Structure and Properties of Recycled Aromatic Thermoplastic Polyester Nanocomposites

2012 ◽  
Vol 527 ◽  
pp. 44-49
Author(s):  
Remo Merijs Meri ◽  
Janis Zicans ◽  
Tatjana Ivanova ◽  
Rita Berzina ◽  
Guntis Japins ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Mechanical And Thermal Properties ◽  
Structure And Properties ◽  
Screw Extruder ◽  
Melt Compounding ◽  
Weight Content ◽  
Recycled Polyethylene ◽  
Twin Screw ◽  
Nanofiller Content ◽  
Montmorillonite Nanoclay

Structure as well as mechanical and thermal properties of the nanocomposites based on recycled polyethylene terephthalate (RPET) are investigated. 1, 2 and 5 wt. % of unmodified montmorillonite nanoclay (MMT) were introduced in the RPET matrix by melt compounding in a twin screw extruder. Results of the investigations testify that optimum content of MMT for modification of RPET is between 1 and 2 wt. %. Up to this nanofiller weight content, the most rapid increase of stiffness, strength and impact toughness is observed. Besides it, at this nanofiller weight content the investigated composite have somewhat improved thermal resistance. It is demonstrated that the improvement of these properties is due to better distribution of MMT in the polymer matrix. At higher nanofiller content, the undesirable effects of the nanofiller agglomeration becomes more important.

Mechanical and thermal characterization of grafted PP-NCC nanocomposites

2019 ◽  
pp. 089270571987822
Author(s):  
Saud Aldajah ◽  
Mohammad Y Al-Haik ◽  
Waseem Siddique ◽  
Mohammad M Kabir ◽  
Yousef Haik
Keyword(s):  
Thermal Properties ◽  
Interfacial Adhesion ◽  
Thermal Characterization ◽  
Mechanical And Thermal Properties ◽  
Screw Extruder ◽  
Scanning Calorimetry ◽  
Three Point Bending ◽  
Twin Screw ◽  
Thermal Stability Of

This study reveals the enhancement of mechanical and thermal properties of maleic anhydride-grafted polypropylene (PP- g-MA) with the addition of nanocrystalline cellulose (NCC). A nanocomposite was manufactured by blending various percentages of PP, MA, and NCC nanoparticles by means of a twin-screw extruder. The influence of varying the percentages of NCC on the mechanical and thermal behavior of the nanocomposite was studied by performing three-point bending, nanoindentation, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and Fourier-transform infrared (FTIR) spectroscopy tests. The novelty of this study stems on the NCC nanoparticles and their ability to enhance the mechanical and thermal properties of PP. Three-point bending and nanoindentation tests revealed improvement in the mechanical properties in terms of strength, modulus, and hardness of the PP- g-MA nanocomposites as the addition of NCC increased. SEM showed homogeneity between the mixtures which proved the presence of interfacial adhesion between the PP- g-MA incorporated with NCC nanoparticles that was confirmed by the FTIR results. DSC and TGA measurements showed that the thermal stability of the nanocomposites was not compromised due to the addition of the coupling agent and reinforced nanoparticles.

Performance of polylactide against UV irradiation: Synergism of an organic UV absorber with micron and nano-sized TiO2

2020 ◽  
Vol 54 (18) ◽  
pp. 2489-2504 ◽  
Author(s):  
Ulas Can ◽  
Cevdet Kaynak
Keyword(s):  
Weight Loss ◽  
Thermal Properties ◽  
Uv Irradiation ◽  
Chemical Structure ◽  
Mechanical And Thermal Properties ◽  
Screw Extruder ◽  
Melt Mixing ◽  
Uv Absorber ◽  
Fluorescent Lamps ◽  
Twin Screw

The main purpose of this study was to investigate mechanical and thermal performance of polylactide specimens against UV irradiation; first when only adding benzotriazole benzotriazole-based organic UV absorber (UVA), micro (200 nm) and nano (50 nm) sized titania (TiO2) particles alone, and then to reveal possible synergism when they are added together. Compounds were prepared by twin-screw extruder melt mixing, while the 2 mm thick specimens were shaped by compression molding. Specimens were exposed to UV irradiation under fluorescent lamps (UVB-313) with 0.50 W/m2 for the periods of 12 and 24 days. Changes in the performance of UV irradiated specimens were evaluated in terms of % weight loss, changes in color and chemical structure, including the decreases in the mechanical and thermal properties. Various tests and analysis revealed that synergistic benefits of using micro and nano TiO2 particles together with benzotriazole-type UVA were not only due to the effective stiffening, strengthening and toughening actions of titania particles, but also due to their very significant “UV screening” actions absorbing the photons of the UV irradiation, thus decreasing the degree of the detrimental photodegradation reactions leading to chain scissions in their PLA matrix.

Morphological, mechanical, and thermal properties of PP/SEBS/talc composites

2019 ◽  
pp. 089270571987667 ◽  
Author(s):  
Carlos Ivan Ribeiro de Oliveira ◽  
Marisa Cristina Guimarães Rocha ◽  
Joaquim Teixeira de Assis ◽  
Ana Lúcia Nazareth da Silva
Keyword(s):  
Thermal Properties ◽  
Impact Resistance ◽  
Mechanical And Thermal Properties ◽  
Processing Conditions ◽  
Screw Extruder ◽  
Crystallinity Degree ◽  
Twin Screw ◽  
The Impact ◽  
Scanning Electron ◽  
Nucleating Effect

The aim of this study is to evaluate the effect of some experimental variables such as the content of styrene–ethylene–butylene–styrene (SEBS) and talc, processing conditions and mixing protocol on the properties of polypropylene (PP). To achieve this objective, PP/SEBS blends and PP/SEBS/talc composites were processed in a corotating twin-screw extruder. A masterbatch of PP/talc was prepared before the extrusion of PP/SEBS/talc composites. The morphology of blends and composites was evaluated by scanning electron microscopy, which revealed the dispersion of small rubber droplets in the PP matrix. Moreover, the micrographs also showed that SEBS and talc particles were uniformly dispersed and distributed in the polymer matrix. Results of thermal properties showed that talc had a nucleating effect, which promoted the increase of both PP crystallization temperature and crystallinity degree. The incorporation of talc in PP/SEBS blends led to an expressive increase in the impact resistance by 70% as compared with the reference blend: PP/SEBS 80/20% (w/w). This result reveals that although the PP/SEBS/talc composites showed a separated morphology, the good dispersion and distribution of this mineral filler in the polymers contributed to avoid crack propagation and increase the impact properties. The tensile properties in the elastic region were not significantly affected.

scholarly journals Mechanical and thermal properties of bacterial-cellulose-fibre-reinforced Mater-Bi® bionanocomposite

2013 ◽  
Vol 4 ◽  
pp. 325-329 ◽  
Author(s):  
Hamonangan Nainggolan ◽  
Saharman Gea ◽  
Emiliano Bilotti ◽  
Ton Peijs ◽  
Sabar D Hutagalung
Keyword(s):  
Thermal Properties ◽  
Bacterial Cellulose ◽  
Volume Fraction ◽  
Cellulose Fibre ◽  
Tensile Tests ◽  
Mechanical And Thermal Properties ◽  
Screw Extruder ◽  
Elongation At Break ◽  
Freeze Dried ◽  
Twin Screw

The effects of the addition of fibres of bacterial cellulose (FBC) to commercial starch of Mater-Bi® have been investigated. FBC produced by cultivating Acetobacter xylinum for 21 days in glucose-based medium were purified by sodium hydroxide 2.5 wt % and sodium hypochlorite 2.5 wt % overnight, consecutively. To obtain water-free BC nanofibres, the pellicles were freeze dried at a pressure of 130 mbar at a cooling rate of 10 °C min−1. Both Mater-Bi and FBC were blended by using a mini twin-screw extruder at 160 °C for 10 min at a rotor speed of 50 rpm. Tensile tests were performed according to ASTM D638 to measure the Young’s modulus, tensile strength and elongation at break. A field emission scanning electron microscope was used to observe the morphology at an accelerating voltage of 10 kV. The crystallinity (T c) and melting temperature (T m) were measured by DSC. Results showed a significant improvement in mechanical and thermal properties in accordance with the addition of FBC into Mater-Bi. FBC is easily incorporated in Mater-Bi matrix and produces homogeneous Mater-Bi/FBC composite. The crystallinity of the Mater-Bi/FBC composites decrease in relation to the increase in the volume fraction of FBC.

The Effects of Melt Compounding Method on the Ambient and In Vitro Mechanical Properties of EVA/MMT Nanocomposites

2015 ◽  
Vol 789-790 ◽  
pp. 75-79 ◽  
Author(s):  
Azlin Fazlina Osman ◽  
Tew Wei Hong ◽  
Abdulkader M. Alakrach
Keyword(s):  
Mechanical Properties ◽  
Mechanical Performance ◽  
Twin Screw Extruder ◽  
Screw Extruder ◽  
Melt Compounding ◽  
Twin Screw ◽  
Internal Mixer ◽  
Nanofiller Content ◽  
Eva Copolymer

The in vitro biostability of ethyl vinyl acetate (EVA) nanocomposite incorporating the organically modified montmorillonite (organo-MMT) was investgated as a new material for biomedical applications. The effects of compounding process and filler loadings on the ambient and in vitro (exposed in oxidizing condition, 37°C) mechanical properties were studied. We have observed that, the melt compounded EVA copolymer by internal mixer (Brabender plasticoder) achieved the highest ambient and in vitro mechanical properties at low nanofiller content (1wt% organo-MMT). In contrast, the melt compounded EVA copolymer by twin screw extruder achieved the highest ambient and in vitro mechanical properties at high nanofiller content (5wt% organo-MMT). We suggest that this was due to the capability of the twin screw extruder to provide greater shear force for the exfoliation and dispersion of the high content organo-MMT as compared to internal mixer (Brabender plasticoder). However, compounding by twin screw extruder caused more severe reduction in tensile toughness of the EVA containing 5 wt% organo-MMT, after this material was exposed to oxidative agent, 37°C. These studies show that the melt compounding method may bring significant effect to both the ambient and in vitro mechanical performance of the EVA nanocomposites, and hence further investigation towards optimization should be pursued.

scholarly journals Effect of Organo-Modified Montmorillonite Nanoclay on Mechanical, Thermo-Mechanical, and Thermal Properties of Carbon Fiber-Reinforced Phenolic Composites

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 754
Author(s):  
Jantrawan Pumchusak ◽  
Nonthawat Thajina ◽  
Watcharakorn Keawsujai ◽  
Pattarakamon Chaiwan
Keyword(s):  
Thermal Properties ◽  
Carbon Fiber ◽  
Bending Strength ◽  
Mechanical And Thermal Properties ◽  
Fiber Reinforced ◽  
Heat Resistant ◽  
Degradation Temperature ◽  
Modified Montmorillonite ◽  
Carbon Fiber Reinforced ◽  
Montmorillonite Nanoclay

This work aims to explore the effect of organo-modified montmorillonite nanoclay (O-MMT) on the mechanical, thermo-mechanical, and thermal properties of carbon fiber-reinforced phenolic composites (CFRP). CFRP at variable O-MMT contents (from 0 to 2.5 wt%) were prepared. The addition of 1.5 wt% O-MMT was found to give the heat resistant polymer composite optimum properties. Compared to the CFRP, the CFRP with 1.5 wt% O-MMT provided a higher tensile strength of 64 MPa (+20%), higher impact strength of 49 kJ/m2 (+51%), but a little lower bending strength of 162 MPa (−1%). The composite showed a 64% higher storage modulus at 30 °C of 6.4 GPa. It also could reserve its high modulus up to 145 °C. Moreover, it had a higher heat deflection temperature of 152 °C (+1%) and a higher thermal degradation temperature of 630 °C. This composite could maintain its mechanical properties at high temperature and was a good candidate for heat resistant material.

Behaviour of PLA/POSS nanocomposites: Effects of filler content, functional group and copolymer compatibilization

2021 ◽  
pp. 096739112110080
Author(s):  
Yelda Meyva Zeybek ◽  
Cevdet Kaynak
Keyword(s):  
Functional Group ◽  
Filler Content ◽  
Mechanical And Thermal Properties ◽  
Screw Extruder ◽  
Melt Mixing ◽  
Grafted Copolymer ◽  
Before And After ◽  
Twin Screw ◽  
Oligomeric Silsesquioxane ◽  
Matrix Nanocomposites

The main purpose of this study was to investigate influences of three parameters on the mechanical and thermal properties of the polylactide (PLA) matrix nanocomposites filled with polyhedral oligomeric silsesquioxane (POSS) particles. For the first parameter of “Filler Content”, nanocomposites with 1, 3, 5, 7 wt% basic POSS structure were compared. For the second parameter of “Functional Group,” basic POSS structure having only nonpolar isobutyl groups were compared with three other functionalized POSS structures; i.e. aminopropylisobutyl-POSS (ap-POSS), propanediolisobutyl-POSS (pd-POSS) and octasilane-POSS (os-POSS). Finally, for the third parameter of “Copolymer Compatibilization,” all specimens were compared before and after their maleic anhydride (MA) grafted copolymer compatibilization. Specimens were produced with twin-screw extruder melt mixing and shaped under compression molding. Various tests and analyses indicated that the optimum filler content for the improved mechanical properties was 1 wt%; while the optimum structure for strength and modulus was pd-POSS structure, in terms of fracture toughness it was basic POSS structure. Additional use of MA compatibilization was especially effective for the basic POSS and os-POSS particles.

Structure and Mechanical Behavior of Isotactic Polypropylene Composites Filled with Silver Nanoparticles

e-Polymers ◽  
2007 ◽  
Vol 7 (1) ◽  
Author(s):  
Sie Chin Tjong ◽  
Suping Bao
Keyword(s):  
Mechanical Behavior ◽  
Isotactic Polypropylene ◽  
Ag Nanoparticles ◽  
Screw Extruder ◽  
Additional Increase ◽  
Polypropylene Composites ◽  
Melt Compounding ◽  
Twin Screw ◽  
Izod Impact ◽  
The Impact

AbstractIsotactic polypropylene (PP) nanocomposites containing 0.1, 0.3, 0.5 and 1.0 wt % silver (Ag) nanoparticles were prepared via melt compounding in a twin-screw extruder followed by injection molding The effects of the Ag nanoparticle additions on the structure and mechanical behavior of PP were studied using DSC, WXRD, optical microscopy, tensile and Izod impact techniques. DSC and WXRD measurements showed that the addition of only 0.1 wt% Ag nanoparticles promote the formation of β-form PP. Further increasing Ag content would not lead to additional increase of the β-PP phase content. The induced β- form PP phase is beneficial to enhance the impact strength and tensile ductility of the PP/Ag nanocomposites.

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