The Magneto-Dimensional Transformation Properties of the Ultradispersed Metallic Media as a Mechanism for Managing the Macrodynamic Features of Crystallizing Thermoplastic Nanocomposites

2021 ◽  
Vol 899 ◽  
pp. 292-299
Author(s):  
N.I. Mashukov ◽  
Albina M. Altueva ◽  
Galina M. Danilova-Volkovskaya ◽  
Gennady B. Shustov
Keyword(s):  
Chemical Potential ◽  
Mutual Influence ◽  
Three Dimensional ◽  
Polymeric Materials ◽  
Condensed State ◽  
Structural Elements ◽  
Structure Property ◽  
Coherent Wave ◽  
Thermoplastic Matrix ◽  
Dimensional Parameters

The work considers the main elements of the magneto-dimensional transformation properties in the ultradispersed metallic media (UDM) as a nanomodifier in the process of the formation of nanocompositional polymeric materials (NCPM) based on polyolefins () from a melt. It has been shown that UDM nanoparticles in a melt under the influence and interaction with a thermoplastic matrix are capable of transforming their magnetic properties (to the level of superparamagnetic), structural-dimensional parameters, and chemical potential. With this mutual influence, the nanomodifier has an active effect on the thermoplastic melt at all stages of the formation of the structure-property relationship: structureless ensembles of macromolecules → formation of clusters (domains), lamellas, crystallites → formation of a network of intermolecular entanglements → crystallization of the thermoplastic matrix → transition to a condensed state. An important component of the formation of a fine-crystalline anisotropic NCPM structure is the intramatrix orientation of the structural elements of the thermoplastic in the melt under the influence of the magneto-dimensional transformable manifestations of the nanomodifier. A consequence of the formation of a fine-crystalline anisotropic structure of the NCPM is an increased level of a complex of physicochemical properties (such as deformation-strength, rheological, etc.). An assumption is made about the possibility of the formation of coherent wave packets from clusters (domains) and lamellas of crystallites of matrix thermoplastic with a minimum three-dimensional geometry under the action of superparamagnetic forces of nanoparticles of the nanomodifier.

Combined TEM/SEI of polymer membranes

1984 ◽  
Vol 42 ◽  
pp. 386-387
Author(s):  
L. C. Sawyer
Keyword(s):  
Three Dimensional ◽  
Polymer Membranes ◽  
Industrial Process ◽  
Polymeric Materials ◽  
Structure Property ◽  
Shape Distribution ◽  
Structure Property Relationships ◽  
Wide Range ◽  
Fundamental Understanding ◽  
Potential Applications

Structure-property relationships are important in the process optimization and fundamental understanding of many polymeric materials, including membranes. Polymer membranes are currently being used for separation, concentration or purification in a wide range of industrial process applications. The process used to manufacture the membrane, and the polymer type, determines the morphology, which influences the membrane transport properties and potential applications. The morphology includes: pore size, shape, distribution and their overall three dimensional arrangement. Microscopical methods are needed to image the structures formed by the various processes, in order to systematically study changes in variables for specific applications.

Designing TIMP (tissue inhibitor of metalloproteinases) variants that are selective metalloproteinase inhibitors

2003 ◽  
Vol 70 ◽  
pp. 201-212 ◽  
Author(s):  
Hideaki Nagase ◽  
Keith Brew
Keyword(s):  
Three Dimensional ◽  
Therapeutic Interventions ◽  
Tissue Inhibitors Of Metalloproteinases ◽  
Structural Basis ◽  
Structural Elements ◽  
Ridge Structure ◽  
Extracellular Matrix Components ◽  
Metalloproteinase Inhibitors ◽  
The Matrix ◽  
A Disintegrin And Metalloproteinase

The tissue inhibitors of metalloproteinases (TIMPs) are endogenous inhibitors of the matrix metalloproteinases (MMPs), enzymes that play central roles in the degradation of extracellular matrix components. The balance between MMPs and TIMPs is important in the maintenance of tissues, and its disruption affects tissue homoeostasis. Four related TIMPs (TIMP-1 to TIMP-4) can each form a complex with MMPs in a 1:1 stoichiometry with high affinity, but their inhibitory activities towards different MMPs are not particularly selective. The three-dimensional structures of TIMP-MMP complexes reveal that TIMPs have an extended ridge structure that slots into the active site of MMPs. Mutation of three separate residues in the ridge, at positions 2, 4 and 68 in the amino acid sequence of the N-terminal inhibitory domain of TIMP-1 (N-TIMP-1), separately and in combination has produced N-TIMP-1 variants with higher binding affinity and specificity for individual MMPs. TIMP-3 is unique in that it inhibits not only MMPs, but also several ADAM (a disintegrin and metalloproteinase) and ADAMTS (ADAM with thrombospondin motifs) metalloproteinases. Inhibition of the latter groups of metalloproteinases, as exemplified with ADAMTS-4 (aggrecanase 1), requires additional structural elements in TIMP-3 that have not yet been identified. Knowledge of the structural basis of the inhibitory action of TIMPs will facilitate the design of selective TIMP variants for investigating the biological roles of specific MMPs and for developing therapeutic interventions for MMP-associated diseases.

Superfluidity and Superconductivity

2018 ◽  
Author(s):  
Norman J. Morgenstern Horing
Keyword(s):  
Magnetic Field ◽  
Wave Function ◽  
Wave Packet ◽  
Long Range ◽  
Cooper Pair ◽  
Bose Condensation ◽  
Range Order ◽  
Condensed State ◽  
Long Range Order ◽  
Coherent Wave

Chapter 13 addresses Bose condensation in superfluids (and superconductors), which involves the field operator ψ‎ having a c-number component (<ψ(x,t)>≠0), challenging number conservation. The nonlinear Gross-Pitaevskii equation is derived for this condensate wave function<ψ>=ψ−ψ˜, facilitating identification of the coherence length and the core region of vortex motion. The noncondensate Green’s function G˜1(1,1′)=−i<(ψ˜(1)ψ˜+(1′))+> and the nonvanishing anomalous correlation function F˜∗(2,1′)=−i<(ψ˜+(2)ψ˜+(1′))+> describe the dynamics and elementary excitations of the non-condensate states and are discussed in conjunction with Landau’s criterion for viscosity. Associated concepts of off-diagonal long-range order and the interpretation of <ψ> as a superfluid order parameter are also introduced. Anderson’s Bose-condensed state, as a phase-coherent wave packet superposition of number states, resolves issues of number conservation. Superconductivity involves bound Cooper pairs of electrons capable of Bose condensation and superfluid behavior. Correspondingly, the two-particle Green’s function has a term involving a product of anomalous bound-Cooper-pair condensate wave functions of the type F(1,2)=−i<(ψ(1)ψ(2))+>≠0, such that G2(1,2;1′,2′)=F(1,2)F+(1′,2′)+G˜2(1,2;1′,2′). Here, G˜2 describes the dynamics/excitations of the non-superfluid-condensate states, while nonvanishing F,F+ represent a phase-coherent wave packet superposition of Cooper-pair number states and off-diagonal long range order. Employing this form of G2 in the G1-equation couples the condensed state with the non-condensate excitations. Taken jointly with the dynamical equation for F(1,2), this leads to the Gorkov equations, encompassing the Bardeen–Cooper–Schrieffer (BCS) energy gap, critical temperature, and Bogoliubov-de Gennes eigenfunction Bogoliubons. Superconductor thermodynamics and critical magnetic field are discussed. For a weak magnetic field, the Gorkov-equations lead to Ginzburg–Landau theory and a nonlinear Schrödinger-like equation for the pair wave function and the associated supercurrent, along with identification of the Cooper pair density. Furthermore, Chapter 13 addresses the apparent lack of gauge invariance of London theory with an elegant variational analysis involving re-gauging the potentials, yielding a manifestly gauge invariant generalization of the London equation. Consistency with the equation of continuity implies the existence of Anderson’s acoustic normal mode, which is supplanted by the plasmon for Coulomb interaction. Type II superconductors and the penetration (and interaction) of quantized magnetic flux lines are also discussed. Finally, Chapter 13 addresses Josephson tunneling between superconductors.

scholarly journals Magnetotelluric study in the Los Lagos Region (Chile) to investigate volcano-tectonic processes in the Southern Andes

2021 ◽  
Vol 73 (1) ◽  
Author(s):  
Maria Jose Segovia ◽  
Daniel Diaz ◽  
Katarzyna Slezak ◽  
Felipe Zuñiga
Keyword(s):  
Electrical Resistivity ◽  
Three Dimensional ◽  
Phase Changes ◽  
Fault System ◽  
Electrical Anisotropy ◽  
Mountain Range ◽  
Southern Andes ◽  
Nazca Plate ◽  
First Results ◽  
Dimensional Parameters

AbstractTo analyze the process of subduction of the Nazca and South American plates in the area of the Southern Andes, and its relationship with the tectonic and volcanic regime of the place, magnetotelluric measurements were made through a transversal profile of the Chilean continental margin. The data-processing stage included the analysis of dimensional parameters, which as first results showed a three-dimensional environment for periods less than 1 s and two-dimensional for periods greater than 10 s. In addition, through the geomagnetic transfer function (tipper), the presence of structural electrical anisotropy was identified in the data. After the dimensional analysis, a deep electrical resistivity image was obtained by inverting a 2D and a 3D model. Surface conductive anomalies were obtained beneath the central depression related to the early dehydration of the slab and the serpentinization process of the mantle that coincides in location with a discontinuity in the electrical resistivity of a regional body that we identified as the Nazca plate. A shallow conductive body was located around the Calbuco volcano and was correlated with a magmatic chamber or reservoir which in turn appears to be connected to the Liquiñe Ofqui fault system and the Andean Transverse Fault system. In addition to the serpentinization process, when the oceanic crust reaches a depth of 80–100 km, the ascending fluids produced by the dehydration and phase changes of the minerals present in the oceanic plate produce basaltic melts in the wedge of the subcontinental mantle that give rise to an eclogitization process and this explains a large conductivity anomaly present beneath the main mountain range.

A test of airborne, side-looking synthetic-aperture radar in central Newfoundland for geological reconnaissance

1991 ◽  
Vol 28 (2) ◽  
pp. 257-265 ◽  
Author(s):  
D. F. Graham ◽  
D. R. Grant
Keyword(s):  
Surface Roughness ◽  
Synthetic Aperture Radar ◽  
Three Dimensional ◽  
Synthetic Aperture ◽  
Structural Elements ◽  
Terrain Classification ◽  
Regional Trends ◽  
Valuable Complement ◽  
Wide Swath ◽  
Aperture Radar

Side-looking, C-band synthetic-aperture radar (SAR) penetrates cloud and fog, and operates day or night, to produce pseudo-three-dimensional terrain images with enhanced topography and surface roughness. The images, which have a 20 m resolution and cover large areas, have been used to map the regional trends, patterns of lineaments, and terrain types over a 6200 km2 area of complex lithology, structure, and drift cover. Four lineament classes are differentiated. Glacial trends are clear, and bedrock structures (faults, fractures, joints, foliation, and folded bedding) with relief expression at the surface show through the drift as lineaments. They accurately reproduce most known features when compared with bedrock and Quatenary geology maps. Hitherto unrecognized structural elements are revealed. Tones and textures reflect minute surface roughness variations useful in terrain classification. SAR wide-swath-mode imagery is thus a valuable complement to aerial photography, and is superior in revealing hummocky moraine, ribbed moraine, boulder fields and stony till. Wider use of this imagery is encouraged.

scholarly journals Numerical simulation of dual-phase steel based on real and virtual three-dimensional microstructures

2021 ◽  
Author(s):  
Frederik Scherff ◽  
Jessica Gola ◽  
Sebastian Scholl ◽  
Kinshuk Srivastava ◽  
Thorsten Staudt ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Simulation Model ◽  
Dual Phase Steel ◽  
Three Dimensional ◽  
Simultaneous Increase ◽  
Dual Phase ◽  
Structure Property ◽  
Heavy Plate ◽  
Property Correlation ◽  
Process Route

AbstractDual-phase steel shows a strong connection between its microstructure and its mechanical properties. This structure–property correlation is caused by the composition of the microstructure of a soft ferritic matrix with embedded hard martensite areas, leading to a simultaneous increase in strength and ductility. As a result, dual-phase steels are widely used especially for strength-relevant and energy-absorbing sheet metal structures. However, their use as heavy plate steel is also desirable. Therefore, a better understanding of the structure–property correlation is of great interest. Microstructure-based simulation is essential for a realistic simulation of the mechanical properties of dual-phase steel. This paper describes the entire process route of such a simulation, from the extraction of the microstructure by 3D tomography and the determination of the properties of the individual phases by nanoindentation, to the implementation of a simulation model and its validation by experiments. In addition to simulations based on real microstructures, simulations based on virtual microstructures are also of great importance. Thus, a model for the generation of virtual microstructures is presented, allowing for the same statistical properties as real microstructures. With the help of these structures and the aforementioned simulation model, it is then possible to predict the mechanical properties of a dual-phase steel, whose three-dimensional (3D) microstructure is not yet known with high accuracy. This will enable future investigations of new dual-phase steel microstructures within a virtual laboratory even before their production.

Theoretical analysis of SWCNT- MWCNT/H2O hybrid flow over an upward/downward moving rotating disk

2021 ◽  
pp. 239779142098028
Author(s):  
R.J. Punith Gowda ◽  
R. Naveenkumar ◽  
J.K. Madhukesh ◽  
B.C. Prasannakumara ◽  
Rama Subba Reddy Gorla
Keyword(s):  
Heterogeneous Reaction ◽  
Three Dimensional ◽  
Rotating Disk ◽  
Heterogeneous Reactions ◽  
Hybrid Nanofluid ◽  
Boundary Constraints ◽  
Wide Range ◽  
Contraction Parameter ◽  
Dimensional Parameters ◽  
Source Sink

The flow-through various disk movement has wide range of applications in manufacturing processes like, computer storage equipment’s, rotating machines, electronic and various types of medical equipment’s. Inspired from these applications, here we scrutinised the consequences of homogeneous-heterogeneous reactions and uniform heat source/sink on the three-dimensional (3D) hybrid SWCNT-MWCNT’s flow on time dependent moving upward/downward rotating disk. The renowned innovation of this paper is the application of the hybrid nanofluid made up of SWCNT and MWCNT’s. Heat generation/absorption effect for the disk that does not move up or down creates a dual flow on the disk. Alternatively, the rotation and upright motion of the disk creates a 3D flow on the surface which has not been considered in the open literature. The modelled PDE’s are reduced in to ODE’s by opting suitable similarity variables and boundary constraints. Here, we used RKF-45 method to obtain the numerical approximations by adopting shooting technique. The analysis of rate of heat transfer is done through graphs. Further, change in velocity, thermal and concentration profiles for various non-dimensional parameters are deliberated briefly and illustrated with the help of suitable plots. The results reveal that, the, rise in values of homogeneous and heterogeneous reaction parameters improve the rate of reaction which results in reduction of the distribution rate and diminishes the concentration gradient. An increase in expansion/contraction parameter enhances the velocity and thermal gradients.

scholarly journals Finite element solution of the three-dimensional system of equations of heat dynamics of friction and wear during single braking

2018 ◽  
Vol 10 (11) ◽  
pp. 168781401880864 ◽  
Author(s):  
Piotr Grzes
Keyword(s):  
Friction And Wear ◽  
Mutual Influence ◽  
Three Dimensional ◽  
Maximum Temperature ◽  
Dimensional System ◽  
System Of Equations ◽  
Sliding Velocity ◽  
Flash Temperature ◽  
Disk Brake ◽  
Discrete Contact

A three-dimensional numerical model of a disk brake to study temperature on a discrete contact of rough surfaces has been developed. It includes the system of equations formulated based on thermotribological postulates of heat dynamics of friction and wear with mutual influence of contact pressure, velocity, properties of materials, and temperature. Two approaches of calculation of the flash temperature and its influence on the maximum temperature during a single braking application were studied. Changes in the contact temperature, sliding velocity, and the thermomechanical wear during braking were shown and discussed. It was found that two of the examined variants of calculation of the flash temperature agree well for the three considered materials of the brake pads combined with the cast iron disk, at each initial sliding velocity in the range from 5 to 20 m s−1.

scholarly journals Supercritical carbon dioxide design strategies: from drug carriers to soft killers

2015 ◽  
Vol 373 (2057) ◽  
pp. 20150009 ◽  
Author(s):  
Ana Aguiar-Ricardo ◽  
Vasco D. B. Bonifácio ◽  
Teresa Casimiro ◽  
Vanessa G. Correia
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Three Dimensional ◽  
Polymeric Materials ◽  
Drug Carriers ◽  
Water Soluble ◽  
Materials Processing ◽  
Design Strategies ◽  
Simple Economic ◽  
Supercritical Carbon

The integrated use of supercritical carbon dioxide (scCO 2 ) and micro- and nanotechnologies has enabled new sustainable strategies for the manufacturing of new medications. ‘Green’ scCO 2 -based methodologies are well suited to improve either the synthesis or materials processing leading to the assembly of three-dimensional multifunctional constructs. By using scCO 2 either as C1 feedstock or as solvent, simple, economic, efficient and clean routes can be designed to synthesize materials with unique properties such as polyurea dendrimers and oxazoline-based polymers/oligomers. These new biocompatible, biodegradable and water-soluble polymeric materials can be engineered into multifunctional constructs with antimicrobial activity, targeting moieties, labelling units and/or efficiently loaded with therapeutics. This mini-review highlights the particular features exhibited by these materials resulting directly from the followed supercritical routes.

Numerical Comparative Analysis of In-Cylinder Tumble Flow Structures in Small PFI Engines Equipped by Heads Having Different Shapes and Squish Areas

2012 ◽  
Author(s):  
Stefania Falfari ◽  
Gian Marco Bianchi ◽  
Luca Nuti
Keyword(s):  
Flow Structure ◽  
Mutual Influence ◽  
Ignition Time ◽  
Three Dimensional ◽  
Valve Lift ◽  
Spark Plug ◽  
Piston Valve ◽  
Cylinder Flow ◽  
Roof Angle ◽  
Motorcycle Engine

For increasing the thermal engine efficiency, faster combustion and low cycle-to-cycle variation are required. In PFI engines the organization of in-cylinder flow structure is thus mandatory for achieving increased efficiency. In particular the formation of a coherent tumble vortex with dimensions comparable to engine stroke largely promotes proper turbulence production extending the engine tolerance to dilute/lean mixture. For motorbike and scooter applications, tumble has been considered as an effective way to further improve combustion system efficiency and to achieve emission reduction since layout and weight constraints limit the adoption of more advanced concepts. In literature chamber geometry was found to have a significant influence on bulk motion and turbulence levels at ignition time, while intake system influences mainly the formation of tumble vortices during suction phase. The most common engine parameters believed to affect in-cylinder flow structure are: 1. Intake duct angle; 2. Inlet valve shape and lift; 3. Piston shape; 4. Pent-roof angle. The present paper deals with the computational analysis of three different head shapes equipping a scooter/motorcycle engine and their influence on the tumble flow formation and breakdown, up to the final turbulent kinetic energy distribution at spark plug. The engine in analysis is a 3-valves pent-roof motorcycle engine. The three dimensional CFD simulations were run at 6500 rpm with AVL FIRE code on the three engines characterised by the same piston, valve lift, pent-roof angle and compression ratio. They differ only in head shape and squish areas. The aim of the present paper is to demonstrate the influence of different head shapes on in-cylinder flow motion, with particular care to tumble motion and turbulence level at ignition time. Moreover, an analysis of the mutual influence between tumble motion and squish motion was carried out in order to assess the role of both these motions in promoting a proper level of turbulence at ignition time close to spark plug in small 3-valves engines.

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