  
Reinforced Polymer ◽  
Carbon Fibre Reinforced Polymer ◽  
Fibre Reinforced Polymer ◽  
Thrust And Torque

Carbon fibre reinforced polymer composites (CFRPs) can be costly to manufacture, but they are typically used anywhere a high strength-to-weight ratio and a high steadiness (rigidity) are needed in many industrial applications, particularly in aerospace. Drilling composites with a laser tends to be a feasible method since one of the composite phases is often in the form of a polymer, and polymers in general have a very high absorption coefficient for infrared radiation. The feasibility of sequential laser–mechanical drilling for a thick CFRP is discussed in this article. A 1 kW fibre laser was chosen as a pre-drilling instrument (or initial stage), and mechanical drilling was the final step. The sequential drilling method dropped the overall thrust and torque by an average of 61%, which greatly increased the productivity and reduced the mechanical stress on the cutting tool while also increasing the lifespan of the bit. The sequential drilling (i.e., laser 8 mm and mechanical 8 mm) for both drill bits (i.e., 2- and 3-flute uncoated tungsten carbide) and the laser pre-drilling techniques has demonstrated the highest delamination factor (SFDSR) ratios. A new laser–mechanical sequence drilling technique is thus established, assessed, and tested when thick CFRP composites are drilled.

The Fire Resistance Performance of Double-Layer Square Pyramid Silo-Shell Structure under Fire

2013 ◽  
Vol 405-408 ◽  
pp. 2305-2310
Author(s):  
Ling Feng Gong ◽  
Yin Bai ◽  
Jian Lei Zhai
Keyword(s):  
Double Layer ◽  
Fire Resistance ◽  
Shell Structure ◽  
Room Temperature ◽  
Uniform Temperature ◽  
Global Instability ◽  
Element Analysis ◽  
Fire Temperature ◽  
Resistance Performance ◽  
Typical Temperature

With fire temperature rising, elastic modulus of steel would be reduce, which then would lead to global instability phenomenon of double-layer square pyramid silo-shell structure. In order to analyze its fire resistance performance under high fire temperature, different geometric parameters were set based on the effect factors when it operated normally at room temperature. To analyze its displacement change by conducting nonlinear finite element analysis which was under the two typical temperature rising cases including global non-uniform temperature and localized high temperature. Then, with the temperature rising, the fire resistance performance and the maxium displacement changing rule were obtained.

Effects of heterionic montmorillonites on flame resistances of polystyrene nanocomposites and the flame retardant mechanism

2017 ◽  
Vol 52 (10) ◽  
pp. 1295-1303 ◽  
Author(s):  
Yijiao Xue ◽  
Mingxia Shen ◽  
Fengling Lu ◽  
Yongqin Han ◽  
Shaohua Zeng ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Flame Retardants ◽  
Reducing Power ◽  
Infrared Analysis ◽  
X Ray Diffraction ◽  
Flame Resistance ◽  
Cone Calorimeter Test ◽  
Intumescent Flame Retardants ◽  
Thermal Stability Of ◽  
Better Than

To improve the flame resistance of polystyrene, three kinds of organophilic heterionic montmorillonites (Na-montmorillonite, Ca-montmorillonite, and Fe-montmorillonite) reinforced polystyrene nanocomposites were prepared by melt dispersion method. The structure and composition of the organo montmorillonites were characterized by using X-ray diffraction and Fourier-transform infrared analysis. The adhesion between organo montmorillonites and polystyrene was investigated by scanning electron microscopy. The flame resistance and thermal stability of the polystyrene/organo montmorillonites were evaluated by cone calorimeter test and thermogravimetric analysis. The interlayer space of organo montmorillonites increased with the increase of the oxidation state of the cations. With the addition of organo montmorillonites, the peak values of all the flame resistance indexes of the polystyrene/organo montmorillonites nanocomposites decreased, among which the PHRR values have decreased the most, compared with those of polystyrene. Their corresponding test times have all been delayed following almost precisely the same trend. Therefore, their flame retardant ability come from their lamellated structures, their charring forming abilities, and the reducing power of Fe3+ in polystyrene/Fe-montmorillonite. Organo montmorillonites mainly act as a kind of intumescent flame retardants. The flame resistance of polystyrene/Na-montmorillonite nanocomposite was the best, and the polystyrene/Ca-montmorillonite came second, which is slightly better than that of polystyrene/Fe-montmorillonite.

scholarly journals RECENT APPLICATIONS AND INNOVATIONS OF CELLULOSE BASED MATERIALS: A CRITICAL REVIEW

2021 ◽  
Vol 55 (1-2) ◽  
pp. 1-12
Author(s):  
TSHWAFO ELIAS MOTAUNG
Keyword(s):  
Mechanical Properties ◽  
Optical Properties ◽  
Thermal Degradation ◽  
Polymer Composites ◽  
Critical Review ◽  
Industrial Applications ◽  
Knowledge Gaps ◽  
Cellulosic Materials ◽  
Synthetic Fibers ◽  
Industrial Needs

"This review presents recent research on cellulosic materials and its latest uses, as well as scientific possibilities for more applications. Cellulose continues to display its advantages over synthetic fibers and its potential to replace fossilbased materials, which are known to harm ecosystems. Common attractive applications of cellulose include packaging, healthcare materials, electronics and printing. Most applications seem to rotate around the equilibrium of hydrophilicity, its mechanical properties and optical properties. Details on industrial applications, knowledge gaps and green innovations in cellulose conductivity, as well as limitations of its thermal degradation, are thoroughly covered. Most innovations are motivated by industrial needs, because renewability and inexpensiveness are the latest additional values to most industries. All common and innovative pretreatments are well summarized in this review. Furthermore, the paper provides interesting details on cellulose polymer composites, their applications and some recommendations for further research."

scholarly journals Flammability and Thermal Kinetic Analysis of UiO-66-Based PMMA Polymer Composites

Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4113
Author(s):  
Ruiqing Shen ◽  
Tian-Hao Yan ◽  
Rong Ma ◽  
Elizabeth Joseph ◽  
Yufeng Quan ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Mass Loss ◽  
Polymer Composites ◽  
Flame Retardants ◽  
Loss Rate ◽  
Mass Loss Rate ◽  
Protective Layer ◽  
Average Mass ◽  
Microscale Combustion Calorimeter ◽  
Combustion Calorimeter

Metal–organic frameworks (MOFs) are emerging as novel flame retardants for polymers, which, typically, can improve their thermal stability and flame retardancy. However, there is a lack of specific studies on the thermal decomposition kinetics of MOF-based polymer composites, although it is known that they are important for the modeling of flaming ignition, burning, and flame spread over them. The thermal decomposition mechanisms of poly (methyl methacrylate) (PMMA) have been well investigated, which makes PMMA an ideal polymer to evaluate how fillers affect its decomposition process and kinetics. Thus, in this study, UiO-66, a common type of MOF, was embedded into PMMA to form a composite. Based on the results from the microscale combustion calorimeter, the values of the apparent activation energy of PMMA/UiO-66 composites were calculated and compared against those of neat PMMA. Furthermore, under cone calorimeter tests, UiO-66, at only 1.5 wt%, can reduce the maximum burning intensity and average mass loss rate of PMMA by 14.3% and 12.4%, respectively. By combining UiO-66 and SiO2 to form a composite, it can contribute to forming a more compact protective layer, which shows a synergistic effect on reducing the maximum burning intensity and average mass loss rate of PMMA by 22.0% and 14.7%, respectively.

Graphene Composites

2019 ◽  
Vol 23 ◽  
pp. 57-63 ◽  
Author(s):  
Chin Wei Lai
Keyword(s):  
Mechanical Properties ◽  
Graphene Oxide ◽  
Polymer Composites ◽  
Applied Research ◽  
Scientific Literature ◽  
Filler Content ◽  
2D Materials ◽  
Industrial Applications ◽  
Research Interest ◽  
Two Dimensional

This chapter reviews recent development of graphene-based polymer composites. The formation of graphene oxide and graphene are a vital two dimensional (2D) material has received a lot of research interest in commercialization aspect due to its excellent electrical, thermal as well as mechanical properties at very low filler content. In this manner, utilization of graphene-based polymer composites with different polymer matrixes have been attracted increasing attention in recent years for both fundamental studies and applied research into industrial applications in many fields. Herein, novel properties of polymer (epoxy, polystyrene, and PANI) / graphene composites will be reviewed along with detailed examples drawn from the scientific literature. Keywords: Graphene-based polymer composites, thermo-mechanical properties, two dimensional (2D) materials

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