Phenol Degradation Characteristics and Immobilization of Acinetobacte Strain HY1

2012 ◽  
Vol 549 ◽  
pp. 172-176 ◽  
Author(s):  
Jian Bo Jia ◽  
Yong Yang ◽  
Hu Peng Yu
Keyword(s):  
Degradation Rate ◽  
Phenol Degradation ◽  
Phenol Concentration ◽  
Liquid Volume ◽  
Phenol Solution ◽  
Immobilized Bacteria ◽  
Culture Time

The phenol degradation characteristics and immobilization of an Acinetobacte strain HY1 were carried out. The effects of phenol concentration, temperature, pH and NaCl dosage on the growth of HY1 and phenol degradation rate were investigated. The results showed that When the bacteria was cultured in 0.5 g/L phenol solution at 35 °C and pH 7.5 with shaking speed 120 r/min, liquid volume in flask 50 mL and inoculation amount 20 % for 6 h, the degradation rate of phenol was over 95 %. Compared with free bacteria, immobilized bacteria had a higher phenol degradation rate after a long culture time.

Degradation of Phenol by Fe3+ Doped Nano-TiO2 Photocatalyst

2013 ◽  
Vol 859 ◽  
pp. 361-364 ◽  
Author(s):  
Jing Wang ◽  
Du Shu Huang ◽  
Wei Liu ◽  
Qing Shan Pan ◽  
Yong Min
Keyword(s):  
Degradation Rate ◽  
Annealing Temperature ◽  
Sol Gel ◽  
Phenol Degradation ◽  
Nano Tio2 ◽  
Phenol Solution ◽  
Sol Gel Process ◽  
Two Peaks ◽  
Degradation Properties ◽  
Better Than

Degradation properties of phenol using nano-TiO2 as photocatalyst in aqueous solution were investigated. The effect of annealing temperature and ionic modification on the degradation was studied. The results showed that, 500 °C annealed TiO2 was better than 700 °C annealed. Photocatalyst nano-TiO2 material doped with Fe3+ was prepared quickly by sol-gel process and was used as photocatalyst to degrade phenol solution of 100mg/L under UV irradiation for 3 hours. UV spectrophotometer testing was made and found that two peaks at 210 nm and 270 nm were significantly become low, indicating that the phenol has been degraded. The phenol degradation rate was 94.18%.

Accelerated Phenol Removal by Amplifying the Metabolic Pathway with a Recombinant Plasmid Encoding Catechol 2, 3 Oxygenase

1992 ◽  
Vol 26 (9-11) ◽  
pp. 2191-2194 ◽  
Author(s):  
M. Fujita ◽  
M. Ike ◽  
T. Kamiya
Keyword(s):  
Metabolic Pathway ◽  
Recombinant Plasmid ◽  
Removal Rate ◽  
Phenol Degradation ◽  
Wild Strain ◽  
Phenol Concentration ◽  
Phenol Removal

The metabolic pathway of the phenol degradation in Pseudomonasputida BH was amplified by introducing the recombinant plasmid containing catechol 2,3 oxygenase gene isolated fron the chromosome of BH. This strain could degrade phenol and grow much faster than the wild strain at the phenol concentration of 100mg/L. This strain seems to accelerate the phenol removal rate if it is applied to the treatment of wastewater containing phenol.

scholarly journals Photodegradation of Phenolic Compounds from Water in the Presence of a Pd-Containing Exhausted Adsorbent

2020 ◽  
Vol 10 (23) ◽  
pp. 8440
Author(s):  
Lavinia Lupa ◽  
Laura Cocheci ◽  
Bogdan Trica ◽  
Adina Coroaba ◽  
Adriana Popa
Keyword(s):  
Phenol Degradation ◽  
Magnesium Silicate ◽  
Degradation Process ◽  
Liquid Ratio ◽  
Phenol Solution ◽  
Secondary Sources ◽  
Great Economic Importance ◽  
Phenol Photodegradation ◽  
Cyphos Il 101 ◽  
Solid Liquid

A closed-cycle technology regarding the use of an exhausted Pd-based adsorbent as a photocatalyst in the degradation process of phenol is presented. Pd (II) represents a precious metal of great economic importance. Its obtained from natural sources become more difficult to achieve. Therefore, also considering the regulations of the “circular economy,” its recovery from secondary sources turn out to be a stringent issue in the last years. Pd(II) ions are removed from aqueous solution through adsorption onto Florisil (an inorganic solid support—magnesium silicate) impregnated with Cyphos IL 101 (trihexyl tetradecyl phosphonium chloride). It was observed that the presence of the ionic liquid (IL) in the adsorbent structure doubles the adsorption efficiency of the studied materials. The newly obtained Pd-based photocatalyst was exhaustively characterized and was used in the degradation process of phenol from aqueous solutions. The phenol degradation process was studied in terms of the nature of the photocatalyst used, time of photodegradation and solid: liquid ratio. It was observed that both the presence of IL and Pd lead to an increase in the efficiency of the phenol degradation process. The new Pd-based photocatalyst could be efficiently used in more cycles of phenol photodegradation processes. When is used as a photocatalyst the Florisil impregnated with IL and loaded with 2 mg/g of Pd, a degree of mineralization of 93.75% is obtained after 180 min of irradiation of a phenol solution having a concentration of 20 mg/L and using a solid:liquid ratio = 1:1.

Phenol Degradation by UV-Enhanced Catalytic Wet Peroxide Oxidation Process

2014 ◽  
Vol 17 (1) ◽  
Author(s):  
Peng Liu ◽  
Chaolin Li ◽  
Qi Han ◽  
Gang Lu ◽  
Xiaoqing Dong ◽  
...  
Keyword(s):  
Oxidation Process ◽  
Phenol Degradation ◽  
Cod Removal ◽  
Peroxide Oxidation ◽  
Homogeneous Catalysts ◽  
Phenol Solution ◽  
Wet Peroxide Oxidation ◽  
Catalytic Wet Peroxide Oxidation

AbstractIn this study, degradation of phenol solution by the ultraviolet-enhanced catalytic wet peroxide oxidation process (UV-CWPO) were evaluated via COD removal. Six kinds of homogeneous catalysts (Fe

Study of Porous Plate Hydrodynamic Cavitation Device for P-Nitrophenol

2014 ◽  
Vol 1015 ◽  
pp. 385-388 ◽  
Author(s):  
Jie Deng
Keyword(s):  
Waste Water ◽  
Ph Value ◽  
Phenol Degradation ◽  
Porous Plate ◽  
Hydrodynamic Cavitation ◽  
Phenol Solution ◽  
Initial Ph ◽  
Relationship Of ◽  
The Relationship ◽  
Water Waste

Design a set of practical and effective hydraulic cavitation experiment device, hydraulic cavitation reactor, using porous plate for nitro phenol solution to simulate wastewater, respectively in different cavitation number initial pH value, initial concentration of the waste water, waste water, the cycle time, use different types of porous surface processing and analysis, through the experimental research, it is concluded that these factors and the relationship of nitro phenol degradation rate.

scholarly journals Phenol Removal by a Novel Non-Photo-Dependent Semiconductor Catalyst in a Pilot-Scaled Study: Effects of Initial Phenol Concentration, Light, and Catalyst Loading

2014 ◽  
Vol 2014 ◽  
pp. 1-8
Author(s):  
Xiao Chen ◽  
Yan Liang ◽  
Xuefei Zhou ◽  
Yanling Zhang
Keyword(s):  
Titanium Dioxide ◽  
Uv Radiation ◽  
Phenol Degradation ◽  
Phenol Concentration ◽  
Catalyst Loading ◽  
Phenol Removal ◽  
Operational Parameters ◽  
Initial Concentration ◽  
Light Area ◽  
Initial Phenol Concentration

A novel non-photo-dependent semiconductor catalyst (CT) was employed to degrade phenol in the present pilot-scaled study. Effect of operational parameters such as phenol initial concentration, light area, and catalyst loading on phenol degradation, was compared between CT catalyst and the conventional photocatalyst titanium dioxide. CT catalyst excelled titanium dioxide in treating and mineralizing low-level phenol, under both mild UV radiation and thunder conditions of nonphoton. The result suggested that CT catalyst could be applied in circumstances when light is not easily accessible in pollutant-carrying media (e.g., particles, cloudy water, and colored water).

Effect of Ultrasonic Intensity on the Degradation of Phenol Solution

2011 ◽  
Vol 393-395 ◽  
pp. 1173-1176 ◽  
Author(s):  
Mei Juan Yin ◽  
Peng Cui ◽  
Zhi Hu ◽  
Ya Zhong Chen ◽  
Wei Xiong
Keyword(s):  
Degradation Rate ◽  
Vertical Direction ◽  
Power Input ◽  
Ultrasonic Frequency ◽  
Ultrasonic Power ◽  
Phenol Solution ◽  
Ultrasonic Bath ◽  
Ultrasonic Degradation ◽  
Ultrasonic Parameters ◽  
Ultrasonic Intensity

Effect of ultrasonic intensity on the degradation of phenol solution is investigated by changing the nominal ultrasonic power, ultrasonic frequency and the position of reactor. The actual ultrasonic intensity (I) that reaches reactor is measured by ultrasonic power measuring meter. It can be found that the ultrasonic intensity varies with ultrasonic parameters. With the nominal power input improving from 60 W to 150 W, the ultrasonic intensity rises from 0.21 W•cm-2 to 1.06 W•cm-2 and the degradation rate of phenol solution (η) increases from 21.7% to 43.7%. However, when I reaches the highest value of 1.71 W•cm-2 at the frequency of 100 kHz, η decreases to the lowest value of 21.5%. The ultrasonic intensity distribution is uneven in the ultrasonic bath and η increases with an increase of I in the vertical direction. The ultrasonic degradation of phenol solution is affected by ultrasonic intensity, but η doesn’t definitely increase with an increase of ultrasonic intensity.

scholarly journals Enhanced Photocatalytic Degradation of Phenol Using Urchin-Like ZnO Microrod-Reduced Graphene Oxide Composite under Visible-Light Irradiation

2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
S. Mary Margaret ◽  
Albin John P. Paul Winston ◽  
S. Muthupandi ◽  
P. Shobha ◽  
P. Sagayaraj
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Phenol Degradation ◽  
Hydrothermal Process ◽  
Light Irradiation ◽  
Light Illumination ◽  
Order Kinetic ◽  
Phenol Solution ◽  
Vis Spectroscopy

In this study, visible-light-driven ZnO microrod-rGO heterojunction composites were successfully synthesized via a facile and scalable hydrothermal process. The prepared photocatalyst heterojunction was examined using different techniques including XRD, SEM, FTIR, UV-Vis spectroscopy, and TGA to reveal their crystal phase, morphology, and other optical properties. The photocatalytic performance of the obtained ZnO-rGO composites was measured by the photodegradation of phenol under visible light illumination. The addition of graphene over the catalyst exhibited an enhanced photocatalytic activity for phenol degradation due to its high surface area and decreasing rate of electron-hole separation. Kinetic studies proved that the degradation of phenol process happened by following the pseudo-first-order kinetic model. The effective conditions for degradation of phenol using ZnO-rGO composite were 0.2 g L-1catalyst dose, pH -4, and initial concentration 20 ppm of phenol solution. Comparing with ZnO microrods, the heterojunction composite degraded the organic pollutants of phenol solution up to 84.2% of efficiency displaying the highest photocatalytic activity, whereas urchin-like ZnO catalyst exhibited much less photocatalytic activity for phenol degradation under visible light irradiation. This result envisages immense properties, showing a great potential industrial application for the removal of phenolic wastewater.

scholarly journals A comparative study of the performance of zinc oxide and iron oxide doped-zinc oxide photocatalysts toward the oxidization of phenol under UV-radiation and sunlight

2021 ◽  
Vol 899 (1) ◽  
pp. 012069
Author(s):  
M V Karavasilis ◽  
M A Theodoropoulou ◽  
C D Tsakiroglou
Keyword(s):  
Zinc Oxide ◽  
Comparative Analysis ◽  
Iron Oxide ◽  
Degradation Rate ◽  
Phenol Degradation ◽  
Cost Effective ◽  
Immobilized Catalyst ◽  
Cost Effective Method ◽  
Different Types ◽  
Uva Light

Abstract In the present work, a comparative analysis of the photocatalytic degradation of phenol, was done for two different types of immobilized photocatalytic nanoparticles immobilized on 5mm sodalime beads by a facile and cost-effective method: (1) Zinc oxide (ZnO) and (2) Iron doped Zinc Oxide (Fe-ZnO). Tests of phenol degradation by using the immobilized catalyst were conducted in batch photoreactors under UVA light of 22W and summertime sunlight. These tests allowed us to evaluate the phenol degradation rate and photocatalyst durability under controlled conditions.

Incidence of wave-frequency on the reaction rates during ultrasonic wastewater treatment

1997 ◽  
Vol 35 (4) ◽  
pp. 175-180 ◽  
Author(s):  
Christian Petrier ◽  
Anne Francony
Keyword(s):  
Carbon Tetrachloride ◽  
Degradation Rate ◽  
Phenol Degradation ◽  
Chemical Properties ◽  
Reaction Rates ◽  
Ultrasonic Waves ◽  
Peroxide Formation ◽  
Hydrogen Peroxide Formation ◽  
Physical And Chemical ◽  
And Chemical Properties

Organic compounds in aqueous solution submitted to an ultrasonic irradiation behave differently according to their physical and chemical properties. In this work, degradation rate of phenol and carbon tetrachloride, has been studied at different frequencies, 20 kHz, 200 kHz, 500 kHz and 800 kHz. Whatever the frequency, it's easier to decompose CCl4 than phenol by means of ultrasonic waves. It is shown that the rates of reactions involving hydroxyl radicals (hydrogen peroxide formation and phenol degradation) have a maximal value at 200 kHz. The best yield observed at 200 kHz for the phenol degradation may be the result of a better HO° radicals availability outside of the bubble of cavitation. The degradation rate for carbon tetrachloride which decomposes into the bubble of cavitation increases with the frequency.

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