Accelerated Weathering Testing of Polypropylene Tank Materials

2021 ◽  
Vol 1037 ◽  
pp. 154-160
Author(s):  
Alfred M. Suleymanov ◽  
Ekaterina B. Tuisina ◽  
L.N. Shafigullin ◽  
Roman Rinberg ◽  
Azat T. Gabdrakhmanov
Keyword(s):  
Impact Strength ◽  
Uv Radiation ◽  
Flexural Modulus ◽  
Operating Conditions ◽  
Accelerated Weathering ◽  
Interior Structure ◽  
Elongation At Break ◽  
Inner Pressure ◽  
Strain Behaviour ◽  
Higher Temperature

Polypropylene expansion tanks have been subjected to accelerated weathering testing according to the developed procedure of accelerated weathering testing. The objective of the study was to determine an arbitrary lifetime of tanks under operating conditions at higher temperatures, humidity, and UV radiation (climate regions of India and Venezuela). As a result of the studies of the polypropylene expansion tanks the following has been established: the failure of the both tank types (A and B) occurred in the area of the weld in the upper and lower part after four arbitrary years of accelerated weathering testing; the stress-strain behaviour in the outer tank walls is influenced by the interior structure of the partitions. The tanks with a larger opening in the partitions feature significant deformations when the inner pressure increases as a result of a higher temperature; the “sensitive indicators” of ageing and failure of the tank material have been found: elongation at break, flexural modulus, and impact strength.

scholarly journals The Structure and Mechanical Properties of Hemp Fibers-Reinforced Poly(ε-Caprolactone) Composites Modified by Electron Beam Irradiation

2021 ◽  
Vol 11 (12) ◽  
pp. 5317
Author(s):  
Rafał Malinowski ◽  
Aneta Raszkowska-Kaczor ◽  
Krzysztof Moraczewski ◽  
Wojciech Głuszewski ◽  
Volodymyr Krasinskyi ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Electron Beam ◽  
Impact Strength ◽  
Flexural Modulus ◽  
Natural Fibers ◽  
High Energy ◽  
Electron Radiation ◽  
Elongation At Break ◽  
Hemp Fibers

The need for the development of new biodegradable materials and modification of the properties the current ones possess has essentially increased in recent years. The aim of this study was the comparison of changes occurring in poly(ε-caprolactone) (PCL) due to its modification by high-energy electron beam derived from a linear electron accelerator, as well as the addition of natural fibers in the form of cut hemp fibers. Changes to the fibers structure in the obtained composites and the geometrical surface structure of sample fractures with the use of scanning electron microscopy were investigated. Moreover, the mechanical properties were examined, including tensile strength, elongation at break, flexural modulus and impact strength of the modified PCL. It was found that PCL, modified with hemp fibers and/or electron radiation, exhibited enhanced flexural modulus but the elongation at break and impact strength decreased. Depending on the electron radiation dose and the hemp fibers content, tensile strength decreased or increased. It was also found that hemp fibers caused greater changes to the mechanical properties of PCL than electron radiation. The prepared composites exhibited uniform distribution of the dispersed phase in the polymer matrix and adequate adhesion at the interface between the two components.

scholarly journals Improving Mechanical Properties of PLA/Starch Blends Using Masterbatch Containing Vegetable Oil Based Active Ingredients

Polymers ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2981
Author(s):  
Bianka Nagy ◽  
Norbert Miskolczi ◽  
Zoltán Eller
Keyword(s):  
Impact Strength ◽  
Vegetable Oil ◽  
Rapeseed Oil ◽  
Flexural Modulus ◽  
Charpy Impact ◽  
Sem Images ◽  
Elongation At Break ◽  
Starch Concentration ◽  
Starch Blends ◽  
Charpy Impact Strength

The aim of this research was to increase the compatibility between PLA and starch with vegetable oil-based additives. Based on tensile results, it can be stated, that Charpy impact strength could be improved for 70/30 and 60/40 blends in both unconditioned and conditioned cases, regardless of vegetable oil, while no advantageous change in impact strength was obtained with PLA-g-MA. Considering sample with the highest starch concentration (50%), the flexural modulus was improved by using sunflower oil-based additive, Charpy impact strength and elongation at break was increased using rapeseed oil-based additive in both conditioned and unconditioned cases. SEM images confirmed the improvement of compatibility between components.

Effect of wood particle size on selected properties of neat and recycled wood polypropylene composites

BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 3427-3442
Author(s):  
Vedat Çavuş ◽  
Fatih Mengeloğlu
Keyword(s):  
Particle Size ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
Wood Flour ◽  
Flexural Modulus ◽  
Tensile Modulus ◽  
Wood Particle ◽  
Sem Analysis ◽  
Elongation At Break

Neat polypropylene (PP)- and post-industrial recycled polypropylene (rPP)-based wood-plastic composites (WPC) were manufactured using 40% mahogany wood flour (WF). The effect of particle size (0.074 to 0.149 mm, 0.177 to 0.250 mm, and 0.400 to 0.841 mm) on the selected properties of PP and rPP composites was studied. The influence of 3% maleic anhydride grafted polypropylene (MAPP) presence in the formulation was also evaluated. Test specimens were manufactured using a combination of extrusion and injection molding processes. The density and mechanical properties, such as flexural strength, flexural modulus, tensile strength, tensile modulus, elongation at break, hardness and impact strength values were determined. Morphology of the manufactured composites was also studied using scanning electron microscopy (SEM) analysis. Results showed that the particle size, polypropylene type (neat or recycled), and presence of MAPP had important effects on WPC’s properties. Density, flexural modulus, tensile modulus, and impact strength values increased with decreased particle size regardless of the presence of MAPP. Flexural strength values increased with decreased particle size without MAPP. Regardless of particle size, addition of MAPP in composites provided higher flexural strength, flexural modulus, tensile strength, and tensile modulus values but lower elongation at break values compared to composites without MAPP.

Evaluation of morphological characteristics and mechanical performance of Rockforce mineral fiber- and glass fiber-reinforced polyamide-6 composites

2014 ◽  
Vol 21 (3) ◽  
pp. 323-328 ◽  
Author(s):  
Huseyin Unal ◽  
A. Mimaroglu
Keyword(s):  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
Glass Fiber ◽  
Flexural Modulus ◽  
Morphological Characteristics ◽  
Tensile Modulus ◽  
Polyamide 6 ◽  
Uniaxial Tensile ◽  
Elongation At Break

AbstractIn this study, the effect of addition of Rockforce mineral and glass fiber fillers on the mechanical properties and morphological characteristics of polyamide-6 composites were evaluated and compared. Reinforcements, single and mixed compounds by various weight ratios between 10 and 30 wt%, were added to polyamide-6 polymer. Uniaxial tensile, Izod impact, and flexural tests were carried out. Tensile strength, elongation at break, tensile modulus, flexural strength, flexural modulus, and impact strength were obtained. The results showed that the tensile strength, tensile modulus, flexural strength, and flexural modulus of polyamide-6 composite increased with the increase in the glass fiber ratio and are slightly influenced by the addition of Rockforce mineral fibers. Moreover, the impact strength follows an increasing and decreasing profile, whereas elongation at break values decreased with the increase in reinforcement ratio. Finally, scanning electron microscopy was used for comparison and evaluation of the fracture surface of the polyamide-6 composite.

Effect of SEBS on the Mechanical Properties and Miscibility of Polystyrene Rich Polystyrene/ Polypropylene Blends

2005 ◽  
Vol 21 (4) ◽  
pp. 261-276 ◽  
Author(s):  
Sani Amril Samsudin ◽  
Azman Hassan ◽  
Munirah Mokhtar ◽  
Syed Mustafa Syed Jamaluddin
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Flexural Modulus ◽  
Elongation At Break ◽  
Blend Composition ◽  
Twin Screw ◽  
Strength And Stiffness ◽  
Polypropylene Blends ◽  
Pp Blends ◽  
The Impact

Blends of polystyrene (PS) with polypropylene (PP) are usually developed to overcome the inherent brittleness of PS. However, PS with PP are immiscible and (in the absence of a compatibiliser) incompatible. The present study investigated the effects of styrene-b (ethylene-co-butylene)-b-styrene (SEBS) on the mechanical properties and compatibility of PS-rich PS/PP blends. Using a Brabender PL2000 twin-screw extruder, blends of PS/PP in various compositions ranging from 100-60 wt% PS with and without SEBS were prepared and injection moulded. The overall results clearly showed that the mechanical properties of PS/PP blends are dependent on blend composition (ratio of PS/PP) and SEBS content. The impact strength and elongation at break of the PS/PP blends increase with SEBS content, at the expense of tensile strength and flexural modulus. The improvements in impact strength and elongation at break with the addition of SEBS are due to the improved interfacial adhesion between the dispersed phase (PP) and matrix phase (PS). The improvement in miscibility of the PS/PP blend with the addition of SEBS is supported by DMA analysis. This showed that the 60/40 PS/PP blends possess two endothermic peaks whereas 60/40/25 PS/PP/SEBS blends have a single endothermic peak at 102 °C, indicating that they have an improved miscibility. The effectiveness of SEBS in enhancing the blends depends on the blend composition. A significant improvement was observed upon addition of more than 10 phr of SEBS into the 70/30 and 60/40 PS/PP blends, but not much improvement in the case of the 90/10 and 80/20 PS/PP blends. However, a higher SEBS content is more effective at higher PS contents, as illustrated by the 90/10/25 PS/PP/SEBS blends having higher impact strengths than 60/40/25 PS/PP/SEBS. The optimum blend, based on achieving a balance between toughness (impact strength) and stiffness (flexural modulus), is 90/10/25 PS/PP/SEBS, followed by 80/20/25 PS/PP/SEBS.

Impact Strength, Flexural Modulus and Wear Rate of PMMA Composites Reinforced by Eggshell Powders

2020 ◽  
Vol 38 (7A) ◽  
pp. 960-966
Author(s):  
Aseel M. Abdullah ◽  
Hussein Jaber ◽  
Hanaa A. Al-Kaisy
Keyword(s):  
Impact Strength ◽  
Wear Rate ◽  
Flexural Modulus ◽  
Matrix Material ◽  
Weight Fraction ◽  
Pure Pmma ◽  
Calcination Process ◽  
The Matrix ◽  
The Impact ◽  
Interface Bond

In the present study, the impact strength, flexural modulus, and wear rate of poly methyl methacrylate (PMMA) with eggshell powder (ESP) composites have been investigated. The PMMA used as a matrix material reinforced with ESP at two different states (including untreated eggshell powder (UTESP) and treated eggshell powder (TESP)). Both UTESP and TESP were mixed with PMMA at different weight fractions ranged from (1-5) wt.%. The results revealed that the mechanical properties of the PMMA/ESP composites were enhanced steadily with increasing eggshell contents. The samples with 5 wt.% of UTESP and TESP additions give the maximum values of impact strength, about twice the value of the pure PMMA sample. The calcination process of eggshells powders gives better properties of the PMMA samples compared with the UTESP at the same weight fraction due to improvements in the interface bond between the matrix and particles. The wear characteristics of the PMMA composites decrease by about 57% with increases the weight fraction of TESP up to 5 wt.%. The flexural modulus values are slightly enhanced by increasing of the ESP contents in the PMMA composites.

scholarly journals Low-Temperature Mechanical Properties of High-Density and Low-Density Polyethylene and Their Blends

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1821
Author(s):  
Ildar I. Salakhov ◽  
Nadim M. Shaidullin ◽  
Anatoly E. Chalykh ◽  
Mikhail A. Matsko ◽  
Alexey V. Shapagin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Impact Strength ◽  
Relative Elongation ◽  
High Density ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Subzero Temperatures ◽  
Izod Impact

Low-temperature properties of high-density polyethylene (HDPE), low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), and their blends were studied. The analyzed low-temperature mechanical properties involve the deformation resistance and impact strength characteristics. HDPE is a bimodal ethylene/1-hexene copolymer; LDPE is a branched ethylene homopolymer containing short-chain branches of different length; LLDPE is a binary ethylene/1-butene copolymer and an ethylene/1-butene/1-hexene terpolymer. The samples of copolymers and their blends were studied by gel permeation chromatography (GPC), differential scanning calorimetry (DSC), 13С NMR spectroscopy, and dynamic mechanical analysis (DMA) using testing machines equipped with a cryochamber. It is proposed that such parameters as “relative elongation at break at −45 °C” and “Izod impact strength at −40 °C” are used instead of the ductile-to-brittle transition temperature to assess frost resistance properties because these parameters are more sensitive to deformation and impact at subzero temperatures for HDPE. LLDPE is shown to exhibit higher relative elongation at break at −45 °C and Izod impact strength at −20 ÷ 60 °C compared to those of LDPE. LLDPE terpolymer added to HDPE (at a content ≥ 25 wt.%) simultaneously increases flow properties and improves tensile properties of the blend at −45 °C. Changes in low-temperature properties as a function of molecular weight, MWD, crystallinity, and branch content were determined for HDPE, LLDPE, and their blends. The DMA data prove the resulting dependences. The reported findings allow one to understand and predict mechanical properties in the HDPE–LLDPE systems at subzero temperatures.

Mechanical, Thermal, and Morphological Properties of Thermoplastic Starch/Poly(lactic acid/Poly(butylene adipate-co-terephthalate) Blends

2014 ◽  
Vol 970 ◽  
pp. 312-316
Author(s):  
Sujaree Tachaphiboonsap ◽  
Kasama Jarukumjorn
Keyword(s):  
Lactic Acid ◽  
Impact Strength ◽  
Interfacial Adhesion ◽  
Tensile Modulus ◽  
Thermoplastic Starch ◽  
Morphological Properties ◽  
Poly Lactic Acid ◽  
Melt Blending ◽  
Elongation At Break ◽  
Blending Method

Thermoplastic starch (TPS)/poly (lactic acid) (PLA) blend and thermoplastic starch (TPS)/poly (lactic acid) (PLA)/poly (butylene adipate-co-terephthalate) (PBAT) blend were prepared by melt blending method. PLA grafted with maleic anhydride (PLA-g-MA) was used as a compatibilizer to improve the compatibility of the blends. As TPS was incorporated into PLA, elongation at break was increased while tensile strength, tensile modulus, and impact strength were decreased. Tensile properties and impact properties of TPS/PLA blend were improved with adding PLA-g-MA indicating the enhancement of interfacial adhesion between PLA and TPS. With increasing PBAT content, elongation at break and impact strength of TPS/PLA blends were improved. The addition of TPS decreased glass transition temperature (Tg), crystallization temperature (Tc), and melting temperature (Tm) of PLA. Tgand Tcof TPS/PLA blend were decreased by incorporating PLA-g-MA. However, the presence of PBAT reduced Tcof TPS/PLA blend. Thermal properties of TPS/PLA/PBAT blends did not change with increasing PBAT content. SEM micrographs revealed that the compatibilized TPS/PLA blends exhibited finer morphology when compared to the uncompatibilized TPS/PLA blend.

Experimental Investigation on the Rubbing Process of Labyrinth Seals Considering the Material Combination

2020 ◽  
Author(s):  
Lisa Hühn ◽  
Oliver Munz ◽  
Corina Schwitzke ◽  
Hans-Jörg Bauer
Keyword(s):  
Turbine Blades ◽  
Design Guidelines ◽  
Operating Conditions ◽  
Contact Forces ◽  
Experimental Investigations ◽  
Process Data ◽  
Labyrinth Seals ◽  
Material Combination ◽  
Higher Temperature ◽  
And Control

Abstract Labyrinth seals are used to prevent and control the mass flow rate between rotating components. Due to thermally and mechanically induced expansions during operation and transient flight maneuvers, a contact, the so-called rubbing process, between rotor and stator cannot be excluded. A large amount of rubbing process data concerning numerical and experimental investigations is available in public literature as well as at the Institute of Thermal Turbomachinery (ITS). The investigations were carried out for different operating conditions, material combinations, and component geometries. In combination with the experiments presented in this paper, the effects of the different variables on load due to rubbing are compared, and discussed with the focus lying on the material combination. The influence of the material on the loads can be identified as detailed as never before. For example, the contact forces in the current experiments are higher due to a higher temperature resistance of Young’s modulus. The analysis will also be based on the rubbing of turbine blades. Design guidelines are derived for labyrinth seals with improved properties regarding tolerance of rub events. Based on the knowledge obtained, guidelines for designing reliable labyrinth seals for future engines are discussed.

scholarly journals Effect of Gamma Radiation on the Mechanical Properties of Natural Fabric Reinforced Polyester Composites

2019 ◽  
Vol 27 (4(136)) ◽  
pp. 88-93
Author(s):  
K.Z.M. Abdul Motaleb ◽  
Md Shariful Islam ◽  
Rimvydas Milašius
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Gamma Radiation ◽  
Bending Strength ◽  
Polyester Resin ◽  
Radiation Doses ◽  
Elongation At Break ◽  
Bending Modulus ◽  
Polyester Composites

Two types of composites:(1) pineapple fabric reinforced polyester resin (Pineapple/PR) and (2) jute fabric reinforced polyester resin (Jute/PR) were prepared and the mechanical properties investigated for various gamma radiation doses ranging from 100-500 krad. Properties like tensile strength, Young’s modulus, elongation-at-break, bending strength, bending modulus and impact strength were increased significantly by 19%, 32%, 45%, 32%, 47% and 20%, respectively, at a dose of 300 krad for Pineapple/PR, and by 47%, 49%, 42%, 45%, 52% and 65%, respectively, at a dose of 200 krad for the Jute/PR composite in comparison to the non-irradiated composite. Gamma radiation improved the mechanical properties, but overdoses of radiation even caused a reduction in them.

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