Effect of the Mg3N2 Sub-Micron Particle on the Grain Refinement of AZ80 Alloy

AZ80 alloy has been widely used to produce high performance Mg casting and wrought parts for high-end applications due to its high mechanical properties and deformation ability. However, at least two important issues still need to be solved in order to further improve its mechanical properties and deformation ability. Firstly, the grain size of α-Mg in AZ80 alloy is relatively large (more than 1000 µm) due to a lack of efficient grain refinement methodologies. Secondly, the size of the eutectic Mg17Al12 phase is also large and the distribution of the eutectic Mg17Al12 phase is continuous, which is very harmful for the mechanical properties, in particular to elongation. In this paper, these two important issues are investigated by adding Mg3N2 sub-micron particle into AZ80 alloy and thereby refining the α-Mg and the eutectic Mg17Al12 phase. Firstly, the Mg3N2 sub-micron particle was directly added into AZ80 alloy by using mechanically stirring in the semi-solid state, subsequently the melting temperature was increased above the liquidous temperature, and finally the melting was casted in the liquid state. It was found that the grain size of α-Mg can be refined from 883.8 µm to 169.9 µm. More importantly, the eutectic Mg17Al12 phase was also refined and the distribution became discontinuous. It should be noted that directly adding the Mg3N2 sub-micron particle into AZ80 alloy leads to a great loss of the Mg3N2 sub-micron particle due to the weak wetting behavior between the Mg3N2 sub-micron particle and Mg melt. The second methodology through mixing Mg3N2 sub-micron particles with AZ91 chips using a twin extruder was also used to prepare AZ91 master alloy with 3wt.% Mg3N2 sub-micron particle, which was subsequently added into AZ80 alloy in the liquid state. In this way, a significant grain refinement of α-Mg and a simultaneous refinement of the eutectic Mg17Al12 phase in AZ80 alloy was also achieved. The grain size of α-Mg can be refined from 883.8 µm to 325.9 µm. However, no significant grain refinement by using UST was observed. Instead, the grain size increases from 325.9 µm to 448.6 µm, indicating that the Mg3N2 sub-micron particle may lose its grain refinement potency due to possible aggregation and clustering. This paper provides an efficient and simple methodology for the grain refinement of α-Mg and the simultaneous refinement of the eutectic Mg17Al12 phase in AZ80 alloy.

Simplified Analytical Model for Predicting Neutral Cross-Section Position of Lenticular Deployable Composite Boom in Tensile Deformation

Foldable and deployable flexible composite thin-walled structures have the characteristics of light weight, excellent mechanical properties and large deformation ability, which means they have good application prospects in the aerospace field. In this paper, a simplified theoretical model for predicting the position of the neutral section of a lenticular deployable composite boom (DCB) in tensile deformation is proposed. The three-dimensional lenticular DCB is simplified as a two-dimensional spring system and a rigid rod, distributed in parallel along the length direction. The position of the neutral cross-section can be determined by solving the balance equations and geometric relations. In order to verify the validity of the theoretical model, a finite element model of the tensile deformation of a lenticular DCB was established. The theoretical prediction results were compared with the finite element calculation results, and the two results were in good agreement.

The Evolution of Micromechanical Properties for Zr-Based Metallic Glass Induced by Laser Shock Peening

The micromechanical properties of Zr-based metallic glass (MG) induced by laser shock peening (LSP) were studied through the use of nanoindentation. The serrations in representative load-displacement (P-h) curves exhibited a transformation from stairstep-like to ripple-shaped from untreated zone to shock region, which implied an increase in plastic deformation ability of material after LSP. Significant hardening was also observed in the impact zone, which can be attributed to the effect of compressive residual stress. Both increase in hardness and plastic deformation ability in shock region indicate the excellent effect of LSP on the micromechanical properties of investigated Zr-based MG, which provide a new way to study the deformation mechanism in metallic glasses and a further understanding of plasticization.

Experiment and Research on Calculation Methods on Flexural Mechanical Behaviors of Non-Metallic Reinforced ECC Beams

Engineered cementitious composites (ECC) has high tenacity and the characteristics of strain hardening. In the bending test, ECC beams equipped with carbon fiber reinforced polymer (CFRP) in the tensile region show good deformation ability and bending ability. In this paper, the constitutive models of ECC and CFRP materials are established by uniaxial tensile compression test. Based on the plane section supposition, the analysis theory of bending capacity of cross section for ECC beams with non-metallic reinforcement is proposed. The calculation results are compared with the four-point bending test results. The results show that: (1) ECC beams with non-metallic reinforcement reflect the advantages of the two materials, and have strong deformation capacity before bending failure. (2) The calculation results based on the theory of flexural capacity of normal section are in good agreement with the experimental results, and the maximum error is less than 4%. The research results can provide the basis and reference for the calculation analysis and practical application of non-metallic reinforced high toughness material structure.

Development of a new poly-ε-caprolactone with low melting point for creating a thermoset mask used in radiation therapy

This study aimed to develop a poly-ε-caprolactone (PCL) material that has a low melting point while maintaining the deformation ability. The new PCL (abbreviated as 4b45/2b20) was fabricated by mixing two types of PCL with different molecular weights, numbers of branches, and physical properties. To investigate the melting point, crystallization temperature, elastic modulus, and elongation at break for 4b45/2b20 and three commercially available masks, differential scanning calorimetry and tensile tests were performed. The melting point of 4b45/2b20 was 46.0 °C, and that of the commercially available masks was approximately 56.0 °C (55.7 °C–56.5 °C). The elastic modulus at 60 °C of 4b45/2b20 was significantly lower than the commercially available masks (1.1 ± 0.3 MPa and 46.3 ± 5.4 MPa, p = 0.0357). In addition, the elongation at break of 4b45/2b20 were significantly larger than the commercially available masks (275.2 ± 25.0% and 216.0 ± 15.2%, p = 0.0347). The crystallization temperature of 4b45/2b20 (22.1 °C) was clinically acceptable and no significant difference was found in the elastic modulus at 23 °C (253.7 ± 24.3 MPa and 282.0 ± 44.3 MPa, p = 0.4). As a shape memory-based thermoset material, 4b45/2b20 has a low melting point and large deformation ability. In addition, the crystallization temperature and strength are within the clinically acceptable standards. Because masks made using the new PCL material are formed with less pressure on the face than commercially available masks, it is a promising material for making a radiotherapy mask that can reduce the burden on patients.

Flexural Behavior of UHPC Beams Prestressed with External CFRP Tendons

This paper presents an experimental investigation on the flexural behavior of ultra-high-performance concrete (UHPC) beams prestressed with external carbon fiber-reinforced polymer (CFRP) tendons. A total of eight T-shaped beam specimens were fabricated and tested, and the effects of the effective prestressing stress, partial prestressing ratio, deviated angle, and loading condition on the flexural behavior were analyzed. The experimental results indicate that the fully prestressed beams experienced a brittle failure, and the shear capacity of these beams was mainly controlled by the effective prestressing stress in CFRP tendons and the ultimate tensile strength of UHPC, whereas the partially prestressed beams failed in a ductile manner. The presence of internal steel reinforcement could significantly improve the flexural capacity and deformation ability. Thus, internal reinforcements should not be omitted from UHPC beams with CFRP tendons. A higher effective prestressing stress resulted in enhanced cracking load and flexural capacity. The deviated angle enhanced the utilization efficiency of high strength CFRP tendons. The loading condition exerted a slight influence on the flexural behavior of the specimens. Moreover, a method considering the effect of steel fibers was proposed and verified to predict the flexural capacity of UHPC beams prestressed with external CFRP tendons.

Damping Properties and Microstructure Analysis of Microbial Consolidated Rubber Sand

Up to now, there are few reports on the application of microbial-induced calcium carbonate precipitation (MICP) consolidated rubber sand. By means of uniaxial or cyclic loading test and SEM test, the consolidation effect of rubber sand samples with different rubber particle content after MICP consolidation is tested and analyzed. The results show that MICP is not affected by the amount of rubber particles; rubber particles improve the compressive strength and deformation ability of consolidated rubber sand samples and significantly enhance the damping ratio, resistance to deformation, and energy dissipation ability of consolidated rubber sand samples. Rubber sand after MICP consolidation is a good shock damping material. The conclusion of this paper provides reference data for the application of microbial-induced calcium carbonate precipitation consolidated rubber sand.

THE LEVEL OF PLASTICITY OF THE PHASES IN NON-METALLIC INCLUSIONS WITH A COMPLEX STRUCTURE

Purpose. It is necessary to study of the effect of heterophase inclusions on the technological ductility of steels for various purposes. The goal of the work was to study of the nature and level of plasticity of multiphase inclusions in steels under conditions of hot and cold deformation. Methods. Comprehensive methods for the study of heterophase non-metallic inclusions (metallographic, petrographic, X-ray microanalysis methods) were used. Results. Plastic phases in multiphase inclusions of different types under conditions of hot and cold deformation of steels were investigated. It is shown that each type of multiphase inclusions, which are microcomposite formations in steels, is characterized by its laws of development of deformation processes, which are determined by their chemical and phase composition, structure, deformation ability of the phases of inclusions. Scientific novelty. Peculiarities of plastic behavior of multiphase inclusions of different types are established. The inhibitory effect of non-deformable phases of inclusions on the deformability of plastic phases in a wide range of steel deformation temperatures is established. Peculiarities of the nature of plasticity of multiphase inclusions having different compositions and structure are discussed. Practical significance. Using the results obtained will allow developing technologies for producing steels with regulated content and types of multiphase non-metallic inclusions, which will significantly increase their technological plasticity, as well as prevent the formation of various kinds of defects during the processing of steels by pressure.

Ab Initio Study of the Influence of Alloying Elements on Stability and Mechanical Properties of Selected TixAly Intermetallic Compounds and Their TixAly/Al, TixAly/Ti Interfaces in Explosively Welded Metal–Metal Composites

The overall performance of joints fabricated using the explosive welding method depends directly on the brittleness of created intermetallic phases and their cohesion with metallic substrates. In this article, we used first principles calculations to show that Sn, V, Cu, and Mg alloying elements present in Ti- and Al-based alloys have a significant influence on the elastic properties and plastic deformation ability of γ-TiAl and Ti3Al. Selected solutes exhibit diversified preferential site occupancy in bulk phases and ordered phase/metallic substrate interface regions. The largest positive effect on ductility and cleavage energy was found for Cu addition (25 pct increase in the B/G ratio), while Sn largely deteriorates cleavage resistance (up to 8 pct). The presented results reveal that further development in the explosive welding field can be reached through the design/application of new alloys composed of elements that improve the properties of the ordered phases present in the joints.