Effect of ZnO Nanoparticles on Grain Refinement of Mg-Al-Zn Alloy by Thixoforming Process

2019 ◽  
Vol 811 ◽  
pp. 170-178
Author(s):  
Kusharjanto Kusharjanto ◽  
Syoni Soepriyanto ◽  
Akhmad Ardian Korda ◽  
Supono Adi Dwiwanto
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Grain Refinement ◽  
Zno Nanoparticles ◽  
Raw Materials ◽  
Fuel Efficiency ◽  
Environmental Friendliness ◽  
Lightweight Structures ◽  
Set Up ◽  
Zn Alloy

Thixoforming process is one method to improve the mechanical properties, especially in the manufacture of magnesium alloy components. This method is an alternative to lightweight structures and simultaneously efficient use of raw materials, fuel efficiency and environmental friendliness. The aim of this study is investigates the effect of ZnO nanoparticles addition on grain refinement of Mg-Al-Zn alloy by thixoforming. In these experiments, ZnO nanoparticles added from 0.1, 0.2, 0.3, 0.4 and 0.5 wt. % to Mg-Al-Zn alloy and thixoforming temperature set-up at 530°C. The results showed that the increasing of weight % ZnO nanoparticles cause decreasing grain size average of Mg-Al-Zn alloy both as-cast and thixoforming. On 0.5 wt. % ZnO addition was obtained grain refinement 39.87 μm (decreased 29.29%) and hardness 73.80 HB (increased 53.94%) compared to as-cast.

scholarly journals Grain Refinement Of Magnesium and Az19E Magnesium Alloy By Addition Of MgB2 Inoculant

2021 ◽  
Author(s):  
Payam Emadi
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Thermal Expansion ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Coefficient Of Thermal Expansion ◽  
Fuel Efficiency ◽  
Grain Refining ◽  
Nano Particle ◽  
Thermal Expansion Mismatch

The increased use of magnesium alloys with improved mechanical properties is a prominent strategy towards increasing fuel efficiency of vehicles and decreasing emissions. This study investigates the grain refining efficiency and fading of MgB2 micro- and nano-particle added Pure Mg and AZ91E. Addition of micro and nano-sized MgB2 provided a reduction in grain size for Pure Mg and AZ91E. Enhanced heterogeneous nucleation and grain growth restriction was believed to be the source of refinement. Fading was observed for both Pure Mg and AZ91E, with the nano-particle added castings showing an increased resistance. The elongation of the Pure Mg samples showed improvements, whereas no improvements for UTS and YS was seen. The improved ductility was believed to be due to the grain refinement and coefficient of thermal expansion mismatch. The AZ91E samples did not show improvements in mechanical properties. This was believed to be due to stress concentration from Al-Mn intermetallics.

scholarly journals Grain Refinement Of Magnesium and Az19E Magnesium Alloy By Addition Of MgB2 Inoculant

2021 ◽  
Author(s):  
Payam Emadi
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Thermal Expansion ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Coefficient Of Thermal Expansion ◽  
Fuel Efficiency ◽  
Grain Refining ◽  
Nano Particle ◽  
Thermal Expansion Mismatch

The increased use of magnesium alloys with improved mechanical properties is a prominent strategy towards increasing fuel efficiency of vehicles and decreasing emissions. This study investigates the grain refining efficiency and fading of MgB2 micro- and nano-particle added Pure Mg and AZ91E. Addition of micro and nano-sized MgB2 provided a reduction in grain size for Pure Mg and AZ91E. Enhanced heterogeneous nucleation and grain growth restriction was believed to be the source of refinement. Fading was observed for both Pure Mg and AZ91E, with the nano-particle added castings showing an increased resistance. The elongation of the Pure Mg samples showed improvements, whereas no improvements for UTS and YS was seen. The improved ductility was believed to be due to the grain refinement and coefficient of thermal expansion mismatch. The AZ91E samples did not show improvements in mechanical properties. This was believed to be due to stress concentration from Al-Mn intermetallics.

Effect of Composite Master Alloy on Mechanical Properties and Electrochemical Corrosion of ZL101 Alloy

2013 ◽  
Vol 749 ◽  
pp. 407-413
Author(s):  
Hong Xu ◽  
Xin Zhang ◽  
Ji Ping Ren ◽  
Min Peng ◽  
Shi Yang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Tensile Strength ◽  
Grain Refinement ◽  
Master Alloy ◽  
Mass Fraction ◽  
Electrochemical Corrosion ◽  
Corrosion Performance ◽  
Obvious Effect ◽  
Mechanical Properties And Corrosion

The mechanical properties and corrosion performances of the ZL101 alloy modified by the composite master alloy were investigated. The results showed that the master alloy had not only obvious effect of grain refinement, but also a significant role in refining dendrite grain of ZL101 alloy. The grain size decreased dramatically from 150μm to 62μm when the addition of composite master alloy is up to 0.5%(mass fraction) and the temperature is 720 for 30 minutes,. Its tensile strength and elongation increased by 27% and 42% respectively. The grain refinement of ZL101 alloy decreased its corrosion performance. The morphology of Si changed into globular from needle modified by NaF, instead of AlTiB.

scholarly journals Fabrication of (SiC-AlN)/ZrB2 Composite with Nano-Micron Hybrid Microstructure via PCS-Derived Ceramics Route

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 334
Author(s):  
Aidong Xia ◽  
Jie Yin ◽  
Xiao Chen ◽  
Zhengren Huang ◽  
Xuejian Liu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Flexural Strength ◽  
Hot Pressing ◽  
Raw Materials ◽  
Secondary Phase ◽  
Pressing Temperature ◽  
Xrd Pattern ◽  
Mean Grain Size ◽  
The Mean

In this work, a (SiC-AlN)/ZrB2 composite with outstanding mechanical properties was prepared by using polymer-derived ceramics (PDCs) and hot-pressing technique. Flexural strength reached up to 460 ± 41 MPa, while AlN and ZrB2 contents were 10 wt%, and 15 wt%, respectively, under a hot-pressing temperature of 2000 °C. XRD pattern-evidenced SiC generated by pyrolysis of polycarbosilane (PCS) was mainly composed by 2H-SiC and 4H-SiC, both belonging to α-SiC. Micron-level ZrB2 secondary phase was observed inside the (SiC-AlN)/ZrB2 composite, while the mean grain size (MGS) of SiC-AlN matrix was approximately 97 nm. This unique nano-micron hybrid microstructure enhanced the mechanical properties. The present investigation provided a feasible tactic for strengthening ceramics from PDCs raw materials.

scholarly journals Novel grain refinement of AZ91E magnesium alloy and the effect on hot tearing during solidfication

2021 ◽  
Author(s):  
Abdallah Elsayed
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Magnesium Alloys ◽  
Hot Tearing ◽  
Grain Refining ◽  
Grain Refiner ◽  
Structural Applications ◽  
Hot Tearing Susceptibility

For the A1-5Ti-1B grain refiner, the addition of 0.1 wt.% provided a 68 % reduction in grain size as compared to the unrefined AZ91E alloy at a holding time of five minutes. Grain growth restriction by TiB₂ particles was the source of grain refinement. With the addition of A1-5Ti-1B, only a small reduction in hot tearing susceptibility ws observed because large TiA1₃ particles bonded poorly with the eutectic and blocked feeding channels.The addition of 1.0 wt.% A1-1Ti-3B provided a grain size reduction of 63% as compared to the unrefined AZ91E alloy at a holding time of five minutes. The grain refinement with A1-1Ti-3B addition was attributed to a combination of TiB₂ grain growth restriction and A1B₂ nucleating sites. A significant reduction in hot tearing susceptibility was observed with A1-1Ti-3B addition as a result of a higher cooling rate and shorter local soldification time as compared to the AZ91E alloy. The reduction in hot tearing susceptibility was attributed to the good interface between eutectic and TiB₂ particles. Both grain refiners demonstrated a good resistance to fading during the holding times investigated. In addition, the AZ91E + A1-5Ti-1B and AZ91E + A1-1Ti-3B castings showed much fewer dislocation networks as compared to the untreated AZ91E casting.The development of efficient A1-Ti-B refiners can also improve castability of magnesium alloys. In addition, the fade resistant A1-Ti-B grain refiners can reduce operating costs and maintain productivity on the foundry floor. Thus, magnesium alloy with A1-Ti-B treatment have the potential for more demanding structural applications in the automobile and aerospace industries. Vehicle weight in the aerospace and automotive industries directly impacts carbon emissions and fuel efficiency. An increase in the use of lightweight materials for structural applications will result in lighter vehicles. Low density materials, such as magnesium (1.74 g/cm³) are a potential alternative to aluminium (2.70 g/cm³), to reduce component weight in structural applications.However, current magnesium alloys still do not have adequate mechanical properties and castability to meet the performance specifications of the automotive and aerospace industries. Grain refinement can significantly improve mechanical properties and reduce hot tearing during permanent mould casting. Recently, Al-Ti-B based grain refiners have shown potential in grain refining magnesium-aluminum alloys such as AZ91E. This study investigates the grain refining efficiency and fading of A1-5Ti-1B and A1-1Ti-3B in AZ91E magnesium alloy and their subsequent effect on hot tearing.The grain refiners were added at 0.1, 0.2, 0.5 and 1.0 wt.% levels. For the grain refinement and fading experiments, the castings were prepared using graphite moulds with holding times of 5, 10 and 20 minutes. For the hot tearing experiments, castings were produced representing the optimal addition level of each grain refiner. The castings were prepared using a permanent mould with pouring and mould temperatures of 720 and 180 ºC, respectively. The castings were characterized using SEM, TEM, optical microscopy and thermal analysis.

Effect of the Mg3N2 Sub-Micron Particle on the Grain Refinement of AZ80 Alloy

2022 ◽  
Vol 327 ◽  
pp. 45-53
Author(s):  
Jiehua Li ◽  
Maria Pammer ◽  
Ernst Neunteufl ◽  
Peter Schumacher
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Grain Refinement ◽  
Liquid State ◽  
High Performance ◽  
Great Loss ◽  
Micron Particle ◽  
Deformation Ability ◽  
Semi Solid ◽  
Az80 Alloy

AZ80 alloy has been widely used to produce high performance Mg casting and wrought parts for high-end applications due to its high mechanical properties and deformation ability. However, at least two important issues still need to be solved in order to further improve its mechanical properties and deformation ability. Firstly, the grain size of α-Mg in AZ80 alloy is relatively large (more than 1000 µm) due to a lack of efficient grain refinement methodologies. Secondly, the size of the eutectic Mg17Al12 phase is also large and the distribution of the eutectic Mg17Al12 phase is continuous, which is very harmful for the mechanical properties, in particular to elongation. In this paper, these two important issues are investigated by adding Mg3N2 sub-micron particle into AZ80 alloy and thereby refining the α-Mg and the eutectic Mg17Al12 phase. Firstly, the Mg3N2 sub-micron particle was directly added into AZ80 alloy by using mechanically stirring in the semi-solid state, subsequently the melting temperature was increased above the liquidous temperature, and finally the melting was casted in the liquid state. It was found that the grain size of α-Mg can be refined from 883.8 µm to 169.9 µm. More importantly, the eutectic Mg17Al12 phase was also refined and the distribution became discontinuous. It should be noted that directly adding the Mg3N2 sub-micron particle into AZ80 alloy leads to a great loss of the Mg3N2 sub-micron particle due to the weak wetting behavior between the Mg3N2 sub-micron particle and Mg melt. The second methodology through mixing Mg3N2 sub-micron particles with AZ91 chips using a twin extruder was also used to prepare AZ91 master alloy with 3wt.% Mg3N2 sub-micron particle, which was subsequently added into AZ80 alloy in the liquid state. In this way, a significant grain refinement of α-Mg and a simultaneous refinement of the eutectic Mg17Al12 phase in AZ80 alloy was also achieved. The grain size of α-Mg can be refined from 883.8 µm to 325.9 µm. However, no significant grain refinement by using UST was observed. Instead, the grain size increases from 325.9 µm to 448.6 µm, indicating that the Mg3N2 sub-micron particle may lose its grain refinement potency due to possible aggregation and clustering. This paper provides an efficient and simple methodology for the grain refinement of α-Mg and the simultaneous refinement of the eutectic Mg17Al12 phase in AZ80 alloy.

Grain Refinement and Texture Evolution in AZ31 Alloy during ECAP Process and Their Effects on Mechanical Properties

2005 ◽  
Vol 475-479 ◽  
pp. 549-554 ◽  
Author(s):  
H.S. Kim ◽  
Hyo Tae Jeong ◽  
Ha Guk Jeong ◽  
Woo Jin Kim
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Grain Refinement ◽  
Texture Evolution ◽  
Az31 Alloy ◽  
Mg Alloys ◽  
Fine Grained ◽  
Ecap Process ◽  
Texture Modification ◽  
Similar Texture

The softening of fine-grained ECAPed AZ31 Mg alloys could be ascribed to the texture modification during ECAP. Lower ECAP temperature is more effective in refining the microstructure. The strength of the ECAPed AZ 31 Mg alloys increased with decrease in grain size when they have similar texture.

Effect of AlN on Microstructure and Mechanical Properties of Mg-Al-Zn Alloy

2011 ◽  
Vol 704-705 ◽  
pp. 1095-1099
Author(s):  
Peng Liu ◽  
Hao Ran Geng ◽  
Zhen Qing Wang ◽  
Jian Rong Zhu ◽  
Fu Sen Pan ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Tensile Strength ◽  
Tensile Testing ◽  
Cast Alloy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Β Phase ◽  
Microstructure And Mechanical Properties ◽  
Zn Alloy

Effects of AlN addition on the microstructure and mechanical properties of as-cast Mg-Al-Zn magnesium alloy were investigated using optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and tensile testing. Five different samples were made with different amounts of AlN(0wt%, 0.12wt%, 0.30wt%, 0.48wt%, 0. 60wt%). The results show that the phases of as-cast alloy are composed of α-Mg,β-Mg17Al12. The addition of AlN suppressed the precipitation of the β-phase. And, with the increase of AlN content, the microstructure of β-phase was changed from the reticulum to fine grains. When AlN content was up to 0.48wt% in the alloy, the β-phase became most uniform distribution. After adding 0.3wt% AlN to Al-Mg-Zn alloy, the average alloy grain size reduced from 102μm to 35μm ,the tensile strength of alloy was the highest. The average tensile strength increased from 139MPa to 169.91MPa, the hardness increased from 77.7HB to 98.4HB, but the elongation changes indistinctively. However, when more amount of AlN was added, the average alloy grain size did not reduce sequentially and increased to 50μm by adding 0.6wt% AlN and the β-phase became a little more. Keywords: Al-Mg-Zn alloy; AlN; β-Mg17Al12; Tensile strength

Microstructure and Mechanical Properties of Extruded Mg-Al-Ca Based Alloys

2005 ◽  
Vol 488-489 ◽  
pp. 275-278 ◽  
Author(s):  
Rong Shi Chen ◽  
Jean Jacques Blandin ◽  
Michel Suéry ◽  
En Hou Han
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Elevated Temperature ◽  
Yield Strength ◽  
Ambient Temperature ◽  
Grain Refinement ◽  
Tensile Tests ◽  
Az91 Alloy ◽  
Microstructure And Mechanical Properties ◽  
Ca Addition

Mechanical properties and microstructure of extruded AZ91(-Ca) alloys have been studied in this paper. The results showed that Ca has no significant effect on reducing grain size of the extruded AZ91 alloy. The ambient temperature tensile tests showed that the ultimate and yield strength of extruded AZ91 alloy decreased by addition of Ca. At elevated temperature, Ca addition improves the yield strength of both AZ91 alloy. The variations in microstructure and mechanical properties of the AZ91 alloy are also discussed in terms of the effects of Ca on grain refinement and formation of constituent phases.

Effect of La-Rich Misch Metal on Microstructure and Mechanical Properties of As-Extruded Mg-14Li-3Al Alloy

2011 ◽  
Vol 391-392 ◽  
pp. 32-36 ◽  
Author(s):  
Bin Liu ◽  
Jing Huai Zhang ◽  
Zhong Yi Niu ◽  
Jun Qing Li
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Tensile Properties ◽  
Grain Refinement ◽  
Hot Extrusion ◽  
Vacuum Melting ◽  
Melting Method ◽  
Misch Metal ◽  
Microstructure And Mechanical Properties

The as-cast Mg-14Li-3Al-(0-0.9)RE alloys were prepared with vacuum melting method, then processed by hot extrusion. The microstructure and tensile properties were investigated. The results show that both addition of RE and extrusion deformation can refine the grain size. Al3La compounds are formed with addition of La-rich misch metal. The as-extruded Mg-14Li-3Al-0.6RE alloy obtains the finest grain size (4.28 μm) and the highest mechanical properties (σb=222.75 MPa, δ=23.8%), which is related to the grain refinement and the formation of Al3La.

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