scholarly journals Mechanical Properties of Green Recycled Polypropylene Composites: Effect of Maleic Anhydride Grafted Polypropylene (MAPP) Coupling Agent

2013 ◽  
Vol 812 ◽  
pp. 187-191 ◽  
Author(s):  
Nur Izzati Zulkifli ◽  
Noorasikin Samat
Keyword(s):  
Mechanical Properties ◽  
Maleic Anhydride ◽  
Coupling Agent ◽  
Filler Content ◽  
Mechanical Analysis ◽  
Morphological Properties ◽  
Appreciable Change ◽  
Polypropylene Composites ◽  
Recycled Polypropylene ◽  
Tensile Impact

Recycled polypropylene/microcrystalline cellulose (rPP/MCC) composites were prepared by adding different loadings of maleic anhydride grafted polypropylene (MAPP) coupling agent. The tensile, impact and morphological properties of the composites were investigated. The obtained results show that the tensile and impact strengths of the composites were significantly enhanced with the addition of MAPP loading from 2 to 5 wt%, as compared with unfilled rPP/MCC composites. However, it was found that at low filler content, different amounts of MAPP resulted in no appreciable change in the tensile strength and modulus. Moreover, dynamic mechanical analysis (DMA) results indicated that, increasing the amount of MAPP loading from 2 to 5 wt% in rPP/MCC provide better stiffness of the composite compared to those neat rPP and neat PP. Field emission scanning microscopy (FESEM) has shown that the composite, with MAPP loading, promotes better fibermatrix interaction.

Mechanical and Morphological Properties of Silicon Carbide Filled Polypropylene Composites with PP-g-MA as Compatibilizer

2013 ◽  
Vol 747 ◽  
pp. 39-42 ◽  
Author(s):  
Apaipan Rattanapan ◽  
Surakit Tuampoemsab ◽  
Rapeephun Dangtungee
Keyword(s):  
Mechanical Properties ◽  
Silicon Carbide ◽  
Maleic Anhydride ◽  
Compression Molding ◽  
Morphological Properties ◽  
Molding Machine ◽  
Polypropylene Composites ◽  
Roll Mill ◽  
Superior Mechanical Properties ◽  
Sic Composites

In the present study, the series of PP/SiC composites, containing 5, 10, 15, 20 and 30 wt% of waste SiC particles from abrasive industry, were prepared in order to obtain composites with superior mechanical properties. PP/SiC composites with appropriate amount of SiC were used in order to study the effect of polypropylene-grafted-maleic anhydride (PP-g-MA) as a compatibilizer. PP-g-MA loadings of 0, 1, 3, 5, 7, and 10 wt% were filled composites material by using a two roll mill, extruder and shaped in a hydraulic compression molding machine. Mechanical

scholarly journals Selected properties of mahogany wood flour filled polypropylene composites: The effect of maleic anhydride-grafted polypropylene (MAPP)

BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 2227-2236
Author(s):  
Vedat Çavuş
Keyword(s):  
Mechanical Properties ◽  
Maleic Anhydride ◽  
Wood Flour ◽  
Zinc Stearate ◽  
Test Results ◽  
Composite Manufacturing ◽  
Polypropylene Composites ◽  
Tensile Impact ◽  
Interfacial Compatibility ◽  
Scanning Electron

The aim of this study was to produce mahogany (Swietenia macrophylla) wood flour filled polypropylene (both recycled and virgin) composites and to determine the effects of maleic anhydride-grafted polypropylene (MAPP) on the interfacial compatibility, density, and other mechanical properties of the resulting composites. Approximately 40 wt% of mahogany wood flour, and 60 wt% of polypropylene, 3 wt% of MAPP, 1.5 wt% of zinc stearate, and 1.5 wt% of wax were used during composite manufacturing. Test specimens were manufactured using extrusion and injection molding processes. The flexural, tensile, impact, and hardness properties of all specimens were determined. Scanning electron microscopy was used to study the morphology and interfacial compatibility of the filler in prepared composites. The test results showed that MAPP use and the filler rates affected the density and mechanical properties of test specimens.

Effect of Coupling Agent on Mechanical Properties of Composite from Microcrystalline Cellulose and Recycled Polypropylene

2012 ◽  
Vol 576 ◽  
pp. 390-393 ◽  
Author(s):  
J. Awanis ◽  
S. Anis Sofia ◽  
Noorasikin Samat
Keyword(s):  
Mechanical Properties ◽  
Maleic Anhydride ◽  
Impact Strength ◽  
Flexural Strength ◽  
Microcrystalline Cellulose ◽  
Coupling Agent ◽  
Impact Test ◽  
Flexural Test ◽  
Recycled Polypropylene ◽  
The Impact

This study shows the effect of using 3-aminopropyltriethoxysilane (APS) and maleic anhydride-grafted polypropylene (MAPP) as coupling agent on composite of RPP/MCC fiber. The compositions of MCC were varied from 0, 2, 4, 8 and 12 wt%. The compounded samples were prepared into test specimens by using injection moulding. The RPP/MCC composites with and without the coupling agent were characterized through mechanical testing of flexural and impact test. The incorporation of the modified MCC was found to increase the modulus and flexural strength. The flexural test indicates that the addition of 4 wt% MCC-APS and 8 wt% MCC-MAPP significantly increased the flexural strength of the RPP composite compared to the unmodified MCC. The impact test shows higher impact strength at 4 wt% of RPP/MCC-APS and 2 wt% of RPP/MCC-MAPP, respectively.

Effect of maleic anhydride grafted polylactic acid concentration on mechanical and thermal properties of thermoplasticized starch filled polylactic acid blends

2021 ◽  
pp. 096739112110041
Author(s):  
Shakti Chauhan ◽  
N Raghu ◽  
Anand Raj
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
Maleic Anhydride ◽  
Polylactic Acid ◽  
Coupling Agent ◽  
Thermo Gravimetric Analysis ◽  
Mechanical Analysis ◽  
Strength Properties ◽  
Mechanical And Thermal Properties ◽  
Gravimetric Analysis

Polylactic acid (PLA) is blended with native starch or thermo plasticized starch (TPS) for preparing biodegradable composites. However, poor compatibility of PLA with starch results in the composites with inferior mechanical properties. This study examines the effect of Maleic Anhydride-Grafted-PLA (GMAPLA) coupling agent and its concentration on the extent of improvements in mechanical and thermal properties of PLA –TPS blends. Maleic anhydride was grafted on PLA in Haake torque rheometer, characterized and used as the coupling agent. PLA/TPS (wt/wt) blends (70/30 and 50/50) were prepared by twin screw extrusion. GMAPLA at three different levels 5%, 10% and 15% (wt%) with respect to PLA content was taken to study its effect on mechanical properties of blends. Presence of GMAPLA significantly improved the mechanical properties (tensile, flexural and impact strength) of TPS/PLA blends. Among the three concentrations, 10% GMAPLA in the blend was found to give the maximum improvement in strength properties. Dynamic mechanical analysis and thermo-gravimetric analysis indicated no significant effect of GMAPLA content on transition temperatures and thermal degradation behavior of the blends.

scholarly journals Improvement of Mechanical Properties of Noil Hemp Fiber Reinforced Polypropylene Composites by Resin Modification and Fiber Treatment

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Zili Yan ◽  
Jianchun Zhang ◽  
Hua Zhang ◽  
Hao Wang
Keyword(s):  
Mechanical Properties ◽  
Mechanical Analysis ◽  
Interfacial Bonding ◽  
Hydroxyethyl Cellulose ◽  
Hemp Fiber ◽  
Polypropylene Composites ◽  
Hydrophobically Modified ◽  
Fiber Treatment ◽  
Fibre Treatment ◽  
Adhesion Factor

The present study aims to improve the reinforcement of hemp fibre to polypropylene (PP) by simple resin modification and fibre treatment. Maleic anhydride grafted polypropylene (MAPP) was used as resin modifier by direct mixing with PP, and hydrophobically modified hydroxyethyl cellulose (HMHEC) was used as fibre treatment reagent by immersing fibre into its aqueous solution. The influences of fibre content, resin modification, and fibre treatment on the mechanical properties (tensile, flexural, and impact strengths) of composites were investigated. The change of interfacial bonding between fibre and resin in composites caused by MAPP and HMHEC was studied by scanning electron microscopy and dynamic mechanical analysis. Resin modification and fibre treatment were effective to enhance the mechanical properties of the composites. The improvement in interfacial bonding is quantitatively evaluated with adhesion factor.

Dynamic Mechanical Properties of Grafted Polypropylene Composites Reinforced with Acetylated Wheat Straw Fibers

2015 ◽  
Vol 1767 ◽  
pp. 139-143
Author(s):  
Ramón Sánchez ◽  
Jacobo Aguilar ◽  
Silvia Y. Martínez ◽  
Reyes J. Sanjuan ◽  
Gerardo A. Mejía ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Wheat Straw ◽  
Coupling Agent ◽  
Optical Microscope ◽  
Dynamic Mechanical Properties ◽  
Particle Sizes ◽  
Polypropylene Composites ◽  
Dynamic Mechanical ◽  
Twin Screw ◽  
Composite Pellets

ABSTRACTDynamic mechanical properties of polypropylene (PP) and grafted polypropylene (PP-g-MA) composites reinforced with acetylated wheat straw fibers (WSF) is reported in this work. The materials were prepared with different fiber particle sizes (40, 80 and 140 U.S. mesh) and at different fiber contents (5, 10 and 15 wt.%). The PP and PP-g-MA composites, where anhydride maleic (MA) was used as coupling agent, were obtained using a twin-screw extruder; whereas an injection-molding machine molded the composite pellets into testing specimens. To observe the morphology of the composites, micrographs were taken with an optical microscope. The Dynamic mechanical properties were analyzed using a torsional rheometer. The morphological analysis showed a high porous structure somehow similar to foamed materials. The storage modulus (G′) increased by increasing the fiber content, and decreased with fiber particle sizes for the PP composites. Meanwhile, the use of the coupling agent additive promoted a modulus increase due to higher fiber-polymer interaction, from better adhesion and chemical bonds formation between the fibers-coupling agent-PP.

Revaluation of Australian palm residues in polypropylene composites: Statistical influence of fiber treatment

2020 ◽  
pp. 002199832096053 ◽  
Author(s):  
Noelle C Zanini ◽  
Rennan FS Barbosa ◽  
Alana G de Souza ◽  
Derval S Rosa ◽  
Daniella R Mulinari
Keyword(s):  
Mechanical Properties ◽  
Tensile Properties ◽  
Mechanical Performance ◽  
Alkali Treatment ◽  
Mechanical Analysis ◽  
Melt Mixing ◽  
Polypropylene Composites ◽  
Matrix Interactions ◽  
Fiber Treatment ◽  
Fiber Matrix

Australian palm residues are generated by palm heart industry in large quantities and are considered an underused material with a composition rich in lignocellulosic structures. This residue is generally utilized as briquettes for energy or sheep feed; however, few works investigate this residue as composite fillers. This work aimed to revalue Australian palm residues (PR) by preparing polypropylene composites through melt mixing, using different fiber contents (0, 5, 10, 20, and 30 wt%), and evaluate the statistical influence of fibers (residues) alkali treatment (MPR) in composites mechanical properties. PR and MPR were evaluated by FTIR, XRD, SEM, TGA, and composites were assessed using thermal and mechanical analysis, in which ANOVA statistical analysis was applied. The residues addition increased the mechanical properties and their treatment enhanced the stiffness of the composites compared to pristine PP. However, ANOVA demonstrated that at low residues contents, surface treatment does not increase fiber-matrix interactions effectively, then tensile properties were statistically similar to PP. Considering tensile properties, 20% MPR showed statistically distinct properties, with significative enhancements; no filler contents dependence was verified. Flexural properties were more sensitive to residue loading, and composites with 30% PR and MPR presented superior mechanical performance. This difference is associated with a higher sensitivity of tensile stress towards fiber-matrix interactions, which was improved with fiber treatment. Also, the residues content and treatment influenced the composites' thermal stability, with better results for PP-MPR. Results indicate that palm residue is an excellent filler for improving composites' thermal and mechanical properties, with a greener character.

Mechanical and Morphological Properties of Sisal/Glass Fiber-Polypropylene Composites

2008 ◽  
Vol 47-50 ◽  
pp. 486-489 ◽  
Author(s):  
Kasama Jarukumjorn ◽  
Nitinat Suppakarn ◽  
Jongrak Kluengsamrong
Keyword(s):  
Mechanical Properties ◽  
Glass Fiber ◽  
Natural Fiber ◽  
Hybrid Composites ◽  
Weight Ratio ◽  
Morphological Properties ◽  
Fiber Reinforced ◽  
Polypropylene Composites ◽  
Specific Strength ◽  
Fiber Reinforced Polymer Composites

Natural fiber reinforced polymer composites became more attractive due to their light weight, high specific strength, biodegradability. However, some limitations e.g. low modulus, poor moisture resistance were reported. The mechanical properties of natural fiber reinforced composites can be improved by hybridization with synthetic fibers such as glass fiber. In this research, mechanical properties of short sisal-PP composites and short sisal/glass fiber hybrid composites were studied. Polypropylene grafted with maleic anhydride (PP-g-MA) was used as a compatibilizer to enhance the compatibility between the fibers and polypropylene. Effect of weight ratio of sisal and glass fiber at 30 % by weight on the mechanical properties of the composites was investigated. Morphology of fracture surface of each composite was also observed.

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