Evaluation of Physicochemical and Biodegradability Properties of Selected Nigerian Non-Edible Oilseeds as Potential Cutting Fluids

2015 ◽  
Vol 58 (3) ◽  
pp. 122-129
Author(s):  
Titilope John Jayeoye ◽  
Mary Bosede Ogundiran ◽  
David Abimbola Fadare ◽  
Adeniyi Adewale Ogunjobi
Keyword(s):  
Specific Gravity ◽  
Iodine Value ◽  
Peroxide Value ◽  
Physicochemical Parameters ◽  
Extraction Process ◽  
Mineral Oil ◽  
Oil Extraction ◽  
Cutting Fluid ◽  
Cutting Fluids ◽  
Saponification Value

This paper reports evaluation of physicochemical and biodegradability properties of selected non edible Nigerian oilseeds as a potential cutting fluid. Oil extraction process was carried on the oilseeds, with physicochemical parameters and biodegradability of the extracts were equally assessed. The established physicochemical parameters were percentage oil yield (5.58-61.8%), specific gravity (0.86-0.94), acidvalue (2.89-18.2 mgKOH/g), iodine value (15.7-104 mg iodine/g), peroxide value (1.35-10.9 mg/g oil), saponification value (173-286 mg KOH/g) and viscosity (37.9-53.1centipoises), while biodegradabilityranged between (50.0-63.8%) in comparison with the mineral oil with values less than 20%. Based on this study, the oil extracts of Caesalpinia bonduc and Calophyllum inophyllum appeared to be the most suitable as potential cutting fluids for further formulation studies and machining trials. 

scholarly journals Effects of Extracting Solvents on the Physicochemical Properties of Alchornea cordiforlia, Hura crepitans, Irvingia gabonensis and Pycnanthus angollensis Oils

2020 ◽  
pp. 20-27
Author(s):  
Michael Akomaye Akpe ◽  
Faith Patrick Inezi
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Specific Gravity ◽  
Physicochemical Properties ◽  
Petroleum Ether ◽  
Iodine Value ◽  
Peroxide Value ◽  
Acid Value ◽  
Flash Point ◽  
Saponification Value

Aims and Objectives: To determine the effect of extracting solvents on the physicochemical properties of oils extracted from four locally available plant seeds in Nigeria namely: Alchornea cordiforlia, Hura crepitans, Irvingia gabonensis and Pycnanthus angollensis using three different solvents namely; n-Hexane, Petroleum ether and Dichloromethane. Place and Duration of Study: Department of Chemistry Laboratory, University of Calabar, Nigeria. The study was carried out between August 2019 and December 2019, (5 months). Methodology: Each plant seed was ground into a paste and extracted for its oil using a Soxhlet extractor and three different solvents namely; n-Hexane, Petroleum ether and Dichloromethane. The physicochemical properties of the oils were then analysed. Results: The results revealed the mean values of the physicochemical properties of A. cordifolia oil extracted using Hexane, Petroleum ether and Dichloromethane respectively were % yield (36.50, 34.50 and 32.00), specific gravity (0.91, 0.91 and 0.92), flash point (156.00, 155.00 and 191.00°C), Acid value (23.76, 25.10 and 26.80 mEqk-1), % free fatty acid (11.88, 12.55 and 13.40), Peroxide value (6.56, 6.38 and 6.90 mEqK-1), Saponification value (163.20, 156.40 and 165.50 mgKOHg-1) and iodine value (25.40, 48.60 and 46.50 g/100 g). The mean values of the properties of H. crepitans oil across the 3 solvents respectively were % yield (32.20, 31.50 and 29.00), specific gravity (0.92, 0.93 and 0.94), flash point (271.00, 259.00 and 240.00°C), Acid value (21.00, 21.80 and 22.20 mEqk-1), % free fatty acid (10.50, 10.90 and 11.10), Peroxide value (5.85, 6.26 and 7.10 mEqK-1), Saponification value (172.50, 190.40 and 185.60 mgKOHg-1) and Iodine value (43.60, 34.50 and 26.90 g/100 g). Properties of the I. gabonensis oil were % yield (33.20, 34.00 and 32.50), Specific gravity (0.92, 0.94 and 0.94), flash point (230.00, 236.00 and 260.00°C), Acid value (3.72, 3.70 and 3.90 mEqk-1), % free fatty acid (1.86, 1.85 and 1.95), Peroxide value (2.98, 4.26 and 3.63), Saponification value (239.50, 252.40 and 245.80) and Iodine value (25.30, 11.70 and 44.20). Mean values of P. angollensis oil properties were % yield (34.10, 36.20 and 33.00), Specific gravity (0.92, 0.92 and 0.93), flash point (260.00, 258.00 and 256.00°C), Acid value (23.68, 25.00 and 26.00 mEqk-1), % free fatty acid (11.84, 12.50 and 13.00), Peroxide value (4.25, 5.30 and 5.96), Saponification value (25.30, 52.50 and 57.30) and Iodine value (25.20, 11.68 and 44.40). The odour, colour and physical state of all the oils at room temperature was the same across the 3 solvents. Conclusion: The results indicate that the physicochemical properties of the oils vary with the extracting solvent and its polarity. Their properties revealed that some of them can be used for many domestic and industrial purposes especially for the making of paints, soap, cosmetics, lubricants and varnishes.

scholarly journals Physiochemical analysis of oil extracted from Vitelleria paradoxa seed obtained from Wukari North Eastern Nigeria

2021 ◽  
Vol 4 (1) ◽  
pp. 059-066
Author(s):  
Azuaga TI ◽  
Azuaga IC ◽  
Okpaegbe UC ◽  
Ibrahim AI ◽  
Manasseh CK
Keyword(s):  
Fatty Acid ◽  
Melting Point ◽  
Free Fatty Acid ◽  
Specific Gravity ◽  
Moisture Content ◽  
Iodine Value ◽  
Oil Recovery ◽  
Acid Value ◽  
Ash Content ◽  
Saponification Value

Soxhlet extraction of oil from seeds of Vitelleria paradoxa was carried out using n-hexane as the solvent. Standards methods were adopted in the analysis of the physiochemical properties; moisture content, melting point, total ash content, pH, specific gravity, iodine value, saponification value, acid value, free fatty acid value and ester value were all evaluated. The oil recovery rate was good with 32.6% yield, moisture content of 3.1%, melting point of 52oC and pH 5.7. Total ash content was 50.3%, specific gravity of 0.9 g/cm3, iodine value 39 mg/L, saponification value 224.6 mgKOH/g, acid value 59.9 mgKOH/g free fatty acid (FFA) 29.9 mgKOH/L and ester value 164.7 mg/L. The results shows that oil from Vitelleria paradoxa seed holds the potentials for wider applications in foods, cosmetics, pharmaceuticals, lubricants and soap making.

scholarly journals COMPARATIVE PHARMACEUTICO ANALYTICAL STUDY TO EVALUATE THE CONCEPT OF AVARTANA WITH SPECIAL REFERENCE TO 1, 10, 50, 100 AVARTITA MADHUKA TAILA

2021 ◽  
Vol 9 (7) ◽  
pp. 1334-1343
Author(s):  
Anagha. V. G ◽  
Vikram. S
Keyword(s):  
Refractive Index ◽  
Specific Gravity ◽  
Iodine Value ◽  
Peroxide Value ◽  
Milk Fat ◽  
Analytical Study ◽  
Acid Value ◽  
High Potency ◽  
Active Constituents ◽  
Rf Values

Avartana is a unique concept mentioned for Sneha Kalpana. The more the number of Avartana the more potent will be the formulation. “Shata Paka Madhuka Taila" is one such formulation that is explained in Charaka Chikitsa Vataraktha Adhikara. Samples were subjected to pharmaceutico - Analytical study to compare the probable changes that would have happened pharmaceutically & analytically. Shata paka Madhuka Taila was prepared as per reference & samples were Analysed. The change in the organoleptic characters of all the Avartita samples was noted. Consistency of taila to semisolid consistency of ghruta in proceeding Avartana was observed. A slight increase in specific gravity & Refractive index were noted, decrease in acid value & iodine value was observed. Rancidity test passed & peroxide value was nil. slight acidic pH was noted. The presence of more bands with different Rf values was seen towards 50th, 75th & 100th Avartita samples on TLC. Pharmaceutical procedure reveals that concentration of the Active bio constituents of yastimadhu & milk fat gets increased in each Avartana., And it was evident from organoleptic characters like conversion of liquid Consistency of taila to semisolid consistency of ghruta (on cooling) in proceeding Avartana. A slight increase in specific gravity & Refractive index suggests more active constituents, decrease in acid value & iodine value suggests products are more stable & less chance of rancid on successive avartana. Rancidity & peroxide value tells product are not rancid. pH changes indicate slight acidicnature & may be irritant due to high potency. TLC shows the presence of more bands towards 50th, 75th& 100th avarti samples shows more active constituents. Hence Avartana process helps for potentiating the formulation by adding active constituents. Keywords: Sneha Kalpana, Avartana, Shata Paka Madhuka Taila.

Compositional characteristics of cherry kernel oil as influenced by gamma irradiation and storage periods

2020 ◽  
pp. 108201322095673
Author(s):  
M Al-Bachir ◽  
Y Koudsi
Keyword(s):  
Refractive Index ◽  
Gamma Irradiation ◽  
Iodine Value ◽  
Peroxide Value ◽  
Research Work ◽  
Thiobarbituric Acid ◽  
Acid Value ◽  
Thiobarbituric Acid Reactive Substances ◽  
Saponification Value ◽  
And Storage

This research work was undertaken to evaluate the physicochemical parameters of oil from the cherry kernel non-irradiated and irradiated at 3 and 6 kGy of gamma irradiation for two storage periods (0 and 12 months). The acid value, peroxide value, thiobarbituric acid reactive substances value, iodine value, saponification value refractive index (peroxide value), and the color parameters of cherry kernel oils were determined. The results indicated that the extracted cherry kernel oils were liquid at room temperature with color varying from light yellow to deep red. The physicochemical properties of cherry kernel oils including acid value, peroxide value, thiobarbituric acid reactive substances, iodine value, saponification value, and refractive index values were 1.19 mg KOH g−1, 9.01 meq2 kg−1, 0.014 mg MDA kg−1, 99.48 KOH g−1 I2 100 g−1, 194.50 mg KOH g−1, and 1.472, respectively. Generally, gamma irradiation doses and storage time increased acid value, peroxide value, thiobarbituric acid reactive substances, and refractive index value of cherry kernel oils, whereas no significant (p > 0.05) change due to irradiation was recorded in iodine value, saponification value, and in color parameter (L*, a*, b*, and ΔE values) of cherry kernel oils. However, the properties of cherry kernel oils revealed that the cherry kernel is a good source of oil which could be used for industrial purposes.

scholarly journals Experimental Determination of Cutting Power for Turning and Material Removal Rate for Drilling of AA 6061-T6 Using Vegetable Oils as Cutting Fluid

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Y. M. Shashidhara ◽  
S. R. Jayaram
Keyword(s):  
Vegetable Oils ◽  
Material Removal Rate ◽  
Cutting Forces ◽  
Material Removal ◽  
Removal Rate ◽  
Mineral Oil ◽  
Cutting Fluid ◽  
Cutting Fluids ◽  
Cutting Power ◽  
Thrust Forces

The raw and modified versions of two nonedible vegetable oils, Pongam (Pogammia pinnata) and Jatropha (Jatropha curcas), and a commercially available branded mineral oil are used as straight cutting fluids for turning AA 6061 to assess cutting forces. Minimum quantity lubrication is utilized for the supply of cutting fluids. Cutting and thrust forces are measured. Cutting power is determined for various cutting speeds, depths of cut, and feed rates. Also, drilling is performed on the material to understand the material removal rate (MRR) under these oils. The performances of vegetable oils are compared to mineral oil. A noticeable reduction in cutting forces is observed under the Jatropha family of oils compared to mineral oil. Further, better material removal rate is seen under both the vegetable oils and their versions compared to under petroleum oil for the range of thrust forces.

scholarly journals Effect of Solvents and Extraction Conditions on the Properties of Crude Rice Bran Oil

2021 ◽  
Vol 18 (17) ◽  
Author(s):  
Benchamaporn PIMPA ◽  
Chakree THONGRAUNG ◽  
Pornpong SUTTHIRAK
Keyword(s):  
Fatty Acids ◽  
Rice Bran ◽  
Iodine Value ◽  
Rice Bran Oil ◽  
Oil Extraction ◽  
Optimum Conditions ◽  
Hexane Extraction ◽  
Ethanol Extraction ◽  
Effect Of Solvents ◽  
Saponification Value

This research aimed to study the effect of solvents, namely n-hexane and ethanol, on the yield of crude rice bran oil extraction. The effects of extraction temperatures of 50, 60, and 70 ºC and extraction times of 1, 3, 6, 12, and 24 h were investigated. Rice bran composition was determined. It was found that protein, lipid, moisture, fiber, ash, and carbohydrate content were 12.65±0.56, 16.32±0.81, 7.65±0.62, 10.25±0.64, 6.38±0.59, and 46.75 %, respectively. From the results, the rice bran oil yield from n-hexane extraction was significantly higher than ethanol extraction, with p < 0.05. The maximum rice bran oil obtained from n-hexane extraction was 16.23±0.34 %. The highest yield of rice bran oil was obtained from extraction temperature of 60 - 70 ºC for 12 - 24 h. After extraction by the optimum conditions at 60 ºC for 12 h, the rice bran oil was kept for 1, 2, 3, 4, and 8 weeks for investigation of its quality changes. It can be concluded that the optimum conditions for rice bran oil extraction was with using n-hexane as a solvent for extraction at a temperature of 60 ºC for 12 h. Storing oil for 0, 1, 2, 4, and 8 weeks resulted in the increase of free fatty acids (FFA) and peroxide value, whereas iodine value and saponification value were relatively constant. HIGHLIGHTS n-Hexane and ethanol effect the yield of crude rice bran oil extraction The rice bran oil yield from n-hexane extraction was higher than ethanol extraction The optimum conditions for rice bran oil extraction were with using n-hexane as a solvent for extraction at a temperature of 60 ºC for 12 h Storing rice bran oil for 8 weeks resulted in the increase of free fatty acids (FFA) and peroxide value, whereas iodine value and saponification value were relatively constant

scholarly journals Performance Evaluation of Jatropha Seed Oil and Mineral Oil-Based Cutting Fluids in Turning AISI 304 Alloy Steel

2020 ◽  
Vol 5 (3) ◽  
pp. 85-97
Author(s):  
Emmanuel Awode ◽  
Sunday Albert Lawal ◽  
Matthew Sunday Abolarin ◽  
Oyewole Adedipe
Keyword(s):  
Surface Roughness ◽  
Tool Wear ◽  
Alloy Steel ◽  
Seed Oil ◽  
Mineral Oil ◽  
Cutting Fluid ◽  
Cutting Fluids ◽  
Aisi 304 ◽  
Physiochemical Property ◽  
Jatropha Seed

Cutting fluids play a major role in machine operations, life of tools, workpiece quality and overall high productivity which are considered as potential input for minimal tool wear, minimal surface roughness and better machining finished product owing to the ability to prevent overheating of the workpiece and cutting tool. In this paper, the challenge of environmental biodegradability, tool wear and workpiece surface roughness prompt the need to evaluate and compare the performance of Jatropha oil based cutting fluid (JBCF) with mineral oil based cutting fluid (MBCF) during turning with AISI 304 Alloy steel which are presented. Test were conducted on the Physiochemical property, fatty acid composition (FAC), cutting fluids formulation of oil ratio to water ratio in proportion of 1:9, turning operation and response surface methodology (RSM) design of experiment were carried out and used respectively. Results from FAC indicated that jatropha seed oil (JSO) has an approximately 21.6% saturated fat with the main contributors being 14.2% palmitic acid. The physiochemical property results show pH value 8.36, Viscosity 0.52 mm2/s, resistant to corrosion, good stability and a milky colouration. The S/N ratio for main effect plot for JBCF and MBCF stand at 1250 CS, 1.15 FR and 0.65 DOC; and 500 CS, 1.15 FR and 0.65 respectively with R-sq = 85.14% and R-sq(adj) = 71.76% for JBCF Ra and R-sq = 71.24% and R-sq(adj) = 56.35% for JBCF Tw,  compared to R-sq = 84.44% R-sq(adj) = 70.43% is for MBCF Ra, and R-sq = 70.48% and  R-sq(adj)  = 55.92% for MBCF Tw. Conclusively, JBCF exhibit minimal surface roughness, minimal tool wear, minimal environmental biodegradability and overall better performance compare to MBCF which makes it more suitable for turning of AISI 304 Alloy steel and is in good agreement with previous work.

Examining the Effect of Various Vegetable Oil-Based Cutting Fluids on Surface Integrity in Drilling Steel - A Review

2013 ◽  
Vol 845 ◽  
pp. 809-813 ◽  
Author(s):  
A.Z. Sultan ◽  
S. Sharif ◽  
Denni Kurniawan
Keyword(s):  
Vegetable Oil ◽  
Surface Integrity ◽  
Manufacturing Industry ◽  
Mineral Oil ◽  
Cutting Fluid ◽  
Health Impacts ◽  
Metalworking Fluids ◽  
Drilling Process ◽  
Cutting Fluids ◽  
Industrial Activities

Increased attention on environmental and health impacts by industrial activities forces the manufacturing industry to reduce the mineral oil-based metalworking fluids as a cutting fluid. The advantages of using vegetable oil-based cutting fluids on tool wear and the cutting force have been reported in the literature, but those reporting the effects of their use on the surface finish of the workpiece are still lacking. This mini-review gives an overview of the influence of vegetable oil-based cutting fluids on surface integrity of steel during drilling process. Effect of the different cooling strategies on surface integrity is also presented.

A Review on the Performance of Tribological Properties of Cutting Fluids

2015 ◽  
Vol 812 ◽  
pp. 102-106
Author(s):  
S. Ganesh ◽  
Jamaludeen Umar Mohamed ◽  
C. Rajaganapathy ◽  
V. Saravanakumar
Keyword(s):  
Titanium Alloys ◽  
Metal Removal ◽  
Mineral Oil ◽  
Industrial Sector ◽  
Cutting Fluid ◽  
Cutting Fluids ◽  
Mechanical Field ◽  
Major Application ◽  
Machining Operations

Tribology deals with friction, wear and lubricants. It plays an important role in mechanical field. It finds its major application in industrial and automotive sector, in which this thesis considered the tribology in metal removal industrial sector. In that application, the role of cutting fluid in lathe machining operations have been chosen. One of the most important challenging cases is to minimize the friction in machining of titanium alloys. While machining, the heat should be minimized as low as possible. This thesis deals with the study of cutting fluids in machining of titanium alloys. The problem occurs while using mineral oil as a cutting fluid in machining that it is non-biodegradable in nature and affects the environment while disposing it. This thesis aims to identify the alternate cutting fluids instead of mineral oil, which is to be effective cooling and non-toxic to environment. For that, Machining condition should be controllable by using some grammar rule without affecting the Productivity.

scholarly journals Chemical composition, oxidative stability, and sensory properties of Boerhavia elegana Choisy (alhydwan) seed oil/peanut oil blends

2020 ◽  
Vol 71 (3) ◽  
pp. 367
Author(s):  
A. Al-Farga ◽  
M. Baeshen ◽  
F. M. Aqlan ◽  
A. Siddeeg ◽  
M. Afifi ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Refractive Index ◽  
Oxidative Stability ◽  
Free Fatty Acids ◽  
Iodine Value ◽  
Peroxide Value ◽  
Seed Oil ◽  
Peanut Oil ◽  
Oil Blends ◽  
Saponification Value

This study investigated the effects of blending alhydwan seed oil and peanut oil as a way of enhancing the stability and chemical characteristics of plant seed oils and to discover more innovative foods of high nutraceutical value which can be used in other food production systems. Alhydwan seed oil and peanut oil blended at proportions of 10:90, 20:80, 30:70, 40:60 and 50:50 (v/v) were evaluated according to their physi­cochemical properties, including refractive index, relative density, saponification value, peroxide value, iodine value, free fatty acids, oxidative stability index, and tocopherol contents using various standard and published methods. At room temperature, all of the oil blends were in the liquid state. The physicochemical profiles of the blended oils showed significant decreases (p < 0.05) in peroxide value (6.97–6.02 meq O2/kg oil), refractive index at 25 °C (1.462–1.446), free fatty acids (2.29–1.71%), and saponification value (186.44–183.77 mg KOH/g), and increases in iodine value and relative density at 25 °C (98.10–102.89 and 0.89–0.91, respectively), especially with an analhydwan seed oil to peanut oil ratio of 10:90. Among the fatty acids, oleic and linoleic acids were most abundant in the 50:50 and 10:90 alhydwan seed oil to peanut oil blends, respectively. Oxidative stability increased as the proportion of alhydwan oil increased. In terms of tocopherol contents (γ, δ, and α), γ-tocopherol had the highest values across all of the blended proportions, followed by δ-tocopherol. The overall acceptability was good for all blends. The incorporation of alhydwan seed oil into peanut oil resulted in inexpensive, high-quality blended oil that may be useful in health food products and pharmaceuticals without compromising sensory characteristics.

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