scholarly journals Investigation of Electrical Properties of BiFeO3/LDPE Nanocomposite Dielectrics with Magnetization Treatments

Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2622
Author(s):  
Wei Song ◽  
Yu Sun ◽  
Tian-Jiao Yu ◽  
Yu-Zhang Fan ◽  
Zhi Sun ◽  
...  

The purpose of this paper is to study the effect of nano-bismuth ferrite (BiFeO3) on the electrical properties of low-density polyethylene (LDPE) under magnetic-field treatment at different temperatures. BiFeO3/LDPE nanocomposites with 2% mass fraction were prepared by the melt-blending method, and their electrical properties were studied. The results showed that compared with LDPE alone, nanocomposites increased the crystal concentration of LDPE and the spherulites of LDPE. Filamentous flake aggregates could be observed. The spherulite change was more obvious under high-temperature magnetization. An agglomerate phenomenon appeared in the composite, and the particle distribution was clear. Under high-temperature magnetization, BiFeO3 particles were increased and showed a certain order, but the change for room-temperature magnetization was not obvious. The addition of BiFeO3 increased the crystallinity of LDPE. Although the crystallinity decreased after magnetization, it was higher than that of LDPE. An AC test showed that the breakdown strength of the composite was higher than that of LDPE. The breakdown strength increased after magnetization. The increase of breakdown strength at high temperature was less, but the breakdown field strength of the composite was higher than that of LDPE. Compared with LDPE, the conductive current of the composite was lower. So, adding BiFeO3 could improve the dielectric properties of LDPE. The current of the composite decayed faster with time. The current decayed slowly after magnetization.

Energies ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4722
Author(s):  
Xiying Dai ◽  
Fuqiang Tian ◽  
Fei Li ◽  
Shuting Zhang ◽  
Zhaoliang Xing ◽  
...  

The charge transport in polypropylene was studied under DC electric fields at different temperatures. By the experimental measurement and simulation of the BCT model, we studied conduction currents, breakdown strength, and space charge distribution. In particular, the conduction characteristics under high temperature and high field, especially the conduction characteristics before the breakdown, were studied by systematic experiments, and the conduction characteristics and the breakdown mechanism were further studied by simulation. The results show that in the process of measuring conduction currents until breakdown, both high temperature and high electric field will promote charge transport. However, the free volume will increase at high temperature, which will easily lead to faster charge transport and breakdown. In the breakdown process at different temperatures, there are different breakdown mechanisms. At 20–60 °C, the electric breakdown process has mainly occurred in polypropylene film, and the breakdown strength is almost unchanged. At 80 °C, electric breakdown and thermal breakdown act together, and the charge transport is faster, and the breakdown field becomes smaller. Finally, we conclude that thermal stress plays a very important role in charge transport. In a high-temperature environment, the volume expansion of polypropylene will promote charge transport, and the insulation of polypropylene capacitor films will be damaged.


1989 ◽  
Vol 146 ◽  
Author(s):  
Paihung Pan ◽  
Ahmad Kermani ◽  
Wayne Berry ◽  
Jimmy Liao

ABSTRACTElectrical properties of thin (12 nm) SiO2 films with and without in-situ deposited poly Si electrodes have been studied. Thin SiO2 films were grown by the rapid thermal oxidation (RTO) process and the poly Si films were deposited by the rapid thermal chemical vapor deposition (RTCVD) technique at 675°C and 800°C. Good electrical properties were observed for SiO2 films with thin in-situ poly Si deposition; the flatband voltage was ∼ -0.86 V, the interface state density was < 2 × 1010/cm2/eV, and breakdown strength was > 10 MV/cm. The properties of RTCVD poly Si were also studied. The grain size was 10-60 rim before anneal and was 50-120 rim after anneal. Voids were found in thin (< 70 nm) RTCVD poly Si films. No difference in either SiO2 properties or poly Si properties was observed for poly Si films deposited at different temperatures.


Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1818
Author(s):  
Andrea Mura ◽  
Alessando Ricci ◽  
Giancarlo Canavese

Plastics are widely used in structural components where cyclic loads may cause fatigue failure. In particular, in some applications such as in vehicles, the working temperature may change and therefore the strength of the polymeric materials. In this work, the fatigue behavior of two thermoplastic materials (ABS and PC-ABS) at different temperatures has been investigated. In particular, three temperatures have been considered representing the working condition at room temperature, at low temperature (winter conditions), and high temperature (summer conditions and/or components close to the engine). Results show that high temperature have big impact on fatigue performance, while low temperatures may also have a slight positive effect.


Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1922 ◽  
Author(s):  
Lunzhi Li ◽  
Lisheng Zhong ◽  
Kai Zhang ◽  
Jinghui Gao ◽  
Man Xu

There is a long-standing puzzle concerning whether polyethylene blends are a suitable substitution for cable-insulation-used crosslinking polyethylene (XLPE) especially at elevated temperatures. In this paper, we investigate temperature dependence of mechanical, electrical properties of blends with 70 wt % linear low density polyethylene (LLDPE) and 30 wt % high density polyethylene (HDPE) (abbreviated as 70 L-30 H). Our results show that the dielectric loss of 70 L-30 H is about an order of magnitude lower than XLPE, and the AC breakdown strength is 22% higher than XLPE at 90 °C. Moreover, the dynamic mechanical thermal analysis (DMA) measurement and hot set tests suggest that the blends shows optimal mechanical properties especially at high temperature with considerable temperature stability. Further scanning electron microscope (SEM) observation and X-ray diffraction (XRD) analysis uncover the reason for the excellent high temperature performance and temperature stability, which can be ascribed to the uniform fine-spherulite structure in 70 L-30 H blends with high crystallinity sustaining at high temperature. Therefore, our findings may enable the potential application of the blends as cable insulation material with higher thermal-endurance ability.


Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1601
Author(s):  
Xing Wang ◽  
Hongxia Liu ◽  
Lu Zhao ◽  
Yongte Wang

The impact of stress relieved preoxide (SRPO) interface engineering on the physical and electrical properties of LaxAlyO films was investigated. It was proved that the SRPO pretreatment has little influence on the surface morphology of LaxAlyO films and the chemical bond composition of LaxAlyO/Si interface. However, the SRPO pretreated MIS capacitor displayed obvious improvement in decreasing the amount of trapped oxide charges and interfacial traps. As a result, a reduction of more than one order of magnitude in the gate leakage current density was obtained. The breakdown field strength and TDDB reliability of the LaxAlyO film treated with SRPO were also enhanced.


2015 ◽  
Vol 2015 (CICMT) ◽  
pp. 000116-000120 ◽  
Author(s):  
Takuya Hoshina ◽  
Mikio Yamazaki ◽  
Hiroaki Takeda ◽  
Takaaki Tsurumi

We precisely measured the dielectric breakdown strength of SrTiO3, CaTiO3, and CaZrO3 ceramics as a function of temperature, and revealed the dielectric breakdown mechanism of the ceramics. For the dielectric breakdown test, ceramics specimens with a lot of round-bottom holes were prepared. Using the specimens, the breakdown positions were stabilized and a reliability of breakdown strength was improved as well as the measurement efficiency. As a result of the dielectric breakdown tests, it was found that the dielectric breakdown strength decreased with increasing permittivity at room temperature and the permittivity dependence of breakdown strength obeyed Griffith type energy release rate model. At high temperature above 100ºC, the dielectric breakdown mechanism of SrTiO3 and CaTiO3 ceramics was explained by an intrinsic breakdown model. In contrast, an intrinsic dielectric breakdown of CaZrO3 ceramics didn't occur in the measurement temperature range up to 210ºC. To obtain a high dielectric breakdown strength at high temperature, the dielectric permittivity is required to be low to some extent and the defect concentration of oxygen vacancies should be minimized in the perovskite-structured oxide.


2015 ◽  
Vol 233-234 ◽  
pp. 265-268 ◽  
Author(s):  
Irene Iglesias ◽  
Rhimou El Kammouni ◽  
Kseniay Chichay ◽  
Manuel Vazquez ◽  
Valeria Rodionova

The objective of this work has been to analyze the high-temperature behavior of magnetically single-and biphase microwires because of its interest from fundamental and applications viewpoints. Two alloy compositions with amorphous structure covered by glass have been prepared as magnetically single phase microwires by quenching & drawing technique: CoFe-based with near zero saturation magnetostriction constant and Fe-based with positive saturation magnetostriction constant. The same wires were used as the core for magnetically biphase microwires. Second CoNi phase was deposited by electroplating. Magnitudes as saturation magnetization and hysteresis parameters are determined in the temperature range from room temperature up to 1200 K. We proceed to a comparative analysis of their magnetic behaviour at different temperatures as well as after cooling down to room temperature. Information on the Curie temperature of different phases and on the influence of heating process on the magnetic properties is thus derived.


2014 ◽  
Vol 975 ◽  
pp. 168-172
Author(s):  
Tiago Delbrücke ◽  
Igor Schmidt ◽  
Sergio Cava ◽  
Vânia Caldas Sousa

The addition of different dopants affects the densification and electrical properties of TiO2 based varistor ceramics. The nonlinear current (I) and voltage (V) characteristics of titanium dioxide are examined when doped with small quantities (0.5-2 at.%) of strontium oxide. This paper discusses the electrical properties of such an SrO doped TiO2 system, and demonstrates that some combinations produce electrical properties suitable for use as low voltage varistors. The high value of the nonlinear coefficient (α) (6.6), the breakdown field strength (Eb) (328 V/cm) and the leakage current (Ir) (0.22 mA/cm2) obtained in a system newly doped with SrO, are all adequate properties for application in low voltage varistors.


2017 ◽  
Vol 139 (4) ◽  
Author(s):  
Tai Ran Fu ◽  
Ji Bin Tian ◽  
Hua Sheng Wang

Soot aggregates frequently occur during combustion or pyrolysis of fuels. The radiative properties of soot aggregates at high temperature are important for understanding soot characteristics and evaluating heat transfer in combustion systems. However, few data for soot radiative properties at high temperature were available. This work experimentally investigated the apparent emissivity of the soot aggregate coating at high temperature using spectral and total hemispherical measurements. The soot aggregate coatings were formed on nickel substrates by a paraffin flame. The surface and inner morphology of the coatings were characterized by scanning electron microscope (SEM). The thickness of the coating was 30.16 μm so the contribution of the smooth nickel substrate to the apparent radiation from the coating could be neglected. The total hemispherical emissivity of the coating on the nickel substrate was measured using the steady-state calorimetric method at different temperatures. The spectral directional emissivity of the coating was measured for the wavelength of 0.38–16.0 μm at the room temperature. The measurements show that the total hemispherical emissivity decreases from 0.895 to 0.746 as the temperature increases from 438 K to 1052 K. The total hemispherical emissivity of the coating deposited on the nickel substrate is much larger than those of the nickel substrate and a nickel oxidization film. The measured spectral emissivity of the coating at the room temperature was used to theoretically calculate the total hemispherical emissivity at different temperatures by integration with respect to wavelength. The measured and calculated total hemispherical emissivities were similar, but their changes relative to temperature were completely opposite. This difference is due to the fact that the spectral emissivity of the coating is a function of temperature. The present results provide useful reference data for analyzing radiative heat transfer at high temperature of soot aggregates in combustion processes.


2016 ◽  
Vol 4 (4) ◽  
pp. 780-792 ◽  
Author(s):  
Smita Chaturvedi ◽  
Rabindranath Bag ◽  
Vasant Sathe ◽  
Sulabha Kulkarni ◽  
Surjeet Singh

Ho-doped sample simultaneously exhibits high-coercivity and enhanced remnant magnetization with a polar R3c symmetry at room temperature. The onset of R3c to Pnma phase transition is observed at high temperatures in the Ho-doped samples.


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