Effect of Sintering Temperature on the Oxygen Adsorption Property of Ba0.8Sr0.2Fe0.5Co0.5O3-δ

2013 ◽  
Vol 710 ◽  
pp. 72-75
Author(s):  
Meng Ni Wang ◽  
Dan Dan Yu ◽  
Qiao Jun ◽  
Xiang Hong Huang
Keyword(s):  
Elevated Temperature ◽  
Mass Loss ◽  
Adsorption Capacity ◽  
Sintering Temperature ◽  
Adsorption Property ◽  
Oxygen Adsorption ◽  
Citrate Method ◽  
Sorption Ability ◽  
Different Temperatures ◽  
Tga Analysis

A serial of Ba0.8Sr0.2Fe0.5Co0.5O3-δoxides were prepared by the citrate method and sintered at different temperatures from 400°C to 900°C. The mass loss of various samples with elevated temperature was characterized by TGA analysis. The results indicated that several kinds of compositions lost from the samples in the elevated temperature process. The oxygen adsorption capacity of these samples over a temperature range of 200-900°C were calculated by the data of TGA experiment. The sample sintered at 400°C exhibited the best oxygen sorption ability.

Influence of Sintering Temperature on the Structure of SrFeCoO3-δ Oxide

2012 ◽  
Vol 550-553 ◽  
pp. 2719-2722
Author(s):  
Su Qin Chen ◽  
Xiang Hong Huang
Keyword(s):  
Particle Size ◽  
Perovskite Structure ◽  
Sintering Temperature ◽  
Perovskite Phase ◽  
Experimental Results ◽  
Citrate Method ◽  
Different Temperatures ◽  
Diffraction Peaks

SrFeCoO3-δ oxides have been synthesized by citrate method and the effect of sintering temperature on the structure of the samples has been analyzed. The experimental results show that the samples sintered at different temperatures are mainly composed of SrFe0.5Co0.5O3 with perovskite structure. The impure phases decrease and the intensity of the diffraction peaks of the SrFe0.5Co0.5O3 perovskite phase increases with the increase of the sintering temperature. High pure SrFe0.5Co0.5O3 perovskite phase can be obtained after sintering at 1000°C and 1100°C. The particle size with irregular morphology increases with the increase of the sintering temperature.

scholarly journals Characterizing Bacterial Cellulose Produced byKomagataeibacter sucrofermentans H-110 on Molasses Medium and Obtaining a Biocomposite Based on It for the Adsorption of Fluoride

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1422
Author(s):  
Viktor V. Revin ◽  
Alexander V. Dolganov ◽  
Elena V. Liyaskina ◽  
Natalia B. Nazarova ◽  
Anastasia V. Balandina ◽  
...  
Keyword(s):  
Composite Material ◽  
Adsorption Capacity ◽  
Bacterial Cellulose ◽  
Functional Materials ◽  
Degree Of Crystallinity ◽  
Maximum Adsorption Capacity ◽  
Fluoride Ions ◽  
Sorption Ability ◽  
Wide Range ◽  
Biocomposite Material

Currently, there is an increased demand for biodegradable materials in society due to growing environmental problems. Special attention is paid to bacterial cellulose, which, due to its unique properties, has great prospects for obtaining functional materials for a wide range of applications, including adsorbents. In this regard, the aim of this study was to obtain a biocomposite material with adsorption properties in relation to fluoride ions based on bacterial cellulose using a highly productive strain of Komagataeibacter sucrofermentans H-110 on molasses medium. Films of bacterial cellulose were obtained. Their structure and properties were investigated by FTIR spectroscopy, NMR, atomic force microscopy, scanning electron microscopy, and X-ray structural analysis. The results show that the fiber thickness of the bacterial cellulose formed by the K. sucrofermentans H-110 strain on molasses medium was 60–90 nm. The degree of crystallinity of bacterial cellulose formed on the medium was higher than on standard Hestrin and Schramm medium and amounted to 83.02%. A new biocomposite material was obtained based on bacterial cellulose chemically immobilized on its surface using atomic-layer deposition of nanosized aluminum oxide films. The composite material has high sorption ability to remove fluoride ions from an aqueous medium. The maximum adsorption capacity of the composite is 80.1 mg/g (F/composite). The obtained composite material has the highest adsorption capacity of fluoride from water in comparison with other sorbents. The results prove the potential of bacterial cellulose-based biocomposites as highly effective sorbents for fluoride.

Effect of Reinforcement and Tribological Behaviour of AA 7068 Hybrid Composites Manufactured through Powder Metallurgy Techniques

2017 ◽  
Vol 867 ◽  
pp. 19-28 ◽  
Author(s):  
J. Lakshmipathy ◽  
Subburaj Rajesh Kannan ◽  
K. Manisekar ◽  
S. Vinoth Kumar
Keyword(s):  
Sintering Temperature ◽  
Hybrid Composites ◽  
High Strength ◽  
Phase Changes ◽  
Wear Loss ◽  
X Ray Diffraction ◽  
Tribological Behaviour ◽  
Different Temperatures ◽  
Pin On Disc ◽  
Sliding Distance

In this article, an attempt was made to study the mechanical behaviour of AA7068 - 6 vol. % of MoS2 - X vol. % of WC (X = 0, 5, 10 and 15) hybrid aluminium composites produced by blend–press–sinter methodology. Compacted Powders (700MPa) were sintered at different temperatures (450 0c, 500 0c and 550 0c ) in order to find the influence of sintering temperature on mechanical properties and tribological behavior of AA7068 hybrid composites.The sintered samples have been characterized by x-ray diffraction (XRD) method for identification of phases and also to investigate the phase changes. The change in density, hardness and porosity values of composites were reported. The composite with 15 vol. % of tungsten carbide and 6 vol. % of MoS2 showed the highest hardness and density at the sintering temperature range of 550 0c. Pin-on-disc type apparatus was used for determining the wear loss occurring at different conditions. The hybridization of the two reinforcements enhanced the wear resistance of the composites, especially under high applied load, sliding distance and sliding speeds. Due to this, the hybrid aluminium composites can be considered as an outstanding material where high strength and wear-resistant components are of major importance, predominantly in the aerospace and automotive engineering sectors. The morphology of the wear debris and the worn out surfaces were analyzed to understand the wear mechanisms.

scholarly journals Removal of toxic metals from aqueous solution by biochars derived from long-root Eichhornia crassipes

2018 ◽  
Vol 5 (10) ◽  
pp. 180966 ◽  
Author(s):  
Qiang Li ◽  
Lizhou Tang ◽  
Jiang Hu ◽  
Ming Jiang ◽  
Xiaodong Shi ◽  
...  
Keyword(s):  
Toxic Metals ◽  
Eichhornia Crassipes ◽  
Adsorption Process ◽  
Correlation Coefficients ◽  
Sorption Ability ◽  
Different Temperatures ◽  
Lead Zinc ◽  
Pseudo Second Order ◽  
Cyano Groups ◽  
Maximum Removal

Biochars were produced from long-root Eichhornia crassipes at four temperatures: 200, 300, 400 and 500°C, referred to as LEC200, LEC300, LEC400 and LEC500, respectively. The sorption ability of lead, zinc, copper and cadmium from aqueous solutions by four kinds of biochars was investigated. All the biochars had lower values of CEC and higher values of pH. LEC500 was the best one to bind toxic metals which can be reflected in the results of SEM, BET and elemental analyser. It was also found that alkyl, carboxyl, phosphate and cyano groups in the biochars can play a role in binding metals. In addition, the sorption processes of four metals by the biochars in different metal concentration were all excellently represented by the pseudo-second-order model with all correlation coefficients R 2 > 0.95. And the sorption processes of four metals in different temperatures could be described satisfactorily by the Langmuir isotherms. According to calculated results by the Langmuir equation, the maximum removal capacities of Pb(II), Zn(II), Cu(II) and Cd(II) at 298 K were 39.09 mg g −1 , 45.40 mg g −1 , 48.20 mg g −1 and 44.04 mg g −1 , respectively. The positive value of the Δ H 0 confirmed the adsorption process was endothermic and the negative value of Δ G 0 confirmed the adsorption process was spontaneous. The sorption capacities were compared with several other lignocellulosic materials which implied the potential of long-root Eichhornia crassipes waste as an economic and excellent biosorbent for eliminating metal ions from contaminated waters.

CHARACTERIZATION OF HYDROXYAPATITE/TI6AL4V COMPOSITE POWDER UNDER VARIOUS SINTERING TEMPERATURE

2015 ◽  
Vol 75 (7) ◽  
Author(s):  
Amir Arifin ◽  
Abu Bakar Sulong ◽  
Norhamidi Muhamad ◽  
Junaidi Syarif
Keyword(s):  
Mechanical Properties ◽  
Composite Powder ◽  
Sintering Temperature ◽  
Physical And Mechanical Properties ◽  
Xrd Analysis ◽  
X Ray Diffraction ◽  
Different Temperatures ◽  
Two Phases ◽  
Work Interaction

Hydroxyapatite (HA) has been widely used in biomedical applications due to its excellent biocompatibility. However, Hydroxyapatite possesses poor mechanical properties and only tolerate limited loads for implants. Titanium is well-known materials applied in implant that has advantage in mechanical properties but poor in biocompatibility. The combination of the Titanium alloy and HA is expected to produce bio-implants with good in term of mechanical properties and biocompatabilty. In this work, interaction and mechanical properties of HA/Ti6Al4V was analyzed. The physical and mechanical properties of HA/Ti6Al4V composite powder obtained from compaction (powder metallurgy) of 60 wt.% Ti6Al4V and 40 wt.% HA and sintering at different temperatures in air were investigated in this study. Interactions of the mixed powders were investigated using X-ray diffraction. The hardness and density of the HA/Ti6Al4V composites were also measured. Based on the results of XRD analysis, the oxidation of Ti began at 700 °C. At 1000 °C, two phases were formed (i.e., TiO2 and CaTiO3). The results showed that the hardness HA/Ti6Al4V composites increased by 221.6% with increasing sintering temperature from 700oC to 1000oC. In contrast, the density of the composites decreased by 1.9% with increasing sintering temperature. 

Sintering Temperature Effect on Hardness of Self-Synthetisized Porcelain Made from Natural Sumatran Sand without Kaolin

2018 ◽  
Vol 782 ◽  
pp. 227-232
Author(s):  
Sianny Surya Putri Kurnia ◽  
Dede Taufik ◽  
Veni Takarini ◽  
Zulia Hasratiningsih
Keyword(s):  
Temperature Effect ◽  
Potassium Salt ◽  
Sintering Temperature ◽  
The Self ◽  
The Other ◽  
P Value ◽  
Natural Sand ◽  
Average Hardness ◽  
Different Temperatures ◽  
Statistic Result

Dental porcelain is one of the indirect restoration material with excellent aesthetic properties,on the other hand porcelain hardness frequently causing excessive wear of antagonist teeth. This study aiming to evaluate the effect of sintering temperature on the self-synthesized porcelain hardness. In this experiment, 25 porcelain samples were synthesized using Sumatran sand from Pangaribuan and Belitung regions, with the composition of 65 wt% Pangaribuan feldspar, 25 wt% Belitung silica and 10 wt% potassium salt. The samples were sintered in five different temperatures, which were 1110°C (A), 1120°C (B), 1130°C (C), 1140°C (D), and 1150°C (E). These samples were then invested on 5cm diameter resin each. The hardness was tested using Zwick Roell ZHμ Micro Vickers with 900 gram load for 15 seconds in 5 different indented areas for each sample. The result shows average hardness of 435.8 VHN (A), 461.0 VHN (B), 472.0 VHN (C), 487.6 VHN (D), and 528.7 VHN (E), which were increasing as the sintering temperature increased. Statistic result shows that sintering temperature significantly affected the hardness value of the porcelain (p value < 0.05). In conclusion sintering temperature affects the hardness of self-synthesized porcelain made from Sumatran natural sand without kaolin, although the average hardness of self-synthesized porcelain is still higher than average hardness of teeth enamel.

scholarly journals Effect of Sintering Temperature on Metal-Insulator Phase Transition in La1-xCaxMnO3 Perovskites

2020 ◽  
Vol 2 (1) ◽  
pp. 37-42
Author(s):  
Arunachalam M ◽  
Thamilmaran P ◽  
Sakthipandi K
Keyword(s):  
Phase Transition ◽  
Bulk Modulus ◽  
Sintering Temperature ◽  
Magnetic Sensors ◽  
Temperature Dependent ◽  
Metal Insulator ◽  
Wide Range ◽  
Different Temperatures ◽  
Insulator Phase Transition

Lanthanum calcium based perovskites are found to be advantageous for the possible applications in magnetic sensors/reading heads, cathodes in solid oxide fuel cells, and frequency switching devices. In the present investigation La0.3Ca0.7MnO3 perovskites were synthesised through solid state reaction and sintered at four different temperatures such as 900, 1000, 1100 and 1200˚ C. X-ray powder diffraction pattern confirms that the prepared La0.3Ca0.7MnO3 perovskites have orthorhombic structure with Pnma space group. Ultrasonic in-situ measurements have been carried out on the La0.3Ca0.7MnO3 perovskites over wide range of temperature and elastic constants such as bulk modulus of the prepared La0.3Ca0.7MnO3 perovskites was obtained as function of temperature. The temperature-dependent bulk modulus has shown an interesting anomaly at the metal-insulator phase transition. The metal insulator transition temperature derived from temperature-dependent bulk modulus increases from temperature 352˚ C to 367˚ C with the increase of sintering temperature from 900 to 1200˚ C.

Origin of enhanced stability and oxygen adsorption capacity of medium-sized Pt–Ni nanoclusters

2018 ◽  
Vol 30 (28) ◽  
pp. 285503 ◽  
Author(s):  
Yang Yang ◽  
Haiyan Yu ◽  
Yushun Cai ◽  
Riccardo Ferrando ◽  
Daojian Cheng
Keyword(s):  
Adsorption Capacity ◽  
Oxygen Adsorption ◽  
Enhanced Stability

Investigation of Isothermal Treatment on the Structural, Microstructure and Physical Properties of Li2O-Al2O3-SiO2 Glass-Ceramic

2020 ◽  
Author(s):  
Husniyah Aliyah Lutpi ◽  
Hasmaliza Mohamad ◽  
Tuti Katrina Abdullah
Keyword(s):  
Grain Size ◽  
Elevated Temperature ◽  
Physical Properties ◽  
Thermal Shock ◽  
Glass Ceramic ◽  
Crystalline Phase ◽  
Sintering Temperature ◽  
Isothermal Treatment ◽  
Crystalline Phases ◽  
Average Grain Size

Abstract The present work aims to investigate the effects of isothermal treatment on the structural, microstructure and physical properties of Li2O-Al2O3-SiO2 glass-ceramic. Sintering temperature plays a major role in producing the desired lithium aluminosilicate (LAS) glass-ceramic crystalline phases. This work also aims to achieve a low thermal expansion coefficient β-spodumene (LiAlSi2O6) crystalline phase with improved density and lower porosity, which can be useful for the applications with thermal shock properties. The LAS glass-ceramic was fabricated by the melt-quenching technique at 1550 °C for 5 h before being isothermally sintered at an elevated temperature of 900 to 1200 °C for 30 min. The evolution of LAS glass-ceramic crystalline phases was identified using differential thermal analysis and the β-spodumene exothermic peak appeared at 999 °C. Based on the X-ray diffraction results, the complete transformation of β-spodumene from high-quartz solid solution (β-quartz) occurred at 1000 °C. However, the sintering temperature did not change the crystalline phase when sintered above 1000 °C, but the lattice parameter of the crystal structure was slightly altered. Moreover, it was observed that the LAS glass-ceramic grain size increased with temperature, whereby the smallest average grain size recorded (0.61 µm) for LAS glass-ceramic sintered at 1100 °C. Meanwhile, the fully densified LAS glass-ceramic at 1100 ° C was measured at 2.47 g/cm3 with 0.52% porosity. The isothermal treatment at elevated temperature indicated that sintering at 1100 °C provided a denser, less porous, and small average grain size which is preferred for thermal shock resistance applications.

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