Influence of 1-Butanol Additives on Palm Biodiesel Fuel Characteristics and Low Temperature Flow Properties

2013 ◽  
Vol 465-466 ◽  
pp. 130-136 ◽  
Author(s):  
Obed M. Ali ◽  
Rizalman Mamat ◽  
Che Ku M. Faizal
Keyword(s):  
Palm Oil ◽  
Diesel Engines ◽  
Energy Demand ◽  
Pour Point ◽  
Alternative Fuels ◽  
Energy Content ◽  
Methyl Esters ◽  
Fuel Properties ◽  
Biodiesel Production ◽  
Biodiesel Fuel

Diesel engines are widely used in almost all professions and cannot be dispensed with in the near future. Now the fossil fuels which are mainly used in diesel engines are depleting continually accompanied by increasing consumption and prices, there is the need to find alternative fuel to fulfil the worlds energy demand. Alternative fuels like biodiesel, are being used as effective alternative for diesel. The feasibility of biodiesel production from palm oil was investigated with respect to its fuel properties. Though biodiesel can replace diesel satisfactorily, problems related to fuel properties persist. In this study an oxygenated additive 1-butanol (BU) was blended with palm oil biodiesel (POME) in the ratios of 1%, 3%, 5% and 7% and tested for their properties improvement. These blends were tested for energy content and various fuel properties according to ASTM standards. Qualifying of the effect of additive on palm biodiesel fuel properties can serve the researchers who work on biodiesel fuels to indicate the fuel suitability for diesel engines according to fuel standards. Blends of BU in POME resulted in an improvement in acid value, viscosity, density and pour point with increasing content of BU in the blend. Further improvement in the pour point temperature of the palm oil methyl esters 1-butanol blends (B-BU) at 7°C can be achieved by adding 7% BU additive to POME, accompanied by 8.07% decrease in energy content of biodiesel.

Characterization of Blended Biodiesel Fuel Properties with Small Portion of Butanol as a Fuel Additive

2013 ◽  
Vol 465-466 ◽  
pp. 137-141 ◽  
Author(s):  
Obed M. Ali ◽  
Rizalman Mamat ◽  
Che Ku M. Faizal
Keyword(s):  
Palm Oil ◽  
Energy Demand ◽  
Fossil Fuels ◽  
Acid Value ◽  
Fuel Properties ◽  
Biodiesel Production ◽  
Biodiesel Fuel ◽  
Fuel Additive ◽  
Density Maximum ◽  
Maximum Decrease

The increasing energy demand challenge, in addition to the crises of mineral oils depletion that becoming a very serious topic. As the main fuel used in energy production for all scopes of life now is the fossil fuels, there is an urgent need to find out an alternative fuel to fulfill the energy demand of the world. The feasibility of biodiesel production from palm oil was investigated with respect to its fuel properties and blending characteristics with petroleum diesel. Though biodiesel can replace diesel satisfactorily, problems related to fuel properties persist. In this study an oxygenated additive butanol (BU) was added to palm oil biodiesel (POME)-diesel blend B50 (50% POME + 50% diesel) in the ratios of 1%, 3%, 5% and 7% and tested for their properties improvement. The results showed slight improvement in acid value, significant viscosity and density. Maximum decrease in pour point by 6 °C at 5% butanol, on the other hand maximum decrease in energy contenent about 11% at 7% butanol compare to blended fuel B50.

High Performance Alternative Diesel Engine Fuel using Modified Rice Straw Catalyst

2020 ◽  
Author(s):  
Rehab Metwally ◽  
hassan Abu Hashish ◽  
Haitham Abd El-Samad ◽  
Mostafa Awad ◽  
Ghada Kadry
Keyword(s):  
Rice Straw ◽  
Conversion Efficiency ◽  
Diesel Engines ◽  
High Performance ◽  
Alternative Fuels ◽  
Fossil Fuels ◽  
Methyl Esters ◽  
Agricultural Waste ◽  
Biodiesel Production ◽  
Engine Fuel

Abstract Background: The world depends almost on fossil fuels. This leads to depletion of oil and an increase in environmental pollution. Therefore, the researchers search to find alternative fuels. Waste cooking oil (WCO) was selected as feedstock for biodiesel production to eliminates the pollution problems. The agricultural waste is very big and without cost, this leads to the use of the rice straw in preparing a catalyst for biodiesel production. Results: The reusability of the acidic catalyst confirmed that the conversion efficiency was high until after 8 cycles of the production. The highest conversion efficiency of the converting WCO extended to 90.38% with 92.5% maximum mass yield and methyl ester content 97.7% wt. at the optimized conditions. The result was indicating that B15 is the best blend for thermal efficiency and specific fuel consumption. All emission concentrations decrease with increasing the engine load, especially for B15 fuels compared to the diesel oil.Conclusion: The novelty of this paper is assessing the methyl esters from the local WCO as an alternative fuel for diesel engines using a heterogeneous catalyst based on the agricultural waste. The performance of the diesel engines and its exhaust emissions have been experimentally investigated with the produced biodiesel of WCO as a blend (B10, B15, and B20) compared to the diesel.

Lipase-catalysed production of biodiesel fuel from some Nigerian lauric oils

2000 ◽  
Vol 28 (6) ◽  
pp. 979-981 ◽  
Author(s):  
R. D. Abigor ◽  
P. O. Uadia ◽  
T. A. Foglia ◽  
M. J. Haas ◽  
K. C. Jones ◽  
...  
Keyword(s):  
Cloud Point ◽  
Pour Point ◽  
Methyl Esters ◽  
Palm Kernel ◽  
Coconut Oil ◽  
Fuel Properties ◽  
Biodiesel Fuel ◽  
Alkyl Esters ◽  
Palm Kernel Oil ◽  
Kernel Oil

Fatty acids esters were produced from two Nigerian lauric oils, palm kernel oil and coconut oil, by transesterification of the oils with different alcohols using PS30 lipase as a catalyst. In the conversion of palm kernel oil to alkyl esters (biodiesel), ethanol gave the highest conversion of 72%, t-butanol 62%, 1-butanol 42%, n-propanol 42% and iso-propanol 24%, while only 15% methyl ester was observed with methanol. With coconut oil, 1-butanol and iso-butanol achieved 40% conversion, 1-propanol 16% and ethanol 35%, while only traces of methyl esters were observed using methanol. Studies on some fuel properties of palm kernel oil and its biodiesel showed that palm kernel oil had a viscosity of 32.40 mm2/s, a cloud point of 28°C and a pour point of 22°C, while its biodiesel fuel had a viscosity of 9.33 mm2/s, a cloud point of 12°C and a pour point of 8°C. Coconut oil had a viscosity of 28.58 mm2/s, a cloud point of 27°C and a pour point of 20°C, while its biodiesel fuel had a viscosity of 7.34 mm2/s, a cloud point of 5°C and a pour point of - 8°C. Some of the fuel properties compared favourably with international biodiesel specifications.

scholarly journals A Comprehensive Review on Oil Extraction and Biodiesel Production Technologies

2021 ◽  
Vol 13 (2) ◽  
pp. 788
Author(s):  
Zulqarnain ◽  
Muhammad Ayoub ◽  
Mohd Hizami Mohd Yusoff ◽  
Muhammad Hamza Nazir ◽  
Imtisal Zahid ◽  
...  
Keyword(s):  
Energy Demand ◽  
Alternative Fuels ◽  
Fossil Fuels ◽  
Significant Proportion ◽  
Waste Cooking Oil ◽  
Oil Extraction ◽  
Biodiesel Production ◽  
Waste Oils ◽  
Biodiesel Synthesis ◽  
Production Technologies

Dependence on fossil fuels for meeting the growing energy demand is damaging the world’s environment. There is a dire need to look for alternative fuels that are less potent to greenhouse gas emissions. Biofuels offer several advantages with less harmful effects on the environment. Biodiesel is synthesized from the organic wastes produced extensively like edible, non-edible, microbial, and waste oils. This study reviews the feasibility of the state-of-the-art feedstocks for sustainable biodiesel synthesis such as availability, and capacity to cover a significant proportion of fossil fuels. Biodiesel synthesized from oil crops, vegetable oils, and animal fats are the potential renewable carbon-neutral substitute to petroleum fuels. This study concludes that waste oils with higher oil content including waste cooking oil, waste palm oil, and algal oil are the most favorable feedstocks. The comparison of biodiesel production and parametric analysis is done critically, which is necessary to come up with the most appropriate feedstock for biodiesel synthesis. Since the critical comparison of feedstocks along with oil extraction and biodiesel production technologies has never been done before, this will help to direct future researchers to use more sustainable feedstocks for biodiesel synthesis. This study concluded that the use of third-generation feedstocks (wastes) is the most appropriate way for sustainable biodiesel production. The use of innovative costless oil extraction technologies including supercritical and microwave-assisted transesterification method is recommended for oil extraction.

scholarly journals Box-Behnken Design for Optimization on Biodiesel Production from Palm Oil and Methyl Acetate using Ultrasound Assisted Interesterification Method

2021 ◽  
Author(s):  
Mahfud Mahfud ◽  
Ansori Ansori
Keyword(s):  
Palm Oil ◽  
Energy Demand ◽  
Alternative Energy ◽  
Methyl Acetate ◽  
Catalyst Concentration ◽  
Separation Process ◽  
Operating Conditions ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Box Behnken Design

Energy demand is currently increasing in line with technological and economic developments, but not accompanied by an increase in energy reserves. So we need another alternative energy that can be renewed, namely biodiesel. Biodiesel has been produced commercially through the transesterification from vegetable oil with methanol using catalyst that produces esters and glycerol. The formation of glycerol which is by-product can reduce its economic value, so it needs to be done the separation process. Therefore, a new route is proposed in this study, namely the interesterification reaction (non-alcoholic route) using methyl acetate as an alkyl group supplier and potassium methoxide catalyst. The superiority of the product produced by the interesterification reaction is biodiesel with triacetin byproducts which have an economical value and can be added to biodiesel formulations because of their solubility so that no side product separation process is needed. To increase the yield of biodiesel and the interesterification rate, the ultrasound method was used in this study. To optimize the factors that affect the interesterification reaction (molar ratio of methyl acetate to oil, catalyst concentration, temperature, and interesterification time), the Box-Behnken design (BBD) is used. Optimal operating conditions to produce the yields of biodiesel of 98.64 % are at molar ratio of methyl acetate to palm oil of 18.74, catalyst concentration of 1.24 %, temperature of 57.84 °C, and interesterification time of 12.69 minutes.

The effect of polymers and surfactants on the pour point of palm oil methyl esters

2007 ◽  
Vol 109 (4) ◽  
pp. 440-444 ◽  
Author(s):  
Cheah Han Sern ◽  
Choo Yuen May ◽  
Zuriati Zakaria ◽  
Rusli Daik ◽  
Cheng Sit Foon
Keyword(s):  
Palm Oil ◽  
Pour Point ◽  
Methyl Esters

Parameters Influences during Biodiesel Production

2010 ◽  
Vol 44-47 ◽  
pp. 4167-4175
Author(s):  
Anita Kovač Kralj ◽  
Davorin Kralj
Keyword(s):  
Aqueous Solution ◽  
Sodium Hydroxide ◽  
Diesel Engines ◽  
Renewable Resources ◽  
Batch Reactor ◽  
Methyl Esters ◽  
Alternative Fuel ◽  
Biodiesel Production ◽  
Compression Ignition ◽  
Diesel Production

Bio-diesel is a clean burning alternative fuel, produced from domestic, renewable resources. Bio-diesel can be blended at any level with petroleum diesel to create a bio-diesel blend. It can be used in compression-ignition (diesel) engines with little or no modification. Bio-diesel is simple to use, biodegradable, non-toxic, and essentially free of sulphur and aromatics. This paper presents the two following identifiable topic areas as key themes: 1. preparation of an aqueous solution of sodium hydroxide – as a catalyst, which can be activated by the most MeO- active groups, and can therefore be converted to methyl esters (biodiesel) from triglyceride. Methoxide (MeO-) was produced from sodium hydroxide (NaOH) and methanol (MeOH) in a batch reactor: NaOH + MeOH = H2O + Na+ + MeO-. During bio-diesel production, methoxide is incorrectly referred to as the product of mixing methanol and sodium hydroxide. An aqueous solution of sodium hydroxide – was prepared as a catalyst, by using different amounts of water at the same temperature. The reaction with lower water took place at the highest and quickest degrees of NaOH conversion and thus more MeO- active groups. The water was effective as an inhibitor.

Performance and Emission Characteristics of Diesel Engine Running on Blended Palm Oil

2013 ◽  
Vol 795 ◽  
pp. 164-169 ◽  
Author(s):  
A.M. Iqbal ◽  
Z.A. Zainal ◽  
M. Mazlan ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
M.S. Salim
Keyword(s):  
Diesel Engine ◽  
Palm Oil ◽  
Energy Demand ◽  
Fossil Fuel ◽  
Energy Content ◽  
High Energy ◽  
Emission Characteristics ◽  
Performance And Emission ◽  
Suitable Climate ◽  
New Energy

Rapid increasing of industrialization and motorization has led arising of petroleum and energy demand. This pursue a new energy blends to cater the depletion of fossil fuel and the environmental degradation condition. Malaysia is blessed, which has suitable climate to plant alternative fuel (palm oil) and become one of the largest exporters to the world. Palm oil in its refined form as cooking oil has high energy content which can be adopted as an alternative to the petroleum based fuel. This paper evaluates the performance and emission characteristics of refined palm oil (RPO) as a fuel to the diesel engine. Palm oil and its blends composition with 20%, 40%, 60% as well as pure palm oil (100%) and diesel were tested separately under various engine loads. Five series of tests data on each type of fuel were analyzed and compared. Moreover, by increasing the percentage of RPO in blends would lead a character of higher percentage in density and viscosity. Studied revealed that the small percentage of RPO composition promises a good thermal efficiency together with the emission released.

Evaluation of Palm Biodiesel - Diesel Blending Properties, Storage Stability and Corrosion Behavior

2014 ◽  
Vol 695 ◽  
pp. 265-268
Author(s):  
Ramli Mat ◽  
Wan Nurul Aini Wan Nor Yuhaidi ◽  
Mohd Johari Kamaruddin ◽  
Onn Hassan
Keyword(s):  
Corrosion Rate ◽  
Palm Oil ◽  
Diesel Engines ◽  
Pour Point ◽  
Kinematic Viscosity ◽  
Storage Time ◽  
Slight Modification ◽  
Fuel Blend ◽  
Diesel Fuels ◽  
Average Corrosion Rate

Palm Biodiesel, which can be produced from transesterification palm oil with methanol, is an alternative fuel for diesel engines. It can be mixed with diesel fuels and used in diesel engines with no or slight modification. Therefore, in this study, commercially available diesel fuel was blended with biodiesel produced from transesterification of palm oil. The stability of the pure palm biodiesel (B100) was investigated over a storage time of 2, 4 and 6 months. The study assessed the corrosion rate of metals exposed to palm biodiesel. The kinematic viscosity, density and flash points of the blends increased with biodiesel amount in the fuel blend. However, pour point of the blends decreased as the amount of biodiesel in the blends is increased. Kinematic viscosity, pour point and flash point slightly increased with storage time. The average corrosion rate for copper is 0.5341 mpy, 0.2438 mpy for aluminium and 0.1802 mpy for mild steel.

scholarly journals The Performance and Exhaust Emissions of a Diesel Engine Fuelled with Calophyllum inophyllum—Palm Biodiesel

Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 597 ◽  
Author(s):  
Damanik ◽  
Ong ◽  
Mofijur ◽  
Tong ◽  
Silitonga ◽  
...  
Keyword(s):  
Diesel Engine ◽  
Methyl Ester ◽  
Palm Oil ◽  
Alternative Fuels ◽  
Acid Methyl Ester ◽  
International Standards ◽  
Biodiesel Production ◽  
Calophyllum Inophyllum ◽  
Harmful Emission ◽  
High Heating Value

Nowadays, increased interest among the scientific community to explore the Calophyllum inophyllum as alternative fuels for diesel engines is observed. This research is about using mixed Calophyllum inophyllum-palm oil biodiesel production and evaluation that biodiesel in a diesel engine. The Calophyllum inophyllum–palm oil methyl ester (CPME) is processed using the following procedure: (1) the crude Calophyllum inophyllum and palm oils are mixed at the same ratio of 50:50 volume %, (2) degumming, (3) acid-catalysed esterification, (4) purification, and (5) alkaline-catalysed transesterification. The results are indeed encouraging which satisfy the international standards, CPME shows the high heating value (37.9 MJ/kg) but lower kinematic viscosity (4.50 mm2/s) due to change the fatty acid methyl ester (FAME) composition compared to Calophyllum inophyllum methyl ester (CIME). The average results show that the blended fuels have higher Brake Specific Fuel Consumption (BSFC) and NOx emissions, lower Brake Thermal Efficiency (BTE), along with CO and HC emissions than diesel fuel over the entire range of speeds. Among the blends, CPME5 offered better performance compared to other fuels. It can be recommended that the CPME blend has great potential as an alternative fuel because of its excellent characteristics, better performance, and less harmful emission than CIME blends.

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